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A blast furnace is a type of
metallurgical furnace A metallurgical furnace, more commonly referred to as a furnace, is a device used to heat and melt metal ore to remove gangue, primarily in iron and steel production. The heat energy to fuel a furnace may be supplied directly by fuel combustion, ...
used for
smelting Smelting is a process of applying heat to ore, to extract a base metal. It is a form of extractive metallurgy. It is used to extract many metals from their ores, including silver, iron, copper, and other base metals. Smelting uses heat and a c ...
to produce industrial metals, generally pig iron, but also others such as
lead Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cut, l ...
or copper. ''Blast'' refers to the combustion air being "forced" or supplied above atmospheric pressure. In a blast furnace, fuel ( coke),
ores Ore is natural rock or sediment that contains one or more valuable minerals, typically containing metals, that can be mined, treated and sold at a profit.Encyclopædia Britannica. "Ore". Encyclopædia Britannica Online. Retrieved 7 April ...
, and
flux Flux describes any effect that appears to pass or travel (whether it actually moves or not) through a surface or substance. Flux is a concept in applied mathematics and vector calculus which has many applications to physics. For transport ph ...
(
limestone Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms when ...
) are continuously supplied through the top of the furnace, while a hot blast of
air The atmosphere of Earth is the layer of gases, known collectively as air, retained by Earth's gravity that surrounds the planet and forms its planetary atmosphere. The atmosphere of Earth protects life on Earth by creating pressure allowing for ...
(sometimes with
oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as well ...
enrichment) is blown into the lower section of the furnace through a series of pipes called
tuyeres A tuyere or tuyère (; ) is a tube, nozzle or pipe through which air is blown into a furnace or hearth.W. K. V. Gale, The iron and Steel industry: a dictionary of terms (David and Charles, Newton Abbot 1972), 216–217. Air or oxygen is inj ...
, so that the
chemical reactions A chemical reaction is a process that leads to the chemical transformation of one set of chemical substances to another. Classically, chemical reactions encompass changes that only involve the positions of electrons in the forming and breaking ...
take place throughout the furnace as the material falls downward. The end products are usually molten metal and
slag Slag is a by-product of smelting ( pyrometallurgical) ores and used metals. Broadly, it can be classified as ferrous (by-products of processing iron and steel), ferroalloy (by-product of ferroalloy production) or non-ferrous/base metals (by-pr ...
phases tapped from the bottom, and waste gases (
flue gas Flue gas is the gas exiting to the atmosphere via a flue, which is a pipe or channel for conveying exhaust gases from a fireplace, oven, furnace, boiler or steam generator. Quite often, the flue gas refers to the combustion exhaust gas produced ...
) exiting from the top of the furnace. The downward flow of the ore along with the flux in contact with an upflow of hot,
carbon monoxide Carbon monoxide (chemical formula CO) is a colorless, poisonous, odorless, tasteless, flammable gas that is slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the simpl ...
-rich combustion gases is a countercurrent exchange and chemical reaction process. In contrast, air furnaces (such as
reverberatory furnace A reverberatory furnace is a metallurgical or process furnace that isolates the material being processed from contact with the fuel, but not from contact with combustion gases. The term ''reverberation'' is used here in a generic sense of ''re ...
s) are naturally aspirated, usually by the
convection Convection is single or multiphase fluid flow that occurs spontaneously due to the combined effects of material property heterogeneity and body forces on a fluid, most commonly density and gravity (see buoyancy). When the cause of the convecti ...
of hot gases in a chimney flue. According to this broad definition,
bloomeries A bloomery is a type of metallurgical furnace once used widely for smelting iron from its oxides. The bloomery was the earliest form of smelter capable of smelting iron. Bloomeries produce a porous mass of iron and slag called a ''bloom''. ...
for iron,
blowing house A blowing house or blowing mill was a building used for smelting tin in Cornwall and on Dartmoor in Devon, in South West England. Blowing houses contained a furnace and a pair of bellows that were powered by an adjacent water wheel, and they wer ...
s for
tin Tin is a chemical element with the symbol Sn (from la, stannum) and atomic number 50. Tin is a silvery-coloured metal. Tin is soft enough to be cut with little force and a bar of tin can be bent by hand with little effort. When bent, t ...
, and
smelt mill Smeltmills were water-powered mills used to smelt lead or other metals. The older method of smelting lead on wind-blown bole hills began to be superseded by artificially-blown smelters. The first such furnace was built by Burchard Kranich at ...
s for
lead Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cut, l ...
would be classified as blast furnaces. However, the term has usually been limited to those used for smelting
iron ore Iron ores are rocks and minerals from which metallic iron can be economically extracted. The ores are usually rich in iron oxides and vary in color from dark grey, bright yellow, or deep purple to rusty red. The iron is usually found in the for ...
to produce pig iron, an intermediate material used in the production of commercial iron and
steel Steel is an alloy made up of iron with added carbon to improve its strength and fracture resistance compared to other forms of iron. Many other elements may be present or added. Stainless steels that are corrosion- and oxidation-resistant t ...
