Ooids are small (commonly ≤2 mm in diameter), spheroidal, "coated" (layered)
sedimentary
Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particles ...
grains, usually composed of
calcium carbonate, but sometimes made up of
iron
Iron () is a chemical element with Symbol (chemistry), symbol Fe (from la, Wikt:ferrum, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 element, group 8 of the periodic table. It is, Abundanc ...
- or
phosphate
In chemistry, a phosphate is an anion, salt, functional group or ester derived from a phosphoric acid. It most commonly means orthophosphate, a derivative of orthophosphoric acid .
The phosphate or orthophosphate ion is derived from phosph ...
-based minerals. Ooids usually form on the
sea floor, most commonly in shallow tropical seas (around the
Bahamas
The Bahamas (), officially the Commonwealth of The Bahamas, is an island country within the Lucayan Archipelago of the West Indies in the North Atlantic. It takes up 97% of the Lucayan Archipelago's land area and is home to 88% of the ar ...
, for example, or in the
Persian Gulf
The Persian Gulf ( fa, خلیج فارس, translit=xalij-e fârs, lit=Gulf of Fars, ), sometimes called the ( ar, اَلْخَلِيْجُ ٱلْعَرَبِيُّ, Al-Khalīj al-ˁArabī), is a mediterranean sea in Western Asia. The bod ...
). After being buried under additional
sediment
Sediment is a naturally occurring material that is broken down by processes of weathering and erosion, and is subsequently transported by the action of wind, water, or ice or by the force of gravity acting on the particles. For example, sa ...
, these ooid grains can be cemented together to form a
sedimentary rock
Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particles ...
called an ''
oolite''. Oolites usually consist of calcium carbonate; these belong to the
limestone
Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms whe ...
rock family.
Pisoids are similar to ooids, but are larger than 2 mm in diameter, often considerably larger, as with the pisoids in the hot springs at Carlsbad (
Karlovy Vary) in the
Czech Republic
The Czech Republic, or simply Czechia, is a landlocked country in Central Europe. Historically known as Bohemia, it is bordered by Austria to the south, Germany to the west, Poland to the northeast, and Slovakia to the southeast. The ...
.
Formation
An ooid forms as a series of concentric layers around a nucleus. The layers contain crystals arranged radially, tangentially or randomly. The nucleus can be a shell fragment, quartz grain or any other small fragment. Most modern ooids are
aragonite
Aragonite is a carbonate mineral, one of the three most common naturally occurring crystal forms of calcium carbonate, (the other forms being the minerals calcite and vaterite). It is formed by biological and physical processes, including pre ...
, a
polymorph of calcium carbonate; some are composed of high-magnesium
calcite, and some are bimineralic (layers of calcite and aragonite). Ancient ooids can be calcitic, either originally precipitated as calcite (as in
calcite seas), or formed by alteration (neomorphic replacement) of
aragonitic ooids (or the aragonite layers in originally bimineralic ooids). Moldic ooids (or molds later filled in by calcite cement) occur in both young and ancient rocks, indicating the removal of a soluble polymorph (usually aragonite).
Variation
Whether ooids become calcitic or aragonitic can be linked to
strontium/
calcium
Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar t ...
substitution within the
crystalline structure
In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions or molecules in a crystalline material. Ordered structures occur from the intrinsic nature of the constituent particles to form symmetric patterns t ...
. This has been shown in some examples to be due to temperature fluctuations in
marine environment
Marine habitats are habitats that support marine life. Marine life depends in some way on the saltwater that is in the sea (the term ''marine'' comes from the Latin ''mare'', meaning sea or ocean). A habitat is an ecological or environmental ...
s, which affects
salinity levels, which in turn facilitate the substitution. Marine calcitic ooids were typically formed during
calcite sea intervals, especially during the
Ordovician
The Ordovician ( ) is a geologic period and system, the second of six periods of the Paleozoic Era. The Ordovician spans 41.6 million years from the end of the Cambrian Period million years ago (Mya) to the start of the Silurian Period Mya.
T ...
and the
Jurassic
The Jurassic ( ) is a geologic period and stratigraphic system that spanned from the end of the Triassic Period million years ago (Mya) to the beginning of the Cretaceous Period, approximately Mya. The Jurassic constitutes the middle period of ...
Periods. The geochemistry of these seas was a function of
seafloor spreading
Seafloor spreading or Seafloor spread is a process that occurs at mid-ocean ridges, where new oceanic crust is formed through volcanic activity and then gradually moves away from the ridge.
History of study
Earlier theories by Alfred Wegener a ...
and fluctuating Mg/Ca ratios. Low Mg/Ca ratios favor the precipitation of low-magnesium calcite.
Growth mode
Ooids with radial crystals (such as the aragonitic ooids in the
Great Salt Lake, Utah, US) grow by ions extending the lattices of the radial crystals. The mode of growth of ooids with tangential (usually minute needle-like) crystals is less clear. They may be accumulated in a "snowball" fashion from tiny crystals in the sediment or water, or they may crystallize in place on the ooid surface. A hypothesis of growth by accretion (like a snowball) from the polymineralic sediment of fine aragonite, high-magnesium calcite (HMC) and low-magnesium calcite (LMC), must explain how only aragonite needles are added to the ooid cortex. Both in tangential and in radial ooids, the cortex is composed of many very fine increments of growth. Some modern (and ancient) ooids partially or totally lack clear layering and have a micritic (very fine grained) texture. Examination of such micritic ooids by scanning electron microscopy often shows evidence of microbial borings later filled by fine cement.
Growth factors
There are several factors that affect ooid growth:
supersaturation of the water with respect to calcium carbonate, the availability of nuclei, agitation of the ooids, water depth, and the role of
microbes
A microorganism, or microbe,, ''mikros'', "small") and ''organism'' from the el, ὀργανισμός, ''organismós'', "organism"). It is usually written as a single word but is sometimes hyphenated (''micro-organism''), especially in olde ...
.
Ooimmuration
Sometimes
fossils are included in ooids, often forming the nuclei. This
taphonomic process is termed ''ooimmuration'' (Wilson et al., 2021). The formation of the ooid cortex around the test or shell protects it from abrasion, fragmentation and bioerosion. Ooimmuration also retains fine organic remains that would ordinarily be winnowed away by currents.
References
Flügel, Erik (2010),
Microfacies of Carbonate Rocks: Analysis, Interpretation and Application', 2nd ed.
Springer pp. 242–244. . Accessed 2014-06-23.
Wilson, M.A., Cooke, A.M., Judge, S.A. and Palmer, T.J. 2021. Ooimmuration: Enhanced fossil preservation by ooids, with examples from the Middle Jurassic of southwestern Utah, USA. ''Palaios'' 36: 326-329. https://doi.org/10.2110/palo.2021.036
External links
*{{webarchive , url=https://web.archive.org/web/20130620192517/http://www.geologyrocks.co.uk/tutorials/ooid_formation , date=20 June 2013 , title= Ooid Formation
Sedimentary rocks
Limestone
Petrology