A paleoatmosphere (or ''palaeoatmosphere'') is an

atmosphere An atmosphere () is a layer of gas or layers of gases that envelop a planet, and is held in place by the gravity of the planetary body. A planet retains an atmosphere when the gravity is great and the temperature of the atmosphere is low. A s ...

, particularly that of

Earth Earth is the third planet from the Sun and the only astronomical object known to harbor life. While large volumes of water can be found throughout the Solar System, only Earth sustains liquid surface water. About 71% of Earth's surfa ...

, at some unspecified time in the geological past. The composition of Earth's paleoatmosphere can be inferred today from the study of the abundance of proxy materials such as

iron oxide Iron oxides are chemical compounds composed of iron and oxygen. Several iron oxides are recognized. All are black magnetic solids. Often they are non-stoichiometric. Oxyhydroxides are a related class of compounds, perhaps the best known of whic ...

s and

charcoal Charcoal is a lightweight black carbon residue produced by strongly heating wood (or other animal and plant materials) in minimal oxygen to remove all water and volatile constituents. In the traditional version of this pyrolysis process, cal ...

and the fossil data, such as the

stomata In botany, a stoma (from Greek ''στόμα'', "mouth", plural "stomata"), also called a stomate (plural "stomates"), is a pore found in the epidermis of leaves, stems, and other organs, that controls the rate of gas exchange. The pore is bor ...

l density of fossil leaves in geological deposits. Although today's atmosphere is dominated by

nitrogen Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at se ...

(about 78%),

oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as wel ...

(about 21%), and

argon Argon is a chemical element with the symbol Ar and atomic number 18. It is in group 18 of the periodic table and is a noble gas. Argon is the third-most abundant gas in Earth's atmosphere, at 0.934% (9340 ppmv). It is more than twice as abu ...

(about 1%), the pre-biological atmosphere is thought to have been a highly

reducing atmosphere A reducing atmosphere is an atmospheric condition in which oxidation is prevented by removal of oxygen and other oxidizing gases or vapours, and which may contain actively reducing gases such as hydrogen, carbon monoxide, and gases such as hydro ...

, having virtually no free oxygen, virtually no argon, which is generated by the

radioactive decay Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consid ...

of ⁴⁰ K, and to have been dominated by nitrogen,

carbon dioxide Carbon dioxide (chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is transpar ...

and

methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane on Eart ...

. Appreciable concentrations of free oxygen were probably not present until about 2,500 million years ago ( Ma). After the

Great Oxygenation Event The Great Oxidation Event (GOE), also called the Great Oxygenation Event, the Oxygen Catastrophe, the Oxygen Revolution, the Oxygen Crisis, or the Oxygen Holocaust, was a time interval during the Paleoproterozoic era when the Earth's atmosphere ...

, quantities of oxygen produced as a by-product of

photosynthesis Photosynthesis is a process used by plants and other organisms to convert light energy into chemical energy that, through cellular respiration, can later be released to fuel the organism's activities. Some of this chemical energy is stored i ...

cyanobacteria Cyanobacteria (), also known as Cyanophyta, are a phylum of gram-negative bacteria that obtain energy via photosynthesis. The name ''cyanobacteria'' refers to their color (), which similarly forms the basis of cyanobacteria's common name, blu ...

(sometimes erroneously referred to as blue-green algae) began to exceed the quantities of chemically reducing materials, notably dissolved iron. By the beginning of the

Cambrian The Cambrian Period ( ; sometimes symbolized C with bar, Ꞓ) was the first geological period of the Paleozoic Era, and of the Phanerozoic Eon. The Cambrian lasted 53.4 million years from the end of the preceding Ediacaran Period 538.8 million ...

period 541 Ma, free oxygen concentrations had increased sufficiently to enable the evolution of multicellular organisms. Following the subsequent appearance, rapid evolution and radiation of

land plants The Embryophyta (), or land plants, are the most familiar group of green plants that comprise vegetation on Earth. Embryophytes () have a common ancestor with green algae, having emerged within the Phragmoplastophyta clade of green algae as siste ...

