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Marine clay is a type of
clay Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4). Clays develop plasticity when wet, due to a molecular film of water surrounding the clay pa ...
found in coastal regions around the world. In the northern, deglaciated regions, it can sometimes be quick clay, which is notorious for being involved in landslides. Marine clay is a particle of soil that is dedicated to a particle size class, this is usually associated with USDA's classification with
sand Sand is a granular material composed of finely divided mineral particles. Sand has various compositions but is defined by its grain size. Sand grains are smaller than gravel and coarser than silt. Sand can also refer to a textural class ...
at 0.05mm,
silt Silt is granular material of a size between sand and clay and composed mostly of broken grains of quartz. Silt may occur as a soil (often mixed with sand or clay) or as sediment mixed in suspension with water. Silt usually has a floury feel ...
at 0.05-.002mm and clay being less than 0.002 mm in diameter. Paired with the fact this size of particle was deposited within a marine system involving the
erosion Erosion is the action of surface processes (such as water flow or wind) that removes soil, rock, or dissolved material from one location on the Earth's crust, and then transports it to another location where it is deposited. Erosion is d ...
and
transportation Transport (in British English), or transportation (in American English), is the intentional movement of humans, animals, and goods from one location to another. Modes of transport include air, land ( rail and road), water, cable, pipelin ...
of the clay into the ocean. Soil particles become suspended when in a
solution Solution may refer to: * Solution (chemistry), a mixture where one substance is dissolved in another * Solution (equation), in mathematics ** Numerical solution, in numerical analysis, approximate solutions within specified error bounds * Solutio ...
with water, with sand being affected by the force of gravity first with suspended silt and clay still floating in solution. This is also known as
turbidity Turbidity is the cloudiness or haziness of a fluid caused by large numbers of individual particles that are generally invisible to the naked eye, similar to smoke in air. The measurement of turbidity is a key test of water quality. Fluids ...
, in which floating soil particles create a murky brown color to a water solution. These clay particles are then transferred to the
abyssal plain An abyssal plain is an underwater plain on the deep ocean floor, usually found at depths between and . Lying generally between the foot of a continental rise and a mid-ocean ridge, abyssal plains cover more than 50% of the Earth's surface ...
in which they are deposited in high percentages of clay. Once the clay is deposited on the ocean floor it can change its structure through a process known as
flocculation Flocculation, in the field of chemistry, is a process by which colloidal particles come out of suspension to sediment under the form of floc or flake, either spontaneously or due to the addition of a clarifying agent. The action differs from ...
, process by which fine particulates are caused to clump together or floc. These can be either edge to edge flocculation or edge to face flocculation. Relating to individual clay particles interacting with each other. Clays can also be aggregated or shifted in their structure besides being flocculated.


Particles configurations

Clay particles can self-assemble into various configurations, each with totally different properties. This change in structure to the clay particles is due to a swap in
cations An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by con ...
with the basic structure of a clay particle. This basic structure of the clay particle is known as a silica
tetrahedral In geometry, a tetrahedron (plural: tetrahedra or tetrahedrons), also known as a triangular pyramid, is a polyhedron composed of four triangular faces, six straight edges, and four vertex corners. The tetrahedron is the simplest of all the ...
or aluminum
octahedral In geometry, an octahedron (plural: octahedra, octahedrons) is a polyhedron with eight faces. The term is most commonly used to refer to the regular octahedron, a Platonic solid composed of eight equilateral triangles, four of which meet a ...
. They are the basic structure of clay particles composing of one
cation An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conven ...
, usually
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is ...
or
aluminum Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It ha ...
surrounded by
hydroxide Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. ...
anions An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by con ...
, these particles form in sheets forming what we know as clay particles and have very specific properties to them including micro
porosity Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measur ...
which is the ability of clay to hold water against the force of gravity, shrink swell capacity and
absorption Absorption may refer to: Chemistry and biology *Absorption (biology), digestion **Absorption (small intestine) *Absorption (chemistry), diffusion of particles of gas or liquid into liquid or solid materials *Absorption (skin), a route by which s ...
capabilities. When clay is deposited in the
ocean The ocean (also the sea or the world ocean) is the body of salt water that covers approximately 70.8% of the surface of Earth and contains 97% of Earth's water. An ocean can also refer to any of the large bodies of water into which the wor ...
, the presence of excess ions in seawater causes a loose, open structure of the clay particles to form, a process known as
flocculation Flocculation, in the field of chemistry, is a process by which colloidal particles come out of suspension to sediment under the form of floc or flake, either spontaneously or due to the addition of a clarifying agent. The action differs from ...
. Once stranded and dried by ancient changing ocean levels, this open framework means that such clay is open to water infiltration. Construction in marine clays thus presents a
geotechnical engineering Geotechnical engineering is the branch of civil engineering concerned with the engineering behavior of earth materials. It uses the principles of soil mechanics and rock mechanics for the solution of its respective engineering problems. It ...
challenge."Overcoming Problems with Marine Clays", Fairfax County, Virginia
/ref> Where clay overlies peat, a lateral movement of the coastline is indicated and shows a rise in relative sea level


