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The nuclear fuel cycle, also called nuclear fuel chain, is the progression of
nuclear fuel Nuclear fuel is material used in nuclear power stations to produce heat to power turbines. Heat is created when nuclear fuel undergoes nuclear fission. Most nuclear fuels contain heavy fissile actinide elements that are capable of undergo ...
through a series of differing stages. It consists of steps in the ''front end'', which are the preparation of the fuel, steps in the ''service period'' in which the fuel is used during reactor operation, and steps in the ''back end'', which are necessary to safely manage, contain, and either reprocess or dispose of
spent nuclear fuel Spent nuclear fuel, occasionally called used nuclear fuel, is nuclear fuel that has been irradiated in a nuclear reactor (usually at a nuclear power plant). It is no longer useful in sustaining a nuclear reaction in an ordinary thermal reactor and ...
. If spent fuel is not reprocessed, the fuel cycle is referred to as an ''open fuel cycle'' (or a ''once-through fuel cycle''); if the spent fuel is reprocessed, it is referred to as a ''closed fuel cycle''.


Basic concepts

Nuclear power Nuclear power is the use of nuclear reactions to produce electricity. Nuclear power can be obtained from nuclear fission, nuclear decay and nuclear fusion reactions. Presently, the vast majority of electricity from nuclear power is produced b ...
relies on fissionable material that can sustain a
chain reaction A chain reaction is a sequence of reactions where a reactive product or by-product causes additional reactions to take place. In a chain reaction, positive feedback leads to a self-amplifying chain of events. Chain reactions are one way that sys ...
with
neutron The neutron is a subatomic particle, symbol or , which has a neutral (not positive or negative) charge, and a mass slightly greater than that of a proton. Protons and neutrons constitute the atomic nucleus, nuclei of atoms. Since protons and ...
s. Examples of such materials include
uranium Uranium is a chemical element with the symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium is weak ...
and
plutonium Plutonium is a radioactive chemical element with the symbol Pu and atomic number 94. It is an actinide metal of silvery-gray appearance that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exh ...
. Most nuclear reactors use a moderator to lower the
kinetic energy In physics, the kinetic energy of an object is the energy that it possesses due to its motion. It is defined as the work needed to accelerate a body of a given mass from rest to its stated velocity. Having gained this energy during its acce ...
of the neutrons and increase the probability that fission will occur. This allows reactors to use material with far lower concentration of
fissile In nuclear engineering, fissile material is material capable of sustaining a nuclear fission chain reaction. By definition, fissile material can sustain a chain reaction with neutrons of thermal energy. The predominant neutron energy may be t ...
isotopes Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers ( mass numbers ...
than are needed for
nuclear weapon A nuclear weapon is an explosive device that derives its destructive force from nuclear reactions, either fission (fission bomb) or a combination of fission and fusion reactions ( thermonuclear bomb), producing a nuclear explosion. Both bomb ...
s.
Graphite Graphite () is a crystalline form of the element carbon. It consists of stacked layers of graphene. Graphite occurs naturally and is the most stable form of carbon under standard conditions. Synthetic and natural graphite are consumed on la ...
and heavy water are the most effective moderators, because they slow the neutrons through collisions without absorbing them. Reactors using heavy water or graphite as the moderator can operate using
natural uranium Natural uranium (NU or Unat) refers to uranium with the same isotopic ratio as found in nature. It contains 0.711% uranium-235, 99.284% uranium-238, and a trace of uranium-234 by weight (0.0055%). Approximately 2.2% of its radioactivity comes ...
. A
light water reactor The light-water reactor (LWR) is a type of thermal-neutron reactor that uses normal water, as opposed to heavy water, as both its coolant and neutron moderator; furthermore a solid form of fissile elements is used as fuel. Thermal-neutron react ...
(LWR) uses water in the form that occurs in nature, and requires fuel enriched to higher concentrations of fissile isotopes. Typically, LWRs use uranium enriched to 3–5% U-235, the only fissile isotope that is found in significant quantity in nature. One alternative to this low-enriched uranium (LEU) fuel is
mixed oxide In chemistry, a mixed oxide is a somewhat informal name for an oxide that contains cations of more than one chemical element or cations of a single element in several states of oxidation.Advanced Inorganic Chemistry, F. A. Cotton, G. Wilkinson ...
(MOX) fuel produced by blending plutonium with natural or depleted uranium, and these fuels provide an avenue to utilize surplus
weapons-grade Weapons-grade nuclear material is any fissionable nuclear material that is pure enough to make a nuclear weapon or has properties that make it particularly suitable for nuclear weapons use. Plutonium and uranium in grades normally used in nucle ...
plutonium. Another type of MOX fuel involves mixing LEU with
thorium Thorium is a weakly radioactive metallic chemical element with the symbol Th and atomic number 90. Thorium is silvery and tarnishes black when it is exposed to air, forming thorium dioxide; it is moderately soft and malleable and has a high ...
, which generates the fissile isotope U-233. Both plutonium and U-233 are produced from the absorption of neutrons by irradiating
fertile material Fertile material is a material that, although not itself fissionable by thermal neutrons, can be converted into a fissile material by neutron absorption and subsequent nuclei conversions. Naturally occurring fertile materials Naturally occurring ...
s in a reactor, in particular the common uranium isotope U-238 and
thorium Thorium is a weakly radioactive metallic chemical element with the symbol Th and atomic number 90. Thorium is silvery and tarnishes black when it is exposed to air, forming thorium dioxide; it is moderately soft and malleable and has a high ...
, respectively, and can be separated from spent uranium and thorium fuels in reprocessing plants. Some reactors do not use moderators to slow the neutrons. Like nuclear weapons, which also use unmoderated or "fast" neutrons, these
fast-neutron reactor A fast-neutron reactor (FNR) or fast-spectrum reactor or simply a fast reactor is a category of nuclear reactor in which the fission chain reaction is sustained by fast neutrons (carrying energies above 1 MeV or greater, on average), as oppose ...
s require much higher concentrations of fissile isotopes in order to sustain a chain reaction. They are also capable of
breeding Breeding is sexual reproduction that produces offspring, usually animals or plants. It can only occur between a male and a female animal or plant. Breeding may refer to: * Animal husbandry, through selected specimens such as dogs, horses, and r ...
fissile isotopes from fertile materials; a
breeder reactor A breeder reactor is a nuclear reactor that generates more fissile material than it consumes. Breeder reactors achieve this because their neutron economy is high enough to create more fissile fuel than they use, by irradiation of a fertile mate ...
is one that generates more fissile material in this way than it consumes. During the nuclear reaction inside a reactor, the fissile isotopes in nuclear fuel are consumed, producing more and more
fission products Nuclear fission products are the atomic fragments left after a large atomic nucleus undergoes nuclear fission. Typically, a large nucleus like that of uranium fissions by splitting into two smaller nuclei, along with a few neutrons, the release ...
, most of which are considered
radioactive waste Radioactive waste is a type of hazardous waste that contains radioactive material. Radioactive waste is a result of many activities, including nuclear medicine, nuclear research, nuclear power generation, rare-earth mining, and nuclear weapon ...
. The buildup of fission products and consumption of fissile isotopes eventually stop the nuclear reaction, causing the fuel to become a
spent nuclear fuel Spent nuclear fuel, occasionally called used nuclear fuel, is nuclear fuel that has been irradiated in a nuclear reactor (usually at a nuclear power plant). It is no longer useful in sustaining a nuclear reaction in an ordinary thermal reactor and ...
. When 3% enriched LEU fuel is used, the spent fuel typically consists of roughly 1% U-235, 95% U-238, 1% plutonium and 3% fission products. Spent fuel and other high-level radioactive waste is extremely hazardous, although nuclear reactors produce orders of magnitude smaller volumes of waste compared to other power plants because of the high energy density of nuclear fuel. Safe management of these byproducts of nuclear power, including their storage and disposal, is a difficult problem for any country using nuclear power.


Front end

Image:Uranium ore square.jpg, 1
Uranium ore Uranium ore deposits are economically recoverable concentrations of uranium within the Earth's crust. Uranium is one of the more common elements in the Earth's crust, being 40 times more common than silver and 500 times more common than gold. It ...
– the principal raw material of nuclear fuel Image:Yellowcake.jpg, 2
Yellowcake Yellowcake (also called urania) is a type of uranium concentrate powder obtained from leach solutions, in an intermediate step in the processing of uranium ores. It is a step in the processing of uranium after it has been mined but before f ...
– the form in which uranium is transported to a conversion plant Image:UF6 square.jpg, 3 UF6 – used in enrichment Image:Nuclear fuel pellets.jpeg, 4
Nuclear fuel Nuclear fuel is material used in nuclear power stations to produce heat to power turbines. Heat is created when nuclear fuel undergoes nuclear fission. Most nuclear fuels contain heavy fissile actinide elements that are capable of undergo ...
– a compact, inert, insoluble solid


Exploration

A deposit of uranium, such as
uraninite Uraninite, formerly pitchblende, is a radioactive, uranium-rich mineral and ore with a chemical composition that is largely UO2 but because of oxidation typically contains variable proportions of U3O8. Radioactive decay of the uranium causes ...
, discovered by geophysical techniques, is evaluated and sampled to determine the amounts of uranium materials that are extractable at specified costs from the deposit. Uranium reserves are the amounts of ore that are estimated to be recoverable at stated costs. Naturally occurring uranium consists primarily of two isotopes U-238 and U-235, with 99.28% of the metal being U-238 while 0.71% is U-235, and the remaining 0.01% is mostly U-234. The number in such names refers to the
isotope Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers ( mass num ...
's atomic
mass number The mass number (symbol ''A'', from the German word ''Atomgewicht'' tomic weight, also called atomic mass number or nucleon number, is the total number of protons and neutrons (together known as nucleons) in an atomic nucleus. It is approxima ...
, which is the number of
proton A proton is a stable subatomic particle, symbol , H+, or 1H+ with a positive electric charge of +1 ''e'' elementary charge. Its mass is slightly less than that of a neutron and 1,836 times the mass of an electron (the proton–electron mass ...
s plus the number of
neutron The neutron is a subatomic particle, symbol or , which has a neutral (not positive or negative) charge, and a mass slightly greater than that of a proton. Protons and neutrons constitute the atomic nucleus, nuclei of atoms. Since protons and ...
s in the
atomic nucleus The atomic nucleus is the small, dense region consisting of protons and neutrons at the center of an atom, discovered in 1911 by Ernest Rutherford based on the 1909 Geiger–Marsden gold foil experiment. After the discovery of the neutron ...
. The atomic nucleus of U-235 will nearly always fission when struck by a
free neutron The neutron is a subatomic particle, symbol or , which has a neutral (not positive or negative) charge, and a mass slightly greater than that of a proton. Protons and neutrons constitute the nuclei of atoms. Since protons and neutrons behave ...
, and the isotope is therefore said to be a "
fissile In nuclear engineering, fissile material is material capable of sustaining a nuclear fission chain reaction. By definition, fissile material can sustain a chain reaction with neutrons of thermal energy. The predominant neutron energy may be t ...
" isotope. The nucleus of a U-238 atom on the other hand, rather than undergoing fission when struck by a free neutron, will nearly always absorb the neutron and yield an atom of the isotope U-239. This isotope then undergoes natural radioactive decay to yield Pu-239, which, like U-235, is a fissile isotope. The atoms of U-238 are said to be fertile, because, through neutron irradiation in the core, some eventually yield atoms of fissile Pu-239.


