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Varnish is a clear
transparent Transparency, transparence or transparent most often refer to: * Transparency (optics), the physical property of allowing the transmission of light through a material They may also refer to: Literal uses * Transparency (photography), a still, ...
hard protective coating or film. It is not a
stain A stain is a discoloration that can be clearly distinguished from the surface, material, or medium it is found upon. They are caused by the chemical or physical interaction of two dissimilar materials. Accidental staining may make materials ap ...
. It usually has a yellowish shade from the manufacturing process and materials used, but it may also be
pigment A pigment is a colored material that is completely or nearly insoluble in water. In contrast, dyes are typically soluble, at least at some stage in their use. Generally dyes are often organic compounds whereas pigments are often inorganic compou ...
ed as desired, and is sold commercially in various shades. Varnish is primarily used as a
wood finish Wood finishing refers to the process of refining or protecting a wooden surface, especially in the production of furniture where typically it represents between 5 and 30% of manufacturing costs. Finishing is the final step of the manufacturing ...
where, stained or not, the distinctive tones and grains in the wood are intended to be visible. Varnish finishes are naturally
glossy Gloss is an optical property which indicates how well a surface reflects light in a specular (mirror-like) direction. It is one of the important parameters that are used to describe the visual appearance of an object. The factors that affect glo ...
, but satin/semi-gloss and flat sheens are available.


History

The word "varnish" comes from Mediaeval
Latin Latin (, or , ) is a classical language belonging to the Italic languages, Italic branch of the Indo-European languages. Latin was originally a dialect spoken in the lower Tiber area (then known as Latium) around present-day Rome, but through ...
''vernix'', meaning odorous resin, itself derived from Middle Greek ''berōnikón'' or ''beroníkē'', meaning amber or amber-colored glass. A false etymology traces the word to the Greek '' Berenice'', the ancient name of modern
Benghazi Benghazi () , ; it, Bengasi; tr, Bingazi; ber, Bernîk, script=Latn; also: ''Bengasi'', ''Benghasi'', ''Banghāzī'', ''Binghāzī'', ''Bengazi''; grc, Βερενίκη ('' Berenice'') and ''Hesperides''., group=note (''lit. Son of he Ghaz ...
in Libya, where the first varnishes in the Mediterranean area were supposedly used and where resins from the trees of now-vanished forests were sold. Early varnishes were developed by mixing resin—pine sap, for example—with a solvent and applying them with a brush to get the golden and hardened effect one sees in today's varnishes. Varnishing was a technique well known in ancient Egypt. Varnishing is also recorded in the history of East and South Asia; in
India India, officially the Republic of India (Hindi: ), is a country in South Asia. It is the List of countries and dependencies by area, seventh-largest country by area, the List of countries and dependencies by population, second-most populous ...
,
China China, officially the People's Republic of China (PRC), is a country in East Asia. It is the world's List of countries and dependencies by population, most populous country, with a Population of China, population exceeding 1.4 billion, slig ...
and
Japan Japan ( ja, 日本, or , and formally , ''Nihonkoku'') is an island country in East Asia. It is situated in the northwest Pacific Ocean, and is bordered on the west by the Sea of Japan, while extending from the Sea of Okhotsk in the n ...
, where the practice of
lacquer Lacquer is a type of hard and usually shiny coating or finish applied to materials such as wood or metal. It is most often made from resin extracted from trees and waxes and has been in use since antiquity. Asian lacquerware, which may be c ...
work, a species of varnish application, was known at a very early date. The Tang Chinese used medieval chemistry experiments to produce a varnish for clothes and weapons, employing complex chemical formulas applied to silk clothes of
underwater divers This is a list of underwater divers whose exploits have made them notable. Underwater divers are people who take part in underwater diving activities – Underwater diving is practiced as part of an occupation, or for recreation, where t ...
, a cream designated for polishing bronze mirrors, and other formulas.


Safety

Because of flammability concerns, many product containers list safety precautions for storage and disposal for varnishes and
drying oils A drying oil is an oil that hardens to a tough, solid film after a period of exposure to air, at room temperature. The oil hardens through a chemical reaction in which the components crosslink (and hence, polymerize) by the action of oxygen (not ...
as they are flammable, and materials used to apply the varnishes may spontaneously combust. Many varnishes contain plant-derived oils (e.g.
linseed oil Linseed oil, also known as flaxseed oil or flax oil (in its edible form), is a colourless to yellowish oil obtained from the dried, ripened seeds of the flax plant (''Linum usitatissimum''). The oil is obtained by pressing, sometimes followed by ...
), synthetic oils (e.g.
polyurethane Polyurethane (; often abbreviated PUR and PU) refers to a class of polymers composed of organic units joined by carbamate (urethane) links. In contrast to other common polymers such as polyethylene and polystyrene, polyurethane is produced from ...
s) or resins as their binder in combination with organic solvents. These are flammable in their liquid state. All
drying oils A drying oil is an oil that hardens to a tough, solid film after a period of exposure to air, at room temperature. The oil hardens through a chemical reaction in which the components crosslink (and hence, polymerize) by the action of oxygen (not ...
, certain
alkyd An alkyd is a polyester resin modified by the addition of fatty acids and other components. Alkyds are derived from polyols and organic acids including dicarboxylic acids or carboxylic acid anhydride and triglyceride oils. The term ''alkyd'' is a m ...
s (including
paint Paint is any pigmented liquid, liquefiable, or solid mastic composition that, after application to a substrate in a thin layer, converts to a solid film. It is most commonly used to protect, color, or provide texture. Paint can be made in many ...
s), and many
polyurethane Polyurethane (; often abbreviated PUR and PU) refers to a class of polymers composed of organic units joined by carbamate (urethane) links. In contrast to other common polymers such as polyethylene and polystyrene, polyurethane is produced from ...
s produce heat (an
exothermic In thermodynamics, an exothermic process () is a thermodynamic process or reaction that releases energy from the system to its surroundings, usually in the form of heat, but also in a form of light (e.g. a spark, flame, or flash), electricity ...
reaction) during the curing process. Thus, oil-soaked rags and paper can smolder and ignite into flames, even several hours after use if proper precautions are not taken. Therefore, many manufacturers list proper disposal practices for rags and other items used to apply the finish, such as disposal in a water filled container.