, and the shaft furnaces used in combination with
sinter plant Sinter plants agglomerate iron ore fines (dust) with other fine materials at high temperature, to create a product that can be used in a blast furnace. The final product, a sinter, is a small, irregular nodule of iron mixed with small amounts o ...
s in
base metals A base metal is a common and inexpensive metal, as opposed to a precious metal such as gold or silver. In numismatics, coins often derived their value from the precious metal content; however, base metals have also been used in coins in the past ...
smelting. Blast furnaces are estimated to have been responsible for over 4% of global
greenhouse gas emissions Greenhouse gas emissions from human activities strengthen the greenhouse effect, contributing to climate change. Most is carbon dioxide from burning fossil fuels: coal, oil, and natural gas. The largest emitters include coal in China and lar ...
between 1900 and 2015, but are difficult to decarbonize.


Process engineering and chemistry

Blast furnaces operate on the principle of chemical reduction whereby carbon monoxide converts iron oxides to elemental iron. Blast furnaces differ from
bloomeries A bloomery is a type of metallurgical furnace once used widely for smelting iron from its oxides. The bloomery was the earliest form of smelter capable of smelting iron. Bloomeries produce a porous mass of iron and slag called a ''bloom''. ...
and
reverberatory furnace A reverberatory furnace is a metallurgical or process furnace that isolates the material being processed from contact with the fuel, but not from contact with combustion gases. The term ''reverberation'' is used here in a generic sense of ''re ...
s in that in a blast furnace, flue gas is in direct contact with the ore and iron, allowing carbon monoxide to diffuse into the ore and reduce the iron oxide. The blast furnace operates as a countercurrent exchange process whereas a bloomery does not. Another difference is that bloomeries operate as a batch process whereas blast furnaces operate continuously for long periods. Continuous operation is also preferred because blast furnaces are difficult to start and stop. Also, the carbon in pig iron lowers the melting point below that of steel or pure iron; in contrast, iron does not melt in a bloomery.
Silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...
has to be removed from the pig iron. It reacts with
calcium oxide Calcium oxide (CaO), commonly known as quicklime or burnt lime, is a widely used chemical compound. It is a white, caustic, alkaline, crystalline solid at room temperature. The broadly used term "''lime''" connotes calcium-containing inorganic ...
(burned limestone) and forms silicates, which float to the surface of the molten pig iron as "slag". Historically, to prevent contamination from sulfur, the best quality iron was produced with charcoal. The downward moving column of ore, flux, coke or charcoal and reaction products must be sufficiently porous for the flue gas to pass through. To ensure this permeability the particle size of the coke or charcoal is of great relevance. Therefore, the coke must be strong enough so it will not be crushed by the weight of the material above it. Besides the physical strength of its particles, the coke must also be low in sulfur,
phosphorus Phosphorus is a chemical element with the symbol P and atomic number 15. Elemental phosphorus exists in two major forms, white phosphorus and red phosphorus, but because it is highly reactive, phosphorus is never found as a free element on Ea ...
, and ash. The main chemical reaction producing the molten iron is: :Fe2O3 + 3CO → 2Fe + 3CO2 This reaction might be divided into multiple steps, with the first being that preheated air blown into the furnace reacts with the carbon in the form of coke to produce
carbon monoxide Carbon monoxide (chemical formula CO) is a colorless, poisonous, odorless, tasteless, flammable gas that is slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the simpl ...
and heat: :2 C(s) + O2(g) → 2 CO(g) The hot carbon monoxide is the reducing agent for the iron ore and reacts with the
iron oxide Iron oxides are chemical compounds composed of iron and oxygen. Several iron oxides are recognized. All are black magnetic solids. Often they are non-stoichiometric. Oxyhydroxides are a related class of compounds, perhaps the best known of which ...
to produce molten iron and carbon dioxide. Depending on the temperature in the different parts of the furnace (warmest at the bottom) the iron is reduced in several steps. At the top, where the temperature usually is in the range between 200 °C and 700 °C, the iron oxide is partially reduced to iron(II,III) oxide, Fe3O4. :3 Fe2O3(s) + CO(g) → 2 Fe3O4(s) + CO2(g) The temperatures 850 °C, further down in the furnace, the iron(II,III) is reduced further to iron(II) oxide: :Fe3O4(s) + CO(g) → 3 FeO(s) + CO2(g) Hot carbon dioxide, unreacted carbon monoxide, and
nitrogen Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at sevent ...
from the air pass up through the furnace as fresh feed material travels down into the reaction zone. As the material travels downward, the counter-current gases both preheat the feed charge and decompose the limestone to
calcium oxide Calcium oxide (CaO), commonly known as quicklime or burnt lime, is a widely used chemical compound. It is a white, caustic, alkaline, crystalline solid at room temperature. The broadly used term "''lime''" connotes calcium-containing inorganic ...
and carbon dioxide: :CaCO3(s) → CaO(s) + CO2(g) The calcium oxide formed by decomposition reacts with various acidic impurities in the iron (notably
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...
