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Sterling silver is an
alloy An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductili ...
of
silver Silver is a chemical element with the symbol Ag (from the Latin ', derived from the Proto-Indo-European ''h₂erǵ'': "shiny" or "white") and atomic number 47. A soft, white, lustrous transition metal, it exhibits the highest electrical ...
containing 92.5% by weight of silver and 7.5% by weight of other metals, usually
copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pink ...
. The sterling silver standard has a minimum millesimal fineness of 925. '' Fine silver'', which is 99.9% pure silver, is relatively soft, so silver is usually alloyed with copper to increase its hardness and strength. Sterling silver is prone to tarnishing, and elements other than copper can be used in alloys to reduce tarnishing, as well as casting
porosity Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measur ...
and
firescale Firestain is a layer of oxides that is visible on the surface of objects made of metal alloys containing copper when the object is heated, as by a jeweler heating a ring to apply solder during a repair. On copper-containing alloys of gold or of ...
. Such elements include
germanium Germanium is a chemical element with the symbol Ge and atomic number 32. It is lustrous, hard-brittle, grayish-white and similar in appearance to silicon. It is a metalloid in the carbon group that is chemically similar to its group neighbors ...
,
zinc Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodi ...
,
platinum Platinum is a chemical element with the symbol Pt and atomic number 78. It is a dense, malleable, ductile, highly unreactive, precious, silverish-white transition metal. Its name originates from Spanish , a diminutive of "silver". Pla ...
,
silicon Silicon is a chemical element with the symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic luster, and is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic ...
, and
boron Boron is a chemical element with the symbol B and atomic number 5. In its crystalline form it is a brittle, dark, lustrous metalloid; in its amorphous form it is a brown powder. As the lightest element of the '' boron group'' it has t ...
. Recent examples of these alloys include ''argentium'', ''sterlium'' and ''silvadium''.


Etymology

One of the earliest attestations of the term is in
Old French Old French (, , ; Modern French: ) was the language spoken in most of the northern half of France from approximately the 8th to the 14th centuries. Rather than a unified language, Old French was a linkage of Romance dialects, mutually intel ...
form , in a charter of the abbey of
Les Préaux Les Préaux () is a commune in the Eure department and Normandy region of France. History Several archaeological discoveries carried out on the territory of the commune testify to a human presence since the Neolithic period. Polished axes were ...
, dating to either 1085 or 1104. The English chronicler
Orderic Vitalis Orderic Vitalis ( la, Ordericus Vitalis; 16 February 1075 – ) was an English chronicler and Benedictine monk who wrote one of the great contemporary chronicles of 11th- and 12th-century Normandy and Anglo-Norman England. Modern historia ...
(1075 – 1142) uses the Latin forms and . The word in origin refers to the newly introduced Norman silver penny. According to the
Oxford English Dictionary The ''Oxford English Dictionary'' (''OED'') is the first and foundational historical dictionary of the English language, published by Oxford University Press (OUP). It traces the historical development of the English language, providing a c ...
, the most plausible etymology is a derivation from a late Old English (with (or like) a 'little star'), as some early Norman pennies were imprinted with a small star. Another argument is that the
Hanseatic League The Hanseatic League (; gml, Hanse, , ; german: label= Modern German, Deutsche Hanse) was a medieval commercial and defensive confederation of merchant guilds and market towns in Central and Northern Europe. Growing from a few North German to ...
was the source for both the origin of its definition and manufacture, and in its name is that the German name for the Baltic is , or 'East Sea', and from this the Baltic merchants were called "Osterlings", or "Easterlings". In 1260, Henry III granted them a charter of protection. Because the League's money was not frequently debased like that of England, English traders stipulated to be paid in pounds of the Easterlings, which was contracted to ''sterling''. Their Kontor, the Steelyard of London, was called Easterlings Hall, or . The Hanseatic League was officially active in the London trade from 1266 to 1597. This etymology may have been first suggested by Walter de Pinchebek (c. 1300) with the explanation that the coin was originally made by moneyers from that region. The claim has been made in Henry Spelman's glossary () as referenced in ''
Commentaries on the Laws of England The ''Commentaries on the Laws of England'' are an influential 18th-century treatise on the common law of England by Sir William Blackstone, originally published by the Clarendon Press at Oxford, 1765–1770. The work is divided into four volum ...
'' by
William Blackstone Sir William Blackstone (10 July 1723 – 14 February 1780) was an English jurist, judge and Tory politician of the eighteenth century. He is most noted for writing the ''Commentaries on the Laws of England''. Born into a middle-class family ...
. Yet another claim on this same hypothesis is from
William Camden William Camden (2 May 1551 – 9 November 1623) was an English antiquarian, historian, topographer, and herald, best known as author of ''Britannia'', the first chorographical survey of the islands of Great Britain and Ireland, and the ''Ann ...
, as quoted in ''Chamber's Journal of Popular Literature, Science and Arts'', Volume 4. By 1854, the tie between Easterling and Sterling was well-established, as Ronald Zupko quotes in his dictionary of weights. The British numismatist Philip Grierson disagrees with the "star" etymology, as the stars appeared on Norman pennies only for the single three-year issue from 1077 to 1080 (the Normans changed coin designs every three years). Grierson's proposed alternative is that ''sterling'' derives from ''ster''From ancient Greek στερεός tereos= 'solid'. meaning 'strong' or 'stout', by analogy with the Byzantine solidus, originally known as the meaning 'solid gold' or 'reliable gold'. In support of this he cites the fact that one of the first acts of the Normans was to restore the coinage to the consistent weight and purity it had in the days of
Offa, King of Mercia Offa (died 29 July 796 AD) was King of Mercia, a kingdom of Anglo-Saxon England, from 757 until his death. The son of Thingfrith and a descendant of Eowa, Offa came to the throne after a period of civil war following the assassination of Æt ...
. This would have been perceived as a contrast to the progressive debasement of the intervening 200 years, and would therefore be a likely source for a nickname. S.E. Rigold disputes the origin being Norman, stating, "that, while medieval British coins seldom copy or are copied by those of France, they have many typological connexions with the lands to the east—the Netherlands, the Baltic, Germany, and even deeper regions of central Europe."


