oxidizing and reducing flames
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In pyrology,
flame A flame (from Latin '' flamma'') is the visible, gaseous part of a fire. It is caused by a highly exothermic chemical reaction taking place in a thin zone. When flames are hot enough to have ionized gaseous components of sufficient density the ...
s are affected by the fuel introduced and the
oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements ...
available. A flame with a good oxygen-fuel ratio is called a neutral flame. The color of the flame is semi-transparent purple or blue. This flame is optimal for all intentions, because it does not oxidize or get soot onto surfaces.


Oxidizing Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a d ...
flame

If the flame has too much oxygen, an oxidizing flame is produced. When the amount of oxygen increases, the flame shortens due to quicker combustion, its color becomes a more transparent blue, and it hisses/roars."The Anatomy of a Flame"
in: "Jewelry concepts and technology", by Oppi Untracht, 1983,
With some exceptions (e.g., platinum
soldering Soldering (; ) is a process in which two or more items are joined by melting and putting a filler metal ( solder) into the joint, the filler metal having a lower melting point than the adjoining metal. Unlike welding, soldering does not inv ...
in
jewelry Jewellery ( UK) or jewelry ( U.S.) consists of decorative items worn for personal adornment, such as brooches, rings, necklaces, earrings, pendants, bracelets, and cufflinks. Jewellery may be attached to the body or the clothes. From a w ...
), the oxidizing flame is usually undesirable for
welding Welding is a fabrication process that joins materials, usually metals or thermoplastics, by using high heat to melt the parts together and allowing them to cool, causing fusion. Welding is distinct from lower temperature techniques such as b ...
and soldering, since, as its name suggests, it oxidizes the metal's surface. The same principle is important in firing
pottery Pottery is the process and the products of forming vessels and other objects with clay and other ceramic materials, which are fired at high temperatures to give them a hard and durable form. Major types include earthenware, stoneware and ...
.


Reducing flame

A reducing flame is a flame with insufficient oxygen. It has a opaque yellow or orange color due to
carbon Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent—its atom making four electrons available to form covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon ma ...
or
hydrocarbon In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or ...
s which bind with (or reduce) the oxygen contained in the materials the flame processes. The flame is also called carburizing flame, since it tends to introduce carbon soot into the molten metal. The flame also produces
carbon monoxide Carbon monoxide ( chemical formula CO) is a colorless, poisonous, odorless, tasteless, flammable gas that is slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the simpl ...
, a toxic gas.


Reducing flames with no carbon

Reducing zero-carbon fuel flames, such as reducing hydrogen flames, are exceptions. They don't have an opaque yellow or orange glow, nor do they produce soot or carbon monoxide. This is because these flames do not produce
carbon dioxide Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is t ...
.


See also

* for further details about the above types of flame in oxy-fuel burners *
Oxyhydrogen Oxyhydrogen is a mixture of hydrogen (H2) and oxygen (O2) gases. This gaseous mixture is used for torches to process refractory materials and was the first gaseous mixture used for welding. Theoretically, a ratio of 2:1 hydrogen:oxygen is enough ...
*
Redox Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or ...
*
Oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements ...
*
Flame test A flame test is an analytical procedure used in chemistry to detect the presence of certain elements, primarily metal ions, based on each element's characteristic flame emission spectrum (which may be affected by the presence of chloride io ...
* Spark testing


References

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