Mining

Uranium ore can be extracted through conventional mining in open pit and underground methods similar to those used for mining other metals.
In-situ leach In-situ leaching (ISL), also called in-situ recovery (ISR) or solution mining, is a mining process used to recover minerals such as copper and uranium through boreholes drilled into a deposit, ''in situ''. In situ leach works by artificially disso ...
mining Mining is the extraction of valuable minerals or other geological materials from the Earth, usually from an ore body, lode, vein, seam, reef, or placer deposit. The exploitation of these deposits for raw material is based on the econom ...
methods also are used to mine uranium in the
United States The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country Continental United States, primarily located in North America. It consists of 50 U.S. state, states, a Washington, D.C., ...
. In this technology, uranium is leached from the in-place ore through an array of regularly spaced wells and is then recovered from the leach solution at a surface plant. Uranium ores in the United States typically range from about 0.05 to 0.3% uranium oxide (U3O8). Some uranium deposits developed in other countries are of higher grade and are also larger than deposits mined in the United States. Uranium is also present in very low-grade amounts (50 to 200 parts per million) in some domestic
phosphate In chemistry, a phosphate is an anion, salt, functional group or ester derived from a phosphoric acid. It most commonly means orthophosphate, a derivative of orthophosphoric acid . The phosphate or orthophosphate ion is derived from phosph ...
-bearing deposits of marine origin. Because very large quantities of phosphate-bearing rock are mined for the production of wet-process
phosphoric acid Phosphoric acid (orthophosphoric acid, monophosphoric acid or phosphoric(V) acid) is a colorless, odorless phosphorus-containing solid, and inorganic compound with the chemical formula . It is commonly encountered as an 85% aqueous solution, w ...
used in high analysis
fertilizer A fertilizer (American English) or fertiliser (British English; see spelling differences) is any material of natural or synthetic origin that is applied to soil or to plant tissues to supply plant nutrients. Fertilizers may be distinct from ...
s and other phosphate chemicals, at some phosphate processing plants the uranium, although present in very low concentrations, can be economically recovered from the process stream.


Milling

Mined uranium ores normally are processed by grinding the ore materials to a uniform particle size and then treating the ore to extract the uranium by chemical leaching. The milling process commonly yields dry powder-form material consisting of natural uranium, "
yellowcake Yellowcake (also called urania) is a type of uranium concentrate powder obtained from leach solutions, in an intermediate step in the processing of uranium ores. It is a step in the processing of uranium after it has been mined but before f ...
", which is sold on the uranium market as U3O8. Note that the material isn't always yellow.


Uranium conversion

Usually milled uranium oxide, U3O8 ( triuranium octoxide) is then processed into either of two substances depending on the intended use. For use in most reactors, U3O8 is usually converted to uranium hexafluoride (UF6), the input stock for most commercial uranium enrichment facilities. A solid at room temperature, uranium hexafluoride becomes gaseous at 57 °C (134 °F). At this stage of the cycle, the uranium hexafluoride conversion product still has the natural isotopic mix (99.28% of U-238 plus 0.71% of U-235). For use in reactors such as
CANDU The CANDU (Canada Deuterium Uranium) is a Canadian pressurized heavy-water reactor design used to generate electric power. The acronym refers to its deuterium oxide ( heavy water) moderator and its use of (originally, natural) uranium fuel. C ...
which do not require enriched fuel, the U3O8 may instead be converted to
uranium dioxide Uranium dioxide or uranium(IV) oxide (), also known as urania or uranous oxide, is an oxide of uranium, and is a black, radioactive, crystalline powder that naturally occurs in the mineral uraninite. It is used in nuclear fuel rods in nuclear re ...
(UO2) which can be included in
ceramic A ceramic is any of the various hard, brittle, heat-resistant and corrosion-resistant materials made by shaping and then firing an inorganic, nonmetallic material, such as clay, at a high temperature. Common examples are earthenware, porcelain, ...
fuel elements. In the current nuclear industry, the volume of material converted directly to UO2 is typically quite small compared to that converted to UF6.


Enrichment

The natural concentration (0.71%) of the fissionable isotope U-235 is less than that required to sustain a nuclear chain reaction in
light water reactor The light-water reactor (LWR) is a type of thermal-neutron reactor that uses normal water, as opposed to heavy water, as both its coolant and neutron moderator; furthermore a solid form of fissile elements is used as fuel. Thermal-neutron react ...
cores. Accordingly, UF6 produced from natural uranium sources must be enriched to a higher concentration of the fissionable isotope before being used as nuclear fuel in such reactors. The level of enrichment for a particular nuclear fuel order is specified by the customer according to the application they will use it for: light-water reactor fuel normally is enriched to 3.5% U-235, but uranium enriched to lower concentrations is also required. Enrichment is accomplished using any of several methods of
isotope separation Isotope separation is the process of concentrating specific isotopes of a chemical element by removing other isotopes. The use of the nuclides produced is varied. The largest variety is used in research (e.g. in chemistry where atoms of "marker" ...
. Gaseous diffusion and
gas centrifuge A gas centrifuge is a device that performs isotope separation of gases. A centrifuge relies on the principles of centrifugal force accelerating molecules so that particles of different masses are physically separated in a gradient along the radiu ...
are the commonly used uranium enrichment methods, but new enrichment technologies are currently being developed. The bulk (96%) of the byproduct from enrichment is
depleted uranium Depleted uranium (DU; also referred to in the past as Q-metal, depletalloy or D-38) is uranium with a lower content of the fissile isotope than natural uranium.: "Depleted uranium possesses only 60% of the radioactivity of natural uranium, hav ...
(DU), which can be used for
armor Armour (British English) or armor (American English; see spelling differences) is a covering used to protect an object, individual, or vehicle from physical injury or damage, especially direct contact weapons or projectiles during combat, or f ...
,
kinetic energy penetrator A kinetic energy penetrator (KEP), also known as long-rod penetrator (LRP), is a type of ammunition designed to penetrate vehicle armour using a flechette-like, high- sectional density projectile. Like a bullet or kinetic energy weapon, thi ...
s,
radiation shielding Radiation protection, also known as radiological protection, is defined by the International Atomic Energy Agency (IAEA) as "The protection of people from harmful effects of exposure to ionizing radiation, and the means for achieving this". Exposur ...
and
ballast Ballast is material that is used to provide stability to a vehicle or structure. Ballast, other than cargo, may be placed in a vehicle, often a ship or the gondola of a balloon or airship, to provide stability. A compartment within a boat, ship ...
. As of 2008 there are vast quantities of depleted uranium in storage. The
United States Department of Energy The United States Department of Energy (DOE) is an executive department of the U.S. federal government that oversees U.S. national energy policy and manages the research and development of nuclear power and nuclear weapons in the United States ...
alone has 470,000
tonne The tonne ( or ; symbol: t) is a unit of mass equal to 1000  kilograms. It is a non-SI unit accepted for use with SI. It is also referred to as a metric ton to distinguish it from the non-metric units of the short ton ( United State ...
s. About 95% of depleted uranium is stored as uranium hexafluoride (UF6).


Fabrication

For use as nuclear fuel, enriched uranium hexafluoride is converted into
uranium dioxide Uranium dioxide or uranium(IV) oxide (), also known as urania or uranous oxide, is an oxide of uranium, and is a black, radioactive, crystalline powder that naturally occurs in the mineral uraninite. It is used in nuclear fuel rods in nuclear re ...
(UO2) powder that is then processed into pellet form. The pellets are then fired in a high temperature
sintering Clinker nodules produced by sintering Sintering or frittage is the process of compacting and forming a solid mass of material by pressure or heat without melting it to the point of liquefaction. Sintering happens as part of a manufacturing ...
furnace to create hard,
ceramic A ceramic is any of the various hard, brittle, heat-resistant and corrosion-resistant materials made by shaping and then firing an inorganic, nonmetallic material, such as clay, at a high temperature. Common examples are earthenware, porcelain, ...
pellets of
enriched uranium Enriched uranium is a type of uranium in which the percent composition of uranium-235 (written 235U) has been increased through the process of isotope separation. Naturally occurring uranium is composed of three major isotopes: uranium-238 (238U ...
. The cylindrical pellets then undergo a grinding process to achieve a uniform pellet size. The pellets are stacked, according to each
nuclear reactor core A nuclear reactor core is the portion of a nuclear reactor containing the nuclear fuel components where the nuclear reactions take place and the heat is generated. Typically, the fuel will be low- enriched uranium contained in thousands of ind ...
's design specifications, into tubes of corrosion-resistant metal
alloy An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductili ...
. The tubes are sealed to contain the fuel pellets: these tubes are called fuel rods. The finished fuel rods are grouped in special fuel assemblies that are then used to build up the nuclear fuel core of a power reactor. The alloy used for the tubes depends on the design of the reactor.
Stainless steel Stainless steel is an alloy of iron that is resistant to rusting and corrosion. It contains at least 11% chromium and may contain elements such as carbon, other nonmetals and metals to obtain other desired properties. Stainless steel's r ...
was used in the past, but most reactors now use a
zirconium alloy Zirconium alloys are solid solutions of zirconium or other metals, a common subgroup having the trade mark Zircaloy. Zirconium has very low absorption cross-section of thermal neutrons, high hardness, ductility and corrosion resistance. One of th ...
. For the most common types of reactors,
boiling water reactor A boiling water reactor (BWR) is a type of light water nuclear reactor used for the generation of electrical power. It is a design different from a Soviet graphite-moderated RBMK. It is the second most common type of electricity-generating nu ...
s (BWR) and
pressurized water reactor A pressurized water reactor (PWR) is a type of light-water nuclear reactor. PWRs constitute the large majority of the world's nuclear power plants (with notable exceptions being the UK, Japan and Canada). In a PWR, the primary coolant (water) i ...
s (PWR), the tubes are assembled into bundles with the tubes spaced precise distances apart. These bundles are then given a unique identification number, which enables them to be tracked from manufacture through use and into disposal.


Service period


Transport of radioactive materials

Transport Transport (in British English), or transportation (in American English), is the intentional movement of humans, animals, and goods from one location to another. Modes of transport include air, land ( rail and road), water, cable, pipelin ...
is an integral part of the nuclear fuel cycle. There are nuclear power reactors in operation in several countries but uranium mining is viable in only a few areas. Also, in the course of over forty years of operation by the nuclear industry, a number of specialized facilities have been developed in various locations around the world to provide fuel cycle services and there is a need to transport nuclear materials to and from these facilities. Most transports of
nuclear fuel Nuclear fuel is material used in nuclear power stations to produce heat to power turbines. Heat is created when nuclear fuel undergoes nuclear fission. Most nuclear fuels contain heavy fissile actinide elements that are capable of undergo ...
material occur between different stages of the cycle, but occasionally a material may be transported between similar facilities. With some exceptions, nuclear fuel cycle materials are transported in solid form, the exception being uranium hexafluoride (UF6) which is considered a gas. Most of the material used in nuclear fuel is transported several times during the cycle. Transports are frequently international, and are often over large distances. Nuclear materials are generally transported by specialized transport companies. Since nuclear materials are
radioactive Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consi ...
, it is important to ensure that radiation exposure of those involved in the transport of such materials and of the general public along transport routes is limited. Packaging for nuclear materials includes, where appropriate, shielding to reduce potential radiation exposures. In the case of some materials, such as fresh uranium fuel assemblies, the radiation levels are negligible and no shielding is required. Other materials, such as spent fuel and high-level waste, are highly radioactive and require special handling. To limit the risk in transporting highly radioactive materials, containers known as
spent nuclear fuel shipping cask A nuclear flask is a shipping container that is used to transport active nuclear materials between nuclear power station and spent fuel reprocessing facilities. Each shipping container is designed to maintain its integrity under normal transport ...
s are used which are designed to maintain integrity under normal transportation conditions and during hypothetical accident conditions.