Components of varnish

Varnish is traditionally a combination of a
drying oil A drying oil is an oil that hardens to a tough, solid film after a period of exposure to air, at room temperature. The oil hardens through a chemical reaction in which the components crosslink (and hence, polymerize) by the action of oxygen (no ...
, a
resin In polymer chemistry and materials science, resin is a solid or highly viscous substance of plant or synthetic origin that is typically convertible into polymers. Resins are usually mixtures of organic compounds. This article focuses on nat ...
, and a thinner or
solvent A solvent (s) (from the Latin '' solvō'', "loosen, untie, solve") is a substance that dissolves a solute, resulting in a solution. A solvent is usually a liquid but can also be a solid, a gas, or a supercritical fluid. Water is a solvent for ...
plus a metal drier to accelerate the drying. However, different types of varnish have different components. After being applied, the film-forming substances in varnishes either harden directly, as soon as the solvent has fully
evaporated Evaporation is a type of vaporization that occurs on the surface of a liquid as it changes into the gas phase. High concentration of the evaporating substance in the surrounding gas significantly slows down evaporation, such as when humi ...
, or harden after evaporation of the solvent through curing processes, primarily chemical reaction between oils and oxygen from the air (
autoxidation Autoxidation (sometimes auto-oxidation) refers to oxidations brought about by reactions with oxygen at normal temperatures, without the intervention of flame or electric spark. The term is usually used to describe the gradual degradation of organic ...
) and chemical reactions between components of the varnish. Resin varnishes dry by evaporation of the solvent and harden quickly on drying.
Acrylic Acrylic may refer to: Chemicals and materials * Acrylic acid, the simplest acrylic compound * Acrylate polymer, a group of polymers (plastics) noted for transparency and elasticity * Acrylic resin, a group of related thermoplastic or thermosett ...
and waterborne varnishes dry by evaporation of the water but will experience an extended curing period for evaporation of organic solvents absorbed on the latex particles, and possibly chemical curing of the particles. Oil, polyurethane, and epoxy varnishes remain liquid even after evaporation of the solvent but quickly begin to cure, undergoing successive stages from liquid or syrupy, to tacky or sticky, to dry gummy, to dry to the touch, to hard. Environmental factors such as heat and humidity play a large role in the drying and curing times of varnishes. In classic varnish the cure rate depends on the type of oil used and, to some extent, on the ratio of oil to resin. The drying and curing time of all varnishes may be sped up by exposure to an energy source such as
sunlight Sunlight is a portion of the electromagnetic radiation given off by the Sun, in particular infrared, visible, and ultraviolet light. On Earth, sunlight is scattered and filtered through Earth's atmosphere, and is obvious as daylight when ...
,
ultraviolet Ultraviolet (UV) is a form of electromagnetic radiation with wavelength from 10 nm (with a corresponding frequency around 30  PHz) to 400 nm (750  THz), shorter than that of visible light, but longer than X-rays. UV radiation ...
light, or heat.


Drying oil

There are many different types of drying oils, including
linseed oil Linseed oil, also known as flaxseed oil or flax oil (in its edible form), is a colourless to yellowish oil obtained from the dried, ripened seeds of the flax plant (''Linum usitatissimum''). The oil is obtained by pressing, sometimes followed by ...
,
tung oil Tung oil or China wood oil is a drying oil obtained by pressing the seed from the nut of the tung tree (''Vernicia fordii''). The oil and its use are believed to have originated in ancient China and appear in the writings of Confucius from ab ...
, and
walnut oil Walnut oil is oil extracted from walnuts, '' Juglans regia''. The oil contains polyunsaturated fatty acids, monounsaturated fatty acids, and saturated fats. Composition Walnut oil is composed largely of polyunsaturated fatty acids (72% of tota ...
. These contain high levels of polyunsaturated
fatty acids In chemistry, particularly in biochemistry, a fatty acid is a carboxylic acid with an aliphatic chain, which is either saturated and unsaturated compounds#Organic chemistry, saturated or unsaturated. Most naturally occurring fatty acids have an B ...
. Drying oils cure through an
exothermic reaction In thermochemistry, an exothermic reaction is a "reaction for which the overall standard enthalpy change Δ''H''⚬ is negative." Exothermic reactions usually release heat. The term is often confused with exergonic reaction, which IUPAC defines ...
between the polyunsaturated portion of the oil and
oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements ...
from the air. Originally, the term "varnish" referred to finishes that were made entirely of resin dissolved in suitable solvents, either ethanol (alcohol) or turpentine. The advantage to finishes in previous centuries was that resin varnishes had a very rapid cure rate compared to oils; in most cases they are cured practically as soon as the solvent has fully evaporated. By contrast, untreated or "raw" oils may take weeks or months to cure, depending on ambient temperature and other environmental factors. In modern terms, boiled or partially polymerized drying oils with added siccatives or dryers (chemical
catalyst Catalysis () is the process of increasing the rate of a chemical reaction by adding a substance known as a catalyst (). Catalysts are not consumed in the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recyc ...
s) have cure times of less than 24 hours. However, certain non-toxic by-products of the curing process are emitted from the oil film even after it is dry to the touch and over a considerable period of time. It has long been a tradition to combine drying oils with resins to obtain favourable features of both substances.


