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An inert gas is a gas that does not readily undergo chemical reactions with other chemical substances and therefore does not readily form chemical compounds. The
noble gases The noble gases (historically also the inert gases; sometimes referred to as aerogens) make up a class of chemical elements with similar properties; under standard conditions, they are all odorless, colorless, monatomic gases with very low ch ...
often do not react with many substances and were historically referred to as the inert gases. Inert gases are used generally to avoid unwanted chemical reactions degrading a sample. These undesirable chemical reactions are often
oxidation Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a ...
and
hydrolysis Hydrolysis (; ) is any chemical reaction in which a molecule of water breaks one or more chemical bonds. The term is used broadly for substitution, elimination, and solvation reactions in which water is the nucleophile. Biological hydrolys ...
reactions with the oxygen and moisture in
air The atmosphere of Earth is the layer of gases, known collectively as air, retained by Earth's gravity that surrounds the planet and forms its planetary atmosphere. The atmosphere of Earth protects life on Earth by creating pressure allowing f ...
. The term ''inert gas'' is context-dependent because several of the noble gases can be made to react under certain conditions. Purified
argon Argon is a chemical element with the symbol Ar and atomic number 18. It is in group 18 of the periodic table and is a noble gas. Argon is the third-most abundant gas in Earth's atmosphere, at 0.934% (9340 ppmv). It is more than twice as ...
gas is the most commonly used inert gas due to its high natural abundance (78.3% N2, 1% Ar in air) and low relative cost. Unlike
noble gas The noble gases (historically also the inert gases; sometimes referred to as aerogens) make up a class of chemical elements with similar properties; under standard conditions, they are all odorless, colorless, monatomic gases with very low ch ...
es, an inert gas is not necessarily elemental and is often a
compound Compound may refer to: Architecture and built environments * Compound (enclosure), a cluster of buildings having a shared purpose, usually inside a fence or wall ** Compound (fortification), a version of the above fortified with defensive struc ...
gas. Like the noble gases, the tendency for non-reactivity is due to the valence, the outermost
electron shell In chemistry and atomic physics, an electron shell may be thought of as an orbit followed by electrons around an atom's nucleus. The closest shell to the nucleus is called the "1 shell" (also called the "K shell"), followed by the "2 shell" (or ...
, being complete in all the inert gases. This is a tendency, not a rule, as noble gases and other "inert" gases can react to form compounds.


Need/Necessity

The inert gases are obtained by fractional distillation of air, with the exception of
helium Helium (from el, ἥλιος, helios, lit=sun) is a chemical element with the symbol He and atomic number 2. It is a colorless, odorless, tasteless, non-toxic, inert, monatomic gas and the first in the noble gas group in the periodic table. ...
which is separated from a few
natural gas Natural gas (also called fossil gas or simply gas) is a naturally occurring mixture of gaseous hydrocarbons consisting primarily of methane in addition to various smaller amounts of other higher alkanes. Low levels of trace gases like carbo ...
sources rich in this element, through cryogenic distillation or membrane separation. For specialized applications, purified inert gas shall be produced by specialized generators on-site. They are often used by chemical tankers and product carriers (smaller vessels). Benchtop specialized generators are also available for laboratories.


Applications

Because of the non-reactive properties of inert gases, they are often useful to prevent undesirable
chemical reaction A chemical reaction is a process that leads to the IUPAC nomenclature for organic transformations, chemical transformation of one set of chemical substances to another. Classically, chemical reactions encompass changes that only involve the pos ...
s from taking place. Food is packed in an inert gas to remove oxygen gas. This prevents bacteria from growing. It also prevents chemical oxidation by oxygen in normal air. An example is the rancidification (caused by oxidation) of edible oils. In food packaging, inert gases are used as a passive preservative, in contrast to active preservatives like
sodium benzoate Sodium benzoate is the sodium salt of benzoic acid, widely used as a food preservative (with an E number of E211) and a pickling agent. It appears as a white crystalline chemical with the formula C6H5COONa. Production Sodium benzoate is commo ...
(an
antimicrobial An antimicrobial is an agent that kills microorganisms or stops their growth. Antimicrobial medicines can be grouped according to the microorganisms they act primarily against. For example, antibiotics are used against bacteria, and antifungals ar ...
) or BHT (an antioxidant). Historical documents may also be stored under inert gas to avoid degradation. For example, the original documents of the
U.S. Constitution The Constitution of the United States is the supreme law of the United States of America. It superseded the Articles of Confederation, the nation's first constitution, in 1789. Originally comprising seven articles, it delineates the nation ...
are stored under humidified argon. Helium was previously used, but it was less suitable because it diffuses out of the case more quickly than argon. Inert gases are often used in the chemical industry. In a chemical manufacturing plant, reactions can be conducted under inert gas to minimize fire hazards or unwanted reactions. In such plants and in oil refineries, transfer lines and vessels can be
purged In history, religion and political science, a purge is a position removal or execution of people who are considered undesirable by those in power from a government, another organization, their team leaders, or society as a whole. A group undertak ...
with inert gas as a fire and explosion prevention measure. At the bench scale, chemists perform experiments on air-sensitive compounds using
air-free technique Air-free techniques refer to a range of manipulations in the chemistry laboratory for the handling of compounds that are air-sensitive. These techniques prevent the compounds from reacting with components of air, usually water and oxygen; less ...
s developed to handle them under inert gas. Helium, neon, argon, krypton, xenon, and radon are inert gases.