In-core fuel management

A
nuclear reactor core A nuclear reactor core is the portion of a nuclear reactor containing the nuclear fuel components where the nuclear reactions take place and the heat is generated. Typically, the fuel will be low- enriched uranium contained in thousands of ind ...
is composed of a few hundred "assemblies", arranged in a regular array of cells, each cell being formed by a fuel or control rod surrounded, in most designs, by a moderator and
coolant A coolant is a substance, typically liquid, that is used to reduce or regulate the temperature of a system. An ideal coolant has high thermal capacity, low viscosity, is low-cost, non-toxic, chemically inert and neither causes nor promotes corrosi ...
, which is water in most reactors. Because of the fission process that consumes the fuels, the old fuel rods must be replaced periodically with fresh ones (this is called a (replacement) cycle). During a given replacement cycle only some of the assemblies (typically one-third) are replaced since fuel depletion occurs at different rates at different places within the reactor core. Furthermore, for efficiency reasons, it is not a good policy to put the new assemblies exactly at the location of the removed ones. Even bundles of the same age will have different burn-up levels due to their previous positions in the core. Thus the available bundles must be arranged in such a way that the yield is maximized, while safety limitations and operational constraints are satisfied. Consequently, reactor operators are faced with the so-called optimal fuel reloading problem, which consists of optimizing the rearrangement of all the assemblies, the old and fresh ones, while still maximizing the reactivity of the reactor core so as to maximise fuel burn-up and minimise fuel-cycle costs. This is a
discrete optimization Discrete optimization is a branch of optimization in applied mathematics and computer science. Scope As opposed to continuous optimization, some or all of the variables used in a discrete mathematical program are restricted to be discrete varia ...
problem, and computationally infeasible by current
combinatorial Combinatorics is an area of mathematics primarily concerned with counting, both as a means and an end in obtaining results, and certain properties of finite structures. It is closely related to many other areas of mathematics and has many ap ...
methods, due to the huge number of
permutation In mathematics, a permutation of a set is, loosely speaking, an arrangement of its members into a sequence or linear order, or if the set is already ordered, a rearrangement of its elements. The word "permutation" also refers to the act or pro ...
s and the complexity of each computation. Many
numerical method In numerical analysis, a numerical method is a mathematical tool designed to solve numerical problems. The implementation of a numerical method with an appropriate convergence check in a programming language is called a numerical algorithm. Mathem ...
s have been proposed for solving it and many commercial
software Software is a set of computer programs and associated documentation and data. This is in contrast to hardware, from which the system is built and which actually performs the work. At the lowest programming level, executable code consist ...
packages have been written to support fuel management. This is an ongoing issue in reactor operations as no definitive solution to this problem has been found. Operators use a combination of
computation Computation is any type of arithmetic or non-arithmetic calculation that follows a well-defined model (e.g., an algorithm). Mechanical or electronic devices (or, historically, people) that perform computations are known as ''computers''. An esp ...
al and
empirical Empirical evidence for a proposition is evidence, i.e. what supports or counters this proposition, that is constituted by or accessible to sense experience or experimental procedure. Empirical evidence is of central importance to the sciences and ...
techniques to manage this problem.


The study of used fuel

Used nuclear fuel is studied in
Post irradiation examination Post Irradiation Examination (PIE) is the study of used nuclear materials such as nuclear fuel. It has several purposes. It is known that by examination of used fuel that the failure modes which occur during normal use (and the manner in which th ...
, where used fuel is examined to know more about the processes that occur in fuel during use, and how these might alter the outcome of an accident. For example, during normal use, the fuel expands due to thermal expansion, which can cause cracking. Most
nuclear fuel Nuclear fuel is material used in nuclear power stations to produce heat to power turbines. Heat is created when nuclear fuel undergoes nuclear fission. Most nuclear fuels contain heavy fissile actinide elements that are capable of undergo ...
is uranium dioxide, which is a cubic solid with a structure similar to that of
calcium fluoride Calcium fluoride is the inorganic compound of the elements calcium and fluorine with the formula CaF2. It is a white insoluble solid. It occurs as the mineral fluorite (also called fluorspar), which is often deeply coloured owing to impurities. ...
. In used fuel the solid state structure of most of the solid remains the same as that of pure cubic uranium dioxide. SIMFUEL is the name given to the simulated spent fuel which is made by mixing finely ground metal oxides, grinding as a slurry, spray drying it before heating in hydrogen/argon to 1700 °C. In SIMFUEL, 4.1% of the volume of the solid was in the form of metal
nanoparticle A nanoparticle or ultrafine particle is usually defined as a particle of matter that is between 1 and 100 nanometres (nm) in diameter. The term is sometimes used for larger particles, up to 500 nm, or fibers and tubes that are less than 10 ...
s which are made of
molybdenum Molybdenum is a chemical element with the symbol Mo and atomic number 42 which is located in period 5 and group 6. The name is from Neo-Latin ''molybdaenum'', which is based on Ancient Greek ', meaning lead, since its ores were confused with lead ...
,
ruthenium Ruthenium is a chemical element with the symbol Ru and atomic number 44. It is a rare transition metal belonging to the platinum group of the periodic table. Like the other metals of the platinum group, ruthenium is inert to most other chemical ...
,
rhodium Rhodium is a chemical element with the symbol Rh and atomic number 45. It is a very rare, silvery-white, hard, corrosion-resistant transition metal. It is a noble metal and a member of the platinum group. It has only one naturally occurring i ...
and
palladium Palladium is a chemical element with the symbol Pd and atomic number 46. It is a rare and lustrous silvery-white metal discovered in 1803 by the English chemist William Hyde Wollaston. He named it after the asteroid Pallas, which was itself ...
. Most of these metal particles are of the ε phase (
hexagonal In geometry, a hexagon (from Greek , , meaning "six", and , , meaning "corner, angle") is a six-sided polygon. The total of the internal angles of any simple (non-self-intersecting) hexagon is 720°. Regular hexagon A '' regular hexagon'' has ...
) of Mo-Ru-Rh-Pd alloy, while smaller amounts of the α ( cubic) and σ (
tetragonal In crystallography, the tetragonal crystal system is one of the 7 crystal systems. Tetragonal crystal lattices result from stretching a cubic lattice along one of its lattice vectors, so that the cube becomes a rectangular prism with a squar ...
) phases of these metals were found in the SIMFUEL. Also present within the SIMFUEL was a cubic
perovskite Perovskite (pronunciation: ) is a calcium titanium oxide mineral composed of calcium titanate (chemical formula ). Its name is also applied to the class of compounds which have the same type of crystal structure as (XIIA2+VIB4+X2−3), known a ...
phase which is a
barium Barium is a chemical element with the symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element. Th ...
strontium Strontium is the chemical element with the symbol Sr and atomic number 38. An alkaline earth metal, strontium is a soft silver-white yellowish metallic element that is highly chemically reactive. The metal forms a dark oxide layer when it is e ...
zirconate A zirconate is an oxyanion containing zirconium. Examples include Na2ZrO3, Ca2ZrO3 which can be prepared by fusing zirconium dioxide Zirconium dioxide (), sometimes known as zirconia (not to be confused with zircon), is a white crystalline oxide ...
(BaxSr1−xZrO3). Uranium dioxide is very insoluble in water, but after oxidation it can be converted to uranium trioxide or another uranium(VI) compound which is much more soluble. Uranium dioxide (UO2) can be oxidised to an oxygen rich hyperstoichiometric oxide (UO2+x) which can be further oxidised to U4O9, U3O7, U3O8 and UO3.2H2O. Because used fuel contains alpha emitters (plutonium and the minor actinides), the effect of adding an alpha emitter (238Pu) to uranium dioxide on the leaching rate of the oxide has been investigated. For the crushed oxide, adding 238Pu tended to increase the rate of leaching, but the difference in the leaching rate between 0.1 and 10% 238Pu was very small. The concentration of
carbonate A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word ''carbonate'' may also refer to a carbonate ester, an organic compound containing the carbonate ...
in the water which is in contact with the used fuel has a considerable effect on the rate of corrosion, because
uranium Uranium is a chemical element with the symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium is weak ...
(VI) forms soluble anionic carbonate complexes such as O2(CO3)2sup>2− and O2(CO3)3sup>4−. When carbonate ions are absent, and the water is not strongly acidic, the hexavalent uranium compounds which form on oxidation of
uranium dioxide Uranium dioxide or uranium(IV) oxide (), also known as urania or uranous oxide, is an oxide of uranium, and is a black, radioactive, crystalline powder that naturally occurs in the mineral uraninite. It is used in nuclear fuel rods in nuclear re ...
often form insoluble hydrated
uranium trioxide Uranium trioxide (UO3), also called uranyl oxide, uranium(VI) oxide, and uranic oxide, is the hexavalent oxide of uranium. The solid may be obtained by heating uranyl nitrate to 400 °C. Its most commonly encountered polymorph, γ-UO3, is a ...
phases. Thin films of uranium dioxide can be deposited upon gold surfaces by ‘ sputtering’ using uranium metal and an
argon Argon is a chemical element with the symbol Ar and atomic number 18. It is in group 18 of the periodic table and is a noble gas. Argon is the third-most abundant gas in Earth's atmosphere, at 0.934% (9340 ppmv). It is more than twice a ...
/
oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements ...
gas mixture. These gold surfaces modified with uranium dioxide have been used for both
cyclic voltammetry Cyclic voltammetry (CV) is a type of potentiodynamic electrochemical measurement. In a cyclic voltammetry experiment, the working electrode potential is ramped linearly versus time. Unlike in linear sweep voltammetry, after the set potential is r ...
and AC impedance experiments, and these offer an insight into the likely leaching behaviour of uranium dioxide.


Fuel cladding interactions

The study of the nuclear fuel cycle includes the study of the behaviour of nuclear materials both under normal conditions and under accident conditions. For example, there has been much work on how
uranium dioxide Uranium dioxide or uranium(IV) oxide (), also known as urania or uranous oxide, is an oxide of uranium, and is a black, radioactive, crystalline powder that naturally occurs in the mineral uraninite. It is used in nuclear fuel rods in nuclear re ...
based fuel interacts with the
zirconium Zirconium is a chemical element with the symbol Zr and atomic number 40. The name ''zirconium'' is taken from the name of the mineral zircon, the most important source of zirconium. The word is related to Persian '' zargun'' (zircon; ''zar-gun'' ...
alloy tubing used to cover it. During use, the fuel swells due to
thermal expansion Thermal expansion is the tendency of matter to change its shape, area, volume, and density in response to a change in temperature, usually not including phase transitions. Temperature is a monotonic function of the average molecular kin ...
and then starts to react with the surface of the zirconium alloy, forming a new layer which contains both fuel and zirconium (from the cladding). Then, on the fuel side of this mixed layer, there is a layer of fuel which has a higher
caesium Caesium (IUPAC spelling) (or cesium in American English) is a chemical element with the symbol Cs and atomic number 55. It is a soft, silvery-golden alkali metal with a melting point of , which makes it one of only five elemental metals that a ...
to
uranium Uranium is a chemical element with the symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium is weak ...
ratio than most of the fuel. This is because
xenon Xenon is a chemical element with the symbol Xe and atomic number 54. It is a dense, colorless, odorless noble gas found in Earth's atmosphere in trace amounts. Although generally unreactive, it can undergo a few chemical reactions such as the ...
isotopes are formed as
fission products Nuclear fission products are the atomic fragments left after a large atomic nucleus undergoes nuclear fission. Typically, a large nucleus like that of uranium fissions by splitting into two smaller nuclei, along with a few neutrons, the release ...
that diffuse out of the lattice of the fuel into voids such as the narrow gap between the fuel and the cladding. After diffusing into these voids, it decays to caesium isotopes. Because of the thermal gradient which exists in the fuel during use, the volatile fission products tend to be driven from the centre of the pellet to the rim area. Below is a graph of the temperature of uranium metal, uranium nitride and
uranium dioxide Uranium dioxide or uranium(IV) oxide (), also known as urania or uranous oxide, is an oxide of uranium, and is a black, radioactive, crystalline powder that naturally occurs in the mineral uraninite. It is used in nuclear fuel rods in nuclear re ...
as a function of distance from the centre of a 20 mm diameter pellet with a rim temperature of 200 °C. The uranium dioxide (because of its poor thermal conductivity) will overheat at the centre of the pellet, while the other more thermally conductive forms of uranium remain below their melting points.