History

The sterling alloy originated in continental Europe and was being used for commerce as early as the 12th century in the area that is now northern
Germany Germany,, officially the Federal Republic of Germany, is a country in Central Europe. It is the second most populous country in Europe after Russia, and the most populous member state of the European Union. Germany is situated betwee ...
. A piece of sterling silver dating from Henry II's reign was used as a standard in the Trial of the Pyx until it was deposited at the
Royal Mint The Royal Mint is the United Kingdom's oldest company and the official maker of British coins. Operating under the legal name The Royal Mint Limited, it is a limited company that is wholly owned by HM Treasury, His Majesty's Treasury and is un ...
in 1843. It bears the royal stamp ''ENRI. REX'' ("King Henry") but this was added later, in the reign of Henry III. The first legal definition of sterling silver appeared in 1275, when a statute of
Edward I Edward I (17/18 June 1239 – 7 July 1307), also known as Edward Longshanks and the Hammer of the Scots, was King of England and Lord of Ireland from 1272 to 1307. Concurrently, he ruled the duchies of Aquitaine and Gascony as a vas ...
specified that 12  troy ounces of silver for coinage should contain 11 ounces   pennyweights of silver and  pennyweights of alloy, with 20 pennyweights to the troy ounce. This is (not precisely) equivalent to a millesimal fineness of 926. In
Colonial America The colonial history of the United States covers the history of European colonization of North America from the early 17th century until the incorporation of the Thirteen Colonies into the United States after the Revolutionary War. In the ...
, sterling silver was used for currency and general goods as well. Between 1634 and 1776, some 500 silversmiths created items in the "New World" ranging from simple buckles to ornate
Rococo Rococo (, also ), less commonly Roccoco or Late Baroque, is an exceptionally ornamental and theatrical style of architecture, art and decoration which combines asymmetry, scrolling curves, gilding, white and pastel colours, sculpted moulding, ...
coffee pots. Although silversmiths of this era were typically familiar with all precious metals, they primarily worked in sterling silver. The colonies lacked an
assay office Assay offices are institutions set up to assay (test the purity of) precious metals. This is often done to protect consumers from buying fake items. Upon successful completion of an assay (i.e. if the metallurgical content is found be equal or bett ...
during this time (the first would be established in 1814), so American silversmiths adhered to the standard set by the London Goldsmiths Company: sterling silver consisted of 91.5–92.5% by weight silver and 8.5–7.5 wt% copper. Stamping each of their pieces with their personal maker's mark, colonial silversmiths relied upon their own status to guarantee the quality and composition of their products. Colonial silversmiths used many of the techniques developed by those in Europe.
Casting Casting is a manufacturing process in which a liquid material is usually poured into a mold, which contains a hollow cavity of the desired shape, and then allowed to solidify. The solidified part is also known as a ''casting'', which is ejecte ...
was frequently the first step in manufacturing silver pieces, as silver workers would melt down sterling silver into easily manageable
ingots An ingot is a piece of relatively pure material, usually metal, that is cast into a shape suitable for further processing. In steelmaking, it is the first step among semi-finished casting products. Ingots usually require a second procedure of s ...
. Occasionally, they would create small components (e.g. teapot legs) by casting silver into iron or graphite molds, but it was rare for an entire piece to be fabricated via casting. More commonly, a silversmith would
