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Fireproofing is rendering something ( structures, materials, etc.) resistant to fire, or incombustible; or material for use in making anything fire-proof. It is a passive fire protection measure. "Fireproof" or "fireproofing" can be used as a noun, verb or adjective; it may be hyphenated ("fire-proof"). Applying a certification listed fireproofing system to certain structures allows them to have a
fire-resistance rating A fire-resistance rating typically means the duration for which a passive fire protection system can withstand a standard fire resistance test. This can be quantified simply as a measure of time, or it may entail other criteria, involving eviden ...
. The term "fireproofing" may be used in conjunction with standards, as reflected in common North American construction specifications. An item classed as fireproof is resistant in specified circumstances, and may burn or be rendered inoperable by fire exceeding the intensity or duration that it is designed to withstand.


Markets

* Commercial construction * Residential construction * Industrial construction * Marine ( ships) * Offshore construction *
Aerodynamics Aerodynamics, from grc, ἀήρ ''aero'' (air) + grc, δυναμική (dynamics), is the study of the motion of air, particularly when affected by a solid object, such as an airplane wing. It involves topics covered in the field of fluid dyn ...
*
Tunnel A tunnel is an underground passageway, dug through surrounding soil, earth or rock, and enclosed except for the entrance and exit, commonly at each end. A pipeline is not a tunnel, though some recent tunnels have used immersed tube const ...
concrete walls and ceilings or linings * Under- and above-ground mining operations


Applications

* Structural steel to keep below critical temperature ca. 540 °C * Electrical circuits to keep critical electrical circuits below 140 °C so they stay operational * Liquified petroleum gas containers to prevent a BLEVE (boiling liquid expanding vapour explosion) * Vessel skirts and pipe bridges in an
oil refinery An oil refinery or petroleum refinery is an industrial process plant where petroleum (crude oil) is transformed and refined into useful products such as gasoline (petrol), diesel fuel, asphalt base, fuel oils, heating oil, kerosene, liquefie ...
or
chemical plant A chemical plant is an industrial process plant that manufactures (or otherwise processes) chemicals, usually on a large scale. The general objective of a chemical plant is to create new material wealth via the chemical or biological transfor ...
to keep the structural steel below critical temperature ca. 540° * Concrete linings of traffic tunnels * Fireblocking: In a wood frame construction, gaps are created by joists or studs in floor or wall partitions. These hollow spaces allow fire to travel easily from one area to another. Fireblocks are installed internally to divide these areas into smaller intervals. Common materials used include solid lumber, plywood, OSB,
Particle board Particle board, also known as chipboard or low-density fiberboard, is an engineered wood product manufactured from wood chips and a synthetic resin or other suitable binder, which is pressed and extruded. Particle board is often confused with o ...
,
gypsum board Drywall (also called plasterboard, dry lining, wallboard, sheet rock, gypsum board, buster board, custard board, and gypsum panel) is a panel made of calcium sulfate dihydrate (gypsum), with or without additives, typically extruded between thick ...
, cement fiberboard, or glass fiber insulation batts. *
Firewall (construction) A firewall is a fire-resistant barrier used to prevent the spread of fire. Firewalls are built between or through buildings, structures, or electrical substation transformers, or within an aircraft or vehicle. Applications Firewalls can be us ...
is a common method employed to separate a building into small units to restrict or delay the spread of fire from one section to the next. Fire walls usually extend the full length of a building, from foundation to roof. * Fire barriers and fire partitions: They are similar to fire walls in operation; however, their height is limited to a single floor, from the slab of one floor to the underside of the next. *
Coating A coating is a covering that is applied to the surface of an object, usually referred to as the substrate. The purpose of applying the coating may be decorative, functional, or both. Coatings may be applied as liquids, gases or solids e.g. Powde ...
s, e.g. to fireproof wood.