Inert gas systems on ships

Inert gas is produced on board crude oil carriers (above 8,000 tonnes)(from Jan 1, 2016) by burning kerosene in a dedicated
inert gas generator Inert gas generator (IGG) refers to machinery on board marine product tankers. Inert gas generators consist distinctively of a gas producer and a scrubbing system. Process Diesel is burned using atmospheric air in a combustion chamber and the ex ...
. The inert gas system is used to prevent the atmosphere in cargo
tank A tank is an armoured fighting vehicle intended as a primary offensive weapon in front-line ground combat. Tank designs are a balance of heavy firepower, strong armour, and good battlefield mobility provided by tracks and a powerful engi ...
s or
bunker A bunker is a defensive military fortification designed to protect people and valued materials from falling bombs, artillery, or other attacks. Bunkers are almost always underground, in contrast to blockhouses which are mostly above ground. T ...
s from coming into the explosive range. Inert gases keep the
oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as ...
content of the tank atmosphere below 5% (on crude carriers, less for product carriers and gas tankers), thus making any air/hydrocarbon gas mixture in the tank too rich (too high a fuel to oxygen ratio) to ignite. Inert gases are most important during discharging and during the ballast voyage when more
hydrocarbon In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or ...
vapor is likely to be present in the tank atmosphere. Inert gas can also be used to purge the tank of the volatile atmosphere in preparation for gas freeing - replacing the atmosphere with breathable air - or vice versa. The flue gas system uses the boiler exhaust as its source, so it is important that the fuel/air ratio in the boiler burners is properly regulated to ensure that high-quality inert gases are produced. Too much air would result in an oxygen content exceeding 5%, and too much fuel oil would result in the carryover of dangerous hydrocarbon gas. The flue gas is cleaned and cooled by the scrubber tower. Various safety devices prevent overpressure, the return of hydrocarbon gas to the engine room, or having a supply of IG with too high oxygen content. Gas tankers and product carriers cannot rely on flue gas systems (because they require IG with O2 content of 1% or less) and so use inert gas generators instead. The inert gas generator consists of a combustion chamber and scrubber unit supplied by fans and a refrigeration unit which cools the gas. A drier in series with the system removes moisture from the gas before it is supplied to the deck. Cargo tanks on gas carriers are not inerted, but the whole space around them is.


Inert gas systems on aircraft

Inert gas is produced on board commercial and military aircraft in order to passivate fuel tanks. On hot days, fuel vapor in fuel tanks may otherwise form a flammable or explosive mixture which if oxidized, could have catastrophic consequences. Conventionally, Air Separation Modules (ASMs) have been used to generate inert gas. ASMs contain selectively permeable membranes. They are fed compressed air that is extracted from a compressor stage of a gas turbine engine. The pressure drives the separation of oxygen from the air due to the increased permeability of oxygen through the ASMs in comparison to nitrogen. For fuel tank passivation, it is not necessary to remove all oxygen, but rather enough to stay below the lean flammability limit and the lean explosion limit. An oxygen concentration of 10% to 12% is common over the course of a flight.


Welding

In gas tungsten
arc welding Arc welding is a welding process that is used to join metal to metal by using electricity to create enough heat to melt metal, and the melted metals, when cool, result in a binding of the metals. It is a type of welding that uses a welding powe ...
(GTAW), inert gases are used to shield the tungsten from contamination. It also shields the fluid metal (created from the arc) from the reactive gases in air which can cause porosity in the solidified weld puddle. Inert gases are also used in
gas metal arc welding Gas metal arc welding (GMAW), sometimes referred to by its subtypes metal inert gas (MIG) and metal active gas (MAG) is a welding process in which an electric arc forms between a consumable MIG wire electrode and the workpiece metal(s), which hea ...
(GMAW) for welding non-ferrous metals.Davis, J.R., ed. ''Corrosion: Understanding the Basics.'' Materials Park, Ohio: ASM International, 2000. 188. Some gases which are not usually considered inert but which behave like inert gases in all the circumstances likely to be encountered in some use can often be used as a substitute for an inert gas. This is useful when an appropriate pseudo-inert gas can be found which is inexpensive and common. For example,
carbon dioxide Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is trans ...
is sometimes used in gas mixtures for GMAW because it is not reactive to the weld pool created by arc welding. But it is reactive to the arc. The more carbon dioxide that is added to the inert gas, such as argon, will increase your penetration. The amount of carbon dioxide is often determined by what kind of transfer you will be using in GMAW. The most common is spray arc transfer, and the most commonly used gas mixture for spray arc transfer is 90% argon and 10% carbon dioxide.


Diving

In
underwater diving Underwater diving, as a human activity, is the practice of descending below the water's surface to interact with the environment. It is also often referred to as diving, an ambiguous term with several possible meanings, depending on contex ...
an inert gas is a component of the breathing mixture which is not metabolically active and serves to dilute the gas mixture. The inert gas may have effects on the diver, but these are thought to be mostly physical effects, such as tissue damage caused by bubbles in
decompression sickness Decompression sickness (abbreviated DCS; also called divers' disease, the bends, aerobullosis, and caisson disease) is a medical condition caused by dissolved gases emerging from solution as bubbles inside the body tissues during decompressio ...
. The most common inert gas used in breathing gas for commercial diving is
helium Helium (from el, ἥλιος, helios, lit=sun) is a chemical element with the symbol He and atomic number 2. It is a colorless, odorless, tasteless, non-toxic, inert, monatomic gas and the first in the noble gas group in the periodic table. ...
.


See also

* * * for aircraft * * , a fire and explosion prevention procedure to avoid the formation of an ignitable atmosphere, accomplished by flushing a closed system with an inert gas * , a fire and explosion prevention procedure to make an ignitable atmosphere safe, accomplished by injecting an inert gas


References

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