Normal and abnormal conditions

The nuclear chemistry associated with the nuclear fuel cycle can be divided into two main areas; one area is concerned with operation under the intended conditions while the other area is concerned with maloperation conditions where some alteration from the normal operating conditions has occurred or (''more rarely'') an accident is occurring. The releases of radioactivity from normal operations are the small planned releases from uranium ore processing, enrichment, power reactors, reprocessing plants and waste stores. These can be in different chemical/physical form from releases which could occur under accident conditions. In addition the isotope signature of a hypothetical accident may be very different from that of a planned normal operational discharge of radioactivity to the environment. Just because a radioisotope is released it does not mean it will enter a human and then cause harm. For instance, the migration of radioactivity can be altered by the binding of the radioisotope to the surfaces of soil particles. For example,
caesium Caesium (IUPAC spelling) (or cesium in American English) is a chemical element with the symbol Cs and atomic number 55. It is a soft, silvery-golden alkali metal with a melting point of , which makes it one of only five elemental metals that a ...
(Cs) binds tightly to clay minerals such as
illite Illite is a group of closely related non-expanding clay minerals. Illite is a secondary mineral precipitate, and an example of a phyllosilicate, or layered alumino-silicate. Its structure is a 2:1 sandwich of silica tetrahedron (T) – alumina ...
and
montmorillonite Montmorillonite is a very soft phyllosilicate group of minerals that form when they precipitate from water solution as microscopic crystals, known as clay. It is named after Montmorillon in France. Montmorillonite, a member of the smectite gro ...
, hence it remains in the upper layers of soil where it can be accessed by plants with shallow roots (such as grass). Hence grass and mushrooms can carry a considerable amount of 137Cs which can be transferred to humans through the food chain. But 137Cs is not able to migrate quickly through most soils and thus is unlikely to contaminate
well A well is an excavation or structure created in the ground by digging, driving, or drilling to access liquid resources, usually water. The oldest and most common kind of well is a water well, to access groundwater in underground aquifers. The ...
water. Colloids of soil minerals can migrate through soil so simple binding of a metal to the surfaces of soil particles does not completely fix the metal. According to Jiří Hála's
text book A textbook is a book containing a comprehensive compilation of content in a branch of study with the intention of explaining it. Textbooks are produced to meet the needs of educators, usually at educational institutions. Schoolbooks are textbook ...
, the distribution coefficient Kd is the ratio of the soil's radioactivity (Bq g−1) to that of the soil water (Bq ml−1). If the radioisotope is tightly bound to the minerals in the soil, then less radioactivity can be absorbed by crops and
grass Poaceae () or Gramineae () is a large and nearly ubiquitous family of monocotyledonous flowering plants commonly known as grasses. It includes the cereal grasses, bamboos and the grasses of natural grassland and species cultivated in lawns a ...
growing on the soil. * Cs-137 Kd = 1000 *
Pu-239 Plutonium-239 (239Pu or Pu-239) is an isotope of plutonium. Plutonium-239 is the primary fissile isotope used for the production of nuclear weapons, although uranium-235 is also used for that purpose. Plutonium-239 is also one of the three main ...
Kd = 10000 to 100000 * Sr-90 Kd = 80 to 150 * I-131 Kd = 0.007 to 50 In dairy farming, one of the best countermeasures against 137Cs is to mix up the soil by deeply ploughing the soil. This has the effect of putting the 137Cs out of reach of the shallow roots of the grass, hence the level of radioactivity in the grass will be lowered. Also after a nuclear war or serious accident, the removal of top few cm of soil and its burial in a shallow trench will reduce the long-term gamma dose to humans due to 137Cs, as the gamma photons will be attenuated by their passage through the soil. Even after the radioactive element arrives at the roots of the plant, the metal may be rejected by the biochemistry of the plant. The details of the uptake of 90Sr and 137Cs into
sunflower The common sunflower (''Helianthus annuus'') is a large annual forb of the genus ''Helianthus'' grown as a crop for its edible oily seeds. Apart from cooking oil production, it is also used as livestock forage (as a meal or a silage plant), ...
s grown under
hydroponic Hydroponics is a type of horticulture and a subset of hydroculture which involves growing plants, usually crops or medicinal plants, without soil, by using water-based mineral nutrient solutions in aqueous solvents. Terrestrial or aquatic plant ...
conditions has been reported. The
caesium Caesium (IUPAC spelling) (or cesium in American English) is a chemical element with the symbol Cs and atomic number 55. It is a soft, silvery-golden alkali metal with a melting point of , which makes it one of only five elemental metals that a ...
was found in the leaf veins, in the stem and in the
apical Apical means "pertaining to an apex". It may refer to: *Apical ancestor, refers to the last common ancestor of an entire group, such as a species (biology) or a clan (anthropology) *Apical (anatomy), an anatomical term of location for features loc ...
leaves. It was found that 12% of the caesium entered the plant, and 20% of the strontium. This paper also reports details of the effect of
potassium Potassium is the chemical element with the symbol K (from Neo-Latin '' kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmos ...
,
ammonium The ammonium cation is a positively-charged polyatomic ion with the chemical formula or . It is formed by the protonation of ammonia (). Ammonium is also a general name for positively charged or protonated substituted amines and quaterna ...
and
calcium Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar ...
ions on the uptake of the radioisotopes. In
livestock Livestock are the domesticated animals raised in an agricultural setting to provide labor and produce diversified products for consumption such as meat, eggs, milk, fur, leather, and wool. The term is sometimes used to refer solely to ani ...
farming, an important countermeasure against 137Cs is to feed animals a small amount of
Prussian blue Prussian blue (also known as Berlin blue, Brandenburg blue or, in painting, Parisian or Paris blue) is a dark blue pigment produced by oxidation of ferrous ferrocyanide salts. It has the chemical formula Fe CN)">Cyanide.html" ;"title="e(Cyani ...
. This
iron Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in ...
potassium
cyanide Cyanide is a naturally occurring, rapidly acting, toxic chemical that can exist in many different forms. In chemistry, a cyanide () is a chemical compound that contains a functional group. This group, known as the cyano group, consists of ...
compound acts as an
ion-exchanger Ion exchange is a reversible interchange of one kind of ion present in an insoluble solid with another of like charge present in a solution surrounding the solid with the reaction being used especially for softening or making water demineralised, ...
. The cyanide is so tightly bonded to the iron that it is safe for a human to eat several grams of Prussian blue per day. The Prussian blue reduces the
biological half-life Biological half-life (also known as elimination half-life, pharmacologic half-life) is the time taken for concentration of a biological substance (such as a medication) to decrease from its maximum concentration ( Cmax) to half of Cmax in the bl ...
(different from the nuclear half-life) of the caesium. The physical or nuclear half-life of 137Cs is about 30 years. This is a constant which can not be changed but the biological half-life is not a constant. It will change according to the nature and habits of the organism for which it is expressed. Caesium in humans normally has a biological half-life of between one and four months. An added advantage of the Prussian blue is that the caesium which is stripped from the animal in the
droppings Feces ( or faeces), known colloquially and in slang as poo and poop, are the solid or semi-solid remains of food that was not digested in the small intestine, and has been broken down by bacteria in the large intestine. Feces contain a relati ...
is in a form which is not available to plants. Hence it prevents the caesium from being recycled. The form of Prussian blue required for the treatment of humans or animals is a special grade. Attempts to use the
pigment A pigment is a colored material that is completely or nearly insoluble in water. In contrast, dyes are typically soluble, at least at some stage in their use. Generally dyes are often organic compounds whereas pigments are often inorganic compou ...
grade used in
paint Paint is any pigmented liquid, liquefiable, or solid mastic composition that, after application to a substrate in a thin layer, converts to a solid film. It is most commonly used to protect, color, or provide texture. Paint can be made in many ...
s have not been successful. Note that a good source of data on the subject of caesium in
Chernobyl Chernobyl ( , ; russian: Чернобыль, ) or Chornobyl ( uk, Чорнобиль, ) is a partially abandoned city in the Chernobyl Exclusion Zone, situated in the Vyshhorod Raion of northern Kyiv Oblast, Ukraine. Chernobyl is about n ...
fallout exists a

(''Ukrainian Research Institute for Agricultural Radiology'').


Release of radioactivity from fuel during normal use and accidents

The International Atomic Energy Agency, IAEA assume that under normal operation the coolant of a water-cooled reactor will contain some radioactivity but during a reactor accident the coolant radioactivity level may rise. The IAEA states that under a series of different conditions different amounts of the core inventory can be released from the fuel, the four conditions the IAEA consider are ''normal operation'', a spike in coolant activity due to a sudden shutdown/loss of pressure (core remains covered with water), a cladding failure resulting in the release of the activity in the fuel/cladding gap (this could be due to the fuel being uncovered by the loss of water for 15–30 minutes where the cladding reached a temperature of 650–1250 °C) or a melting of the core (the fuel will have to be uncovered for at least 30 minutes, and the cladding would reach a temperature in excess of 1650 °C). Based upon the assumption that a Pressurized water reactor contains 300 tons of
water Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as ...
, and that the activity of the fuel of a 1 GWe reactor is as the IAEA predicts, then the coolant activity after an accident such as the
Three Mile Island accident The Three Mile Island accident was a partial meltdown of the Three Mile Island, Unit 2 (TMI-2) reactor in Pennsylvania, United States. It began at 4 a.m. on March 28, 1979. It is the most significant accident in U.S. commercial nuclea ...
(where a core is uncovered and then recovered with water) can be predicted.