Resin

Many different kinds of resins may be used to create a varnish. Natural resins used for varnish include
amber Amber is fossilized tree resin that has been appreciated for its color and natural beauty since Neolithic times. Much valued from antiquity to the present as a gemstone, amber is made into a variety of decorative objects."Amber" (2004). In M ...
,
kauri gum Kauri gum is resin from kauri trees (''Agathis australis''), which historically had several important industrial uses. It can also be used to make crafts such as jewellery. Kauri forests once covered much of the North Island of New Zealand, bef ...
,
dammar Dammar, also called dammar gum, or damar gum, is a resin obtained from the tree family Dipterocarpaceae in India and Southeast Asia, principally those of the genera '' Shorea'' or '' Hopea'' (synonym ''Balanocarpus''). The resin of some species ...
,
copal Copal is tree resin, particularly the aromatic resins from the copal tree ''Protium copal'' (Burseraceae) used by the cultures of pre-Columbian Mesoamerica as ceremonially burned incense and for other purposes. More generally, copal includes re ...
,
rosin Rosin (), also called colophony or Greek pitch ( la, links=no, pix graeca), is a solid form of resin obtained from pines and some other plants, mostly conifers, produced by heating fresh liquid resin to vaporize the volatile liquid terpene comp ...
(
colophony Rosin (), also called colophony or Greek pitch ( la, links=no, pix graeca), is a solid form of resin obtained from pines and some other plants, mostly conifers, produced by heating fresh liquid resin to vaporize the volatile liquid terpene comp ...
or pine resin), sandarac,
balsam Balsam is the resinous exudate (or sap) which forms on certain kinds of trees and shrubs. Balsam (from Latin balsamum "gum of the balsam tree", ultimately from Semitic, Aramaic ''busma'', Arabic ''balsam'' and Hebrew ''basam'', "spice", "perfume ...
,
elemi ''Canarium luzonicum'', commonly known as elemi, is a tree native to the Philippines. The oleoresin harvested from it is also known as elemi. Synonyms * ''Canarium carapifolium'' G.Perkins * ''Canarium oliganthum'' Merr. * ''Canarium polyanth ...
,
mastic Mastic may refer to: Adhesives and pastes *Mastic (plant resin) *Mastic asphalt, or asphalt, is a sticky, black and highly viscous liquid * Mastic cold porcelain, or salt ceramic, is a traditional salt-based modeling clay. *Mastic, high-grade con ...
, and
shellac Shellac () is a resin secreted by the female lac bug on trees in the forests of India and Thailand. It is processed and sold as dry flakes and dissolved in alcohol to make liquid shellac, which is used as a brush-on colorant, food glaze and ...
. Varnish may also be created from synthetic resins such as
acrylic Acrylic may refer to: Chemicals and materials * Acrylic acid, the simplest acrylic compound * Acrylate polymer, a group of polymers (plastics) noted for transparency and elasticity * Acrylic resin, a group of related thermoplastic or thermosett ...
,
alkyd An alkyd is a polyester resin modified by the addition of fatty acids and other components. Alkyds are derived from polyols and organic acids including dicarboxylic acids or carboxylic acid anhydride and triglyceride oils. The term ''alkyd'' is a m ...
, or
polyurethane Polyurethane (; often abbreviated PUR and PU) refers to a class of polymers composed of organic units joined by carbamate (urethane) links. In contrast to other common polymers such as polyethylene and polystyrene, polyurethane is produced from ...
. A varnish formula might not contain any added resins at all since drying oils can produce a varnish effect by themselves.


