natrolite
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Natrolite is a
tectosilicate Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, silica (silicon dioxide, ) is usually consid ...
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...
species belonging to the
zeolite Zeolites are microporous, crystalline aluminosilicate materials commonly used as commercial adsorbents and catalysts. They mainly consist of silicon, aluminium, oxygen, and have the general formula ・y where is either a metal ion or H+. These pos ...
group. It is a hydrated
sodium Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable iso ...
and
aluminium Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...
silicate In chemistry, a silicate is any member of a family of polyatomic anions consisting of silicon and oxygen, usually with the general formula , where . The family includes orthosilicate (), metasilicate (), and pyrosilicate (, ). The name is al ...
with the formula . The type locality is
Hohentwiel Hohentwiel is an extinct volcano in the Hegau region of Baden-Württemberg in southern Germany The mountain is west of the city of Singen and 20 miles (30 km) from Lake Constance. Hohentwiel began forming, along with the chain of vol ...
,
Hegau The Hegau is an extinct volcanic landscape in southern Germany extending around the industrial city of Singen (Hohentwiel), between Lake Constance in the east, the Rhine River in the south, the Danube River in the north and the Randen—as the so ...
,
Germany Germany,, officially the Federal Republic of Germany, is a country in Central Europe. It is the second most populous country in Europe after Russia, and the most populous member state of the European Union. Germany is situated betwe ...
. It was named natrolite by
Martin Heinrich Klaproth Martin Heinrich Klaproth (1 December 1743 – 1 January 1817) was a German chemist. He trained and worked for much of his life as an apothecary, moving in later life to the university. His shop became the second-largest apothecary in Berlin, and ...
in 1803. The name is derived from ''natron'' (), the Greek word for
soda Soda or SODA may refer to: Chemistry * Some chemical compounds containing sodium ** Sodium carbonate, washing soda or soda ash ** Sodium bicarbonate, baking soda ** Sodium hydroxide, caustic soda ** Sodium oxide, an alkali metal oxide * Sod ...
, in reference to the sodium content, and ''lithos'' (), meaning stone. Needle stone or needle-zeolite are other informal names, alluding to the common acicular habit of the
crystal A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macros ...
s, which are often very slender and are aggregated in divergent tufts. The crystals are frequently epitaxial overgrowths of natrolite,
mesolite Mesolite is a tectosilicate mineral with formula Na2 Ca2( Al2 Si3 O10)3·8 H2O. It is a member of the zeolite group and is closely related to natrolite which it also resembles in appearance. Mesolite crystallizes in the orthorhombic system and t ...
, and gonnardite in various orders.


Properties

Larger crystals most commonly have the form of a square prism terminated by a low pyramid, the prism angle being nearly a right angle. The crystals are tetragonal in appearance, though actually orthorhombic. There are perfect cleavages parallel to the faces of the prism. The mineral also often occurs in compact fibrous aggregates, the fibers having a divergent or radial arrangement. Natrolite is readily distinguished from other fibrous zeolites by its optical characteristics. Between crossed
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s the fibers extinguish parallel to their length, and they do not show an optic figure in convergent polarized light. Natrolite is usually white or colorless, but sometimes reddish or yellowish. The luster is vitreous, or, in finely fibrous specimens, silky. The
specific gravity Relative density, or specific gravity, is the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for liquids is nearly always measured with respect to water (molecule), wa ...
is 2.2, and the
hardness In materials science, hardness (antonym: softness) is a measure of the resistance to localized plastic deformation induced by either mechanical indentation or abrasion. In general, different materials differ in their hardness; for example hard ...
is 5.5. The mineral is readily fusible, melting in a candle-flame to which it imparts a yellow color owing to the presence of sodium. It is decomposed by
hydrochloric acid Hydrochloric acid, also known as muriatic acid, is an aqueous solution of hydrogen chloride. It is a colorless solution with a distinctive pungent smell. It is classified as a strong acid Acid strength is the tendency of an acid, symbol ...
with separation of gelatinous
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...
.


Environment

Natrolite occurs with other zeolites in the amygdaloidal cavities of
basalt Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...
ic
igneous rock Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main The three types of rocks, rock types, the others being Sedimentary rock, sedimentary and metamorphic rock, metamorphic. Igneous rock ...
s. It is also common in nepheline syenites.