=Releases from reprocessing under normal conditions

= It is normal to allow used fuel to stand after the irradiation to allow the short-lived and radiotoxic
iodine Iodine is a chemical element with the Symbol (chemistry), symbol I and atomic number 53. The heaviest of the stable halogens, it exists as a semi-lustrous, non-metallic solid at standard conditions that melts to form a deep violet liquid at , ...
isotopes to decay away. In one experiment in the US, fresh fuel which had not been allowed to decay was reprocessed (the Green runbr>
to investigate the effects of a large iodine release from the reprocessing of short cooled fuel. It is normal in reprocessing plants to scrub the off gases from the dissolver to prevent the emission of iodine. In addition to the emission of iodine the
noble gas The noble gases (historically also the inert gases; sometimes referred to as aerogens) make up a class of chemical elements with similar properties; under standard conditions, they are all odorless, colorless, monatomic gases with very low ch ...
es and
tritium Tritium ( or , ) or hydrogen-3 (symbol T or H) is a rare and radioactive isotope of hydrogen with half-life about 12 years. The nucleus of tritium (t, sometimes called a ''triton'') contains one proton and two neutrons, whereas the nucleus of ...
are released from the fuel when it is dissolved. It has been proposed that by voloxidation (heating the fuel in a furnace under oxidizing conditions) the majority of the tritium can be recovered from the fue

A paper was written on the radioactivity in
oyster Oyster is the common name for a number of different families of salt-water bivalve molluscs that live in marine or brackish habitats. In some species, the valves are highly calcified, and many are somewhat irregular in shape. Many, but not ...
s found in the
Irish Sea The Irish Sea or , gv, Y Keayn Yernagh, sco, Erse Sie, gd, Muir Èireann , Ulster-Scots: ''Airish Sea'', cy, Môr Iwerddon . is an extensive body of water that separates the islands of Ireland and Great Britain. It is linked to the C ...
. These were found by gamma spectroscopy to contain 141Ce, 144Ce, 103Ru, 106Ru, 137Cs, 95Zr and 95Nb. Additionally, a zinc activation product (65Zn) was found, which is thought to be due to the corrosion of
magnox Magnox is a type of nuclear power/production reactor that was designed to run on natural uranium with graphite as the moderator and carbon dioxide gas as the heat exchange coolant. It belongs to the wider class of gas-cooled reactors. The n ...
fuel cladding in
spent fuel pool Spent fuel pools (SFP) are storage pools (or "ponds" in the United Kingdom) for spent fuel from nuclear reactors. They are typically 40 or more feet (12 m) deep, with the bottom 14 feet (4.3 m) equipped with storage racks designed to hold ...
s. It is likely that the modern releases of all these isotopes from the
Windscale Sellafield is a large multi-function nuclear site close to Seascale on the coast of Cumbria, England. As of August 2022, primary activities are nuclear waste storage, nuclear waste processing and storage and nuclear decommissioning. Former act ...
event is smaller.


On-load reactors

Some reactor designs, such as
RBMK The RBMK (russian: реактор большой мощности канальный, РБМК; ''reaktor bolshoy moshchnosti kanalnyy'', "high-power channel-type reactor") is a class of graphite-moderated nuclear power reactor designed and buil ...
s or
CANDU reactor The CANDU (Canada Deuterium Uranium) is a Canadian pressurized heavy-water reactor design used to generate electric power. The acronym refers to its deuterium oxide ( heavy water) moderator and its use of (originally, natural) uranium fuel. C ...
s, can be refueled without being shut down. This is achieved through the use of many small pressure tubes to contain the fuel and coolant, as opposed to one large pressure vessel as in
pressurized water reactor A pressurized water reactor (PWR) is a type of light-water nuclear reactor. PWRs constitute the large majority of the world's nuclear power plants (with notable exceptions being the UK, Japan and Canada). In a PWR, the primary coolant (water) i ...
(PWR) or
boiling water reactor A boiling water reactor (BWR) is a type of light water nuclear reactor used for the generation of electrical power. It is a design different from a Soviet graphite-moderated RBMK. It is the second most common type of electricity-generating nu ...
(BWR) designs. Each tube can be individually isolated and refueled by an operator-controlled fueling machine, typically at a rate of up to 8 channels per day out of roughly 400 in CANDU reactors. On-load refueling allows for the optimal fuel reloading problem to be dealt with continuously, leading to more efficient use of fuel. This increase in efficiency is partially offset by the added complexity of having hundreds of pressure tubes and the fueling machines to service them.


Interim storage

After its operating cycle, the reactor is shut down for refueling. The fuel discharged at that time (spent fuel) is stored either at the reactor site (commonly in a
spent fuel pool Spent fuel pools (SFP) are storage pools (or "ponds" in the United Kingdom) for spent fuel from nuclear reactors. They are typically 40 or more feet (12 m) deep, with the bottom 14 feet (4.3 m) equipped with storage racks designed to hold ...
) or potentially in a common facility away from reactor sites. If on-site pool storage capacity is exceeded, it may be desirable to store the now cooled aged fuel in modular dry storage facilities known as Independent Spent Fuel Storage Installations (ISFSI) at the reactor site or at a facility away from the site. The spent fuel rods are usually stored in water or boric acid, which provides both cooling (the spent fuel continues to generate decay heat as a result of residual radioactive decay) and shielding to protect the environment from residual
ionizing radiation Ionizing radiation (or ionising radiation), including nuclear radiation, consists of subatomic particles or electromagnetic waves that have sufficient energy to ionize atoms or molecules by detaching electrons from them. Some particles can travel ...
, although after at least a year of cooling they may be moved to
dry cask storage Dry cask storage is a method of storing high-level radioactive waste, such as spent nuclear fuel that has already been cooled in the spent fuel pool for at least one year and often as much as ten years. Casks are typically steel cylinders that ar ...
.


Transportation


Reprocessing

Spent fuel discharged from reactors contains appreciable quantities of fissile (U-235 and Pu-239), fertile (U-238), and other
radioactive Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consi ...
materials, including reaction poisons, which is why the fuel had to be removed. These fissile and fertile materials can be chemically separated and recovered from the spent fuel. The recovered uranium and plutonium can, if economic and institutional conditions permit, be recycled for use as nuclear fuel. This is currently not done for civilian spent nuclear fuel in the
United States The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country Continental United States, primarily located in North America. It consists of 50 U.S. state, states, a Washington, D.C., ...
, however it is done in Russia. Russia aims to maximise recycling of fissile materials from used fuel. Hence reprocessing used fuel is a basic practice, with reprocessed uranium being recycled and plutonium used in MOX, at present only for fast reactors. Mixed oxide, or
MOX fuel Mixed oxide fuel, commonly referred to as MOX fuel, is nuclear fuel that contains more than one oxide of fissile material, usually consisting of plutonium blended with natural uranium, reprocessed uranium, or depleted uranium. MOX fuel is an al ...
, is a blend of reprocessed uranium and plutonium and depleted uranium which behaves similarly, although not identically, to the enriched uranium feed for which most nuclear reactors were designed. MOX fuel is an alternative to low-enriched uranium (LEU) fuel used in the light water reactors which predominate nuclear power generation. Currently, plants in Europe are reprocessing spent fuel from utilities in Europe and Japan. Reprocessing of spent commercial-reactor nuclear fuel is currently not permitted in the
United States The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country Continental United States, primarily located in North America. It consists of 50 U.S. state, states, a Washington, D.C., ...
due to the perceived danger of
nuclear proliferation Nuclear proliferation is the spread of nuclear weapons, fissionable material, and weapons-applicable nuclear technology and information to nations not recognized as " Nuclear Weapon States" by the Treaty on the Non-Proliferation of Nuclear Wea ...
. The Bush Administration's Global Nuclear Energy Partnership proposed that the U.S. form an international partnership to see spent nuclear fuel reprocessed in a way that renders the plutonium in it usable for nuclear fuel but not for
nuclear weapon A nuclear weapon is an explosive device that derives its destructive force from nuclear reactions, either fission (fission bomb) or a combination of fission and fusion reactions ( thermonuclear bomb), producing a nuclear explosion. Both bomb ...
s.


Partitioning and transmutation

As an alternative to the disposal of the
PUREX raffinate PUREX (plutonium uranium reduction extraction) is a chemical method used to purify fuel for nuclear reactors or nuclear weapons. PUREX is the '' de facto'' standard aqueous nuclear reprocessing method for the recovery of uranium and pluto ...
in
glass Glass is a non- crystalline, often transparent, amorphous solid that has widespread practical, technological, and decorative use in, for example, window panes, tableware, and optics. Glass is most often formed by rapid cooling (quenchin ...
or
Synroc Synroc, a portmanteau of "synthetic rock", is a means of safely storing radioactive waste. It was pioneered in 1978 by a team led by Professor Ted Ringwood at the Australian National University, with further research undertaken in collaboration with ...
matrix, the most radiotoxic elements could be removed through advanced reprocessing. After separation, the minor actinides and some long-lived
fission product Nuclear fission products are the atomic fragments left after a large atomic nucleus undergoes nuclear fission. Typically, a large nucleus like that of uranium fissions by splitting into two smaller nuclei, along with a few neutrons, the release ...
s could be converted to short-lived or stable
isotope Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers ( mass num ...
s by either
neutron The neutron is a subatomic particle, symbol or , which has a neutral (not positive or negative) charge, and a mass slightly greater than that of a proton. Protons and neutrons constitute the atomic nucleus, nuclei of atoms. Since protons and ...
or
photon A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless, so they alwa ...
irradiation. This is called transmutation. Strong and long-term international cooperation, and many decades of research and huge investments remain necessary before to reach a mature industrial scale where the safety and the economical feasibility of partitioning and transmutation (P&T) could be demonstrated.


Waste disposal

A current concern in the nuclear power field is the safe disposal and isolation of either spent fuel from reactors or, if the reprocessing option is used, wastes from reprocessing plants. These materials must be isolated from the
biosphere The biosphere (from Greek βίος ''bíos'' "life" and σφαῖρα ''sphaira'' "sphere"), also known as the ecosphere (from Greek οἶκος ''oîkos'' "environment" and σφαῖρα), is the worldwide sum of all ecosystems. It can also ...
until the radioactivity contained in them has diminished to a safe level. In the U.S., under the Nuclear Waste Policy Act of 1982 as amended, the
Department of Energy A Ministry of Energy or Department of Energy is a government department in some countries that typically oversees the production of fuel and electricity; in the United States, however, it manages nuclear weapons development and conducts energy-re ...
has responsibility for the development of the waste disposal system for spent nuclear fuel and high-level radioactive waste. Current plans call for the ultimate disposal of the wastes in solid form in a licensed deep, stable geologic structure called a
deep geological repository A deep geological repository is a way of storing hazardous or radioactive waste within a stable geologic environment (typically 200–1000 m deep). It entails a combination of waste form, waste package, engineered seals and geology that is suite ...
. The Department of Energy chose
Yucca Mountain Yucca Mountain is a mountain in Nevada, near its border with California, approximately northwest of Las Vegas. Located in the Great Basin, Yucca Mountain is east of the Amargosa Desert, south of the Nevada Test and Training Range and in the ...
as the location for the repository. Its opening has been repeatedly delayed. Since 1999 thousands of nuclear waste shipments have been stored at the
Waste Isolation Pilot Plant The Waste Isolation Pilot Plant, or WIPP, is the world's third deep geological repository (after Germany's Repository for radioactive waste Morsleben and the Schacht Asse II salt mine) licensed to store transuranic radioactive waste for 10,00 ...
in New Mexico.
Fast-neutron reactor A fast-neutron reactor (FNR) or fast-spectrum reactor or simply a fast reactor is a category of nuclear reactor in which the fission chain reaction is sustained by fast neutrons (carrying energies above 1 MeV or greater, on average), as oppose ...
s can fission all actinides, while the thorium fuel cycle produces low levels of transuranics. Unlike LWRs, in principle these fuel cycles could recycle their
plutonium Plutonium is a radioactive chemical element with the symbol Pu and atomic number 94. It is an actinide metal of silvery-gray appearance that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exh ...
and minor actinides and leave only
fission product Nuclear fission products are the atomic fragments left after a large atomic nucleus undergoes nuclear fission. Typically, a large nucleus like that of uranium fissions by splitting into two smaller nuclei, along with a few neutrons, the release ...
s and
activation product Activation products are materials made radioactive by neutron activation. Fission products and actinides produced by neutron absorption of nuclear fuel itself are normally referred to by those specific names, and ''activation product'' reserved fo ...
s as waste. The highly radioactive
medium-lived fission product Long-lived fission products (LLFPs) are radioactive materials with a long half-life (more than 200,000 years) produced by nuclear fission of uranium and plutonium. Because of their persistent radiotoxicity it is necessary to isolate them from man ...
s Cs-137 and Sr-90 diminish by a factor of 10 each century; while the
long-lived fission product Long-lived fission products (LLFPs) are radioactive materials with a long half-life (more than 200,000 years) produced by nuclear fission of uranium and plutonium. Because of their persistent radiotoxicity it is necessary to isolate them from ma ...
s have relatively low radioactivity, often compared favorably to that of the original uranium ore.
Horizontal drillhole disposal Deep horizontal drillhole disposal is the concept of disposing of high-level radioactive waste from a nuclear reactor in deep horizontal boreholes instead of in more traditional deep geological repositories that are excavated like mines. The desi ...
describes proposals to drill over one kilometer vertically, and two kilometers horizontally in the earth's crust, for the purpose of disposing of high-level waste forms such as
spent nuclear fuel Spent nuclear fuel, occasionally called used nuclear fuel, is nuclear fuel that has been irradiated in a nuclear reactor (usually at a nuclear power plant). It is no longer useful in sustaining a nuclear reaction in an ordinary thermal reactor and ...
,
Caesium-137 Caesium-137 (), cesium-137 (US), or radiocaesium, is a radioactive isotope of caesium that is formed as one of the more common fission products by the nuclear fission of uranium-235 and other fissionable isotopes in nuclear reactors and nucle ...
, or
Strontium-90 Strontium-90 () is a radioactive isotope of strontium produced by nuclear fission, with a half-life of 28.8 years. It undergoes β− decay into yttrium-90, with a decay energy of 0.546 MeV. Strontium-90 has applications in medicine and ...
. After the emplacement and the retrievability period, drillholes would be backfilled and sealed. A series of tests of the technology were carried out in November 2018 and then again publicly in January 2019 by a U.S. based private company. The test demonstrated the emplacement of a test-canister in a horizontal drillhole and retrieval of the same canister. There was no actual high-level waste used in this test.


