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Charring is a chemical process of incomplete
combustion Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combus ...
of certain solids when subjected to high
heat In thermodynamics, heat is defined as the form of energy crossing the boundary of a thermodynamic system by virtue of a temperature difference across the boundary. A thermodynamic system does not ''contain'' heat. Nevertheless, the term is ...
. Heat distillation removes
water vapour (99.9839 °C) , - , Boiling point , , - , specific gas constant , 461.5 J/( kg·K) , - , Heat of vaporization , 2.27 MJ/kg , - , Heat capacity , 1.864 kJ/(kg·K) Water vapor, water vapour or aqueous vapor is the gaseous pha ...
and
volatile organic compound Volatile organic compounds (VOCs) are organic compounds that have a high vapour pressure at room temperature. High vapor pressure correlates with a low boiling point, which relates to the number of the sample's molecules in the surrounding air, a ...
s ( syngas) from the matrix. The residual
black carbon Chemically, black carbon (BC) is a component of fine particulate matter (PM ≤ 2.5 µm in aerodynamic diameter). Black carbon consists of pure carbon in several linked forms. It is formed through the incomplete combustion of fossil fuel ...
material is char, as distinguished from the lighter colored ash. By the action of heat, charring removes
hydrogen Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic ...
and
oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as ...
from the solid, so that the remaining char is composed primarily of
carbon Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent—its atom making four electrons available to form covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon mak ...
. Polymers like
thermoset In materials science, a thermosetting polymer, often called a thermoset, is a polymer that is obtained by irreversibly hardening (" curing") a soft solid or viscous liquid prepolymer ( resin). Curing is induced by heat or suitable radiation ...
, or most solid organic compounds like wood or
biological tissue In biology, tissue is a biological organizational level between cells and a complete organ. A tissue is an ensemble of similar cells and their extracellular matrix from the same origin that together carry out a specific function. Organs are th ...
, exhibit charring behaviour. Charring means partially burning so as to blacken the surface. Charring can result from naturally occurring processes like fire; it is also a deliberate and controlled reaction used in the manufacturing of certain products. The mechanism of charring is part of the normal burning of certain solid fuels like wood. During normal combustion, the volatile compounds created by charring are consumed at the flames within the fire or released to the atmosphere, while combustion of char can be seen as glowing red coals or embers which burn without the presence of flames.


Production of char

Coke and charcoal are both produced by charring, whether on an industrial scale or through normal combustion of coal or wood. Normal combustion consumes the char as well as the gases produced in its creation, while industrial processes seek to recover the purified char with minimal loss to combustion. This is accomplished by either burning the parent fuel (wood or coal) in a low-oxygen environment or by heating it to a high temperature without allowing combustion to occur. In industrial production of coke and charcoal, the volatile compounds driven off during charring are often captured for use in other chemical processes. A "coal burning" blacksmith's forge actually produces the heat necessary for high-temperature
metalworking Metalworking is the process of shaping and reshaping metals to create useful objects, parts, assemblies, and large scale structures. As a term it covers a wide and diverse range of processes, skills, and tools for producing objects on every scal ...
by the continuous production and consumption of coke within a carefully managed fire. An inner ring of burning coke provides heat which converts the encircling coal into coke, which is then itself fed into the center of the fire to provide the required heat and to create more coke; coal itself is incapable of producing the heat required for some blacksmithing operations.


Charring and fire protection

Charring is an important process in the combustion ignition of solid
fuels A fuel is any material that can be made to react with other substances so that it releases energy as thermal energy or to be used for work. The concept was originally applied solely to those materials capable of releasing chemical energy but ...
and in
smouldering Smouldering (British English) or smoldering (American English; see spelling differences) is the slow, flameless form of combustion, sustained by the heat evolved when oxygen directly attacks the surface of a condensed-phase fuel. Many solid mate ...
. In construction of heavy-timbered wood buildings the predictable formation of char is used to determine the fire rating of supporting timbers and is an important consideration in
fire protection Fire protection is the study and practice of mitigating the unwanted effects of potentially destructive fires. It involves the study of the behaviour, compartmentalisation, suppression and investigation of fire and its related emergencies, as we ...
engineering. If a wood column is of large enough diameter, during a structure fire its exposed surface will be converted to char until the thickness of char provides sufficient insulation to prevent additional charring. This layer then serves to protect the remaining structurally sound core of wood, which can continue to carry the building loads if appropriately designed.


Wood preservation

Charring is also a technique used for
wood preservation Wood easily degrades without sufficient preservation. Apart from structural wood preservation measures, there are a number of different chemical preservatives and processes (also known as "timber treatment", "lumber treatment" or "pressure treat ...
. In Japan this traditional technique is called ''
yakisugi ''Yakisugi'' ( 焼 杉) is a traditional Japanese method of wood preservation. ''Yaki'' means to heat with fire, and ''sugi'' is cypress. It is referred to in the West as burnt timber cladding and also available as shou sugi ban® or 焼 ...
'' or ''shō sugi ban''.


Legal definitions

Charring had a special meaning under the
common law In law, common law (also known as judicial precedent, judge-made law, or case law) is the body of law created by judges and similar quasi-judicial tribunals by virtue of being stated in written opinions."The common law is not a brooding omnipres ...
of
England England is a country that is part of the United Kingdom. It shares land borders with Wales to its west and Scotland to its north. The Irish Sea lies northwest and the Celtic Sea to the southwest. It is separated from continental Europe b ...
. Under that system, the crime of arson required charring of a dwelling—actual damage to the fiber of the material from which the structure was built—and not mere "scorching" or damage to the surface, or to surface coverings such as carpets and wallpaper.


See also

* Gasification *
Pyrolysis The pyrolysis (or devolatilization) process is the thermal decomposition of materials at elevated temperatures, often in an inert atmosphere. It involves a change of chemical composition. The word is coined from the Greek-derived elements ''py ...


References

{{Reflist Chemical processes Coal