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Pyroxenite is an ultramafic igneous rock consisting essentially of
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2 ...
s of the pyroxene group, such as augite, diopside, hypersthene,
bronzite Bronzite is a member of the pyroxene group of minerals, belonging with enstatite and hypersthene to the orthorhombic series of the group. Rather than a distinct species, it is really a ferriferous variety of enstatite, which owing to partial ...
or enstatite. Pyroxenites are classified into
clinopyroxenite Pyroxenite is an ultramafic igneous rock consisting essentially of minerals of the pyroxene group, such as augite, diopside, hypersthene, bronzite or enstatite. Pyroxenites are classified into clinopyroxenites, orthopyroxenites, and the webster ...
s,
orthopyroxenite Orthopyroxenite is an ultramafic and ultrabasic rock that is almost exclusively made from the mineral orthopyroxene, the orthorhombic version of pyroxene and a type of pyroxenite. It can have up to a few percent of olivine and clinopyroxene. Orth ...
s, and the
websterite Websterite is ultramafic igneous rock that consists of roughly equal proportions of orthopyroxene and clinopyroxene. It is a type of pyroxenite. Websterite is named after the town Webster in North Carolina North Carolina () is a state ...
s which contain both types of pyroxenes (see diagram below). Closely allied to this group are the hornblendites, consisting essentially of hornblende and other amphiboles. They are essentially of igneous origin, though some pyroxenites are included in the metamorphic
Lewisian complex The Lewisian complex or Lewisian gneiss is a suite of Precambrian metamorphic rocks that outcrop in the northwestern part of Scotland, forming part of the Hebridean Terrane and the North Atlantic Craton. These rocks are of Archaean and Pale ...
of
Scotland Scotland (, ) is a country that is part of the United Kingdom. Covering the northern third of the island of Great Britain, mainland Scotland has a border with England to the southeast and is otherwise surrounded by the Atlantic Ocean to ...
. The pyroxene-rich rocks, which result from the type of contact metamorphism known as pyroxene-hornfels facies, have siliceous sediment or basaltic protoliths, and are respectively metapelites and metabasites.


Intrusive and mantle pyroxenites

Igneous pyroxenites are closely allied to
gabbro Gabbro () is a phaneritic (coarse-grained), mafic intrusive igneous rock formed from the slow cooling of magnesium-rich and iron-rich magma into a holocrystalline mass deep beneath the Earth's surface. Slow-cooling, coarse-grained gabbro is ...
s and
norite Norite is a mafic intrusive igneous rock composed largely of the calcium-rich plagioclase labradorite, orthopyroxene, and olivine. The name ''norite'' is derived from ''Norge'', the Norwegian name for Norway. Norite also known as orthopy ...
s, from which they differ by the absence of
feldspar Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) felds ...
, and to peridotites, which are distinguished from them by containing more than 40%
olivine The mineral olivine () is a magnesium iron silicate with the chemical formula . It is a type of nesosilicate or orthosilicate. The primary component of the Earth's upper mantle, it is a common mineral in Earth's subsurface, but weathers qui ...
. This connection is indicated also by their mode of occurrence, for they usually accompany masses of gabbro and peridotite and seldom are found by themselves. They are often very coarse-grained, containing individual
crystal A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macro ...
s which may be several inches in length. The principal accessory minerals, in addition to olivine and feldspar, are chromite and other spinels,
garnet Garnets () are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives. All species of garnets possess similar physical properties and crystal forms, but differ in chemical composition. The different ...
, magnetite, rutile, and scapolite. Pyroxenites can be formed as cumulates in ultramafic intrusions by accumulation of pyroxene crystals at the base of the magma chamber. Here they are generally associated with gabbro and anorthite cumulate layers and are typically high up in the intrusion. They may be accompanied by magnetite layers, ilmenite layers, but rarely chromite cumulates. Pyroxenites are also found as layers within masses of peridotite. These layers most commonly have been interpreted as products of reaction between ascending magmas and peridotite of the upper mantle. The layers typically are a few centimeters to a meter or so in thickness. Pyroxenites that occur as xenoliths in
basalt Basalt (; ) is an aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the surface of a rocky planet or moon. More than 90 ...
and in kimberlite have been interpreted as fragments of such layers. Although some mantle pyroxenites contain garnet, they are not eclogites, as clinopyroxene in them is less sodic than
omphacite Omphacite is a member of the clinopyroxene group of silicate minerals with formula: ( Ca, Na)( Mg, Fe2+, Al) Si2 O6. It is a variably deep to pale green or nearly colorless variety of clinopyroxene. It normally appears in eclogite, which is t ...
and the pyroxenite compositions typically are unlike that of
basalt Basalt (; ) is an aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the surface of a rocky planet or moon. More than 90 ...
. Pyroxenites might play an important role in basalt genesis (e.g., Lambart et al., 2016), either by contributing directly to the magma production, or indirectly as the result of reaction between peridotite and magma derived from partial melting of eclogite (e.g., Sobolev and others, 2007).