Fuel cycles

Although the most common terminology is ''fuel cycle,'' some argue that the term ''fuel chain'' is more accurate, because the spent fuel is never fully recycled. Spent fuel includes
fission products Nuclear fission products are the atomic fragments left after a large atomic nucleus undergoes nuclear fission. Typically, a large nucleus like that of uranium fissions by splitting into two smaller nuclei, along with a few neutrons, the release ...
, which generally must be treated as
waste Waste (or wastes) are unwanted or unusable materials. Waste is any substance discarded after primary use, or is worthless, defective and of no use. A by-product, by contrast is a joint product of relatively minor economic value. A waste pr ...
, as well as uranium, plutonium, and other transuranic elements. Where plutonium is recycled, it is normally reused once in light water reactors, although fast reactors could lead to more complete recycling of plutonium.


Once-through nuclear fuel cycle

Not a cycle ''per se'', fuel is used once and then sent to storage without further processing save additional packaging to provide for better isolation from the
biosphere The biosphere (from Greek βίος ''bíos'' "life" and σφαῖρα ''sphaira'' "sphere"), also known as the ecosphere (from Greek οἶκος ''oîkos'' "environment" and σφαῖρα), is the worldwide sum of all ecosystems. It can also ...
. This method is favored by six countries: the
United States The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country Continental United States, primarily located in North America. It consists of 50 U.S. state, states, a Washington, D.C., ...
,
Canada Canada is a country in North America. Its ten provinces and three territories extend from the Atlantic Ocean to the Pacific Ocean and northward into the Arctic Ocean, covering over , making it the world's second-largest country by to ...
,
Sweden Sweden, formally the Kingdom of Sweden,The United Nations Group of Experts on Geographical Names states that the country's formal name is the Kingdom of SwedenUNGEGN World Geographical Names, Sweden./ref> is a Nordic countries, Nordic c ...
,
Finland Finland ( fi, Suomi ; sv, Finland ), officially the Republic of Finland (; ), is a Nordic country in Northern Europe. It shares land borders with Sweden to the northwest, Norway to the north, and Russia to the east, with the Gulf of Bot ...
,
Spain , image_flag = Bandera de España.svg , image_coat = Escudo de España (mazonado).svg , national_motto = '' Plus ultra'' (Latin)(English: "Further Beyond") , national_anthem = (English: "Royal March") , ...
and
South Africa South Africa, officially the Republic of South Africa (RSA), is the southernmost country in Africa. It is bounded to the south by of coastline that stretch along the South Atlantic and Indian Oceans; to the north by the neighbouring coun ...
. Some countries, notably Finland, Sweden and Canada, have designed repositories to permit future recovery of the material should the need arise, while others plan for permanent sequestration in a
geological repository A deep geological repository is a way of storing hazardous or radioactive waste within a stable geologic environment (typically 200–1000 m deep). It entails a combination of waste form, waste package, engineered seals and geology that is suited ...
like the
Yucca Mountain nuclear waste repository The Yucca Mountain Nuclear Waste Repository, as designated by the Nuclear Waste Policy Act amendments of 1987, is a proposed deep geological repository storage facility within Yucca Mountain for spent nuclear fuel and other high-level radio ...
in the United States.


Plutonium cycle

Several countries, including Japan, Switzerland, and previously Spain and Germany, are using or have used the reprocessing services offered by
Areva NC Orano Cycle, formerly COGEMA (''Compagnie générale des matières nucléaires'') and Areva NC, is a French nuclear company. It is the main subsidiary of Orano S.A. It is an industrial group active in all stages of the uranium fuel cycle, inclu ...
and previously THORP.
Fission product Nuclear fission products are the atomic fragments left after a large atomic nucleus undergoes nuclear fission. Typically, a large nucleus like that of uranium fissions by splitting into two smaller nuclei, along with a few neutrons, the release ...
s, minor actinides,
activation product Activation products are materials made radioactive by neutron activation. Fission products and actinides produced by neutron absorption of nuclear fuel itself are normally referred to by those specific names, and ''activation product'' reserved fo ...
s, and reprocessed uranium are separated from the reactor-grade
plutonium Plutonium is a radioactive chemical element with the symbol Pu and atomic number 94. It is an actinide metal of silvery-gray appearance that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exh ...
, which can then be fabricated into
MOX fuel Mixed oxide fuel, commonly referred to as MOX fuel, is nuclear fuel that contains more than one oxide of fissile material, usually consisting of plutonium blended with natural uranium, reprocessed uranium, or depleted uranium. MOX fuel is an al ...
. Because the proportion of the non-
fissile In nuclear engineering, fissile material is material capable of sustaining a nuclear fission chain reaction. By definition, fissile material can sustain a chain reaction with neutrons of thermal energy. The predominant neutron energy may be t ...
even Even may refer to: General * Even (given name), a Norwegian male personal name * Even (surname) * Even (people), an ethnic group from Siberia and Russian Far East **Even language, a language spoken by the Evens * Odd and Even, a solitaire game wh ...
-
mass Mass is an intrinsic property of a body. It was traditionally believed to be related to the quantity of matter in a physical body, until the discovery of the atom and particle physics. It was found that different atoms and different ele ...
isotopes of plutonium Plutonium (94Pu) is an artificial element, except for trace quantities resulting from neutron capture by uranium, and thus a standard atomic weight cannot be given. Like all artificial elements, it has no stable isotopes. It was synthesized long ...
rises with each pass through the cycle, there are currently no plans to reuse plutonium from used MOX fuel for a third pass in a
thermal reactor A thermal-neutron reactor is a nuclear reactor that uses slow or thermal neutrons. ("Thermal" does not mean hot in an absolute sense, but means in thermal equilibrium with the medium it is interacting with, the reactor's fuel, moderator and struct ...
. If
fast reactor A fast-neutron reactor (FNR) or fast-spectrum reactor or simply a fast reactor is a category of nuclear reactor in which the fission chain reaction is sustained by fast neutrons (carrying energies above 1 MeV or greater, on average), as oppose ...
s become available, they may be able to burn these, or almost any other
actinide The actinide () or actinoid () series encompasses the 15 metallic chemical elements with atomic numbers from 89 to 103, actinium through lawrencium. The actinide series derives its name from the first element in the series, actinium. The info ...
isotope Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers ( mass num ...
s. The use of a medium-scale reprocessing facility onsite, and the use of
pyroprocessing Pyroprocessing (from Greek Πυρος = ''fire'') is a process in which materials are subjected to high temperatures (typically over 800 °C) in order to bring about a chemical or physical change. Pyroprocessing includes such terms as ore-ro ...
rather than the present day aqueous reprocessing, is claimed to potentially be able to considerably reduce the
nuclear proliferation Nuclear proliferation is the spread of nuclear weapons, fissionable material, and weapons-applicable nuclear technology and information to nations not recognized as " Nuclear Weapon States" by the Treaty on the Non-Proliferation of Nuclear Wea ...
potential or possible diversion of fissile material as the processing facility is in-situ. Similarly as plutonium is not separated on its own in the pyroprocessing cycle, rather all actinides are " electro-won" or "refined" from the spent fuel, the plutonium is never separated on its own, instead it comes over into the new fuel mixed with gamma and alpha emitting actinides, species that "self-protect" it in numerous possible thief scenarios. Beginning in 2016 Russia has been testing and is now deploying Remix Fuel in which the spent nuclear fuel is put through a process like Pyroprocessing that separates the reactor Grade Plutonium and remaining Uranium from the fission products and fuel cladding. This mixed metal is then combined with a small quantity of medium enriched Uranium with approximately 17% U-235 concentration to make a new combined metal oxide fuel with 1% Reactor Grade plutonium and a U-235 concentration of 4%. These fuel rods are suitable for use in standard PWR reactors as the Plutonium content is no higher than that which exists at the end of cycle in the spent nuclear fuel. As of February 2020 Russia was deploying this fuel in some of their fleet of
VVER The water-water energetic reactor (WWER), or VVER (from russian: водо-водяной энергетический реактор; transliterates as ; ''water-water power reactor'') is a series of pressurized water reactor designs originally de ...
reactors.