History

Asbestos Asbestos () is a naturally occurring fibrous silicate mineral. There are six types, all of which are composed of long and thin fibrous crystals, each fibre being composed of many microscopic "fibrils" that can be released into the atmosphere ...
was one material historically used for fireproofing, either on its own, or together with binders such as
cement A cement is a binder, a chemical substance used for construction that sets, hardens, and adheres to other materials to bind them together. Cement is seldom used on its own, but rather to bind sand and gravel ( aggregate) together. Cement mi ...
, either in sprayed form or in pressed sheets, or as additives to a variety of materials and products, including
fabric Textile is an umbrella term that includes various fiber-based materials, including fibers, yarns, filaments, threads, different fabric types, etc. At first, the word "textiles" only referred to woven fabrics. However, weaving is not t ...
s for
protective clothing Personal protective equipment (PPE) is protective clothing, helmets, goggles, or other garments or equipment designed to protect the wearer's body from injury or infection. The hazards addressed by protective equipment include physical, ele ...
and building materials. Because the material was later proven to cause cancer, a large removal-and-replacement industry has been established.
Endothermic In thermochemistry, an endothermic process () is any thermodynamic process with an increase in the enthalpy (or internal energy ) of the system.Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).''Principle of Modern Chemistry'', Brooks Cole. p. ...
materials have also been used to a large extent and are still in use today, such as
gypsum Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, blackboard or sidewalk chalk, and drywa ...
, concrete and other cementitious products. More highly evolved versions of these are used in
aerodynamics Aerodynamics, from grc, ἀήρ ''aero'' (air) + grc, δυναμική (dynamics), is the study of the motion of air, particularly when affected by a solid object, such as an airplane wing. It involves topics covered in the field of fluid dyn ...
, intercontinental ballistic missiles (ICBMs) and re-entry vehicles, such as the Space Shuttles. The use of these older materials has been standardised in "old" systems, such as those listed in BS476, DIN4102 and the
National Building Code of Canada The National Building Code of Canada is the model building code of Canada. It is issued by the National Research Council of Canada. As a model code, it has no legal status until it is adopted by a jurisdiction that regulates construction. History ...
.


Fireproofing of structural steel

In a building fire, structural steel loses strength as the temperature increases. In order to maintain the structural integrity of the steel frame, several fireproofing measurements are taken: * restrictions on the amount of exposed steel set by
building code A building code (also building control or building regulations) is a set of rules that specify the standards for constructed objects such as buildings and non-building structures. Buildings must conform to the code to obtain planning permissi ...
s.Allen 2009, p. 459 * encasing structural steel in
brick A brick is a type of block used to build walls, pavements and other elements in masonry construction. Properly, the term ''brick'' denotes a block composed of dried clay, but is now also used informally to denote other chemically cured cons ...
masonry or concrete to delay exposure to high temperatures. Historically, these masonry encasement methods use large amounts of heavy materials, thus greatly increasing the load to the steel frame. Newer materials and methods have been developed to resolve this issue. The following lists both older and newer methods of fireproofing steel beams ( i-beams): * complete encasement in concrete square column.Allen 2009, p. 460 - 463 * wrapping the i-beam in a thin layer of metal lath and then covering it with gypsum plaster. This method is effective because gypsum plaster contains water crystals that are heat resistant. * applying multiple layers of
gypsum board Drywall (also called plasterboard, dry lining, wallboard, sheet rock, gypsum board, buster board, custard board, and gypsum panel) is a panel made of calcium sulfate dihydrate (gypsum), with or without additives, typically extruded between thick ...
around the i-beam. * applying spray-on fireproofing around the i-beam. Also called spray-applied fire-resistive materials (SFRM) using air pressured spray gun, which can be made from gypsum plaster, mineral fibers mixed with inorganic binder or a cementitious formula using magnesium oxychloride cement. * enclosing the i-beam in sheet metal and fill with loose insulation. * hollow columns filled with liquid water or
antifreeze An antifreeze is an additive which lowers the freezing point of a water-based liquid. An antifreeze mixture is used to achieve freezing-point depression for cold environments. Common antifreezes also increase the boiling point of the liquid, all ...
. When part of the column is exposed to fire, the heat is dissipated throughout by the convection property of the liquid. * encasing the i-beam in rigid concrete slab. * a layer of suspended plaster ceiling isolating the i-beam