forge A forge is a type of hearth used for heating metals, or the workplace (smithy) where such a hearth is located. The forge is used by the smith to heat a piece of metal to a temperature at which it becomes easier to shape by forging, or to th ...
an ingot into the desired shape, often hammering the thinned silver against specially shaped dies to "mass produce" simple shapes like the oval end of a spoon. The hammering occurred at room temperature, and, like any
cold forming In metallurgy, cold forming or cold working is any metalworking process in which metal is shaped below its recrystallization temperature, usually at the ambient temperature. Such processes are contrasted with hot working techniques like hot r ...
process, caused
work hardening In materials science, work hardening, also known as strain hardening, is the strengthening of a metal or polymer by plastic deformation. Work hardening may be desirable, undesirable, or inconsequential, depending on the context. This strengt ...
of the silver, which become increasingly brittle and difficult to shape. To restore the workability, the silversmith would anneal the piece—that is, heat it to a dull red and then quench it in water—to relieve the stresses in the material and return it to a more ductile state. Hammering required more time than all other silver manufacturing processes, and therefore accounted for the majority of labor costs. Silversmiths would then seam parts together to create complex and artistic items, sealing the gaps with a solder of 80 wt% silver and 20 wt% bronze. Finally, they would file and polish their work to remove all seams, finishing off with engraving and stamping the smith's mark. The American revolutionary Paul Revere was regarded as one of the best silversmiths from this "Golden Age of American Silver". Following the Revolutionary War, Revere acquired and made use of a silver rolling mill from England. Not only did the rolling mill increase his rate of production—hammering and flattening silver took most of a silversmith's time—he was able to roll and sell silver of appropriate, uniform thickness to other silversmiths. He retired a wealthy artisan, his success partly due to this strategic investment. Although he is celebrated for his beautiful hollowware, Revere made his fortune primarily on low-end goods produced by the mill, such as flatware. With the onset of the first
Industrial Revolution The Industrial Revolution was the transition to new manufacturing processes in Great Britain, continental Europe, and the United States, that occurred during the period from around 1760 to about 1820–1840. This transition included going f ...
, silversmithing declined as an artistic occupation. From about 1840 to 1940 in the United States and Europe, sterling silver
cutlery Cutlery (also referred to as silverware, flatware, or tableware), includes any hand implement used in preparing, serving, and especially eating food in Western culture. A person who makes or sells cutlery is called a cutler. The city of Sheffie ...
(US: 'flatware') became '' de rigueur'' when setting a proper table. There was a marked increase in the number of silver companies that emerged during that period. The height of the silver craze was during the 50-year period from 1870 to 1920. Flatware lines during this period sometimes included up to 100 different types of pieces.


Hallmarks

Some countries developed systems of hallmarking silver: * To indicate the purity of the silver alloy used in the manufacture or hand-crafting of the piece. * To identify the silversmith or company that made the piece. * To note the date and/or location of the manufacture or tradesman. * To reduce the amount of counterfeiting of silver items.