Minor actinides recycling

It has been proposed that in addition to the use of plutonium, the
minor actinide The minor actinides are the actinide elements in used nuclear fuel other than uranium and plutonium, which are termed the major actinides. The minor actinides include neptunium (element 93), americium (element 95), curium (element 96), berkeliu ...
s could be used in a critical power reactor. Tests are already being conducted in which
americium Americium is a synthetic radioactive chemical element with the symbol Am and atomic number 95. It is a transuranic member of the actinide series, in the periodic table located under the lanthanide element europium, and thus by analogy was n ...
is being used as a fuel. A number of reactor designs, like the
Integral Fast Reactor The integral fast reactor (IFR, originally advanced liquid-metal reactor) is a design for a nuclear reactor using fast neutrons and no neutron moderator (a "fast" reactor). IFR would breed more fuel and is distinguished by a nuclear fuel cycle ...
, have been designed for this rather different fuel cycle. In principle, it should be possible to derive energy from the fission of any actinide nucleus. With a careful reactor design, all the actinides in the fuel can be consumed, leaving only lighter elements with short
half-lives Half-life (symbol ) is the time required for a quantity (of substance) to reduce to half of its initial value. The term is commonly used in nuclear physics to describe how quickly unstable atoms undergo radioactive decay or how long stable ato ...
. Whereas this has been done in prototype plants, no such reactor has ever been operated on a large scale. It so happens that the
neutron cross-section In nuclear physics, the concept of a neutron cross section is used to express the likelihood of interaction between an incident neutron and a target nucleus. The neutron cross section σ can be defined as the area in cm2 for which the number of ...
of many actinides decreases with increasing neutron energy, but the ratio of fission to simple activation (
neutron capture Neutron capture is a nuclear reaction in which an atomic nucleus and one or more neutrons collide and merge to form a heavier nucleus. Since neutrons have no electric charge, they can enter a nucleus more easily than positively charged protons ...
) changes in favour of fission as the neutron energy increases. Thus with a sufficiently high neutron energy, it should be possible to destroy even curium without the generation of the transcurium metals. This could be very desirable as it would make it significantly easier to reprocess and handle the actinide fuel. One promising alternative from this perspective is an
accelerator-driven sub-critical reactor An accelerator-driven subcritical reactor (ADSR) is a nuclear reactor design formed by coupling a substantially subcritical nuclear reactor core with a high-energy proton or electron accelerator. It could use thorium as a fuel, which is more abun ...
/ subcritical reactor. Here a beam of either
proton A proton is a stable subatomic particle, symbol , H+, or 1H+ with a positive electric charge of +1 ''e'' elementary charge. Its mass is slightly less than that of a neutron and 1,836 times the mass of an electron (the proton–electron mass ...
s (United States and European designs) or
electron The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have n ...
s (Japanese design) is directed into a target. In the case of protons, very fast neutrons will spall off the target, while in the case of the electrons, very high energy
photon A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless, so they alwa ...
s will be generated. These high-energy neutrons and photons will then be able to cause the fission of the heavy actinides. Such reactors compare very well to other neutron sources in terms of neutron energy: * Thermal 0 to 100 eV * Epithermal 100 eV to 100 keV * Fast (from
nuclear fission Nuclear fission is a reaction in which the nucleus of an atom splits into two or more smaller nuclei. The fission process often produces gamma photons, and releases a very large amount of energy even by the energetic standards of radio ...
) 100 keV to 3 MeV * DD
fusion Fusion, or synthesis, is the process of combining two or more distinct entities into a new whole. Fusion may also refer to: Science and technology Physics *Nuclear fusion, multiple atomic nuclei combining to form one or more different atomic nucl ...
2.5 MeV * DT fusion 14 MeV * Accelerator driven core 200 MeV (lead driven by 1.6 GeV
proton A proton is a stable subatomic particle, symbol , H+, or 1H+ with a positive electric charge of +1 ''e'' elementary charge. Its mass is slightly less than that of a neutron and 1,836 times the mass of an electron (the proton–electron mass ...
s) * Muon-catalyzed fusion 7 GeV. As an alternative, the curium-244, with a half-life of 18 years, could be left to decay into plutonium-240 before being used in fuel in a fast reactor.


Fuel or targets for this actinide transmutation

To date the nature of the fuel (targets) for actinide transformation has not been chosen. If actinides are transmuted in a Subcritical reactor, it is likely that the fuel will have to be able to tolerate more thermal cycles than conventional fuel. Due to current
particle accelerator A particle accelerator is a machine that uses electromagnetic fields to propel charged particles to very high speeds and energies, and to contain them in well-defined beams. Large accelerators are used for fundamental research in particle ...
s not being optimized for long continuous operation at least the first generation of accelerator-driven sub-critical reactor is unlikely to be able to maintain a constant operation period for equally long times as a critical reactor, and each time the accelerator stops then the fuel will cool down. On the other hand, if actinides are destroyed using a fast reactor, such as an
Integral Fast Reactor The integral fast reactor (IFR, originally advanced liquid-metal reactor) is a design for a nuclear reactor using fast neutrons and no neutron moderator (a "fast" reactor). IFR would breed more fuel and is distinguished by a nuclear fuel cycle ...
, then the fuel will most likely not be exposed to many more thermal cycles than in a normal power station. Depending on the matrix the process can generate more transuranics from the matrix. This could either be viewed as good (generate more fuel) or can be viewed as bad (generation of more ''radiotoxic'' transuranic elements). A series of different matrices exists which can control this production of heavy actinides. Fissile nuclei (such as 233U, 235U, and 239Pu) respond well to delayed neutrons and are thus important to keep a critical reactor stable; this limits the amount of minor actinides that can be destroyed in a critical reactor. As a consequence, it is important that the chosen matrix allows the reactor to keep the ratio of fissile to non-fissile nuclei high, as this enables it to destroy the long-lived actinides safely. In contrast, the power output of a sub-critical reactor is limited by the intensity of the driving particle accelerator, and thus it need not contain any uranium or plutonium at all. In such a system, it may be preferable to have an inert matrix that does not produce additional long-lived isotopes. Having a low fraction of delayed neutrons is not only not a problem in a subcritical reactor, it may even be slightly advantageous as criticality can be brought closer to unity, while still staying subcritical.


=Actinides in an inert matrix

= The actinides will be mixed with a metal which will not form more actinides; for instance, an
alloy An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductili ...
of actinides in a solid such as
zirconia Zirconium dioxide (), sometimes known as zirconia (not to be confused with zircon), is a white crystalline oxide of zirconium. Its most naturally occurring form, with a monoclinic crystalline structure, is the mineral baddeleyite. A dopant ...
could be used. The raison d’être of the Initiative for Inert Matrix Fuel (IMF) is to contribute to Research and Development studies on inert matrix fuels that could be used to utilise, reduce and dispose both weapon- and light water reactor-grade plutonium excesses. In addition to plutonium, the amounts of minor actinides are also increasing. These actinides have to be consequently disposed in a safe, ecological and economical way. The promising strategy that consists of utilising plutonium and minor actinides using a once-through fuel approach within existing commercial nuclear power reactors e.g. US, European, Russian or Japanese Light Water Reactors (LWR), Canadian Pressured Heavy Water Reactors, or in future transmutation units, has been emphasised since the beginning of the initiative. The approach, which makes use of inert matrix fuel is now studied by several groups in the world. This option has the advantage of reducing the plutonium amounts and potentially minor actinide contents prior to geological disposal. The second option is based on using a uranium-free fuel leachable for reprocessing and by following a multi-recycling strategy. In both cases, the advanced fuel material produces energy while consuming plutonium or the minor actinides. This material must, however, be robust. The selected material must be the result of a careful system study including inert matrix – burnable absorbent – fissile material as minimum components and with the addition of stabiliser. This yields a single-phase solid solution or more simply if this option is not selected a composite inert matrix–fissile component. In screening studies pre-selected elements were identified as suitable. In the 90s an IMF once through strategy was adopted considering the following properties: *neutron properties i.e. low absorption cross-section, optimal constant reactivity, suitable Doppler coefficient, *phase stability, chemical inertness, and compatibility, *acceptable thermo-physical properties i.e. heat capacity, thermal conductivity, *good behaviour under irradiation i.e. phase stability, minimum swelling, *retention of fission products or residual actinides, and *optimal properties after irradiation with insolubility for once through then out. This once-through then out strategy may be adapted as a last cycle after multi-recycling if the fission yield is not large enough, in which case the following property is required good leaching properties for reprocessing and multi-recycling.


=Actinides in a thorium matrix

= Upon neutron bombardment,
thorium Thorium is a weakly radioactive metallic chemical element with the symbol Th and atomic number 90. Thorium is silvery and tarnishes black when it is exposed to air, forming thorium dioxide; it is moderately soft and malleable and has a high ...
can be converted to
uranium-233 Uranium-233 (233U or U-233) is a fissile isotope of uranium that is bred from thorium-232 as part of the thorium fuel cycle. Uranium-233 was investigated for use in nuclear weapons and as a reactor fuel. It has been used successfully in exp ...
. 233U is fissile, and has a larger fission cross section than both 235U and 238U, and thus it is far less likely to produce higher actinides through neutron capture.


=Actinides in a uranium matrix

= If the actinides are incorporated into a uranium-metal or uranium-oxide matrix, then the neutron capture of 238U is likely to generate new plutonium-239. An advantage of mixing the actinides with uranium and plutonium is that the large fission cross sections of 235U and 239Pu for the less energetic delayed neutrons could make the reaction stable enough to be carried out in a critical
fast reactor A fast-neutron reactor (FNR) or fast-spectrum reactor or simply a fast reactor is a category of nuclear reactor in which the fission chain reaction is sustained by fast neutrons (carrying energies above 1 MeV or greater, on average), as oppose ...
, which is likely to be both cheaper and simpler than an accelerator driven system.


=Mixed matrix

= It is also possible to create a matrix made from a mix of the above-mentioned materials. This is most commonly done in fast reactors where one may wish to keep the breeding ratio of new fuel high enough to keep powering the reactor, but still low enough that the generated actinides can be safely destroyed without transporting them to another site. One way to do this is to use fuel where actinides and uranium is mixed with inert zirconium, producing fuel elements with the desired properties.


Uranium cycle in renewable mode

To fulfill the conditions required for a nuclear renewable energy concept, one has to explore a combination of processes going from the front end of the nuclear fuel cycle to the fuel production and the energy conversion using specific fluid fuels and reactors, as reported by Degueldre et al. (2019). Extraction of uranium from a diluted fluid ore such as seawater has been studied in various countries worldwide. This extraction should be carried out parsimoniously, as suggested by Degueldre (2017). An extraction rate of kilotons of U per year over centuries would not modify significantly the equilibrium concentration of uranium in the oceans (3.3 ppb). This equilibrium results from the input of 10 kilotons of U per year by river waters and its scavenging on the sea floor from the 1.37 exatons of water in the oceans. For a renewable uranium extraction, the use of a specific biomass material is suggested to adsorb uranium and subsequently other transition metals. The uranium loading on the biomass would be around 100 mg per kg. After contact time, the loaded material would be dried and burned ( neutral) with heat conversion into electricity. The uranium ‘burning’ in a molten salt fast reactor helps to optimize the energy conversion by burning all actinide isotopes with an excellent yield for producing a maximum amount of thermal energy from fission and converting it into electricity. This optimisation can be reached by reducing the moderation and the fission product concentration in the liquid fuel/coolant. These effects can be achieved by using a maximum amount of actinides and a minimum amount of alkaline/earth alkaline elements yielding a harder neutron spectrum. Under these optimal conditions the consumption of natural uranium would be 7 tons per year and per gigawatt (GW) of produced electricity. The coupling of uranium extraction from the sea and its optimal utilisation in a molten salt fast reactor should allow nuclear energy to gain the label renewable. In addition, the amount of seawater used by a nuclear power plant to cool the last coolant fluid and the turbine would be ∼2.1 giga tons per year for a fast molten salt reactor, corresponding to 7 tons of natural uranium extractable per year. This practice justifies the label renewable.


