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The symmetry number or symmetry order of an object is the number of different but indistinguishable (or equivalent) arrangements (or views) of the object, i.e. the Order (group theory), order of its symmetry group. The object can be a molecule, crystal lattice, lattice, tiling, or in a general case any mathematical object in N-dimensions. In statistical thermodynamics, the symmetry number corrects for any overcounting of equivalent molecular conformations in the partition function. In this sense, the symmetry number depends upon how the partition function is formulated. For example, if one writes the partition function of ethane so that the integral includes full methyl group rotation, rotation of a methyl, then the 3-fold rotational symmetry of the methyl group contributes a factor of 3 to the symmetry number; but if one writes the partition function so that the integral includes only one rotational energy well of the methyl, then the methyl rotation does not contribute to the symmetry number. Symmetry Numbers for Rigid, Flexible and Fluxional Molecules: Theory and Applications. M.K. Gilson and K. K. Irikura. J. Phys. Chem. B 114:16304-16317, 2010.


See also

* Group theory, a branch of mathematics which discusses symmetry, symmetry groups, symmetry spaces, symmetry operations * Point groups in three dimensions * Space group in 3 dimensions * Symmetry combinations in 2 dimensions * Molecular symmetry * List of the 230 crystallographic 3D space groups * Fixed points of isometry groups in Euclidean space * Symmetric group, mathematics * Symmetry group, mathematics


References

{{reflist Symmetry