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In
photography Photography is the art, application, and practice of creating durable images by recording light, either electronically by means of an image sensor, or chemically by means of a light-sensitive material such as photographic film. It is emplo ...
, reciprocity is the inverse relationship between the intensity and duration of light that determines the reaction of light-sensitive material. Within a normal exposure range for film stock, for example, the reciprocity law states that the film response will be determined by the total exposure, defined as intensity × time. Therefore, the same response (for example, the
optical density Absorbance is defined as "the logarithm of the ratio of incident to transmitted radiant power through a sample (excluding the effects on cell walls)". Alternatively, for samples which scatter light, absorbance may be defined as "the negative lo ...
of the developed film) can result from reducing duration and increasing light intensity, and vice versa. The reciprocal relationship is assumed in most sensitometry, for example when measuring a Hurter and Driffield curve (optical density versus logarithm of total exposure) for a photographic emulsion. Total exposure of the film or sensor, the product of focal-plane illuminance times exposure time, is measured in
lux The lux (symbol: lx) is the unit of illuminance, or luminous flux per unit area, in the International System of Units (SI). It is equal to one lumen per square metre. In photometry, this is used as a measure of the intensity, as perceived by ...
second The second (symbol: s) is the unit of time in the International System of Units (SI), historically defined as of a day – this factor derived from the division of the day first into 24 hours, then to 60 minutes and finally to 60 seconds ea ...
s.


History

The idea of reciprocity, once known as Bunsen–Roscoe reciprocity, originated from the work of
Robert Bunsen Robert Wilhelm Eberhard Bunsen (; 30 March 1811 – 16 August 1899) was a German chemist. He investigated emission spectra of heated elements, and discovered caesium (in 1860) and rubidium (in 1861) with the physicist Gustav Kirchhoff. The Bu ...
and Henry Roscoe in 1862. Deviations from the reciprocity law were reported by Captain William de Wiveleslie Abney in 1893, and extensively studied by
Karl Schwarzschild Karl Schwarzschild (; 9 October 1873 – 11 May 1916) was a German physicist and astronomer. Schwarzschild provided the first exact solution to the Einstein field equations of general relativity, for the limited case of a single spherical non-r ...
in 1899. Schwarzschild's model was found wanting by Abney and by Englisch, and better models have been proposed in subsequent decades of the early twentieth century. In 1913, Kron formulated an equation to describe the effect in terms of curves of constant density, which J. Halm adopted and modified, leading to the "Kron–Halm
catenary In physics and geometry, a catenary (, ) is the curve that an idealized hanging chain or cable assumes under its own weight when supported only at its ends in a uniform gravitational field. The catenary curve has a U-like shape, superfici ...
equation" or "Kron–Halm–Webb formula" to describe departures from reciprocity.


In chemical photography

In
photography Photography is the art, application, and practice of creating durable images by recording light, either electronically by means of an image sensor, or chemically by means of a light-sensitive material such as photographic film. It is emplo ...
, ''reciprocity'' refers to the relationship whereby the total light energy – proportional to the total exposure, the product of the light intensity and exposure time, controlled by
aperture In optics, an aperture is a hole or an opening through which light travels. More specifically, the aperture and focal length of an optical system determine the cone angle of a bundle of rays that come to a focus in the image plane. An ...
and
shutter speed In photography, shutter speed or exposure time is the length of time that the film or digital sensor inside the camera is exposed to light (that is, when the camera's shutter is open) when taking a photograph. The amount of light that rea ...
, respectively – determines the effect of the light on the film. That is, an increase of brightness by a certain factor is exactly compensated by a decrease of exposure time by the same factor, and vice versa. In other words, there is under normal circumstances a reciprocal proportion between aperture area and shutter speed for a given photographic result, with a wider aperture requiring a faster shutter speed for the same effect. For example, an EV of 10 may be achieved with an aperture (
f-number In optics, the f-number of an optical system such as a camera lens is the ratio of the system's focal length to the diameter of the entrance pupil ("clear aperture").Smith, Warren ''Modern Optical Engineering'', 4th Ed., 2007 McGraw-Hill Pro ...
) of 2.8 and a shutter speed of 1/125  s. The same exposure is achieved by doubling the aperture area to 2 and halving the exposure time to 1/250 s, or by halving the aperture area to 4 and doubling the exposure time to 1/60 s; in each case the response of the film is expected to be the same.


