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Dacite () is a volcanic rock formed by rapid solidification of lava that is high in silica and low in
alkali metal oxide The alkali metals react with oxygen to form several different compounds: suboxides, oxides, peroxides, sesquioxides, superoxides, and ozonides. They all react violently with water. Alkali metal suboxides * Hexarubidium monoxide (Rb6O) h * Nonar ...
s. It has a fine-grained (
aphanitic Aphanites (adj. ''aphanitic''; ) are igneous rocks that are so fine-grained that their component mineral crystals are not visible to the naked eye (in contrast to phanerites, in which the crystals are visible to the unaided eye). This ge ...
) to porphyritic texture and is intermediate in composition between andesite and
rhyolite Rhyolite ( ) is the most silica-rich of volcanic rocks. It is generally glassy or fine-grained (aphanitic) in texture, but may be porphyritic, containing larger mineral crystals ( phenocrysts) in an otherwise fine-grained groundmass. The miner ...
. It is composed predominantly of plagioclase feldspar and quartz. Dacite is relatively common, occurring in many tectonic settings. It is associated with andesite and rhyolite as part of the subalkaline
tholeiitic The tholeiitic magma series is one of two main magma series in subalkaline igneous rocks, the other being the calc-alkaline series. A magma series is a chemically distinct range of magma compositions that describes the evolution of a mafic magma ...
and
calc-alkaline magma series The calc-alkaline magma series is one of two main subdivisions of the subalkaline magma series, the other subalkaline magma series being the tholeiitic series. A magma series is a series of compositions that describes the evolution of a mafic mag ...
.


Composition

Dacite consists mostly of plagioclase feldspar and quartz with
biotite Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula . It is primarily a solid-solution series between the iron-endmember annite, and the magnesium-endmember phlogopite; more alumi ...
, hornblende, and pyroxene (
augite Augite is a common rock-forming pyroxene mineral with formula . The crystals are monoclinic and prismatic. Augite has two prominent cleavages, meeting at angles near 90 degrees. Characteristics Augite is a solid solution in the pyroxene grou ...
or
enstatite Enstatite is a mineral; the magnesium endmember of the pyroxene silicate mineral series enstatite (MgSiO3) – ferrosilite (FeSiO3). The magnesium rich members of the solid solution series are common rock-forming minerals found in igneous and m ...
). The quartz appears as rounded, corroded phenocrysts, or as an element of the ground-mass. The plagioclase in dacite ranges from
oligoclase Oligoclase is a rock-forming mineral belonging to the plagioclase feldspars. In chemical composition and in its crystallographic and physical characters it is intermediate between albite ( Na Al Si3 O8) and anorthite ( CaAl2Si2O8). The albite: ...
to
andesine Andesine is a silicate mineral, a member of the plagioclase feldspar solid solution series. Its chemical formula is ( Ca, Na)( Al, Si)4 O8, where Ca/(Ca + Na) (% anorthite) is between 30–50%. The formula may be written as Na0.7-0.5Ca0.3-0.5 ...
and labradorite. Sanidine occurs, although in small proportions, in some dacites, and when abundant gives rise to rocks that form transitions to the rhyolites. The relative proportions of feldspars and quartz in dacite, and in many other volcanic rocks, are illustrated in the QAPF diagram. This defines dacite as having a content of 20% to 60% quartz, with plagioclase making up 65% or more of its feldspar content. However, while the IUGS recommends classifying volcanic rocks on the basis of their mineral composition whenever possible, dacites are often so fine-grained that mineral identification is impractical. The rock must then be classified chemically based on its content of silica and
alkali metal oxide The alkali metals react with oxygen to form several different compounds: suboxides, oxides, peroxides, sesquioxides, superoxides, and ozonides. They all react violently with water. Alkali metal suboxides * Hexarubidium monoxide (Rb6O) h * Nonar ...
s ( K2O plus Na2O). The TAS classification puts dacite in the O3 sector.


