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Beryllium Hydroxide
Beryllium hydroxide, Be(OH)2, is an amphoteric hydroxide, dissolving in both acids and alkalis. Industrially, it is produced as a by-product in the extraction of beryllium metal from the ores beryl and bertrandite. The natural pure beryllium hydroxide is rare (in form of the mineral behoite, orthorhombic) or very rare (clinobehoite, monoclinic).Mindat, http://www.mindat.org/min-1066.html When alkali is added to beryllium salt solutions the α-form (a gel) is formed. If this left to stand or boiled, the rhombic β-form precipitates.Mary Eagleson, 1994, Concise encyclopedia chemistry, Walter de Gruyter, This has the same structure as zinc hydroxide, Zn(OH)2, with tetrahedral beryllium centers. Reactions Beryllium hydroxide is difficult to dissolve in water. With alkalis it dissolves to form the tetrahydroxoberyllate/tetrahydroxidoberyllate anion, e(OH)4sup>2−.Egon Wiberg, Arnold Frederick Holleman (2001) ''Inorganic Chemistry'', Elsevier With sodium hydroxide solution: :2 NaOH( ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Magnesium Hydroxide
Magnesium hydroxide is the inorganic compound with the chemical formula Mg(OH)2. It occurs in nature as the mineral brucite. It is a white solid with low solubility in water (). Magnesium hydroxide is a common component of antacids, such as milk of magnesia. Preparation Treating the solution of different soluble magnesium salts with alkaline water induces the precipitation of the solid hydroxide Mg(OH)2: :Mg2+ + 2OH− → Mg(OH)2 As is the second most abundant cation present in seawater after , it can be economically extracted directly from seawater by alkalinisation as described here above. On an industrial scale, Mg(OH)2 is produced by treating seawater with lime (Ca(OH)2). A volume of (or 160,000 US gallons) of seawater gives about one ton of Mg(OH)2. Ca(OH)2 is far more soluble than Mg(OH)2 and drastically increases the pH value of seawater from 8.2 to 12.5. The less soluble precipitates because of the common ion effect due to the added by the dissolution of : : U ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Amphoterism
In chemistry, an amphoteric compound () is a molecule or ion that can react both as an acid and as a base. What exactly this can mean depends on which definitions of acids and bases are being used. One type of amphoteric species are amphiprotic molecules, which can either donate or accept a proton (). This is what "amphoteric" means in Brønsted–Lowry acid–base theory. Examples include amino acids and proteins, which have amine () and carboxylic acid () groups, and self-ionizable compounds such as water. Ampholytes are amphoteric molecules that contain both acidic and basic functional groups. For example, an amino acid has both a basic group and an acidic group , and exists as several structures in chemical equilibrium: :H2N-RCH-CO2H + H2O H2N-RCH-COO- + H3O+ H3N+-RCH-COOH + OH- H3N+-RCH-COO- + H2O In approximately neutral aqueous solution (pH ≅ 7), the basic amino group is mostly protonated and the carboxylic acid is mostly deprotonated, so that the predominant sp ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydroxide
Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, a ligand, a nucleophile, and a catalyst. The hydroxide ion forms salts, some of which dissociate in aqueous solution, liberating solvated hydroxide ions. Sodium hydroxide is a multi-million-ton per annum commodity chemical. The corresponding electrically neutral compound HO• is the hydroxyl radical. The corresponding covalently bound group –OH of atoms is the hydroxy group. Both the hydroxide ion and hydroxy group are nucleophiles and can act as catalysts in organic chemistry. Many inorganic substances which bear the word ''hydroxide'' in their names are not ionic compounds of the hydroxide ion, but covalent compounds which contain hydroxy groups. Hydroxide ion The hydroxide ion is a natural p ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Acid
In computer science, ACID ( atomicity, consistency, isolation, durability) is a set of properties of database transactions intended to guarantee data validity despite errors, power failures, and other mishaps. In the context of databases, a sequence of database operations that satisfies the ACID properties (which can be perceived as a single logical operation on the data) is called a ''transaction''. For example, a transfer of funds from one bank account to another, even involving multiple changes such as debiting one account and crediting another, is a single transaction. In 1983, Andreas Reuter and Theo Härder coined the acronym ''ACID'', building on earlier work by Jim Gray who named atomicity, consistency, and durability, but not isolation, when characterizing the transaction concept. These four properties are the major guarantees of the transaction paradigm, which has influenced many aspects of development in database systems. According to Gray and Reuter, the IBM Inf ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Alkali
In chemistry, an alkali (; from ar, القلوي, al-qaly, lit=ashes of the saltwort) is a basic, ionic salt of an alkali metal or an alkaline earth metal. An alkali can also be defined as a base that dissolves in water. A solution of a soluble base has a pH greater than 7.0. The adjective alkaline, and less often, alkalescent, is commonly used in English as a synonym for basic, especially for bases soluble in water. This broad use of the term is likely to have come about because alkalis were the first bases known to obey the Arrhenius definition of a base, and they are still among the most common bases. Etymology The word "alkali" is derived from Arabic ''al qalīy'' (or ''alkali''), meaning ''the calcined ashes'' (see calcination), referring to the original source of alkaline substances. A water-extract of burned plant ashes, called potash and composed mostly of potassium carbonate, was mildly basic. After heating this substance with calcium hydroxide (''slaked lim ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Beryl