Solvent

Originally,
turpentine Turpentine (which is also called spirit of turpentine, oil of turpentine, terebenthene, terebinthine and (colloquially) turps) is a fluid obtained by the distillation of resin harvested from living trees, mainly pines. Mainly used as a special ...
or
alcohol Alcohol most commonly refers to: * Alcohol (chemistry), an organic compound in which a hydroxyl group is bound to a carbon atom * Alcohol (drug), an intoxicant found in alcoholic drinks Alcohol may also refer to: Chemicals * Ethanol, one of sev ...
was used to dissolve the resin and thin the drying oils. The invention of petroleum distillates has led to
turpentine substitute White spirit (AU, UK & Ireland)Primarily in the United Kingdom and Australia. In New Zealand "white spirit" can also refer to Coleman fuel (white gas). or mineral spirits (US, Canada), also known as mineral turpentine (AU/NZ), turpentine substitu ...
s such as
white spirit White spirit (AU, UK & Ireland)Primarily in the United Kingdom and Australia. In New Zealand "white spirit" can also refer to Coleman fuel (white gas). or mineral spirits (US, Canada), also known as mineral turpentine (AU/NZ), turpentine substitu ...
,
paint thinner A paint thinner is a solvent used to thin oil-based paints. Solvents labeled "paint thinner" are usually mineral spirits having a flash point at about 40 °C (104 °F), the same as some popular brands of charcoal starter. Common sol ...
, and
mineral spirit White spirit (AU, UK & Ireland)Primarily in the United Kingdom and Australia. In New Zealand "white spirit" can also refer to Coleman fuel (white gas). or mineral spirits (US, Canada), also known as mineral turpentine (AU/NZ), turpentine substitu ...
. Modern synthetic varnishes may be formulated with water instead of hydrocarbon solvents.


Types


Violin

Violin The violin, sometimes known as a '' fiddle'', is a wooden chordophone ( string instrument) in the violin family. Most violins have a hollow wooden body. It is the smallest and thus highest-pitched instrument ( soprano) in the family in regu ...
varnishing is a multi-step process involving some or all of the following: primer, sealer, ground, color coats, and clear topcoat. Some systems use a drying oil varnish as described below, while others use spirit varnish made of resin(s) dissolved in alcohol. Touchup in repair or restoration is only done with solvent based varnish. Drying oil such as walnut oil or linseed oil may be used in combination with
amber Amber is fossilized tree resin that has been appreciated for its color and natural beauty since Neolithic times. Much valued from antiquity to the present as a gemstone, amber is made into a variety of decorative objects."Amber" (2004). In M ...
,
copal Copal is tree resin, particularly the aromatic resins from the copal tree ''Protium copal'' (Burseraceae) used by the cultures of pre-Columbian Mesoamerica as ceremonially burned incense and for other purposes. More generally, copal includes re ...
,
rosin Rosin (), also called colophony or Greek pitch ( la, links=no, pix graeca), is a solid form of resin obtained from pines and some other plants, mostly conifers, produced by heating fresh liquid resin to vaporize the volatile liquid terpene comp ...
or other
resin In polymer chemistry and materials science, resin is a solid or highly viscous substance of plant or synthetic origin that is typically convertible into polymers. Resins are usually mixtures of organic compounds. This article focuses on nat ...
s. Traditionally the oil is prepared by cooking or exposure to air and sunlight, but modern stand oil is prepared by heating oil at high temperature without oxygen. The refined resin is sometimes available as a translucent solid and is then "run" by cooking or melting it in a pot over heat without solvents. The thickened oil and prepared resin are then cooked together and thinned with turpentine (away from open flame) into a brushable
solution Solution may refer to: * Solution (chemistry), a mixture where one substance is dissolved in another * Solution (equation), in mathematics ** Numerical solution, in numerical analysis, approximate solutions within specified error bounds * Solutio ...
. The ingredients and processes of violin varnish are very diverse, with some highly regarded old examples showing defects (e.g. cracking, crazing) associated with incompatible varnish components. Some violin finishing systems use vernice bianca (egg white and gum arabic) as a sealer or ground. There is also evidence that finely powdered minerals, possibly volcanic ash, were used in some grounds. Some violins made in the late 18th century used ox blood to create a very deep-red coloration. Today this varnish would have faded and currently be a very warm, dark orange.