Uses

Individual eating implements often included: *forks (
dinner fork In cutlery or kitchenware, a fork (from la, furca 'pitchfork') is a utensil, now usually made of metal, whose long handle terminates in a head that branches into several narrow and often slightly curved tines with which one can spear foods eit ...
, salad fork, pastry fork, or shrimp fork) *spoons ( teaspoon,
coffee spoon A teaspoon (tsp.) is an item of cutlery. It is a small spoon that can be used to stir a cup of tea or coffee, or as a tool for measuring volume. The size of teaspoons ranges from about . For cooking purposes and dosing of medicine, a teaspoonf ...
, demitasse spoon, iced tea spoon) and * knives ( dinner knife, butter spreader,
cheese knife A cheese knife is a type of kitchen knife specialized for the cutting of cheese. Different cheeses require different knives, according primarily to hardness. There are also a number of other kitchen tools designed for cutting or slicing cheese, ...
). This was especially true during the Victorian period, when etiquette dictated no food should be touched with one's fingers. Serving pieces were often elaborately decorated and pierced and embellished with
ivory Ivory is a hard, white material from the tusks (traditionally from elephants) and teeth of animals, that consists mainly of dentine, one of the physical structures of teeth and tusks. The chemical structure of the teeth and tusks of mammals i ...
, and could include any or all of the following: carving knife and fork, salad knife and fork, cold meat fork, punch ladle, soup ladle, gravy ladle,
casserole A casserole (French: diminutive of , from Provençal 'pan') is a normally large deep pan or bowl a casserole is anything in a casserole pan. Hot or cold History Baked dishes have existed for thousands of years. Early casserole recipes c ...
-serving spoon, berry spoon, lasagna server,
macaroni Macaroni (, Italian: maccheroni) is dry pasta shaped like narrow tubes.Oxford DictionaryMacaroni/ref> Made with durum wheat, macaroni is commonly cut in short lengths; curved macaroni may be referred to as elbow macaroni. Some home machine ...
server, asparagus server, cucumber server, tomato server, olive spoon, cheese scoop, fish knife and fork, pastry server, '' petit four'' server,
cake Cake is a flour confection made from flour, sugar, and other ingredients, and is usually baked. In their oldest forms, cakes were modifications of bread, but cakes now cover a wide range of preparations that can be simple or elaborate ...
knife, bon bon spoon,
salt spoon A salt spoon is a miniature utensil used with an open salt cellar for individual service. It is a historical and nostalgic item from a time before table salt was free-flowing, as it is today. The spoon itself ranges from 2 to 3 inches (5 to ...
, sugar sifter or caster and crumb remover with brush.
Cutlery Cutlery (also referred to as silverware, flatware, or tableware), includes any hand implement used in preparing, serving, and especially eating food in Western culture. A person who makes or sells cutlery is called a cutler. The city of Sheffie ...
sets were often accompanied by tea sets, hot water pots, chocolate pots, trays and salvers, goblets, demitasse cups and saucers, liqueur cups, bouillon cups, egg cups, plates, napkin rings, water and wine pitchers and coasters, candelabra and even elaborate centerpieces. The interest in sterling silver extended to business ( paper clips, mechanical pencils, letter openers, calling card boxes, cigarette cases), to the boudoir (dresser trays, mirrors, hair and suit brushes, pill bottles, manicure sets,
shoehorn A shoehorn or shoe horn (sometimes called a shoespooner, shoe spoon, shoe schlipp, or shoe tongue) is a tool with a short handle that flares into a longer spoon-like head meant to be held against the inside back of a snug-fitting shoe so that a ...
s, perfume bottles, powder bottles, hair clips) and even to children (cups,
cutlery Cutlery (also referred to as silverware, flatware, or tableware), includes any hand implement used in preparing, serving, and especially eating food in Western culture. A person who makes or sells cutlery is called a cutler. The city of Sheffie ...
, rattles). Other uses of the specific silver alloy include: * Use as surgical and medical instruments as early as Ur, Hellenistic-era Egypt and Rome, and their use continued until largely replaced in Western countries in the mid to late 20th century by cheaper, disposable plastic items and sharper, more durable steel ones. The alloy's natural malleability is an obvious physical advantage, but it is also naturally aseptic. * Some brasswind instrument manufacturers use 92.5% sterling silver as the material for making their instruments, including the flute and saxophone. For example, some leading saxophone manufacturers such as Selmer and Yanagisawa have crafted some of their saxophones from sterling silver. *Use as jewelry rings, bracelets, earrings and necklaces.