Beryl ( ) is a mineral composed of beryllium aluminium silicate with the chemical formula Be3Al2Si6O18. Well-known varieties of beryl include emerald and aquamarine. Naturally occurring, hexagonal crystals of beryl can be up to several meters in size, but terminated crystals are relatively rare. Pure beryl is colorless, but it is frequently tinted by impurities; possible colors are green, blue, yellow, pink, and red (the rarest). It is an ore source of beryllium. Etymology The word ''beryl'' – enm, beril – is borrowed, via fro, beryl and la, beryllus, from Ancient Greek βήρυλλος ''bḗryllos'', which referred to a 'precious blue-green color-of-sea-water stone'; from Prakrit ''veruḷiya'', ''veḷuriya'' 'beryl' (compare the pseudo- Sanskritization वैडूर्य ''vaiḍūrya'' 'cat's eye; jewel; lapis lazuli', traditionally explained as '(brought) from (the city of) Vidūra'), which is ultimately of Dravidian origin, maybe from the name of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bertrandite
Bertrandite is a beryllium sorosilicate hydroxide mineral with composition: Be4Si2O7(OH)2. Bertrandite is a colorless to pale yellow orthorhombic mineral with a hardness of 6-7. It is commonly found in beryllium rich pegmatites and is in part an alteration of beryl. Bertrandite often occurs as a pseudomorphic replacement of beryl. Associated minerals include beryl, phenakite, herderite, tourmaline, muscovite, fluorite and quartz. It, with beryl, are ores of beryllium. It was discovered near Nantes, France in 1883 and named after French mineralogist, Emile Bertrand (1844–1909). One of the world's largest deposits of bertrandite is Spor Mountain, Thomas Range, Utah which is currently the source of most of the world's beryllium production. See also *List of minerals *List of minerals named after people This is a list of minerals named after people. The chemical composition follows name. A * Abelsonite: C31H32N4Ni – American physicist Philip Hauge Abelson (1913–2 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Zinc Hydroxide
Zinc hydroxide Zn( OH)2 is an inorganic chemical compound. It also occurs naturally as 3 rare minerals: wülfingite (orthorhombic), ashoverite and sweetite (both tetragonal). Like the hydroxides of other metals, such as lead, aluminium, beryllium, tin and chromium, Zinc hydroxide (and Zinc oxide), is amphoteric. Thus it will dissolve readily in a dilute solution of a strong acid, such as HCl, and also in a solution of an alkali such as sodium hydroxide. Preparation It can be prepared by adding sodium hydroxide solution, but not in excess, to a solution of any zinc salt. A white precipitate will be seen: :Zn2+ + 2 OH− → Zn(OH)2. Zn2+ is known to form hexa-aqua ions at high water concentrations and tetra-aqua ions at low concentrations of water Sze, Yu-Keung, and Donald E. Irish. "Vibrational spectral studies of ion-ion and ion-solvent interactions. I. Zinc nitrate in water." Journal of Solution Chemistry 7.6 (1978): 395-415. and, thus, this reaction may be better writt ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sodium Hydroxide
Sodium hydroxide, also known as lye and caustic soda, is an inorganic compound with the formula NaOH. It is a white solid ionic compound consisting of sodium cations and hydroxide anions . Sodium hydroxide is a highly caustic base and alkali that decomposes proteins at ordinary ambient temperatures and may cause severe chemical burns. It is highly soluble in water, and readily absorbs moisture and carbon dioxide from the air. It forms a series of hydrates . The monohydrate crystallizes from water solutions between 12.3 and 61.8 °C. The commercially available "sodium hydroxide" is often this monohydrate, and published data may refer to it instead of the anhydrous compound. As one of the simplest hydroxides, sodium hydroxide is frequently used alongside neutral water and acidic hydrochloric acid to demonstrate the pH scale to chemistry students. Sodium hydroxide is used in many industries: in the manufacture of pulp and paper, textiles, drinking water, soap ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sulfuric Acid
Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid ( Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen and hydrogen, with the molecular formula . It is a colorless, odorless and viscous liquid that is miscible with water. Pure sulfuric acid does not exist naturally on Earth due to its strong affinity to water vapor; it is hygroscopic and readily absorbs water vapor from the air. Concentrated sulfuric acid is highly corrosive towards other materials, from rocks to metals, since it is an oxidant with powerful dehydrating properties. Phosphorus pentoxide is a notable exception in that it is not dehydrated by sulfuric acid, but to the contrary dehydrates sulfuric acid to sulfur trioxide. Upon addition of sulfuric acid to water, a considerable amount of heat is released; thus the reverse procedure of adding water to the acid should not be performed since the heat released ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Beryllium Sulfate
Beryllium sulfate normally encountered as the tetrahydrate, e(H2O)4O4 is a white crystalline solid. It was first isolated in 1815 by Jons Jakob Berzelius. Beryllium sulfate may be prepared by treating an aqueous solution of many beryllium salts with sulfuric acid, followed by evaporation of the solution and crystallization. The hydrated product may be converted to anhydrous salt by heating at 400 °C. Structure According to X-ray crystallography the tetrahydrate contains a tetrahedral Be(OH2)42+ unit and sulfate anions. The small size of the Be2+ cation determines the number of water molecules that can be coordinated. In contrast, the analogous magnesium salt, MgSO4·6H2O contains an octahedral Mg(OH2)62+ unit.Wells A.F. (1984) ''Structural Inorganic Chemistry'' 5th edition Oxford Science Publications The existence of the tetrahedral e(OH2)4sup>2+ ion in aqueous solutions of beryllium nitrate and beryllium chloride has been confirmed by vibrational spectroscopy, as ind ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