, which covered much of the Earth's land surface, beginning about 450 Ma, oxygen concentrations reached and later exceeded current values (about 21%) during the early

Carboniferous The Carboniferous ( ) is a geologic period and system of the Paleozoic that spans 60 million years from the end of the Devonian Period million years ago ( Mya), to the beginning of the Permian Period, million years ago. The name ''Carbonifero ...

, when atmospheric carbon dioxide was drawn down below current concentrations (about 400 ppm) by

oxygenic photosynthesis Photosynthesis is a process used by plants and other organisms to convert light energy into chemical energy that, through cellular respiration, can later be released to fuel the organism's activities. Some of this chemical energy is stored in ...

. This may have contributed to the Carboniferous Rainforest Collapse during the Moscovian and

Kasimovian The Kasimovian is a geochronology, geochronologic age (geology), age or chronostratigraphy, chronostratigraphic stage (stratigraphy), stage in the International Commission on Stratigraphy, ICS geologic timescale. It is the third stage in the Penn ...

ages of the Pennsylvanian subperiod.

Indirect measurements

Geological studies of ancient rock formations can give information on paleoatmospheric composition, pressure, density, etc. at specific points in Earth's history.

Density and pressure

A 2012 study looked at the imprints made by falling raindrops onto freshly deposited

volcanic ash Volcanic ash consists of fragments of rock, mineral crystals, and volcanic glass, created during volcano, volcanic eruptions and measuring less than 2 mm (0.079 inches) in diameter. The term volcanic ash is also often loosely used t ...

, laid down in the

Archean The Archean Eon ( , also spelled Archaean or Archæan) is the second of four geologic eons of Earth's history, representing the time from . The Archean was preceded by the Hadean Eon and followed by the Proterozoic. The Earth Earth ...

Eon 2,700 Ma in the

Ventersdorp Ventersdorp is a town of 4,200 in Dr Kenneth Kaunda District Municipality, North West Province, South Africa. It was the seat of the defunct Ventersdorp Local Municipality until 2016. Ventersdorp is centrally located, making it easier to access m ...

Supergroup, South Africa. They linked the

terminal velocity Terminal velocity is the maximum velocity (speed) attainable by an object as it falls through a fluid (air is the most common example). It occurs when the sum of the drag force (''Fd'') and the buoyancy is equal to the downward force of gravit ...

of the raindrops directly to the

air density The density of air or atmospheric density, denoted '' ρ'', is the mass per unit volume of Earth's atmosphere. Air density, like air pressure, decreases with increasing altitude. It also changes with variation in atmospheric pressure, temperature a ...

of the paleoatmosphere and showed that it had less than twice the density of the modern atmosphere, and likely had similar if not lower density. A similar study in 2016 looked at the size distribution of gas bubbles in basaltic lava flows that solidified at sea level also during the Archean (~2,700 Ma). They found an atmospheric pressure of only 0.23 ± 0.23

bar Bar or BAR may refer to: Food and drink * Bar (establishment), selling alcoholic beverages * Candy bar * Chocolate bar Science and technology * Bar (river morphology), a deposit of sediment * Bar (tropical cyclone), a layer of cloud * Bar (u ...

(23 kPa). Both results contradict theories that suggest the Archean was kept warm during the Faint Young Sun period by extremely high levels of carbon dioxide or nitrogen.

Oxygen content

A 2016 study performed

mass spectrometry Mass spectrometry (MS) is an analytical technique that is used to measure the mass-to-charge ratio of ions. The results are presented as a ''mass spectrum'', a plot of intensity as a function of the mass-to-charge ratio. Mass spectrometry is use ...

on air bubbles trapped inside rock salt deposited 813 Myr ago. They detected an oxygen content of 10.9%, much higher than had been expected from indirect measures. This suggested the

Great Oxidation Event The Great Oxidation Event (GOE), also called the Great Oxygenation Event, the Oxygen Catastrophe, the Oxygen Revolution, the Oxygen Crisis, or the Oxygen Holocaust, was a time interval during the Paleoproterozoic era when the Earth's atmosphere ...

may have happened much earlier than previously thought.

References

{{reflist Geological history of Earth Paleoclimatology

Indirect measurements

Density and pressure

Oxygen content

See also

References