Resin

Most resin or gum varnishes consist of a natural, plant- or insect-derived substance dissolved in a solvent, called ''spirit varnish'' or ''solvent varnish.'' The solvent may be
alcohol Alcohol most commonly refers to: * Alcohol (chemistry), an organic compound in which a hydroxyl group is bound to a carbon atom * Alcohol (drug), an intoxicant found in alcoholic drinks Alcohol may also refer to: Chemicals * Ethanol, one of sev ...
, turpentine, or
petroleum Petroleum, also known as crude oil, or simply oil, is a naturally occurring yellowish-black liquid mixture of mainly hydrocarbons, and is found in geological formations. The name ''petroleum'' covers both naturally occurring unprocessed crud ...
-based. Some resins are soluble in both alcohol and turpentine. Generally, petroleum solvents, i.e.
mineral spirits White spirit (AU, UK & Ireland)Primarily in the United Kingdom and Australia. In New Zealand "white spirit" can also refer to Coleman fuel ( white gas). or mineral spirits (US, Canada), also known as mineral turpentine (AU/NZ), turpentine substi ...
or
paint thinner A paint thinner is a solvent used to thin oil-based paints. Solvents labeled "paint thinner" are usually mineral spirits having a flash point at about 40 °C (104 °F), the same as some popular brands of charcoal starter. Common sol ...
, can substitute for turpentine. The resins include
amber Amber is fossilized tree resin that has been appreciated for its color and natural beauty since Neolithic times. Much valued from antiquity to the present as a gemstone, amber is made into a variety of decorative objects."Amber" (2004). In M ...
,
dammar Dammar, also called dammar gum, or damar gum, is a resin obtained from the tree family Dipterocarpaceae in India and Southeast Asia, principally those of the genera '' Shorea'' or '' Hopea'' (synonym ''Balanocarpus''). The resin of some species ...
,
copal Copal is tree resin, particularly the aromatic resins from the copal tree ''Protium copal'' (Burseraceae) used by the cultures of pre-Columbian Mesoamerica as ceremonially burned incense and for other purposes. More generally, copal includes re ...
,
rosin Rosin (), also called colophony or Greek pitch ( la, links=no, pix graeca), is a solid form of resin obtained from pines and some other plants, mostly conifers, produced by heating fresh liquid resin to vaporize the volatile liquid terpene comp ...
, sandarac,
elemi ''Canarium luzonicum'', commonly known as elemi, is a tree native to the Philippines. The oleoresin harvested from it is also known as elemi. Synonyms * ''Canarium carapifolium'' G.Perkins * ''Canarium oliganthum'' Merr. * ''Canarium polyanth ...
, benzoin,
mastic Mastic may refer to: Adhesives and pastes *Mastic (plant resin) *Mastic asphalt, or asphalt, is a sticky, black and highly viscous liquid * Mastic cold porcelain, or salt ceramic, is a traditional salt-based modeling clay. *Mastic, high-grade con ...
, balsam,
shellac Shellac () is a resin secreted by the female lac bug on trees in the forests of India and Thailand. It is processed and sold as dry flakes and dissolved in alcohol to make liquid shellac, which is used as a brush-on colorant, food glaze and ...
, and a multitude of
lacquer Lacquer is a type of hard and usually shiny coating or finish applied to materials such as wood or metal. It is most often made from resin extracted from trees and waxes and has been in use since antiquity. Asian lacquerware, which may be c ...
s.
Synthetic Synthetic things are composed of multiple parts, often with the implication that they are artificial. In particular, 'synthetic' may refer to: Science * Synthetic chemical or compound, produced by the process of chemical synthesis * Synthetic ...
resins such as
phenolic resin Phenol formaldehyde resins (PF) or phenolic resins (also infrequently called phenoplasts) are synthetic polymers obtained by the reaction of phenol or substituted phenol with formaldehyde. Used as the basis for Bakelite, PFs were the first commerc ...
may be employed as a secondary component in certain varnishes and paints. Over centuries, many recipes were developed which involved the combination of resins, oils, and other ingredients such as certain
waxes Waxes are a diverse class of organic compounds that are lipophilic, malleable solids near ambient temperatures. They include higher alkanes and lipids, typically with melting points above about 40 °C (104 °F), melting to give low ...
. These were believed to impart special tonal qualities to musical instruments and thus were sometimes carefully guarded secrets. The interaction of different ingredients is difficult to predict or reproduce, so expert finishers were often prized professionals.


Shellac

Shellac is a very widely used single-component resin varnish that is alcohol-soluble. It is not used for outdoor surfaces or where it will come into repeated contact with water, such as around a sink or bathtub. The source of shellac resin is a brittle or flaky secretion of the female lac insect, ''
Kerria lacca ''Kerria lacca'' is a species of insect in the family Kerriidae, the lac insects. These are in the superfamily Coccoidea, the scale insects. This species is perhaps the most commercially important lac insect, being a main source of lac, a resin ...
'', found in the forests of
Assam Assam (; ) is a state in northeastern India, south of the eastern Himalayas along the Brahmaputra and Barak River valleys. Assam covers an area of . The state is bordered by Bhutan and Arunachal Pradesh to the north; Nagaland and Manipur ...
and
Thailand Thailand ( ), historically known as Siam () and officially the Kingdom of Thailand, is a country in Southeast Asia, located at the centre of the Indochinese Peninsula, spanning , with a population of almost 70 million. The country is b ...
and harvested from the bark of the trees where she deposits it to provide a sticky hold on the trunk. Shellac is the basis of French polish, which for centuries has been the preferred finish for fine furniture. Specified "dewaxed" shellac has been processed to remove the waxy substances from original shellac and can be used as a
primer Primer may refer to: Arts, entertainment, and media Films * ''Primer'' (film), a 2004 feature film written and directed by Shane Carruth * ''Primer'' (video), a documentary about the funk band Living Colour Literature * Primer (textbook), a te ...
and sanding-sealer substrate for other finishes such as polyurethanes, alkyds, oils, and acrylics. Prepared shellac is typically available in "clear" and "amber" (or "orange") varieties, generally as "three-pound cut" or three pounds dry shellac to one US gallon of alcohol. Other natural color shades such as ruby and yellow are available from specialty pigment or woodworker's supply outlets. Dry shellac is available as refined flakes, "sticklac," "button lac," or "seedlac." "White pigmented" shellac primer paint is widely available in retail outlets, billed as a fast-drying interior primer "problem solver", in that it adheres to a variety of surfaces and seals off odors and smoke stains. Shellac clean-up may be done either with pure alcohol or with
ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous ...
cleansers.