Reciprocity failure

For most photographic materials, reciprocity is valid with good accuracy over a range of values of exposure duration, but becomes increasingly inaccurate as this range is departed from: this is reciprocity failure (reciprocity law failure, or the Schwarzschild effect). As the light level decreases out of the reciprocity range, the increase in duration, and hence of total exposure, required to produce an equivalent response becomes higher than the formula states; for instance, at half of the light required for a normal exposure, the duration must be more than doubled for the same result. Multipliers used to correct for this effect are called ''reciprocity factors'' (see model below). At very low light levels,
film A film also called a movie, motion picture, moving picture, picture, photoplay or (slang) flick is a work of visual art that simulates experiences and otherwise communicates ideas, stories, perceptions, feelings, beauty, or atmospher ...
is less responsive. Light can be considered to be a stream of discrete photons, and a light-sensitive emulsion is composed of discrete light-sensitive
grain A grain is a small, hard, dry fruit ( caryopsis) – with or without an attached hull layer – harvested for human or animal consumption. A grain crop is a grain-producing plant. The two main types of commercial grain crops are cereals and legum ...
s, usually
silver halide A silver halide (or silver salt) is one of the chemical compounds that can form between the Chemical element, element silver (Ag) and one of the halogens. In particular, bromine (Br), chlorine (Cl), iodine (I) and fluorine (F) may each combine wi ...
crystal A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macro ...
s. Each grain must absorb a certain number of photons in order for the light-driven reaction to occur and the
latent image {{citations needed, date=November 2015 A latent image is an invisible image produced by the exposure to light of a photosensitive material such as photographic film. When photographic film is developed, the area that was exposed darkens and for ...
to form. In particular, if the surface of the silver halide crystal has a cluster of approximately four or more reduced silver atoms, resulting from absorption of a sufficient number of photons (usually a few dozen photons are required), it is rendered developable. At low light levels, ''i.e.'' few photons per unit time, photons impinge upon each grain relatively infrequently; if the four photons required arrive over a long enough interval, the partial change due to the first one or two is not stable enough to survive before enough photons arrive to make a permanent
latent image {{citations needed, date=November 2015 A latent image is an invisible image produced by the exposure to light of a photosensitive material such as photographic film. When photographic film is developed, the area that was exposed darkens and for ...
center. This breakdown in the usual tradeoff between aperture and shutter speed is known as reciprocity failure. Each different film type has a different response at low light levels. Some films are very susceptible to reciprocity failure, and others much less so. Some films that are very light sensitive at normal illumination levels and normal exposure times lose much of their sensitivity at low light levels, becoming effectively "slow" films for long exposures. Conversely some films that are "slow" under normal exposure duration retain their light sensitivity better at low light levels. For example, for a given film, if a
light meter A light meter is a device used to measure the amount of light. In photography, a light meter (more correctly an exposure meter) is used to determine the proper exposure (photography), exposure for a photograph. The meter will include either a Di ...
indicates a required EV of 5 and the photographer sets the aperture to f/11, then ordinarily a 4-second exposure would be required; a reciprocity correction factor of 1.5 would require the exposure to be extended to 6 seconds for the same result. Reciprocity failure generally becomes significant at exposures of longer than about 1 sec for film, and above 30 sec for paper. Reciprocity also breaks down at extremely high levels of illumination with very short exposures. This is a concern for
scientific Science is a systematic endeavor that builds and organizes knowledge in the form of testable explanations and predictions about the universe. Science may be as old as the human species, and some of the earliest archeological evidence for ...
and
technical Technical may refer to: * Technical (vehicle), an improvised fighting vehicle * Technical analysis, a discipline for forecasting the future direction of prices through the study of past market data * Technical drawing, showing how something is co ...
photography, but rarely to general
photographer A photographer (the Greek φῶς (''phos''), meaning "light", and γραφή (''graphê''), meaning "drawing, writing", together meaning "drawing with light") is a person who makes photographs. Duties and types of photographers As in oth ...
s, as exposures significantly shorter than a
millisecond A millisecond (from '' milli-'' and second; symbol: ms) is a unit of time in the International System of Units (SI) equal to one thousandth (0.001 or 10−3 or 1/1000) of a second and to 1000 microseconds. A unit of 10 milliseconds may be calle ...
are only required for subjects such as
explosion An explosion is a rapid expansion in volume associated with an extreme outward release of energy, usually with the generation of high temperatures and release of high-pressure gases. Supersonic explosions created by high explosives are known ...
s and in
particle physics Particle physics or high energy physics is the study of fundamental particles and forces that constitute matter and radiation. The fundamental particles in the universe are classified in the Standard Model as fermions (matter particles) an ...
, or when taking high-speed motion pictures with very high shutter speeds (1/10,000 sec or faster).


