A permanent marker or indelible marker is a type of

marker pen A marker pen, fine liner, marking pen, felt-tip pen, felt pen, flow marker, sign pen (in South Korea), vivid (in New Zealand), texta (in Australia), sketch pen (in South Asia) or koki (in South Africa), is a pen which has its own ink source ...

that is used to create permanent or semi-permanent writing on an object. In general, the ink comprises a main carrier solvent, a

glyceride Glycerides, more correctly known as acylglycerols, are esters formed from glycerol and fatty acids, and are generally very hydrophobic. Glycerol has three hydroxyl functional groups, which can be esterified with one, two, or three fatty acids ...

, a pyrrolidone, a

resin In polymer chemistry and materials science, resin is a solid or highly viscous substance of plant or synthetic origin that is typically convertible into polymers. Resins are usually mixtures of organic compounds. This article focuses on n ...

and a

colorant A colourant/colour additive (British spelling) or colorant/color additive (American spelling) is a substance that is added or applied in order to change the colour of a material or surface. Colourants can be used for many purposes including printing ...

, making it water resistant. It is capable of writing on a variety of surfaces from

paper Paper is a thin sheet material produced by mechanically or chemically processing cellulose fibres derived from wood, rags, grasses or other vegetable sources in water, draining the water through fine mesh leaving the fibre evenly distrib ...

metal A metal (from Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typicall ...

stone In geology, rock (or stone) is any naturally occurring solid mass or aggregate of minerals or mineraloid matter. It is categorized by the minerals included, its Chemical compound, chemical composition, and the way in which it is formed. Rocks ...

. They come in a variety of tip sizes (ultra fine to wide), shapes (chisel point, bullet tip, and wide bristle), and colors (metallic, or

ultraviolet Ultraviolet (UV) is a form of electromagnetic radiation with wavelength from 10 nm (with a corresponding frequency around 30 PHz) to 400 nm (750 THz), shorter than that of visible light, but longer than X-rays. UV radiation ...

reactive). Most markers have alcohol-based solvents. Other types, called paint markers, like

spray paint Aerosol paint (commonly spray paint) is paint that comes in a sealed, pressurized container and is released in an aerosol spray when a valve button is depressed. Aerosol painting is one form of spray painting; it leaves a smooth, even coat, unli ...

, contain

volatile organic compounds Volatile organic compounds (VOCs) are organic compounds that have a high vapour pressure at room temperature. High vapor pressure correlates with a low boiling point, which relates to the number of the sample's molecules in the surrounding air, a t ...

which evaporate to dry the ink. Due to compounds such as

toluene Toluene (), also known as toluol (), is a substituted aromatic hydrocarbon. It is a colorless, water-insoluble liquid with the smell associated with paint thinners. It is a mono-substituted benzene derivative, consisting of a methyl group (CH3) a ...

and

xylene In organic chemistry, xylene or xylol (; IUPAC name: dimethylbenzene) are any of three organic compounds with the formula . They are derived from the substitution of two hydrogen atoms with methyl groups in a benzene ring; which hydrogens are s ...

often being present in permanent markers, they have a potential for abuse as a recreational drug. The permanent marker was invented in 1952 by Sidney Rosenthal.

Applications

General purpose

They are used for writing on metals, plastics, ceramics, wood, stone, cardboard etc. However, the mark made by them is semi-permanent on some surfaces. Most permanent marker ink can be erased from some plastic surfaces (like

polypropylene Polypropylene (PP), also known as polypropene, is a thermoplastic polymer used in a wide variety of applications. It is produced via chain-growth polymerization from the monomer propylene. Polypropylene belongs to the group of polyolefins a ...

and

teflon Polytetrafluoroethylene (PTFE) is a synthetic fluoropolymer of tetrafluoroethylene that has numerous applications. It is one of the best-known and widely applied PFAS. The commonly known brand name of PTFE-based composition is Teflon by Chemo ...

) with little rubbing pressure. They can be used on ordinary paper, but the ink tends to bleed through and become visible on the other side.

Use in microscopy

In addition to being used for labelling microscopy slides, permanent markers can be used to do a negative stain of a bacterial sample. This means the background is stained with the marker, but the bacteria are not. The bacteria can be seen because they are unstained (lighter) while the background is stained (darker).