Texture

In hand specimen, many of the hornblende and biotite dacites are grey or pale brown and yellow rocks with white feldspars, and black crystals of biotite and hornblende. Other dacites, especially pyroxene-bearing dacites, are darker colored. In thin section, dacites may have an
aphanitic Aphanites (adj. ''aphanitic''; ) are igneous rocks that are so fine-grained that their component mineral crystals are not visible to the naked eye (in contrast to phanerites, in which the crystals are visible to the unaided eye). This ge ...
to porphyritic texture. Porphyritic dacites contain blocky highly zoned plagioclase phenocrysts and/or rounded corroded quartz phenocrysts. Subhedral hornblende and elongated
biotite Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula . It is primarily a solid-solution series between the iron-endmember annite, and the magnesium-endmember phlogopite; more alumi ...
grains are present. Sanidine phenocrysts and
augite Augite is a common rock-forming pyroxene mineral with formula . The crystals are monoclinic and prismatic. Augite has two prominent cleavages, meeting at angles near 90 degrees. Characteristics Augite is a solid solution in the pyroxene grou ...
(or
enstatite Enstatite is a mineral; the magnesium endmember of the pyroxene silicate mineral series enstatite (MgSiO3) – ferrosilite (FeSiO3). The magnesium rich members of the solid solution series are common rock-forming minerals found in igneous and m ...
) are found in some samples. The groundmass of these rocks is often
aphanitic Aphanites (adj. ''aphanitic''; ) are igneous rocks that are so fine-grained that their component mineral crystals are not visible to the naked eye (in contrast to phanerites, in which the crystals are visible to the unaided eye). This ge ...
microcrystalline A microcrystalline material is a crystallized substance or rock that contains small crystals visible only through microscopic examination. There is little agreement on the range of crystal sizes that should be regarded as microcrystalline, but the ...
, with a web of minute feldspars mixed with interstitial grains of quartz or tridymite; but in many dacites it is largely vitreous, while in others it is felsitic or cryptocrystalline.


Geological context and formation

Dacite usually forms as an intrusive rock such as a dike or
sill Sill may refer to: * Sill (dock), a weir at the low water mark retaining water within a dock * Sill (geology), a subhorizontal sheet intrusion of molten or solidified magma * Sill (geostatistics) * Sill (river), a river in Austria * Sill plate, ...
. Examples of this type of dacite outcrop are found in northwestern Montana and northeastern
Bulgaria Bulgaria (; bg, България, Bǎlgariya), officially the Republic of Bulgaria,, ) is a country in Southeast Europe. It is situated on the eastern flank of the Balkans, and is bordered by Romania to the north, Serbia and North Maced ...
. Nevertheless, because of the moderately high silica content, dacitic magma is quite viscous and therefore prone to explosive eruption. A notorious example of this is
Mount St. Helens Mount St. Helens (known as Lawetlat'la to the indigenous Cowlitz people, and Loowit or Louwala-Clough to the Klickitat) is an active stratovolcano located in Skamania County, Washington, in the Pacific Northwest region of the United ...
in which dacite domes formed from previous eruptions.
Pyroclastic flows A pyroclastic flow (also known as a pyroclastic density current or a pyroclastic cloud) is a fast-moving current of hot gas and volcanic matter (collectively known as tephra) that flows along the ground away from a volcano at average speeds of bu ...
may also be of dacitic composition as is the case with the
Fish Canyon Tuff The Fish Canyon Tuff is the large volcanic ash flow or ignimbrite deposit resulting from one of the largest known explosive eruptions on Earth, estimated at . (see List of largest volcanic eruptions). The Fish Canyon Tuff eruption was centred at ...
of La Garita Caldera. Dacitic magma is formed by the subduction of young oceanic crust under a thick
felsic In geology, felsic is a modifier describing igneous rocks that are relatively rich in elements that form feldspar and quartz.Marshak, Stephen, 2009, ''Essentials of Geology,'' W. W. Norton & Company, 3rd ed. It is contrasted with mafic rocks, whi ...
continental plate. Oceanic crust is hydrothermally altered causing addition of quartz and sodium. As the young, hot oceanic plate is subducted under continental crust, the subducted slab partially melts and interacts with the
upper mantle The upper mantle of Earth is a very thick layer of rock inside the planet, which begins just beneath the crust (at about under the oceans and about under the continents) and ends at the top of the lower mantle at . Temperatures range from appro ...
through convection and dehydration reactions. The process of subduction creates metamorphism in the subducting slab. When this slab reaches the mantle and initiates the dehydration reactions, minerals such as talc, serpentine, mica and
amphibole Amphibole () is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is Am ...
s break down generating a more sodic melt. The magma then continues to migrate upwards causing differentiation and becomes even more sodic and silicic as it rises. Once at the cold surface, the sodium rich magma crystallizes plagioclase, quartz and hornblende. Accessory minerals like pyroxenes provide insight to the history of the magma. The formation of dacite provides a great deal of information about the connection between oceanic crust and continental crust. It provides a model for the generation of felsic, buoyant, perennial rock from a mafic, dense, short-lived one.