Effect on building foundations

Swelling of marine clay has the potential to destroy building foundations in only a few years. Due to the changes in climatic conditions on the construction site, the pavement constructed on the marine clay (as subgrade) will have less durability and requires lot of maintenance cost. Some simple precautions, however, can reduce the hazard significantly . The swapping of this positive
cation An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conven ...
with another is what makes different types of clays including
Kaolinite Kaolinite ( ) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is an important industrial mineral. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahed ...
,
montmorillonite Montmorillonite is a very soft phyllosilicate group of minerals that form when they precipitate from water solution as microscopic crystals, known as clay. It is named after Montmorillon in France. Montmorillonite, a member of the smectite gro ...
,
smectite A smectite (from ancient Greek ''σμηκτός'' smektos 'lubricated'; ''σμηκτρίς'' smektris 'walker's earth', 'fuller's earth'; rubbing earth; earth that has the property of cleaning) is a mineral mixtures of various swelling sheet sil ...
and illite. This happens in marine clays because the ocean's water is high in solution with cations making it very easy to overcome the clays negative net charge and swap the clays cation with a less positive one. These marine clays can be what are known as quick clays, which are notorious for its erosive properties. A great example of these quick clays is in the
pacific northwest The Pacific Northwest (sometimes Cascadia, or simply abbreviated as PNW) is a geographic region in western North America bounded by its coastal waters of the Pacific Ocean to the west and, loosely, by the Rocky Mountains to the east. Thou ...
. They are known as
blue goo Blue goo is a sticky, plasticky, blueish-grey, clay-textured soil derived from a highly weathered serpentinite mélange. The name derives from the soil's color; a result of undergoing anaerobic conditions and becoming gleyed. A greyer variation i ...
which is a mix of clay and
mélange In geology, a mélange is a large-scale breccia, a mappable body of rock characterized by a lack of continuous bedding and the inclusion of fragments of rock of all sizes, contained in a fine-grained deformed matrix. The mélange typically cons ...
( greenstone,
basalt Basalt (; ) is an aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the surface of a rocky planet or moon. More than 90 ...
,
chert Chert () is a hard, fine-grained sedimentary rock composed of microcrystalline or cryptocrystalline quartz, the mineral form of silicon dioxide (SiO2). Chert is characteristically of biological origin, but may also occur inorganically as a ...
,
shale Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4) and tiny fragments (silt-sized particles) of other minerals, especiall ...
,
sandstone Sandstone is a clastic sedimentary rock composed mainly of sand-sized (0.0625 to 2 mm) silicate grains. Sandstones comprise about 20–25% of all sedimentary rocks. Most sandstone is composed of quartz or feldspar (both silicat ...
,
schists Schist ( ) is a medium-grained metamorphic rock showing pronounced schistosity. This means that the rock is composed of mineral grains easily seen with a low-power hand lens, oriented in such a way that the rock is easily split into thin flakes o ...
. uplifted through the
accretionary wedge An accretionary wedge or accretionary prism forms from sediments accreted onto the non- subducting tectonic plate at a convergent plate boundary. Most of the material in the accretionary wedge consists of marine sediments scraped off from the d ...
). These quick clays have a very high-risk factor associated with them if they are built upon, as they are very unstable due to the fact that
liquefaction In materials science, liquefaction is a process that generates a liquid from a solid or a gas or that generates a non-liquid phase which behaves in accordance with fluid dynamics. It occurs both naturally and artificially. As an example of th ...
happens when it becomes saturated and literally flows, causing mass wasting events to happen. Other marine clays are used all around the world for many different uses, such as
ceramics A ceramic is any of the various hard, brittle, heat-resistant and corrosion-resistant materials made by shaping and then firing an inorganic, nonmetallic material, such as clay, at a high temperature. Common examples are earthenware, porcelain ...
, building material, including
adobe Adobe ( ; ) is a building material made from earth and organic materials. is Spanish for '' mudbrick''. In some English-speaking regions of Spanish heritage, such as the Southwestern United States, the term is used to refer to any kind of ...
. Clay layers in soils which can be used as an impermeable layer are very important for dumps or
chemical spills A chemical accident is the unintentional release of one or more chemical hazard substances which could harm human health and the environment. Such events include fires, explosions, leakages or release of toxic or hazardous materials that can cause ...
as they have a very high absorption capacity for heavy metals. For these clays to be available for human use they must have been eroded, deposited on the ocean floor and then
uplift Uplift may refer to: Science * Geologic uplift, a geological process ** Tectonic uplift, a geological process * Stellar uplift, the theoretical prospect of moving a stellar mass * Uplift mountains * Llano Uplift * Nemaha Uplift Business * Upli ...
ed through means of
tectonic Tectonics (; ) are the processes that control the structure and properties of the Earth's crust and its evolution through time. These include the processes of mountain building, the growth and behavior of the strong, old cores of continents ...
activity to bring it to land. During the construction of
Marina Barrage Marina Barrage is a dam in southern Singapore built at the confluence of five rivers, across the Marina Channel between Marina East and Marina South. First conceptualised in 1987 by then prime minister Lee Kuan Yew to help achieve greater self ...
in
Singapore Singapore (), officially the Republic of Singapore, is a sovereign island country and city-state in maritime Southeast Asia. It lies about one degree of latitude () north of the equator, off the southern tip of the Malay Peninsula, bor ...
, marine clay was found at the site. Since marine clay was the cause of the Nicoll Highway collapse years previous, the construction team removed all the marine clay to ensure the stability of Marina Barrage. Later on, they found marine clay mixed with seawater even in the deeper underground. Geotechnical problems posed by marine clay can be handled by various ground improvement techniques. Marine clay can be densified by mixing it with cement or similar binding material in specific proportions. Marine clay can be stabilised using wastes of various industries like porcelain industry and tree-cutting industries. This method is usually adopted in highways where marine clay is used as a subgrade soil.