Schwarzschild law

In response to astronomical observations of low intensity reciprocity failure,
Karl Schwarzschild Karl Schwarzschild (; 9 October 1873 – 11 May 1916) was a German physicist and astronomer. Schwarzschild provided the first exact solution to the Einstein field equations of general relativity, for the limited case of a single spherical non-r ...
wrote (circa 1900): : "In determinations of stellar brightness by the photographic method I have recently been able to confirm once more the existence of such deviations, and to follow them up in a quantitative way, and to express them in the following rule, which should replace the law of reciprocity: Sources of light of different intensity ''I'' cause the same degree of blackening under different exposures ''t'' if the products I \times t^ are equal."K. Schwarzschild "On The Deviations From The Law of Reciprocity For Bromide Of Silver Gelatine" ''The Astrophysical Journal'' vol.11 (1900) p.8

/ref> Unfortunately, Schwarzschild's empirically determined ''0.86'' coefficient turned out to be of limited usefulness. A modern formulation of Schwarzschild's law is given as : E = It^p \ where ''E'' is a measure of the "effect of the exposure" that leads to changes in the opacity (optics), opacity of the photosensitive material (in the same degree that an equal value of exposure ''H = It'' does in the reciprocity region), ''I'' is illuminance, ''t'' is exposure duration and ''p'' is the ''Schwarzschild coefficient''. However, a constant value for ''p'' remains elusive, and has not replaced the need for more realistic models or empirical sensitometric data in critical applications. When reciprocity holds, Schwarzschild's law uses ''p'' = 1.0. Since the Schwarzschild's law formula gives unreasonable values for times in the region where reciprocity holds, a modified formula has been found that fits better across a wider range of exposure times. The modification is in terms of a factor the multiplies the ISO
film speed Film speed is the measure of a photographic film's sensitivity to light, determined by sensitometry and measured on various numerical scales, the most recent being the ISO system. A closely related ISO system is used to describe the relation ...
: :Relative film speed = (t + 1)^ \ where the ''t'' + 1 term implies a breakpoint near 1 second separating the region where reciprocity holds from the region where it fails.


Simple model for ''t'' > 1 second

Some models of microscope use automatic electronic models for reciprocity failure compensation, generally of a form for correct time, ''Tc'', expressible as a
power law In statistics, a power law is a functional relationship between two quantities, where a relative change in one quantity results in a proportional relative change in the other quantity, independent of the initial size of those quantities: one q ...
of metered time, ''Tm'', that is, ''Tc=(Tm)p'', for times in seconds. Typical values of ''p'' are 1.25 to 1.45, but some are low as 1.1 and high as 1.8.


The Kron–Halm catenary equation

Kron's equation as modified by Halm states that the response of the film is a function of I t / \psi \ , with the factor defined by a
catenary In physics and geometry, a catenary (, ) is the curve that an idealized hanging chain or cable assumes under its own weight when supported only at its ends in a uniform gravitational field. The catenary curve has a U-like shape, superfici ...
(
hyperbolic cosine In mathematics, hyperbolic functions are analogues of the ordinary trigonometric functions, but defined using the hyperbola rather than the circle. Just as the points form a circle with a unit radius, the points form the right half of the ...
) equation accounting for reciprocity failure at both very high and very low intensities: : \psi = \frac I/I_0)^a + (I/I_0)^ where ''I''0 is the photographic material's optimum intensity level and ''a'' is a constant that characterizes the material's reciprocity failure.