Removal

These markers are generally used on hard, non-porous surfaces, because instead of staining they form a surface layer that can be removed by high pressure cleaning,

paint thinner A paint thinner is a solvent used to thin oil-based paints. Solvents labeled "paint thinner" are usually mineral spirits having a flash point at about 40 °C (104 °F), the same as some popular brands of charcoal starter. Common solv ...

s or

organic solvents A solvent (s) (from the Latin '' solvō'', "loosen, untie, solve") is a substance that dissolves a solute, resulting in a solution. A solvent is usually a liquid but can also be a solid, a gas, or a supercritical fluid. Water is a solvent for p ...

such as

acetone Acetone (2-propanone or dimethyl ketone), is an organic compound with the formula . It is the simplest and smallest ketone (). It is a colorless, highly volatile and flammable liquid with a characteristic pungent odour. Acetone is miscib ...

, or

Isopropyl alcohol Isopropyl alcohol (IUPAC name propan-2-ol and also called isopropanol or 2-propanol) is a colorless, flammable organic compound with a pungent alcoholic odor. As an isopropyl group linked to a hydroxyl group ( chemical formula ) it is the s ...

ethanol Ethanol (abbr. EtOH; also called ethyl alcohol, grain alcohol, drinking alcohol, or simply alcohol) is an organic compound. It is an alcohol with the chemical formula . Its formula can be also written as or (an ethyl group linked to a ...

and

ethyl acetate Ethyl acetate ( systematically ethyl ethanoate, commonly abbreviated EtOAc, ETAC or EA) is the organic compound with the formula , simplified to . This colorless liquid has a characteristic sweet smell (similar to pear drops) and is used in glues ...

are preferred cleaners when used indoors, as their fumes are much less hazardous than toluene and xylene, the main components of

, or longer-chain hydrocarbons found in mineral spirits. Other common non-polar solvents include

benzene Benzene is an organic chemical compound with the molecular formula C6H6. The benzene molecule is composed of six carbon atoms joined in a planar ring with one hydrogen atom attached to each. Because it contains only carbon and hydrogen atoms ...

turpentine Turpentine (which is also called spirit of turpentine, oil of turpentine, terebenthene, terebinthine and (colloquially) turps) is a fluid obtained by the distillation of resin harvested from living trees, mainly pines. Mainly used as a spec ...

and other

terpene Terpenes () are a class of natural products consisting of compounds with the formula (C5H8)n for n > 1. Comprising more than 30,000 compounds, these unsaturated hydrocarbons are produced predominantly by plants, particularly conifers. Terpenes ...

s (which constitute essential oils of many plants with strong scents), most

ether In organic chemistry, ethers are a class of compounds that contain an ether group—an oxygen atom connected to two alkyl or aryl groups. They have the general formula , where R and R′ represent the alkyl or aryl groups. Ethers can again be ...

s, chloroform and dichloromethane,

hydrocarbon In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or ...

fuels, and diacetone alcohol, among many others. Most brands of "OLFA" marker wipe off easily with acetone free nail polish remover, the kind containing

, a relatively non-toxic organic solvent. A permanent marker can also be removed by drawing over it with a dry erase marker on non-porous surfaces such as a

whiteboard A whiteboard (also known by the terms marker board, dry-erase board, dry-wipe board, and pen-board) is a glossy, usually white surface for making non-permanent markings. Whiteboards are analogous to blackboards, but with a smoother surface all ...

as dry erase markers also contain a non-polar solvent. Most dry-erase board cleaner solutions also contain effective organic solvents like 2-butoxyethanol to erase the pigment.

Laws

Due to their potential to be used for

vandalism Vandalism is the action involving deliberate destruction of or damage to public or private property. The term includes property damage, such as graffiti and defacement directed towards any property without permission of the owner. The term ...

, some places, such as

Florida Florida is a state located in the Southeastern region of the United States. Florida is bordered to the west by the Gulf of Mexico, to the northwest by Alabama, to the north by Georgia, to the east by the Bahamas and Atlantic Ocean, and to ...

California California is a state in the Western United States, located along the Pacific Coast. With nearly 39.2million residents across a total area of approximately , it is the most populous U.S. state and the 3rd largest by area. It is also the m ...

New York City New York, often called New York City or NYC, is the most populous city in the United States. With a 2020 population of 8,804,190 distributed over , New York City is also the most densely populated major city in the Un ...

and

Berwyn, Illinois Berwyn is a suburban city in Cook County, Illinois, coterminous with Berwyn Township, Cook County, Illinois, Berwyn Civil township, Township, which was formed in 1908 after breaking off from Cicero Township, Cook County, Illinois, Cicero Townshi ...

, have laws against possessing permanent markers in public and prohibit sales of them to minors.

Applications

General purpose

Use in microscopy

Removal

Laws

Notes and references

See also