Notable localities

Excellent specimens of diverging groups of white prismatic crystals are found in compact
basalt Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...
at the Puy-deMarman,
Puy-de-Dôme Puy-de-Dôme (; oc, label=Auvergnat, lo Puèi de Doma or ''lo Puèi Domat'') is a department in the Auvergne-Rhône-Alpes region in the centre of France. In 2019, it had a population of 662,152.France France (), officially the French Republic ( ), is a country primarily located in Western Europe. It also comprises of Overseas France, overseas regions and territories in the Americas and the Atlantic Ocean, Atlantic, Pacific Ocean, Pac ...
. Huge crystals have been found on the Kola Peninsula, Russia (30 cm by 13 cm). The walls of cavities in the basalt of the
Giants Causeway The Giant's Causeway is an area of about 40,000 interlocking basalt columns, the result of an ancient volcanic fissure eruption. It is located in County Antrim on the north coast of Northern Ireland, about three miles (5 km) northeast of ...
, in
County Antrim County Antrim (named after the town of Antrim, ) is one of six counties of Northern Ireland and one of the thirty-two counties of Ireland. Adjoined to the north-east shore of Lough Neagh, the county covers an area of and has a population o ...
, are frequently encrusted with slender needles of natrolite, and similar material is found abundantly in the volcanic rocks (basalt and
phonolite Phonolite is an uncommon extrusive rock, of intermediate chemical composition between felsic and mafic, with texture ranging from aphanitic (fine-grained) to porphyritic (mixed fine- and coarse-grained). Phonolite is a variation of the igneous ...
) of Salesel, Aussig and several other places in the north of
Bohemia Bohemia ( ; cs, Čechy ; ; hsb, Čěska; szl, Czechy) is the westernmost and largest historical region of the Czech Republic. Bohemia can also refer to a wider area consisting of the historical Lands of the Bohemian Crown ruled by the Bohem ...
. Mont St. Hilaire,
Quebec Quebec ( ; )According to the Canadian government, ''Québec'' (with the acute accent) is the official name in Canadian French and ''Quebec'' (without the accent) is the province's official name in Canadian English is one of the thirtee ...
has produced large crystals associated with many rare minerals. The
Bay of Fundy The Bay of Fundy (french: Baie de Fundy) is a bay between the Canadian provinces of New Brunswick and Nova Scotia, with a small portion touching the U.S. state of Maine. It is an arm of the Gulf of Maine. Its extremely high tidal range is the hi ...
in
Nova Scotia Nova Scotia ( ; ; ) is one of the thirteen provinces and territories of Canada. It is one of the three Maritime provinces and one of the four Atlantic provinces. Nova Scotia is Latin for "New Scotland". Most of the population are native Eng ...
,
New Jersey New Jersey is a state in the Mid-Atlantic and Northeastern regions of the United States. It is bordered on the north and east by the state of New York; on the east, southeast, and south by the Atlantic Ocean; on the west by the Delaware ...
,
Oregon Oregon () is a U.S. state, state in the Pacific Northwest region of the Western United States. The Columbia River delineates much of Oregon's northern boundary with Washington (state), Washington, while the Snake River delineates much of it ...
, and
British Columbia British Columbia (commonly abbreviated as BC) is the westernmost province of Canada, situated between the Pacific Ocean and the Rocky Mountains. It has a diverse geography, with rugged landscapes that include rocky coastlines, sandy beaches, ...
have also produced excellent specimens. Several varieties of natrolite have been distinguished by special Nips. Fargite is a red natrolite from Glenfarg in Perthshire. Bergmannite, or Spreustein, is an impure variety which has resulted by the alteration of other minerals, chiefly
sodalite Sodalite ( ) is a tectosilicate mineral with the formula , with royal blue varieties widely used as an wikt:ornamental, ornamental gemstone. Although massive sodalite samples are opaque, crystals are usually transparent to translucent. Sodalite i ...
, in the
augite Augite is a common rock-forming pyroxene mineral with formula . The crystals are monoclinic and prismatic. Augite has two prominent cleavages, meeting at angles near 90 degrees. Characteristics Augite is a solid solution in the pyroxene group. ...
syenite Syenite is a coarse-grained intrusive igneous rock with a general composition similar to that of granite, but deficient in quartz, which, if present at all, occurs in relatively small concentrations (< 5%). Some syenites contain larger proport ...
of southern Norway. Natrolite is one of the closely associated minerals with Benitoite, a rare mineral with the type locality in San Benito County, California.


Images

File:Zeolite-greenland hg.jpg, Natrolite from the plateau basalts in east Greenland File:Natrolite-61051.jpg, Colorless, radiating natrolite in zeolite pod File:Catapleiite, Natrolite-168971.jpg, Catapleiite and natrolite from Poudrette quarry, Québec, Canada File:Natrolite-Inesite-21148.jpg, Slender needles of natrolite are accented by deep pink inesites File:Natrolite-223955.jpg, Natrolite in spherical clusters inside protective pocket of volcanic rock File:Natrolite-Inesite-37029.jpg, Natrolite sprays of stark white crystals are shooting out from a
vug A vug, vugh, or vugg ( ) is a small- to medium-sized cavity inside rock. It may be formed through a variety of processes. Most commonly, cracks and fissures opened by tectonic activity (folding and faulting) are partially filled by quartz, ...
of inesite


See also

* Pressure-induced hydration


References


External links


Structure type NATWebmineral


Attribution

{{Authority control Tectosilicates Sodium minerals Aluminium minerals Zeolites Orthorhombic minerals Minerals in space group 43 Luminescent minerals