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Tridymite is a high-temperature polymorph of
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is ...
and usually occurs as minute tabular white or colorless pseudo-hexagonal crystals, or scales, in cavities in
felsic In geology, felsic is a modifier describing igneous rocks that are relatively rich in elements that form feldspar and quartz.Marshak, Stephen, 2009, ''Essentials of Geology,'' W. W. Norton & Company, 3rd ed. It is contrasted with mafic rocks, wh ...
volcanic rock Volcanic rock (often shortened to volcanics in scientific contexts) is a rock formed from lava erupted from a volcano. In other words, it differs from other igneous rock by being of volcanic origin. Like all rock types, the concept of volcanic ...
s. Its
chemical formula In chemistry, a chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, ...
is Si O2. Tridymite was first described in 1868 and the type location is in Hidalgo,
Mexico Mexico (Spanish language, Spanish: México), officially the United Mexican States, is a List of sovereign states, country in the southern portion of North America. It is borders of Mexico, bordered to the north by the United States; to the so ...
. The name is from the
Greek Greek may refer to: Greece Anything of, from, or related to Greece, a country in Southern Europe: *Greeks, an ethnic group. *Greek language, a branch of the Indo-European language family. **Proto-Greek language, the assumed last common ancestor ...
''tridymos'' for ''triplet'' as tridymite commonly occurs as twinned crystal '' trillings'' (compound crystals comprising three twinned crystal components).


Structure

Tridymite can occur in seven crystalline forms. Two of the most common at standard pressure are known as α and β. The α-tridymite phase is favored at elevated temperatures (>870 °C) and it converts to β-
cristobalite Cristobalite is a mineral polymorph of silica that is formed at very high temperatures. It has the same chemical formula as quartz, SiO2, but a distinct crystal structure. Both quartz and cristobalite are polymorphs with all the members of the ...
at 1470 °C. However, tridymite does usually not form from pure β-quartz, one needs to add trace amounts of certain compounds to achieve this. Otherwise the β-quartz-tridymite transition is skipped and β-quartz transitions directly to cristobalite at 1050 °C without occurrence of the tridymite phase. In the table, M, O, H, C, P, L and S stand for
monoclinic In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic ...
,
orthorhombic In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic lattices result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular prism with ...
,
hexagonal In geometry, a hexagon (from Greek , , meaning "six", and , , meaning "corner, angle") is a six-sided polygon. The total of the internal angles of any simple (non-self-intersecting) hexagon is 720°. Regular hexagon A '' regular hexagon'' has ...
, centered, primitive, low (temperature) and superlattice. T indicates the temperature, at which the corresponding phase is relatively stable, though the interconversions between phases are complex and sample dependent, and all these forms can coexist at ambient conditions. Mineralogy handbooks often arbitrarily assign tridymite to the
triclinic 180px, Triclinic (a ≠ b ≠ c and α ≠ β ≠ γ ) In crystallography, the triclinic (or anorthic) crystal system is one of the 7 crystal systems. A crystal system is described by three basis vectors. In the triclinic system, the crystal i ...
crystal system, yet use hexagonal
Miller indices Miller indices form a notation system in crystallography for lattice planes in crystal (Bravais) lattices. In particular, a family of lattice planes of a given (direct) Bravais lattice is determined by three integers ''h'', ''k'', and ''� ...
because of the hexagonal crystal shape (see infobox image).


Mars

In December 2015, the team behind
NASA The National Aeronautics and Space Administration (NASA ) is an independent agency of the US federal government responsible for the civil space program, aeronautics research, and space research. NASA was established in 1958, succeedin ...
's
Mars Science Laboratory Mars Science Laboratory (MSL) is a robotic space probe mission to Mars launched by NASA on November 26, 2011, which successfully landed ''Curiosity'', a Mars rover, in Gale Crater on August 6, 2012. The overall objectives include investigati ...
announced the discovery of large amounts of tridymite in Marias Pass on the slope of
Aeolis Mons Mount Sharp, officially Aeolis Mons (), is a mountain on Mars. It forms the central peak within Gale (crater), Gale crater and is located around , rising high from the valley floor. Its ID in the United States Geological Survey's Gazetteer of ...
, popularly known as Mount Sharp, on the planet
Mars Mars is the fourth planet from the Sun and the second-smallest planet in the Solar System, only being larger than Mercury. In the English language, Mars is named for the Roman god of war. Mars is a terrestrial planet with a thin at ...
. This discovery was unexpected given the rarity of the mineral on Earth and the apparent lack of volcanic activity where it was discovered, and at the time of discovery no explanation for how it was formed was forthcoming. Its discovery was serendipitous: two teams, responsible for two different instruments on the ''Curiosity'' rover, both happened to report what in isolation were relatively uninteresting findings related to their instruments: the
ChemCam Chemistry and Camera complex (ChemCam) is a suite of remote sensing instruments on Mars for the ''Curiosity'' rover. As the name implies, ChemCam is actually two different instruments combined as one: a laser-induced breakdown spectroscopy (LIB ...
team reported a region of high silica while the
DAN Dan or DAN may refer to: People * Dan (name), including a list of people with the name ** Dan (king), several kings of Denmark * Dan people, an ethnic group located in West Africa **Dan language, a Mande language spoken primarily in Côte d'Ivoir ...
team reported high neutron readings in what turned out to be the same area. Neither team would have been aware of the other's findings had it not been for a fortuitous Mars
conjunction Conjunction may refer to: * Conjunction (grammar), a part of speech * Logical conjunction, a mathematical operator ** Conjunction introduction, a rule of inference of propositional logic * Conjunction (astronomy), in which two astronomical bodies ...
in July 2015, during which the various international teams took advantage of the downtime to meet in
Paris Paris () is the capital and most populous city of France, with an estimated population of 2,165,423 residents in 2019 in an area of more than 105 km² (41 sq mi), making it the 30th most densely populated city in the world in 2020. Si ...
and discuss their scientific findings. DAN's high neutron readings would normally have been interpreted as meaning the region was hydrogen-rich, and ChemCam's high-silica readings were not surprising given the ubiquity of silica-rich deposits on Mars, but taken together it was clear that further study of the region was needed. Following conjunction, NASA directed the Curiosity rover back to the area where the readings had been taken and discovered that large amounts of tridymite were present. How they were formed remains a mystery.


See also

*
Cristobalite Cristobalite is a mineral polymorph of silica that is formed at very high temperatures. It has the same chemical formula as quartz, SiO2, but a distinct crystal structure. Both quartz and cristobalite are polymorphs with all the members of the ...
*
Coesite Coesite is a form ( polymorph) of silicon dioxide Si O2 that is formed when very high pressure (2–3 gigapascals), and moderately high temperature (), are applied to quartz. Coesite was first synthesized by Loring Coes Jr., a chemist at the ...
*
Stishovite Stishovite is an extremely hard, dense tetragonal form ( polymorph) of silicon dioxide. It is very rare on the Earth's surface; however, it may be a predominant form of silicon dioxide in the Earth, especially in the lower mantle. Stishovite ...


References


External links


Mineral galleriesStudy: Explosive volcanic eruption produced rare mineral on Mars
{{Silica minerals Orthorhombic minerals Minerals in space group 20 Industrial minerals Silica polymorphs Silicon dioxide