Dacite's role in the creation of Archean continental crust

The process by which dacite forms has been used to explain the generation of continental crust during the
Archean eon The Archean Eon ( , also spelled Archaean or Archæan) is the second of four geologic eons of Earth's history, representing the time from . The Archean was preceded by the Hadean Eon and followed by the Proterozoic. The Earth during the Archea ...
. At that time, the production of dacitic magma was more ubiquitous, due to the availability of young, hot oceanic crust. Today, the colder oceanic crust that subducts under most plates is not able to melt prior to the dehydration reactions, thus inhibiting the process.


Molten dacite magma at Kīlauea

Dacitic magma was encountered in a drillhole during geothermal exploration on
Kīlauea Kīlauea ( , ) is an active shield volcano in the Hawaiian Islands. Located along the southeastern shore of the Big Island of Hawaii, the volcano is between 210,000 and 280,000 years old and emerged above sea level about 100,000 years ago. His ...
in 2005. At a depth of 2488 m, the magma flowed up the wellbore. This produced several kilograms of clear, colorless vitric (glassy, non-crystalline) cuttings at the surface. The dacite magma is a residual melt of the typical
basalt Basalt (; ) is an aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the surface of a rocky planet or moon. More than 90% of a ...
magma of Kīlauea.Puna Dacite Magma at Kilauea: Unexpected Drilling Into an Active Magma Posters, 2008 Eos Trans. AGU, 89(53), Fall Meeting
/ref>