Tarnish and corrosion

Chemically, silver is not very reactive—it does not react with
oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements ...
or water at ordinary temperatures, so does not easily form a silver oxide. However, it is attacked by common components of atmospheric pollution:
silver sulfide Silver sulfide is an inorganic compound with the formula . A dense black solid, it is the only sulfide of silver. It is useful as a photosensitizer in photography. It constitutes the tarnish that forms over time on silverware and other silver o ...
slowly appears as a black tarnish during exposure to airborne compounds of sulfur (byproducts of the burning of fossil fuels and some industrial processes), and low level ozone reacts to form silver oxide. As the purity of the silver decreases, the problem of
corrosion Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engi ...
or
tarnishing Tarnish is a thin layer of corrosion that forms over copper, brass, aluminum, magnesium, neodymium and other similar metals as their outermost layer undergoes a chemical reaction. Tarnish does not always result from the sole effects of oxygen in ...
increases because other metals in the alloy, usually copper, may react with oxygen in the air. The black
silver sulfide Silver sulfide is an inorganic compound with the formula . A dense black solid, it is the only sulfide of silver. It is useful as a photosensitizer in photography. It constitutes the tarnish that forms over time on silverware and other silver o ...
(Ag2S) is among the most
insoluble In chemistry, solubility is the ability of a substance, the solute, to form a solution with another substance, the solvent. Insolubility is the opposite property, the inability of the solute to form such a solution. The extent of the solubi ...
salts in
aqueous solution An aqueous solution is a solution in which the solvent is water. It is mostly shown in chemical equations by appending (aq) to the relevant chemical formula. For example, a solution of table salt, or sodium chloride (NaCl), in water would be r ...
, a property that is exploited for separating silver ions from other positive ions. Sodium chloride (NaCl) or common table salt is known to corrode silver-copper alloy, typically seen in silver salt shakers where corrosion appears around the holes in the top. Several products have been developed for the purpose of polishing silver that serve to remove
sulfur Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formul ...
from the metal without damaging or warping it. Because harsh polishing and buffing can permanently damage and devalue a piece of antique silver, valuable items are typically hand-polished to preserve the unique
patina Patina ( or ) is a thin layer that variously forms on the surface of copper, brass, bronze and similar metals and metal alloys ( tarnish produced by oxidation or other chemical processes) or certain stones and wooden furniture (sheen produce ...
s of older pieces. Techniques such as wheel
polishing Polishing is the process of creating a smooth and shiny surface by rubbing it or by applying a chemical treatment, leaving a clean surface with a significant specular reflection (still limited by the index of refraction of the material accordin ...
, which are typically performed by professional jewelers or silver repair companies, are reserved for extreme tarnish or corrosion.


See also

* Britannia silver, a higher grade silver alloy (95.8% compared to Sterling silver's 92.5%) *
Argentium sterling silver Argentium silver (originally patented in 1998) is a brand of modern tarnish-resistant silver alloys, containing either 93.5% or 96% silver. Argentium alloys replace some of the copper (approximately 1% of the copper and other alloys is replaced w ...
, a higher grade silver alloy with unique working properties (93.6% or 96%) * Coin silver, .900 fine silver widely used in pre-1964 United States coinage *
Pound sterling Sterling (abbreviation: stg; Other spelling styles, such as STG and Stg, are also seen. ISO code: GBP) is the currency of the United Kingdom and nine of its associated territories. The pound ( sign: £) is the main unit of sterling, and ...
, the official currency of the United Kingdom, which once was based on a weight in sterling silver * Weighted sterling, items with a silver surface and a composite of other materials


Footnotes


References


Works cited

* ''All About Antique Silver with International Hallmarks'', 2nd printing (2007), by Diana Sanders Cinamon, AAA Publishing, San Bernardino, CA. * ''Origins: A Short Etymological Dictionary of Modern English'', by lexicographer Eric Partridge. * ''Silver in America, 1840–1940: A Century of Splendor'', third edition (1997), by Charles L. Venable; Harry N. Abrams, Inc., New York, NY. * ''Tiffany Silver Flatware, 1845–1905: When Dining Was an Art'', by William P. Hood, Jr.; 1999; published by the Antique Collectors Club Ltd., Suffolk, England. * ''The Encyclopedia of American Silver Manufacturers'', revised fourth edition (1998), by Dorothy T. Rainwater and Judy Redfield; Schiffer Publishing Ltd., Atglen, PA. * ''The Book of Old Silver, English – American – Foreign, With All Available Hallmarks Including Sheffield Plate Marks'', by Seymour B. Wyler; 1937; Crown Publishers, Inc., New York, NY. * ''International Hallmarks on Silver Collected by Tardy'', 5th English Language reprint (2000); original publication date unknown, date of first softcover publication 1985; author unknown; publisher unknown. * * * * {{Jewelry Jewellery Silversmithing Silver Coinage metals and alloys