Alkyd

Modern commercially produced varnishes employ some form of
alkyd An alkyd is a polyester resin modified by the addition of fatty acids and other components. Alkyds are derived from polyols and organic acids including dicarboxylic acids or carboxylic acid anhydride and triglyceride oils. The term ''alkyd'' is a m ...
for producing a protective film. Alkyds have good solvent, moisture and UV light resistance. Alkyds are chemically modified vegetable oils which operate well in a wide range of conditions and can be engineered to speed up the cure rate and thus harden faster. Usually this is by the use of metal salt driers such as
cobalt Cobalt is a chemical element with the symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. The free element, p ...
salts. Better (and more expensive) exterior varnishes employ alkyds made from high performance oils and contain UV-absorbers; this improves gloss-retention and extends the lifetime of the finish. Various resins may also be combined with alkyds as part of the formula for typical "oil" varnishes that are commercially available.


Spar varnish

''
Spar varnish Spar varnish (occasionally also called boat varnish or yacht varnish) is a wood-finishing varnish, originally developed for coating the spars of sailing ships. These formed part of the masts and rigging, and had to withstand rough condition, being ...
'' (also called ''marine varnish'' or ''yacht varnish'') was originally intended for use on
ship A ship is a large watercraft that travels the world's oceans and other sufficiently deep waterways, carrying cargo or passengers, or in support of specialized missions, such as defense, research, and fishing. Ships are generally distinguished ...
or
boat A boat is a watercraft of a large range of types and sizes, but generally smaller than a ship, which is distinguished by its larger size, shape, cargo or passenger capacity, or its ability to carry boats. Small boats are typically found on i ...
spar SPAR, originally DESPAR, styled as DE SPAR, is a Dutch multinational that provides branding, supplies and support services for independently owned and operated food retail stores. It was founded in the Netherlands in 1932, by Adriaan van Well, ...
s, to protect the timber from the effects of sea and weather. Spars bend under the load of their sails. The primary requirements were water resistance and also elasticity, so as to remain adhering as the spars flexed. Elasticity was a pre-condition for weatherproofing too, as a finish that cracked would then allow water through, even if the remaining film was impermeable. Appearance and gloss was of relatively low value. Modified
tung oil Tung oil or China wood oil is a drying oil obtained by pressing the seed from the nut of the tung tree (''Vernicia fordii''). The oil and its use are believed to have originated in ancient China and appear in the writings of Confucius from ab ...
and
phenolic resin Phenol formaldehyde resins (PF) or phenolic resins (also infrequently called phenoplasts) are synthetic polymers obtained by the reaction of phenol or substituted phenol with formaldehyde. Used as the basis for Bakelite, PFs were the first commerc ...
s are often used. When first developed, no varnishes had good UV-resistance. Even after more modern synthetic resins did become resistant, a true spar varnish maintained its elasticity above other virtues, even if this required a compromise in its UV-resistance. Spar varnishes are thus ''not'' necessarily the best choice for outdoor woodwork that does not need to bend in service. Despite this, the widespread perception of "marine products" as "tough" led to domestic outdoor varnishes being
brand A brand is a name, term, design, symbol or any other feature that distinguishes one seller's good or service from those of other sellers. Brands are used in business, marketing, and advertising for recognition and, importantly, to create an ...
ed as "Spar varnish" and sold on the virtue of their weather- and UV-resistance. These claims may be more or less realistic, depending on individual products. Only relatively recently have spar varnishes been available that can offer both effective elasticity and UV-resistance.


Drying oils

Drying oils, such as
linseed Flax, also known as common flax or linseed, is a flowering plant, ''Linum usitatissimum'', in the family Linaceae. It is cultivated as a food and fiber crop in regions of the world with temperate climates. Textiles made from flax are known in W ...
and
tung oil Tung oil or China wood oil is a drying oil obtained by pressing the seed from the nut of the tung tree (''Vernicia fordii''). The oil and its use are believed to have originated in ancient China and appear in the writings of Confucius from ab ...
, are not true varnishes though often in modern terms they accomplish the same thing.