Alternative methods

Among the conventional materials, purpose-designed spray fireproofing
plaster Plaster is a building material used for the protective or decorative coating of walls and ceilings and for moulding and casting decorative elements. In English, "plaster" usually means a material used for the interiors of buildings, while "re ...
s have become abundantly available the world over. The inorganic methods include: *
Gypsum Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, blackboard or sidewalk chalk, and drywa ...
plasters * Cementitious plasters * Fibrous plasters The industry considers
gypsum Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, blackboard or sidewalk chalk, and drywa ...
-based plasters to be "cementitious", even though these contain no Portland, or calcium aluminate cements. Cementitious plasters that contain Portland cement have been traditionally lightened by the use of inorganic lightweight aggregates, such as vermiculite and perlite. Gypsum plasters have been lightened by using chemical additives to create bubbles that displace solids, thus reducing the bulk density. Also, lightweight polystyrene beads have been mixed into the plasters at the factory in an effort to reduce the density, which generally results in a more effective insulation at a lower cost. The resulting plaster has qualified to the A2 combustibility rating as per DIN4102. Fibrous plasters, containing either
mineral wool Mineral wool is any fibrous material formed by spinning or drawing molten mineral or rock materials such as slag and ceramics. Applications of mineral wool include thermal insulation (as both structural insulation and pipe insulation), fil ...
, or ceramic fibres tend to simply entrain more air, thus displacing the heavy fibres. On-site cost reduction efforts, at times purposely contravening the requirements of the
certification listing A certification listing is a document used to guide installations of certified products, against which a field installation is compared to make sure that it complies with a regulation (e.g., a building code). Typically, products or items are req ...
, can further enhance such displacement of solids. This has resulted in
architect An architect is a person who plans, designs and oversees the construction of buildings. To practice architecture means to provide services in connection with the design of buildings and the space within the site surrounding the buildings that h ...
s' specifying the use of on-site testing of proper densities to ensure the products installed meet the certification listings employed for each installed configuration, because excessively light inorganic fireproofing does not provide adequate protection and, thus, could be in violation of the listings. Proprietary boards and sheets, made of
gypsum Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, blackboard or sidewalk chalk, and drywa ...
,
calcium silicate Calcium silicate is the chemical compound Ca2SiO4, also known as calcium orthosilicate and is sometimes formulated as 2CaO·SiO2. It is also referred to by the shortened trade name Cal-Sil or Calsil. It occurs naturally as the mineral larnite. ...
, vermiculite, perlite, mechanically-bonded composite boards made of punched sheet-metal and cellulose-reinforced concrete have all been used to clad items for increased fire resistance. An alternative method to keep building steel below its softening temperature is to use liquid convection cooling in hollow structural members. This method was patented in the 19th century although the first prominent example was 89 years later.


Substandard

Money can be saved fraudulently by using apparently suitable fireproofing that is not built to the required standard. Such fraud can be prevented when documentation is required and checked to ensure that all installed configurations meet the certification standards. Possible cases include: * Entraining too much air in inorganic systems, thus reducing densities below fire-tested, saving on materials and labour. * Spraying inorganic fireproofing materials over through-penetrations and building joints that should be
firestop A firestop or fire-stopping is a form of passive fire protection that is used to seal around openings and between joints in a fire-resistance-rated wall or floor assembly. Firestops are designed to maintain the fire-resistance rating of a wall o ...
ped, not ''fireproofed''. This practice negates fire-separation integrity. Firestops must precede spray fireproofing. * Substitution of intumescent and/or
endothermic In thermochemistry, an endothermic process () is any thermodynamic process with an increase in the enthalpy (or internal energy ) of the system.Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).''Principle of Modern Chemistry'', Brooks Cole. p. ...
fireproofing coatings by less expensive paints of similar appearance, sometimes in the packaging of the correct materials. * The American and Canadian nuclear industries have, historically, not insisted on listing and approval use and compliance, on the basis of the use of accredited certification laboratories. This has allowed the use of Thermo-Lag 330-1, for which the basis of testing has been proven to be faulty, requiring millions of dollars of remedial work. The Thermo-Lag scandal came to light as a result of disclosures by
American American(s) may refer to: * American, something of, from, or related to the United States of America, commonly known as the "United States" or "America" ** Americans, citizens and nationals of the United States of America ** American ancestry, pe ...
whistleblower Gerald W. Brown, who reported the deficiencies in
fire test A fire test is a means of determining whether fire protection products meet minimum performance criteria as set out in a building code or other applicable legislation. Successful tests in laboratories holding national accreditation for testing and ...
ing to the
Nuclear Regulatory Commission The Nuclear Regulatory Commission (NRC) is an independent agency of the United States government tasked with protecting public health and safety related to nuclear energy. Established by the Energy Reorganization Act of 1974, the NRC began oper ...
.
certification Certification is the provision by an independent body of written assurance (a certificate) that the product, service or system in question meets specific requirements. It is the formal attestation or confirmation of certain characteristics of a ...
of fireproofing and firestopping remained optional for systems installed in
nuclear power plant A nuclear power plant (NPP) is a thermal power station in which the heat source is a nuclear reactor. As is typical of thermal power stations, heat is used to generate steam that drives a steam turbine connected to a generator that produces ele ...
s in Canada and the United States. * Reuse of older materials from demolished buildings, in newer buildings.