Pyroxenite lavas

Purely pyroxene-bearing volcanic rocks are rare, restricted to spinifex-textured
sill Sill may refer to: * Sill (dock), a weir at the low water mark retaining water within a dock * Sill (geology), a subhorizontal sheet intrusion of molten or solidified magma * Sill (geostatistics) * Sill (river), a river in Austria * Sill plate, ...
s, lava tubes and thick flows in the Archaean greenstone belts. Here, the pyroxenite lavas are created by in-situ crystallisation and accumulation of pyroxene at the base of a lava flow, creating the distinctive spinifex texture, but also occasionally mesocumulate and orthocumulate segregations. This is in essence similar to the formation of olivine spinifex textures in komatiite lava flows, the chemistry of the magma differing only to favor crystallisation of pyroxene. A type locality is the Gullewa Greenstone Belt, in the Murchison region of Western Australia, and the Duketon Belt near Laverton, where pyroxene spinifex lavas are closely associated with gold deposits.


Distribution

They frequently occur in the form of dikes or segregations in gabbro and peridotite: in Shetland, Cortland on the
Hudson River The Hudson River is a river that flows from north to south primarily through eastern New York. It originates in the Adirondack Mountains of Upstate New York and flows southward through the Hudson Valley to the New York Harbor between Ne ...
,
North Carolina North Carolina () is a U.S. state, state in the Southeastern United States, Southeastern region of the United States. The state is the List of U.S. states and territories by area, 28th largest and List of states and territories of the United ...
(websterite),
Baltimore Baltimore ( , locally: or ) is the most populous city in the U.S. state of Maryland, fourth most populous city in the Mid-Atlantic, and the 30th most populous city in the United States with a population of 585,708 in 2020. Baltimore was ...
,
New Zealand New Zealand ( mi, Aotearoa ) is an island country in the southwestern Pacific Ocean. It consists of two main landmasses—the North Island () and the South Island ()—and over 700 smaller islands. It is the sixth-largest island coun ...
, and in
Saxony Saxony (german: Sachsen ; Upper Saxon German, Upper Saxon: ''Saggsn''; hsb, Sakska), officially the Free State of Saxony (german: Freistaat Sachsen, links=no ; Upper Saxon: ''Freischdaad Saggsn''; hsb, Swobodny stat Sakska, links=no), is a ...
. They are also found in the Bushveld Igneous Complex in South Africa and The Great Dyke in Zimbabwe.Stratigraphy of the BIC http://jgs.lyellcollection.org/content/161/6/903/F2.large.jpg The pyroxenites are often subject serpentinization under low temperature retrograde metamorphism and
weathering Weathering is the deterioration of rocks, soils and minerals as well as wood and artificial materials through contact with water, atmospheric gases, and biological organisms. Weathering occurs '' in situ'' (on site, with little or no movement ...
. The rocks are often completely replaced by serpentines, which sometimes preserve the original structures of the primary minerals, such as the lamination of hypersthene and the rectangular cleavage of augite. Under pressure-metamorphism hornblende is developed and various types of
amphibolite Amphibolite () is a metamorphic rock that contains amphibole, especially hornblende and actinolite, as well as plagioclase feldspar, but with little or no quartz. It is typically dark-colored and dense, with a weakly foliated or schistose (flak ...
and hornblende- schist are produced. Occasionally rocks rich in pyroxene are found as basic facies of nepheline syenite; a good example is provided by the melanite pyroxenites associated with the ''borolanite'' variety found in the Loch Borralan igneous complex of
Scotland Scotland (, ) is a country that is part of the United Kingdom. Covering the northern third of the island of Great Britain, mainland Scotland has a border with England to the southeast and is otherwise surrounded by the Atlantic Ocean to ...
.


References


Lambart, S. L., and others, 2016, ''The role of pyroxenite in basalt genesis: Melt-PX, a melting parameterization for mantle pyroxenites between 0.9 and 5 GPa'', Journal of Geophysical Research - Solid Earth 121, p. 5708–5735Sobolev, A. V., and others, 2007, ''The amount of recycled crust in sources of mantle-derived melts'', Science 316, p. 412-417
(abstract) Retrieved on 6 October 2007


External links

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