Polyurethane

Polyurethane Polyurethane (; often abbreviated PUR and PU) refers to a class of polymers composed of organic units joined by carbamate (urethane) links. In contrast to other common polymers such as polyethylene and polystyrene, polyurethane is produced from ...
varnishes are typically hard, abrasion-resistant, and durable coatings. They are popular for
hardwood Hardwood is wood from dicot trees. These are usually found in broad-leaved temperate and tropical forests. In temperate and boreal latitudes they are mostly deciduous, but in tropics and subtropics mostly evergreen. Hardwood (which comes from ...
floors but are considered by some wood finishers to be difficult or unsuitable for finishing furniture or other detailed pieces. Polyurethanes are comparable in hardness to certain alkyds but generally form a tougher film. Compared to simple oil or shellac varnishes, polyurethane varnish forms a harder, decidedly tougher and more waterproof film. However, a thick film of ordinary polyurethane may de-laminate if subjected to heat or shock, fracturing the film and leaving white patches. This tendency increases with long exposure to sunlight or when it is applied over soft woods like
pine A pine is any conifer tree or shrub in the genus ''Pinus'' () of the family (biology), family Pinaceae. ''Pinus'' is the sole genus in the subfamily Pinoideae. The World Flora Online created by the Royal Botanic Gardens, Kew and Missouri Botanic ...
. This is also in part due to polyurethane's lesser penetration into the wood. Various priming techniques are employed to overcome this problem, including the use of certain oil varnishes, specified "dewaxed" shellac, clear penetrating
epoxy Epoxy is the family of basic components or cured end products of epoxy resins. Epoxy resins, also known as polyepoxides, are a class of reactive prepolymers and polymers which contain epoxide groups. The epoxide functional group is also co ...
sealer, or "oil-modified" polyurethane designed for the purpose. Polyurethane varnish may also lack the "hand-rubbed" lustre of drying oils such as linseed or tung oil; in contrast, however, it is capable of a much faster and higher film build, accomplishing in two coats what may require multiple applications of oil. Polyurethane may also be applied over a straight oil finish, but because of the relatively slow curing time of oils, the emission of certain chemical byproducts, and the need for exposure to oxygen from the air, care must be taken that the oils are sufficiently cured to accept the polyurethane. One of the disadvantages of a polyurethane-based varnish is the tendency to yellow over time. This is because the hydroxyl groups of a regular alkyd are reacted with
TDI TDI (Turbocharged Direct Injection) is Volkswagen Group's term for its current common rail Fuel injection#Direct injection, direct injection turbodiesel engine range that have an intercooler in addition to the turbo compressor. TDI engines are u ...
to produce a urethane-alkyd. This introduces a high degree of aromaticity and hence tendency to yellow. Unlike drying oils and alkyds which cure after evaporation of the solvent and upon reaction with oxygen from the air, true polyurethane coatings cure after
evaporation Evaporation is a type of vaporization that occurs on the surface of a liquid as it changes into the gas phase. High concentration of the evaporating substance in the surrounding gas significantly slows down evaporation, such as when h ...
of the solvent and then either by a variety of reactions of
chemical A chemical substance is a form of matter having constant chemical composition and characteristic properties. Some references add that chemical substance cannot be separated into its constituent elements by physical separation methods, i.e., w ...
s within the original mix, or by reaction with
moisture Moisture is the presence of a liquid, especially water, often in trace amounts. Small amounts of water may be found, for example, in the air (humidity), in foods, and in some commercial products. Moisture also refers to the amount of water vapo ...
from the air. Certain polyurethane products are "hybrids" and combine different aspects of their parent components. "Oil-modified" polyurethanes, whether water-borne or solvent-borne, are currently the most widely used wood floor finishes. Exterior use of polyurethane varnish may be problematic due to its heightened susceptibility to deterioration through
ultra-violet Ultraviolet (UV) is a form of electromagnetic radiation with wavelength from 10 nm (with a corresponding frequency around 30  PHz) to 400 nm (750  THz), shorter than that of visible light, but longer than X-rays. UV radiatio ...
light exposure. All clear or translucent varnishes, and indeed all
film A film also called a movie, motion picture, moving picture, picture, photoplay or (slang) flick is a work of visual art that simulates experiences and otherwise communicates ideas, stories, perceptions, feelings, beauty, or atmospher ...
-
polymer A polymer (; Greek '' poly-'', "many" + '' -mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic a ...
coatings (e.g. paint,
stain A stain is a discoloration that can be clearly distinguished from the surface, material, or medium it is found upon. They are caused by the chemical or physical interaction of two dissimilar materials. Accidental staining may make materials ap ...
, epoxy, synthetic
plastic Plastics are a wide range of synthetic or semi-synthetic materials that use polymers as a main ingredient. Their plasticity makes it possible for plastics to be moulded, extruded or pressed into solid objects of various shapes. This adapta ...
, etc.) are susceptible to this damage in varying degrees.
Pigment A pigment is a colored material that is completely or nearly insoluble in water. In contrast, dyes are typically soluble, at least at some stage in their use. Generally dyes are often organic compounds whereas pigments are often inorganic compou ...
s in paints and stains protect against UV damage. UV-absorbers are added to polyurethane and other varnishes (e.g. spar varnish) to work against UV damage but are decreasingly effective over the course of 2–4 years, depending on the quantity and quality of UV-absorbers added, as well as the severity and duration of sun exposure. Water exposure, humidity, temperature extremes, and other environmental factors affect all finishes.


Lacquer

The word ''lacquer'' refers to quick-drying, solvent-based varnishes or paints. Although their names may be similarly derived, lacquer is not the same as ''
shellac Shellac () is a resin secreted by the female lac bug on trees in the forests of India and Thailand. It is processed and sold as dry flakes and dissolved in alcohol to make liquid shellac, which is used as a brush-on colorant, food glaze and ...
'' and is not dissolved in alcohol. Lacquer is dissolved in lacquer thinner, which is a highly flammable solvent typically containing
butyl acetate ''n''-Butyl acetate is an organic compound with the formula . A colorless, flammable liquid, it is the ester derived from n-butanol and acetic acid. It is found in many types of fruit, where it imparts characteristic flavors and has a sweet smel ...
and
xylene In organic chemistry, xylene or xylol (; IUPAC name: dimethylbenzene) are any of three organic compounds with the formula . They are derived from the substitution of two hydrogen atoms with methyl groups in a benzene ring; which hydrogens are s ...
or
toluene Toluene (), also known as toluol (), is a substituted aromatic hydrocarbon. It is a colorless, water-insoluble liquid with the smell associated with paint thinners. It is a mono-substituted benzene derivative, consisting of a methyl group (CH3) ...
. Lacquer is typically sprayed on, within a ''
spray booth Spray painting is a painting technique in which a device sprays coating material (paint, ink, varnish, etc.) through the air onto a surface. The most common types employ compressed gas—usually air—to atomize and direct the paint particles. ...
'' that evacuates overspray and minimizes the risk of combustion. The rule of thumb is that a clear wood finish formulated to be sprayed is a lacquer, but if it is formulated to be brushed on then it is a varnish. Thus, by far most pieces of wooden furniture are lacquered. Lacquer may be considered different from varnish because it can be re-dissolved later by a solvent (such as the one it was dissolved in when it was applied) and does not chemically change to a solid like other varnishes.


