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Glaucophane is the name of a
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ...
and a mineral group belonging to the sodic
amphibole Amphibole () is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is ...
supergroup of the double chain
inosilicate Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, silica (silicon dioxide, ) is usually consid ...
s, with the chemical formula ☐Na2(Mg3Al2)Si8O22(OH)2. Glaucophane crystallizes in the
monoclinic system In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic ...
.


Name

Glaucophane is named for its typical blue color. In
Greek Greek may refer to: Greece Anything of, from, or related to Greece, a country in Southern Europe: *Greeks, an ethnic group. *Greek language, a branch of the Indo-European language family. **Proto-Greek language, the assumed last common ancestor ...
, ''glaucophane'' means "blue appearing". As the major mineral component, it is glaucophane's color that gives the "
blueschist Blueschist (), also called glaucophane schist, is a metavolcanic rock that forms by the metamorphism of basalt and rocks with similar composition at high pressures and low temperatures (), approximately corresponding to a depth of . The blue ...
"
metamorphic rock Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock (protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, caus ...
type its name.


Characteristics

The blue color is very diagnostic for this species. Glaucophane, along with the closely related mineral
riebeckite Riebeckite is a sodium-rich member of the amphibole group of silicate minerals, chemical formula Na2(Fe2+3Fe3+2)Si8O22(OH)2. It forms a solid solution series with magnesioriebeckite. It crystallizes in the monoclinic system, usually as long pris ...
, to which it forms a series with, and their intermediate crossite, are the only well known
amphiboles Amphibole () is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is A ...
that are commonly blue. Glaucophane forms a
solid solution A solid solution, a term popularly used for metals, is a homogenous mixture of two different kinds of atoms in solid state and have a single crystal structure. Many examples can be found in metallurgy, geology, and solid-state chemistry. The word ...
series with ferroglaucophane (). Glaucophane is the
magnesium Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ta ...
-rich
endmember An endmember (also end-member or end member) in mineralogy is a mineral that is at the extreme end of a mineral series in terms of purity of its chemical composition. Minerals often can be described as solid solutions with varying compositions of ...
and ferroglaucophane is the
iron Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in fro ...
-rich endmember. Ferroglaucophane is similar to glaucophane but is slightly denser and hence increased
specific gravity Relative density, or specific gravity, is the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for liquids is nearly always measured with respect to water at its densest ...
. The two endmembers are indistinguishable in hand specimens and are strongly
pleochroic Pleochroism (from Greek πλέων, ''pléōn'', "more" and χρῶμα, ''khrôma'', "color") is an optical phenomenon in which a substance has different colors when observed at different angles, especially with polarized light. Backgroun ...
. Glaucophane's
hardness In materials science, hardness (antonym: softness) is a measure of the resistance to localized plastic deformation induced by either mechanical indentation or abrasion. In general, different materials differ in their hardness; for example har ...
is 5–6 and its specific gravity is approximately 3–3.2.


Occurrence

The blueschist
metamorphic facies A metamorphic facies is a set of mineral assemblages in metamorphic rocks formed under similar pressures and temperatures.Essentials of Geology, 3rd Edition, Stephen Marshak The assemblage is typical of what is formed in conditions corresponding ...
gets its name from abundant blue minerals glaucophane and
lawsonite Lawsonite is a hydrous calcium aluminium sorosilicate mineral with formula CaAl2Si2O7(OH)2·H2O. Lawsonite crystallizes in the orthorhombic system in prismatic, often tabular crystals. Crystal twinning is common. It forms transparent to transluce ...
. Glaucophane generally forms in blueschist metamorphic rocks of gabbroic or basaltic composition that are rich in
sodium Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable ...
and have experienced low temperature-high pressure
metamorphism Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of ch ...
such as would occur along a
subduction Subduction is a geological process in which the oceanic lithosphere is recycled into the Earth's mantle at convergent boundaries. Where the oceanic lithosphere of a tectonic plate converges with the less dense lithosphere of a second plate, t ...
zone. This material has undergone intense pressure and moderate heat as it was subducted downward toward the mantle. Glaucophane is also found in
eclogite Eclogite () is a metamorphic rock containing garnet (almandine- pyrope) hosted in a matrix of sodium-rich pyroxene ( omphacite). Accessory minerals include kyanite, rutile, quartz, lawsonite, coesite, amphibole, phengite, paragonite, zoisi ...
s that have undergone retrograde metamorphism. There is also a rare amphibole called holmquistite, chemical formula Li2Mg3Al2Si8O22(OH)2, which occurs only in lithium-rich continental rocks. For many years, holmquistite was mistaken for glaucophane, as the two look identical in thin section.


See also

*
List of Minerals This is a list of minerals for which there are articles on Wikipedia. Minerals are distinguished by various chemical and physical properties. Differences in chemical composition and crystal structure distinguish the various ''species''. Within a ...


References

{{Authority control Sodium minerals Magnesium minerals Iron(II) minerals Aluminium minerals Amphibole group Monoclinic minerals Minerals in space group 12