References

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Bibliography

* ̈Effect of pore water chemistry on the hydro-mechanical behaviour of Lianyungang soft marine clay- Deng, Y.F. ; Yue, X.B. ; Cui, Y.J. ; Shao, G.H. ; Liu, S.Y. ; Zhang, D.W. Applied Clay Science, June 2014, Vol.95, pp. 167–175 * ̈Strength of High Water Content Marine Clay Stabilized by Low Amount of Cement; Zhang, R ; Santoso, A ; Tan, T ; Phoon, Kː Journal of Geotechnical and Geoenvironmental Engineering, April 23, 2013 * Structuration and Destructuration Behavior of Cement-Treated Singapore Marine Clay; Kamruzzaman, A ; Chew, S ; Lee, F; Journal of Geotechnical Engineering, Apr. 2009, Issue 4, pp. 573–589 * Sulfidization of lacustrine glacial clay upon Holocene marine transgression (Arkona Basin, Baltic Sea); Holmkvist, Lars ; Kamyshny, Alexey ; Brüchert, Volker ; Ferdelman, Timothy G. ; Jørgensen, Bo Barker; Geochimica et Cosmochimica Acta, 1 October 2014, Vol.142, pp. 75–94 * Linear and Nonlinear Dynamic Response of Piles in Soft Marine Clay; Dezi, Francesca ; Gara, Fabrizio ; Roia, Davide; Journal of Geotechnical and Geoenvironmental Engineering, July 29, 2016, Vol.143(1) Oceanography Sediments