Acrylic

Acrylic resin 186 px, Polyhydroxyethylmethacrylate is a typical acrylate resin. An acrylic resin is a thermoplastic or thermosetting plastic substance typically derived from acrylic acid, methacrylic acid and acrylate monomers such as butyl acrylate and or ...
varnishes are typically water-borne varnishes with the lowest
refractive index In optics, the refractive index (or refraction index) of an optical medium is a dimensionless number that gives the indication of the light bending ability of that medium. The refractive index determines how much the path of light is bent, ...
of all finishes and high transparency. They resist yellowing. Acrylics have the advantage of water clean-up and lack of solvent fumes, but typically do not penetrate into wood as well as oils. They sometimes lack the brushability and self-leveling qualities of solvent-based varnishes. Generally they have good UV-resistance. In the art world, varnishes offer dust-resistance and a harder surface than bare paint – they sometimes have the benefit of ultraviolet light resistors, which help protect artwork from fading in exposure to light. Acrylic varnish should be applied using an isolation coat (a permanent, protective barrier between the painting and the varnish, preferably a soft, glossy gel medium) to make varnish removal and overall conservation easier. Acrylic varnishes used for such a final removable art protection layer are typically mineral-spirit–based acrylic, rather than water-based.


Two-part epoxy

Various
epoxy Epoxy is the family of basic components or cured end products of epoxy resins. Epoxy resins, also known as polyepoxides, are a class of reactive prepolymers and polymers which contain epoxide groups. The epoxide functional group is also co ...
resin systems have been formulated as varnishes or floor finishes whereby two components are mixed directly before application. Sometimes, the two parts are of equal volume and referred to as 1:1 but not always, as 2:1, 3:1, 4:1 and even 5:1 mixing ratios are commercially available. The individual components are usually referred to as Part A and Part B. All two-part epoxies have a pot-life or working time during which the mixed material can be used. Usually the pot-life is a matter of a few hours or less, but this is highly temperature dependent. Both water-borne and solvent-based epoxies are used. Epoxies do have a tendency to yellow over a fairly short period of time.


Conversion

Used when a fast-curing, tough, hard finish is desired, such as for kitchen cabinets and office furniture. Comes in two parts: a resin and an acid catalyst. The first is a blend of an amino resin and an alkyd. The acid catalyst is added right before application in a set ratio determined by the manufacturer. Most produce minimal yellowing. There are, however, two downsides to this finish. The first is that as the finish cures, it gives off
formaldehyde Formaldehyde ( , ) ( systematic name methanal) is a naturally occurring organic compound with the formula and structure . The pure compound is a pungent, colourless gas that polymerises spontaneously into paraformaldehyde (refer to section ...
, which is toxic and carcinogenic. The second is that the finish can crack or craze if too many coats are applied.


See also

* ''
The Artist's Handbook of Materials and Techniques ''The Artist's Handbook of Materials and Techniques'' is a reference book by Ralph Mayer (1895–1979). Intended by the author for use by professional artists, it deals mostly with the chemical and physical properties of traditional painterly mater ...
'' *
Brightwork Brightwork also known historically as "bright work" refers to the exposed and varnished wood or metal work of a boat. The metal is usually brass or bronze that is kept polished, or stainless steel, which requires less maintenance. In the past, d ...
*
Desert varnish Desert varnish or rock varnish is an orange-yellow to black coating found on exposed rock surfaces in arid environments. Desert varnish is approximately one micrometer thick and exhibits nanometer-scale layering. Rock rust and desert patina are o ...
* Tack cloth *
UV coating A UV coating (or more generally a radiation cured coating) is a surface treatment which either is cured by ultraviolet radiation, or which protects the underlying material from such radiation's harmful effects. UV coatings on pipe and tube UV ...
– print finishing *
Alkyd An alkyd is a polyester resin modified by the addition of fatty acids and other components. Alkyds are derived from polyols and organic acids including dicarboxylic acids or carboxylic acid anhydride and triglyceride oils. The term ''alkyd'' is a m ...


References

* Bob Flexner (1993). ''Understanding Wood Finishing: How to Select and Apply the Right Finish''. Rodale Press: Emmaus, PA.


External links


Tung and Linseed Oils
by Steven D. Russel ; Varnish for musical instruments
Varnish for Violins and similar instruments
(archive.org)

by Keith Hill {{Authority control Chinese inventions Painting materials Printing materials Tang dynasty Visual arts materials Wood finishing materials