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Aluminum
Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It has a great affinity towards oxygen, and forms a protective layer of oxide on the surface when exposed to air. Aluminium visually resembles silver, both in its color and in its great ability to reflect light. It is soft, non-magnetic and ductile. It has one stable isotope, 27Al; this isotope is very common, making aluminium the twelfth most common element in the Universe. The radioactivity of 26Al is used in radiodating. Chemically, aluminium is a post-transition metal in the boron group; as is common for the group, aluminium forms compounds primarily in the +3 oxidation state. The aluminium cation Al3+ is small and highly charged; as such, it is polarizing, and bonds aluminium forms tend towards covalency. The strong affinity towa ...
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Charles Martin Hall
Charles Martin Hall (December 6, 1863 – December 27, 1914) was an American inventor, businessman, and chemist. He is best known for his invention in 1886 of an inexpensive method for producing aluminum, which became the first metal to attain widespread use since the prehistoric discovery of iron. He was one of the founders of Alcoa. Alfred E. Hunt, together with Charles Hall and a group of five other individuals – his partner at the Pittsburgh Testing Laboratory, George Hubbard Clapp; his chief chemist, W. S. Sample; Howard Lash, head of the Carbon Steel Company; Millard Hunsiker, sales manager for the Carbon Steel Company; and Robert Scott, a mill superintendent for the Carnegie Steel Company – raised $20,000 to launch the Pittsburgh Reduction Company, which was later renamed Aluminum Company of America and shortened to Alcoa. Biography Early years Charles Martin Hall was born to Herman Bassett Hall and Sophronia H. Brooks on December 6, 1863, in Thompson, Ohio. Cha ...
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Hall–Héroult Process
The Hall–Héroult process is the major industrial process for smelting aluminium. It involves dissolving aluminium oxide (alumina) (obtained most often from bauxite, aluminium's chief ore, through the Bayer process) in molten cryolite, and electrolyzing the molten salt bath, typically in a purpose-built cell. The Hall–Héroult process applied at industrial scale happens at 940–980 °C and produces 99.5–99.8% pure aluminium. Recycled aluminum requires no electrolysis, thus it does not end up in this process. This process contributes to climate change through the emission of carbon dioxide and fluorocarbons in the electrolytic reaction and consumption of large amounts of electrical energy. Process Difficulties faced Elemental aluminium cannot be produced by the electrolysis of an aqueous aluminium salt, because hydronium ions readily oxidize elemental aluminium. Although a molten aluminium salt could be used instead, aluminium oxide has a melting point of 2072&nbs ...
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Metal
A metal (from ancient Greek, Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electrical resistivity and conductivity, electricity and thermal conductivity, heat relatively well. Metals are typically ductile (can be drawn into wires) and malleable (they can be hammered into thin sheets). These properties are the result of the ''metallic bond'' between the atoms or molecules of the metal. A metal may be a chemical element such as iron; an alloy such as stainless steel; or a molecular compound such as polythiazyl, polymeric sulfur nitride. In physics, a metal is generally regarded as any substance capable of conducting electricity at a temperature of absolute zero. Many elements and compounds that are not normally classified as metals become metallic under high pressures. For example, the nonmetal iodine gradually becomes a metal at a pressure of between 40 ...
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Aluminum-26
Aluminium-26 (26Al, Al-26) is a radioactive isotope of the chemical element aluminium, decaying by either positron emission or electron capture to stable magnesium-26. The half-life of 26Al is 7.17 (717,000) years. This is far too short for the isotope to survive as a primordial nuclide, but a small amount of it is produced by collisions of atoms with cosmic ray protons. Decay of aluminium-26 also produces gamma rays and x-rays. The x-rays and Auger electrons are emitted by the excited atomic shell of the daughter 26Mg after the electron capture which typically leaves a hole in one of the lower sub-shells. Because it is radioactive, it is typically stored behind at least of lead. Contact with 26Al may result in radiological contamination necessitating special tools for transfer, use, and storage. Dating Aluminium-26 can be used to calculate the terrestrial age of meteorites and comets. It is produced in significant quantities in extraterrestrial objects via spallation of silico ...
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Silicon
Silicon is a chemical element with the symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic luster, and is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic table: carbon is above it; and germanium, tin, lead, and flerovium are below it. It is relatively unreactive. Because of its high chemical affinity for oxygen, it was not until 1823 that Jöns Jakob Berzelius was first able to prepare it and characterize it in pure form. Its oxides form a family of anions known as silicates. Its melting and boiling points of 1414 °C and 3265 °C, respectively, are the second highest among all the metalloids and nonmetals, being surpassed only by boron. Silicon is the eighth most common element in the universe by mass, but very rarely occurs as the pure element in the Earth's crust. It is widely distributed in space in cosmic dusts, planetoids, and planets as various forms of silico ...
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Passivation (chemistry)
Passivation, in physical chemistry and engineering, refers to coating a material so it becomes "passive", that is, less readily affected or corroded by the environment. Passivation involves creation of an outer layer of shield material that is applied as a microcoating, created by chemical reaction with the base material, or allowed to build by spontaneous oxidation in the air. As a technique, passivation is the use of a light coat of a protective material, such as metal oxide, to create a shield against corrosion. Passivation of silicon is used during fabrication of microelectronic devices. In electrochemical treatment of water, passivation reduces the effectiveness of the treatment by increasing the circuit resistance, and active measures are typically used to overcome this effect, the most common being polarity reversal, which results in limited rejection of the fouling layer. When exposed to air, many metals naturally form a hard, relatively inert surface layer, usually an ...