Thorium cycle

In the thorium fuel cycle thorium-232 absorbs a
neutron The neutron is a subatomic particle, symbol or , which has a neutral (not positive or negative) charge, and a mass slightly greater than that of a proton. Protons and neutrons constitute the atomic nucleus, nuclei of atoms. Since protons and ...
in either a fast or thermal reactor. The thorium-233
beta decay In nuclear physics, beta decay (β-decay) is a type of radioactive decay in which a beta particle (fast energetic electron or positron) is emitted from an atomic nucleus, transforming the original nuclide to an isobar of that nuclide. For ...
s to
protactinium Protactinium (formerly protoactinium) is a chemical element with the symbol Pa and atomic number 91. It is a dense, silvery-gray actinide metal which readily reacts with oxygen, water vapor and inorganic acids. It forms various chemical compounds ...
-233 and then to
uranium-233 Uranium-233 (233U or U-233) is a fissile isotope of uranium that is bred from thorium-232 as part of the thorium fuel cycle. Uranium-233 was investigated for use in nuclear weapons and as a reactor fuel. It has been used successfully in exp ...
, which in turn is used as fuel. Hence, like
uranium-238 Uranium-238 (238U or U-238) is the most common isotope of uranium found in nature, with a relative abundance of 99%. Unlike uranium-235, it is non-fissile, which means it cannot sustain a chain reaction in a thermal-neutron reactor. However ...
, thorium-232 is a
fertile material Fertile material is a material that, although not itself fissionable by thermal neutrons, can be converted into a fissile material by neutron absorption and subsequent nuclei conversions. Naturally occurring fertile materials Naturally occurring ...
. :\overset + ^_Th -> ^_Th -> beta^-^_Pa -> beta^-\overset After starting the reactor with existing U-233 or some other
fissile material In nuclear engineering, fissile material is material capable of sustaining a nuclear fission chain reaction. By definition, fissile material can sustain a chain reaction with neutrons of thermal energy. The predominant neutron energy may be t ...
such as U-235 or
Pu-239 Plutonium-239 (239Pu or Pu-239) is an isotope of plutonium. Plutonium-239 is the primary fissile isotope used for the production of nuclear weapons, although uranium-235 is also used for that purpose. Plutonium-239 is also one of the three main ...
, a breeding cycle similar to but more efficientSee thorium fuel cycle than that with U-238 and plutonium can be created. The Th-232 absorbs a neutron to become Th-233 which quickly decays to
protactinium Protactinium (formerly protoactinium) is a chemical element with the symbol Pa and atomic number 91. It is a dense, silvery-gray actinide metal which readily reacts with oxygen, water vapor and inorganic acids. It forms various chemical compounds ...
-233. Protactinium-233 in turn decays with a half-life of 27 days to U-233. In some
molten salt reactor A molten salt reactor (MSR) is a class of nuclear fission reactor in which the primary nuclear reactor coolant and/or the fuel is a molten salt mixture. Only two MSRs have ever operated, both research reactors in the United States. The 1950's ...
designs, the Pa-233 is extracted and protected from neutrons (which could transform it to Pa-234 and then to U-234), until it has decayed to U-233. This is done in order to improve the breeding ratio which is low compared to
fast reactor A fast-neutron reactor (FNR) or fast-spectrum reactor or simply a fast reactor is a category of nuclear reactor in which the fission chain reaction is sustained by fast neutrons (carrying energies above 1 MeV or greater, on average), as oppose ...
s.
Thorium Thorium is a weakly radioactive metallic chemical element with the symbol Th and atomic number 90. Thorium is silvery and tarnishes black when it is exposed to air, forming thorium dioxide; it is moderately soft and malleable and has a high ...
is at least 4-5 times more abundant in nature than all of uranium isotopes combined; thorium is fairly evenly spread around Earth with a lot of countries having huge supplies of it; preparation of thorium fuel does not require difficult and expensive enrichment processes; the thorium fuel cycle creates mainly Uranium-233 contaminated with Uranium-232 which makes it harder to use in a normal, pre-assembled nuclear weapon which is stable over long periods of time (unfortunately drawbacks are much lower for immediate use weapons or where final assembly occurs just prior to usage time); elimination of at least the transuranic portion of the nuclear waste problem is possible in MSR and other breeder reactor designs. One of the earliest efforts to use a thorium fuel cycle took place at
Oak Ridge National Laboratory Oak Ridge National Laboratory (ORNL) is a U.S. multiprogram science and technology national laboratory sponsored by the U.S. Department of Energy (DOE) and administered, managed, and operated by UT–Battelle as a federally funded research an ...
in the 1960s. An experimental reactor was built based on
molten salt reactor A molten salt reactor (MSR) is a class of nuclear fission reactor in which the primary nuclear reactor coolant and/or the fuel is a molten salt mixture. Only two MSRs have ever operated, both research reactors in the United States. The 1950's ...
technology to study the feasibility of such an approach, using thorium fluoride
salt Salt is a mineral composed primarily of sodium chloride (NaCl), a chemical compound belonging to the larger class of salts; salt in the form of a natural crystalline mineral is known as rock salt or halite. Salt is present in vast quant ...
kept hot enough to be liquid, thus eliminating the need for fabricating fuel elements. This effort culminated in the Molten-Salt Reactor Experiment that used 232Th as the fertile material and 233U as the fissile fuel. Due to a lack of funding, the MSR program was discontinued in 1976. Thorium was first used commercially in the Indian Point Unit 1 reactor which began operation in 1962. The cost of recovering U-233 from the spent fuel was deemed uneconomical, since less than 1% of the thorium was converted to U-233. The plant's owner switched to uranium fuel, which was used until the reactor was permanently shut down in 1974.


Current industrial activity

Currently the only isotopes used as nuclear fuel are
uranium-235 Uranium-235 (235U or U-235) is an isotope of uranium making up about 0.72% of natural uranium. Unlike the predominant isotope uranium-238, it is fissile, i.e., it can sustain a nuclear chain reaction. It is the only fissile isotope that exi ...
(U-235),
uranium-238 Uranium-238 (238U or U-238) is the most common isotope of uranium found in nature, with a relative abundance of 99%. Unlike uranium-235, it is non-fissile, which means it cannot sustain a chain reaction in a thermal-neutron reactor. However ...
(U-238) and
plutonium-239 Plutonium-239 (239Pu or Pu-239) is an isotope of plutonium. Plutonium-239 is the primary fissile isotope used for the production of nuclear weapons, although uranium-235 is also used for that purpose. Plutonium-239 is also one of the three mai ...
, although the proposed thorium fuel cycle has advantages. Some modern reactors, with minor modifications, can use
thorium Thorium is a weakly radioactive metallic chemical element with the symbol Th and atomic number 90. Thorium is silvery and tarnishes black when it is exposed to air, forming thorium dioxide; it is moderately soft and malleable and has a high ...
. Thorium is approximately three times more abundant in the
Earth's crust Earth's crust is Earth's thin outer shell of rock, referring to less than 1% of Earth's radius and volume. It is the top component of the lithosphere, a division of Earth's layers that includes the crust and the upper part of the mantle. The ...
than uranium (and 550 times more abundant than uranium-235). There has been little exploration for thorium resources, and thus the
proven reserves Proven reserves (also called measured reserves, 1P, and reserves) is a measure of fossil fuel energy reserves, such as oil reserves, natural gas reserves, and coal reserves. It is defined as the " antity of energy sources estimated with reasona ...
are comparatively small.
Thorium Thorium is a weakly radioactive metallic chemical element with the symbol Th and atomic number 90. Thorium is silvery and tarnishes black when it is exposed to air, forming thorium dioxide; it is moderately soft and malleable and has a high ...
is more plentiful than
uranium Uranium is a chemical element with the symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium is weak ...
in some countries, notably
India India, officially the Republic of India (Hindi: ), is a country in South Asia. It is the List of countries and dependencies by area, seventh-largest country by area, the List of countries and dependencies by population, second-most populous ...
. The main thorium-bearing mineral,
monazite Monazite is a primarily reddish-brown phosphate mineral that contains rare-earth elements. Due to variability in composition, monazite is considered a group of minerals. The most common species of the group is monazite-(Ce), that is, the ceriu ...
is currently mostly of interest due to its content of
rare earth element The rare-earth elements (REE), also called the rare-earth metals or (in context) rare-earth oxides or sometimes the lanthanides ( yttrium and scandium are usually included as rare earths), are a set of 17 nearly-indistinguishable lustrous sil ...
s and most of the thorium is simply dumped on spoils tips similar to uranium mine tailings. As mining for rare earth elements occurs mainly in China and as it is not associated in the public consciousness with the nuclear fuel cycle, Thorium-containing mine tailings - despite their radioactivity - are not commonly seen as a
nuclear waste Radioactive waste is a type of hazardous waste that contains radioactive material. Radioactive waste is a result of many activities, including nuclear medicine, nuclear research, nuclear power generation, rare-earth mining, and nuclear weapons ...
issue and are not treated as such by regulators. Virtually all ever deployed
heavy water reactor A pressurized heavy-water reactor (PHWR) is a nuclear reactor that uses heavy water ( deuterium oxide D2O) as its coolant and neutron moderator. PHWRs frequently use natural uranium as fuel, but sometimes also use very low enriched uranium. The ...
s and some graphite-moderated reactors can use
natural uranium Natural uranium (NU or Unat) refers to uranium with the same isotopic ratio as found in nature. It contains 0.711% uranium-235, 99.284% uranium-238, and a trace of uranium-234 by weight (0.0055%). Approximately 2.2% of its radioactivity comes ...
, but the vast majority of the world's reactors require
enriched uranium Enriched uranium is a type of uranium in which the percent composition of uranium-235 (written 235U) has been increased through the process of isotope separation. Naturally occurring uranium is composed of three major isotopes: uranium-238 (238U ...
, in which the ratio of U-235 to U-238 is increased. In civilian reactors, the enrichment is increased to 3-5% U-235 and 95% U-238, but in
naval reactors Naval Reactors (NR), also known as the Naval Nuclear Propulsion Program, is an umbrella term for the U.S. government office that has comprehensive responsibility for the safe and reliable operation of the United States Navy's nuclear propulsion p ...
there is as much as 93% U-235. The fissile content in spent fuel from most
light water reactor The light-water reactor (LWR) is a type of thermal-neutron reactor that uses normal water, as opposed to heavy water, as both its coolant and neutron moderator; furthermore a solid form of fissile elements is used as fuel. Thermal-neutron react ...
s is high enough to allow its use as fuel for reactors capable of using natural uranium based fuel. However, this would require at least mechanical and/or thermal reprocessing (forming the spent fuel into a new fuel assembly) and is thus not currently widely done. The term ''
nuclear fuel Nuclear fuel is material used in nuclear power stations to produce heat to power turbines. Heat is created when nuclear fuel undergoes nuclear fission. Most nuclear fuels contain heavy fissile actinide elements that are capable of undergo ...
'' is not normally used in respect to
fusion power Fusion power is a proposed form of power generation that would generate electricity by using heat from nuclear fusion reactions. In a fusion process, two lighter atomic nuclei combine to form a heavier nucleus, while releasing energy. Devices de ...
, which fuses
isotope Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers ( mass num ...
s of
hydrogen Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-to ...
into
helium Helium (from el, ἥλιος, helios, lit=sun) is a chemical element with the symbol He and atomic number 2. It is a colorless, odorless, tasteless, non-toxic, inert, monatomic gas and the first in the noble gas group in the periodic ta ...
to release
energy In physics, energy (from Ancient Greek: ἐνέργεια, ''enérgeia'', “activity”) is the quantitative property that is transferred to a body or to a physical system, recognizable in the performance of work and in the form of ...
.


See also

* Horizontal Drillhole *
Deep Geological Repository A deep geological repository is a way of storing hazardous or radioactive waste within a stable geologic environment (typically 200–1000 m deep). It entails a combination of waste form, waste package, engineered seals and geology that is suite ...
* Deep Borehole


References


External links


World Nuclear Transport Institute
{{DEFAULTSORT:Nuclear fuel cycle Hazardous materials Nuclear fuel infrastructure Nuclear fuels Nuclear reprocessing Nuclear technology Radioactive waste