Work staging

Spray fireproofing products have not been qualified to the thousands of firestop configurations, so they cannot be installed in conformance of a certification listing. Therefore, firestopping must precede fireproofing. Both need one another. If the structural steel is left without fireproofing, it can damage fire barriers and a building can collapse. If the barriers are not firestopped properly, fire and smoke can spread from one compartment to another.


Traffic tunnels

Traffic tunnels may be traversed by vehicles carrying flammable goods, such as petrol,
liquefied petroleum gas Liquefied petroleum gas (LPG or LP gas) is a fuel gas which contains a flammable mixture of hydrocarbon gases, specifically propane, propylene, butylene, isobutane and n-butane. LPG is used as a fuel gas in heating appliances, cooking eq ...
and other hydrocarbons, which are known to cause a very rapid temperature rise and high ultimate temperatures in case of a fire (see the hydrocarbon curves in
fire-resistance rating A fire-resistance rating typically means the duration for which a passive fire protection system can withstand a standard fire resistance test. This can be quantified simply as a measure of time, or it may entail other criteria, involving eviden ...
). Where hydrocarbon transports are permitted in tunnel construction and operations, accidental fires may occur, resulting in the need for fireproofing of traffic tunnels with concrete linings. Traffic tunnels are not ordinarily equipped with fire suppression means, such as
fire sprinkler system A fire sprinkler system is an active fire protection method, consisting of a water supply system, providing adequate pressure and flowrate to a water distribution piping system, onto which fire sprinklers are connected. Although historically on ...
s. It is very difficult to control hydrocarbon fires by
active fire protection Active fire protection (AFP) is an integral part of fire protection. AFP is characterized by items and/or systems, which require a certain amount of motion and response in order to work, contrary to passive fire protection. Categories of active fi ...
means, and it is expensive to equip an entire tunnel along its whole length for the eventuality of a hydrocarbon fire or a BLEVE.


Concrete exposed to hydrocarbon fires

Concrete cannot, by itself, withstand severe hydrocarbon fires. In the
Channel Tunnel The Channel Tunnel (french: Tunnel sous la Manche), also known as the Chunnel, is a railway tunnel that connects Folkestone (Kent, England, UK) with Coquelles ( Hauts-de-France, France) beneath the English Channel at the Strait of Dover. ...
that connects the United Kingdom and France, an intense fire broke out and reduced the concrete lining in the undersea tunnel down to about 50 mm. In ordinary building fires, concrete typically achieves excellent fire-resistance ratings, unless it is too wet, which can cause it to crack and explode. For unprotected concrete, the sudden
endothermic In thermochemistry, an endothermic process () is any thermodynamic process with an increase in the enthalpy (or internal energy ) of the system.Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).''Principle of Modern Chemistry'', Brooks Cole. p. ...
reaction of the hydrates and unbound humidity inside the concrete generates pressure high enough to
spall Spall are fragments of a material that are broken off a larger solid body. It can be produced by a variety of mechanisms, including as a result of projectile impact, corrosion, weathering, cavitation, or excessive rolling pressure (as in a ball ...
off the concrete, which falls in small pieces on the floor of the tunnel. Humidity probes are inserted into all concrete slabs that undergo fire testing to test for this, even for the less severe building elements curve (DIN4102, ASTM E119, BS476, or ULC-S101). The need for fireproofing was demonstrated, among other fire protection measures, in the European "Eureka" Fire Tunnel Research Project, which gave rise to building codes for the trade to avoid the effects of such fires upon traffic tunnels. Cementitious spray fireproofing must be certification-listed and applied in the field as per that listing, using a hydrocarbon fire test curve such as the one used in UL1709.