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Hans Christian Ørsted
Hans Christian Ørsted ( , ; often rendered Oersted in English; 14 August 17779 March 1851) was a Danish physicist and chemist who discovered that electric currents create magnetic fields, which was the first connection found between electricity and magnetism. Oersted's law and the oersted unit (Oe) are named after him. A leader of the Danish Golden Age, Ørsted was a close friend of Hans Christian Andersen and the brother of politician and jurist Anders Sandøe Ørsted, who served as Prime Minister of Denmark from 1853 to 1854. Early life and studies Ørsted was born in Rudkøbing in 1777. As a young boy he developed an interest in science while working for his father, who owned the local pharmacy. He and his brother Anders received most of their early education through self-study at home, going to Copenhagen in 1793 to take entrance exams for the University of Copenhagen, where both brothers excelled academically. By 1796, Ørsted had been awarded honors for his pape ...
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Boron Group
The boron group are the chemical elements in group 13 of the periodic table, comprising boron (B), aluminium (Al), gallium (Ga), indium (In), thallium (Tl), and nihonium (Nh). The elements in the boron group are characterized by having three valence electrons. These elements have also been referred to as the triels. Boron is commonly classified as a (metalloid) while the rest, with the possible exception of nihonium, are considered post-transition metals. Boron occurs sparsely, probably because bombardment by the subatomic particles produced from natural radioactivity disrupts its nuclei. Aluminium occurs widely on earth, and indeed is the third most abundant element in the Earth's crust (8.3%). Gallium is found in the earth with an abundance of 13 ppm. Indium is the 61st most abundant element in the earth's crust, and thallium is found in moderate amounts throughout the planet. Nihonium is not known to occur in nature and therefore is termed a synthetic element. Several gro ...
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Post-transition Metal
The metallic elements in the periodic table located between the transition metals and the chemically weak nonmetallic metalloids have received many names in the literature, such as ''post-transition metals'', ''poor metals'', ''other metals'', ''p-block metals'' and ''chemically weak metals''; none have been recommended by IUPAC. The most common name, ''post-transition metals'', is generally used in this article. Depending on where the adjacent sets of transition metals and metalloids are judged to begin and end, there are at least five competing proposals for which elements to count as post-transition metals: the three most common contain six, ten and thirteen elements, respectively (see image). All proposals include gallium, indium, tin, thallium, lead, and bismuth. Physically, these metals are soft (or brittle), have poor mechanical strength, and usually have melting points lower than those of the transition metals. Being close to the metal-nonmetal border, their crystalli ...
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Chemical Element
A chemical element is a species of atoms that have a given number of protons in their atomic nucleus, nuclei, including the pure Chemical substance, substance consisting only of that species. Unlike chemical compounds, chemical elements cannot be broken down into simpler substances by any chemical reaction. The number of protons in the nucleus is the defining property of an element, and is referred to as its atomic number (represented by the symbol ''Z'') – all atoms with the same atomic number are atoms of the same element. Almost all of the Baryon#Baryonic matter, baryonic matter of the universe is composed of chemical elements (among rare exceptions are neutron stars). When different elements undergo chemical reactions, atoms are rearranged into new chemical compounds, compounds held together by chemical bonds. Only a minority of elements, such as silver and gold, are found uncombined as relatively pure native element minerals. Nearly all other naturally occurring element ...
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Ductility
Ductility is a mechanical property commonly described as a material's amenability to drawing (e.g. into wire). In materials science, ductility is defined by the degree to which a material can sustain plastic deformation under tensile stress before failure. Ductility is an important consideration in engineering and manufacturing. It defines a material's suitability for certain manufacturing operations (such as cold working) and its capacity to absorb mechanical overload.. Some metals that are generally described as ductile include gold and copper. However, not all metals experience ductile failure as some can be characterized with brittle failure like cast iron. Polymers generally can be viewed as ductile materials as they typically allow for plastic deformation. Malleability, a similar mechanical property, is characterized by a material's ability to deform plastically without failure under compressive stress. Historically, materials were considered malleable if they were ...
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Mantle (geology)
A mantle is a layer inside a planetary body bounded below by a core and above by a crust. Mantles are made of rock or ices, and are generally the largest and most massive layer of the planetary body. Mantles are characteristic of planetary bodies that have undergone differentiation by density. All terrestrial planets (including Earth), a number of asteroids, and some planetary moons have mantles. Earth's mantle The Earth's mantle is a layer of silicate rock between the crust and the outer core. Its mass of 4.01 × 1024 kg is 67% the mass of the Earth. It has a thickness of making up about 84% of Earth's volume. It is predominantly solid, but in geological time it behaves as a viscous fluid. Partial melting of the mantle at mid-ocean ridges produces oceanic crust, and partial melting of the mantle at subduction zones produces continental crust. Other planetary mantles Mercury has a silicate mantle approximately thick, constituting only 28% of it ...
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