Glucal is the
glycal
Glycal is a name for cyclic enol ether derivatives of sugars having a double bond between carbon atoms 1 and 2 of the ring. The term “glycal” should not be used for an unsaturated sugar that has a double bond in any position other than between ...
formed from
glucose
Glucose is a simple sugar with the molecular formula . Glucose is overall the most abundant monosaccharide, a subcategory of carbohydrates. Glucose is mainly made by plants and most algae during photosynthesis from water and carbon dioxide, using ...
. It is a chemical intermediate in the synthesis of a variety of
oligosaccharide
An oligosaccharide (/ˌɑlɪgoʊˈsækəˌɹaɪd/; from the Greek ὀλίγος ''olígos'', "a few", and σάκχαρ ''sácchar'', "sugar") is a saccharide polymer containing a small number (typically two to ten) of monosaccharides (simple sugar ...
s.
[Seeberger, P.H., et al. ''Aldrichimica Acta'' 30, 75, (1997)]
Glucal and its derivatives can be converted to other chemically useful sugars using the
Ferrier rearrangement
The Ferrier rearrangement is an organic reaction that involves a nucleophilic substitution reaction combined with an allylic shift in a glycal (a 2,3- unsaturated glycoside). It was discovered by the carbohydrate chemist Robert J. Ferrier.
Me ...
.
References
Monosaccharides
Oxygen heterocycles
Heterocyclic compounds with 1 ring
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