Quantum reciprocity-failure model

Modern models of reciprocity failure incorporate an
exponential function The exponential function is a mathematical function denoted by f(x)=\exp(x) or e^x (where the argument is written as an exponent). Unless otherwise specified, the term generally refers to the positive-valued function of a real variable, ...
, as opposed to
power law In statistics, a power law is a functional relationship between two quantities, where a relative change in one quantity results in a proportional relative change in the other quantity, independent of the initial size of those quantities: one q ...
, dependence on time or intensity at long exposure times or low intensities, based on the distribution of ''interquantic times'' (times between photon absorptions in a grain) and the temperature-dependent ''lifetimes'' of the intermediate states of the partially exposed grains. Baines and Bomback explain the "low intensity inefficiency" this way:


Astrophotography

Reciprocity failure is an important effect in the field of film-based
astrophotography Astrophotography, also known as astronomical imaging, is the photography or imaging of astronomical objects, celestial events, or areas of the night sky. The first photograph of an astronomical object (the Moon) was taken in 1840, but it was no ...
. Deep-sky objects such as galaxies and nebulae are often so faint that they are not visible to the un-aided eye. To make matters worse, many objects' spectra do not line up with the film emulsion's sensitivity curves. Many of these targets are small and require long focal lengths, which can push the focal ratio far above 5. Combined, these parameters make these targets extremely difficult to capture with film; exposures from 30 minutes to well over an hour are typical. As a typical example, capturing an image of the
Andromeda Galaxy The Andromeda Galaxy (IPA: ), also known as Messier 31, M31, or NGC 224 and originally the Andromeda Nebula, is a barred spiral galaxy with the diameter of about approximately from Earth and the nearest large galaxy to the Milky Way. The gal ...
at 4 will take about 30 minutes; to get the same density at 8 would require an exposure of about 200 minutes. When a telescope is tracking an object, every minute is difficult; therefore, reciprocity failure is one of the biggest motivations for astronomers to switch to
digital imaging Digital imaging or digital image acquisition is the creation of a digital representation of the visual characteristics of an object, such as a physical scene or the interior structure of an object. The term is often assumed to imply or include t ...
. Electronic
image sensor An image sensor or imager is a sensor that detects and conveys information used to make an image. It does so by converting the variable attenuation of light waves (as they pass through or reflect off objects) into signals, small bursts of c ...
s have their own limitation at long exposure time and low illuminance levels, not usually referred to as reciprocity failure, namely noise from dark current, but this effect can be controlled by cooling the sensor.


Holography

A similar problem exists in
holography Holography is a technique that enables a wavefront to be recorded and later re-constructed. Holography is best known as a method of generating real three-dimensional images, but it also has a wide range of other applications. In principle, i ...
. The total energy required when exposing holographic film using a continuous wave
laser A laser is a device that emits light through a process of optical amplification based on the stimulated emission of electromagnetic radiation. The word "laser" is an acronym for "light amplification by stimulated emission of radiation". The ...
(i.e. for several seconds) is significantly less than the total energy required when exposing holographic film using a pulsed
laser A laser is a device that emits light through a process of optical amplification based on the stimulated emission of electromagnetic radiation. The word "laser" is an acronym for "light amplification by stimulated emission of radiation". The ...
(i.e. around 20–40
nanosecond A nanosecond (ns) is a unit of time in the International System of Units (SI) equal to one billionth of a second, that is, of a second, or 10 seconds. The term combines the SI prefix ''nano-'' indicating a 1 billionth submultiple of an SI unit ( ...
s) due to a reciprocity failure. It can also be caused by very long or very short exposures with a continuous wave laser. To try to offset the reduced brightness of the film due to reciprocity failure, a method called latensification can be used. This is usually done directly after the holographic exposure and using an incoherent light source (such as a 25–40 W light bulb). Exposing the holographic film to the light for a few seconds can increase the brightness of the hologram by an order of magnitude.


References


External links


''Reciprocity what?''
– a brief explanation in layman's terms.

{{Photography Astrophotography Holography Science of photography