Fireproof vaults

Fireproof vaults to protect important paper documents are usually built using concrete or masonry blocks as the primary building material. In the event of a fire, the chemically-bound water within the concrete or masonry blocks is forced into the vault chamber as steam, which soaks the paper documents to keep them from igniting. This steam also helps keep the temperature inside the vault chamber below the critical threshold, which is the point at which information on paper documents is destroyed. The paper can later be remediated with a freeze drying process if the fire is extinguished before internal temperatures exceed . An alternate less expensive and time-consuming construction method is using dry insulating material. This vault construction method is sufficient for paper documents, but the steam generated by concrete and masonry structures will destroy contents that are more sensitive to heat and moisture. For example, information on
microfilm Microforms are scaled-down reproductions of documents, typically either films or paper, made for the purposes of transmission, storage, reading, and printing. Microform images are commonly reduced to about 4% or of the original document size. F ...
is destroyed at (a.k.a. Class 150) and magnetic media (such as data tapes) lose data above (a.k.a. Class 125). Fireproof vaults built to meet the more stringent Class 125 requirement are called data-rated vaults. All components of fireproof vaults must meet the fire protection rating of the vault itself, including doors, HVAC penetrations and cable penetrations.National Fire Protection Association 232 "Protection of Records"


See also

* BLEVE *
Brominated flame retardant Brominated flame retardants (BFRs) are organobromine compounds that have an inhibitory effect on combustion chemistry and tend to reduce the flammability of products containing them. The brominated variety of commercialized chemical flame retardants ...
*
Cable tray In the electrical wiring of buildings, a cable tray system is used to support insulated electrical cables used for power distribution, control, and communication. Cable trays are used as an alternative to open wiring or electrical conduit syste ...
*
Channel tunnel The Channel Tunnel (french: Tunnel sous la Manche), also known as the Chunnel, is a railway tunnel that connects Folkestone (Kent, England, UK) with Coquelles ( Hauts-de-France, France) beneath the English Channel at the Strait of Dover. ...
*
Circuit integrity Circuit integrity is how little can a fire affect an electrical circuit's operation. It is a form of fire-resistance rating. Circuit integrity is achieved via passive fire protection means, which are subject to listing and approval use and co ...
* Compartmentalisation * Construction *
Endothermic In thermochemistry, an endothermic process () is any thermodynamic process with an increase in the enthalpy (or internal energy ) of the system.Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).''Principle of Modern Chemistry'', Brooks Cole. p. ...
*
Fire Fire is the rapid oxidation of a material (the fuel) in the exothermic chemical process of combustion, releasing heat, light, and various reaction Product (chemistry), products. At a certain point in the combustion reaction, called the ignition ...
* Fire protection *
Fire-resistance rating A fire-resistance rating typically means the duration for which a passive fire protection system can withstand a standard fire resistance test. This can be quantified simply as a measure of time, or it may entail other criteria, involving eviden ...
*
Firestop A firestop or fire-stopping is a form of passive fire protection that is used to seal around openings and between joints in a fire-resistance-rated wall or floor assembly. Firestops are designed to maintain the fire-resistance rating of a wall o ...
* Flame retardant * Hydrates * Intumescent * Liquified petroleum gas * Listing and approval use and compliance * Passive fire protection *
Plaster Plaster is a building material used for the protective or decorative coating of walls and ceilings and for moulding and casting decorative elements. In English, "plaster" usually means a material used for the interiors of buildings, while "re ...
* Product certification *
Sodium silicate Sodium silicate is a generic name for chemical compounds with the formula or ·, such as sodium metasilicate , sodium orthosilicate , and sodium pyrosilicate . The anions are often polymeric. These compounds are generally colorless transparent ...
* Fireproof banknote


References


External links

* National Fireproofing Contractors Association http://www.nfca-online.org/ * Structural Fire Protection - American Institute of Steel Construction https://www.aisc.org/globalassets/modern-steel/archives/2002/12/2002v12_fire.pdf * Additional Fireproofing Methods https://www.thebalance.com/fireproofing-method-structural-members-845033
NFPA Standards
{{HVAC Flame retardants Passive fire protection