Distribution

Dacite is relatively common and occurs in various tectonic and magmatic contexts: * In oceanic volcanic series. Examples: Iceland (Heiðarsporður ridge),
Juan de Fuca Ridge The Juan de Fuca Ridge is a mid-ocean spreading center and divergent plate boundary located off the coast of the Pacific Northwest region of North America. The ridge separates the Pacific Plate to the west and the Juan de Fuca Plate to the eas ...
* In
calc-alkaline The calc-alkaline magma series is one of two main subdivisions of the subalkaline magma series, the other subalkaline magma series being the tholeiitic series. A magma series is a series of compositions that describes the evolution of a mafic ma ...
and
tholeiitic The tholeiitic magma series is one of two main magma series in subalkaline igneous rocks, the other being the calc-alkaline series. A magma series is a chemically distinct range of magma compositions that describes the evolution of a mafic magma ...
volcanic series of the subduction zones of island arcs and active
continental margin A continental margin is the outer edge of continental crust abutting oceanic crust under coastal waters. It is one of the three major zones of the ocean floor, the other two being deep-ocean basins and mid-ocean ridges. The continental margin ...
s. Examples of dacitic magmatism in island arcs are Japan, the Philippines, the
Aleutians The Aleutian Islands (; ; ale, Unangam Tanangin,”Land of the Aleuts", possibly from Chukchi ''aliat'', "island"), also called the Aleut Islands or Aleutic Islands and known before 1867 as the Catherine Archipelago, are a chain of 14 large vo ...
, the
Antilles The Antilles (; gcf, label=Antillean Creole, Antiy; es, Antillas; french: Antilles; nl, Antillen; ht, Antiy; pap, Antias; Jamaican Patois: ''Antiliiz'') is an archipelago bordered by the Caribbean Sea to the south and west, the Gulf of Mex ...
, the Sunda Arc (
Mount Batur Mount Batur ''(Gunung Batur)'' is an active volcano located at the center of two concentric calderas north west of Mount Agung on the island of Bali, Indonesia. The south east side of the larger 10×13 km caldera contains a caldera lake. Bot ...
), Tonga and the
South Sandwich Islands ) , anthem = "God Save the King" , song_type = , song = , image_map = South Georgia and the South Sandwich Islands in United Kingdom.svg , map_caption = Location of South Georgia and the South Sandwich Islands in the southern Atlantic Oce ...
. Examples of dacitic magmatism in active continental margins are the
Cascade Range The Cascade Range or Cascades is a major mountain range of western North America, extending from southern British Columbia through Washington and Oregon to Northern California. It includes both non-volcanic mountains, such as the North Cascades, ...
, Guatemala and the Andes ( Ecuador and
Chile Chile, officially the Republic of Chile, is a country in the western part of South America. It is the southernmost country in the world, and the closest to Antarctica, occupying a long and narrow strip of land between the Andes to the east a ...
). * In continental volcanic series, often in association with tholeiitic basalts and intermediary rocks. The type locality of dacite is Gizella quarry near
Poieni, Cluj Poieni ( hu, Kissebes; german: Klein Weichselburg) is a commune in Cluj County, Transylvania, Romania. It is composed of eight villages: Bologa (''Sebesvár''), Cerbești (''Kecskéstanya''), Hodișu (''Hodosfalva''), Lunca Vișagului (''Viságmez ...
in Romania. Other occurrences of dacite in Europe are Germany ( Weiselberg), Greece ( Nisyros and
Thera Santorini ( el, Σαντορίνη, ), officially Thira (Greek language, Greek: Θήρα ) and classical Greek Thera (English language, English pronunciation ), is an island in the southern Aegean Sea, about 200 km (120 mi) southeast ...
), Italy (in Bozen quartz porphyry, and Sardinia),
Austria Austria, , bar, Östareich officially the Republic of Austria, is a country in the southern part of Central Europe, lying in the Eastern Alps. It is a federation of nine states, one of which is the capital, Vienna, the most populous c ...
(Styrian Volcano Arc), Scotland (
Argyll Argyll (; archaically Argyle, in modern Gaelic, ), sometimes called Argyllshire, is a historic county and registration county of western Scotland. Argyll is of ancient origin, and corresponds to most of the part of the ancient kingdom of ...
), Slovakia, Spain (El Hoyazo near
Almería Almería (, , ) is a city and municipality of Spain, located in Andalusia. It is the capital of the province of the same name. It lies on southeastern Iberia on the Mediterranean Sea. Caliph Abd al-Rahman III founded the city in 955. The city gr ...
), France (
Massif de l'Esterel The Massif de l'Esterel (Occitan Provençal: ''Esterèu''; English: Esterel Massif) is a Mediterranean coastal mountain range in the departments of Var and Alpes-Maritimes on the French Riviera. Neighbouring cities are Mandelieu-la-Napoule and C ...
) and Hungary (Csódi Hill). Sites outside Europe include Iran, Morocco, New Zealand (volcanic region of Taupo), Turkey, USA and Zambia. Dacite is found extraterrestrially at Nili Patera
caldera A caldera ( ) is a large cauldron-like hollow that forms shortly after the emptying of a magma chamber in a volcano eruption. When large volumes of magma are erupted over a short time, structural support for the rock above the magma chamber i ...
of
Syrtis Major Planum Syrtis Major Planum is a "dark spot" (an albedo feature) located in the boundary between the northern lowlands and southern highlands of Mars just west of the impact basin Isidis in the Syrtis Major quadrangle. It was discovered, on the basis o ...
on Mars.


Etymology

The word ''dacite'' comes from Dacia, a province of the
Roman Empire The Roman Empire ( la, Imperium Romanum ; grc-gre, Βασιλεία τῶν Ῥωμαίων, Basileía tôn Rhōmaíōn) was the post-Roman Republic, Republican period of ancient Rome. As a polity, it included large territorial holdings aro ...
which lay between the Danube River and Carpathian Mountains (now modern Romania and
Moldova Moldova ( , ; ), officially the Republic of Moldova ( ro, Republica Moldova), is a Landlocked country, landlocked country in Eastern Europe. It is bordered by Romania to the west and Ukraine to the north, east, and south. The List of states ...
) where the rock was first described. The term ''dacite'' was used for the first time in the scientific literature in the book ''"Geologie Siebenbürgens"'' (''"The Geology of Transylvania"'') by Austrian geologists
Franz Ritter von Hauer Franz Ritter von Hauer, or Franz von Hauer (January 30, 1822 – March 20, 1899), was an Austrian geologist. Biography Hauer was born in Vienna, the son of Joseph von Hauer (1778-1863), who was equally distinguished as a high Austrian offi ...
and Guido Stache. Dacite was originally defined as a new rock type to separate calc-alkaline rocks with oligoclase phenocrysts (dacites) from rocks with orthoclase phenocrysts (rhyolites).


See also

* *


References

{{Authority control Intermediate rocks Felsic rocks Aphanitic rocks Porphyritic rocks Volcanic rocks