), to form a fayalitic slag which is essentially
calcium silicate Calcium silicate is the chemical compound Ca2SiO4, also known as calcium orthosilicate and is sometimes formulated as 2CaO·SiO2. It is also referred to by the shortened trade name Cal-Sil or Calsil. It occurs naturally as the mineral larnite. ...
, : :SiO2 + CaO → CaSiO3Dr. K. E. Lee, Form Two Science (Biology Chemistry Physics) As the iron(II) oxide moves down to the area with higher temperatures, ranging up to 1200 °C degrees, it is reduced further to iron metal: :FeO(s) + CO(g) → Fe(s) + CO2(g) The carbon dioxide formed in this process is re-reduced to carbon monoxide by the coke: :C(s) + CO2(g) → 2 CO(g) The temperature-dependent equilibrium controlling the gas atmosphere in the furnace is called the
Boudouard reaction The Boudouard reaction, named after Octave Leopold Boudouard, is the redox reaction of a chemical equilibrium mixture of carbon monoxide and carbon dioxide at a given temperature. It is the disproportionation of carbon monoxide into carbon dioxide ...
: ::2CO CO2 + C The " pig iron" produced by the blast furnace has a relatively high carbon content of around 4–5% and usually contains too much sulphur, making it very brittle, and of limited immediate commercial use. Some pig iron is used to make
cast iron Cast iron is a class of iron–carbon alloys with a carbon content more than 2%. Its usefulness derives from its relatively low melting temperature. The alloy constituents affect its color when fractured: white cast iron has carbide impuriti ...
. The majority of pig iron produced by blast furnaces undergoes further processing to reduce the carbon and sulphur content and produce various grades of steel used for construction materials, automobiles, ships and machinery. Desulphurisation usually takes place during the transport of the liquid steel to the steelworks. This is done by adding ''calcium oxide'', which reacts with the
iron sulfide Iron sulfide or Iron sulphide can refer to range of chemical compounds composed of iron and sulfur. Minerals By increasing order of stability: * Iron(II) sulfide, FeS * Greigite, Fe3S4 (cubic) * Pyrrhotite, Fe1−xS (where x = 0 to 0.2) (monoclin ...
contained in the pig iron to form
calcium sulfide Calcium sulfide is the chemical compound with the formula Ca S. This white material crystallizes in cubes like rock salt. CaS has been studied as a component in a process that would recycle gypsum, a product of flue-gas desulfurization. Like m ...
(called ''lime desulfurization''). In a further process step, the so-called
basic oxygen steelmaking Basic oxygen steelmaking (BOS, BOP, BOF, or OSM), also known as Linz-Donawitz steelmaking or the oxygen converter processBrock and Elzinga, p. 50. is a method of primary steelmaking in which carbon-rich molten pig iron is made into steel. Blowing ...
, the carbon is oxidized by blowing oxygen onto the liquid pig iron to form ''crude steel''. Although the efficiency of blast furnaces is constantly evolving, the chemical process inside the blast furnace remains the same. One of the biggest drawbacks of the blast furnaces is the inevitable carbon dioxide production as iron is reduced from iron oxides by carbon and as of 2016, there is no economical substitute – steelmaking is one of the largest industrial contributors of the CO2 emissions in the world (see
greenhouse gases A greenhouse gas (GHG or GhG) is a gas that absorbs and emits radiant energy within the thermal infrared range, causing the greenhouse effect. The primary greenhouse gases in Earth's atmosphere are water vapor (), carbon dioxide (), methane ...
). Several alternatives are being investigated such as plastic waste, biomass or hydrogen as reducing agent, which can substantially reduce the carbon emissions. The challenge set by the greenhouse gas emissions of the blast furnace is being addressed in an ongoing European Program called ULCOS (Ultra Low CO2
Steelmaking Steelmaking is the process of producing steel from iron ore and carbon/or scrap. In steelmaking, impurities such as nitrogen, silicon, phosphorus, sulfur and excess carbon (the most important impurity) are removed from the sourced iron, and allo ...
). Several new process routes have been proposed and investigated in depth to cut specific emissions ( per ton of steel) by at least 50%. Some rely on the capture and further storage (CCS) of , while others choose decarbonizing iron and steel production, by turning to hydrogen, electricity and biomass. In the nearer term, a technology that incorporates CCS into the blast furnace process itself and is called the Top-Gas Recycling Blast Furnace is under development, with a scale-up to a commercial size blast furnace under way.


History

Cast iron has been found in China dating to the 5th century BC, but the earliest extant blast furnaces in China date to the 1st century AD and in the West from the
High Middle Ages The High Middle Ages, or High Medieval Period, was the period of European history that lasted from AD 1000 to 1300. The High Middle Ages were preceded by the Early Middle Ages and were followed by the Late Middle Ages, which ended around AD 1500 ...
. They spread from the region around
Namur Namur (; ; nl, Namen ; wa, Nameur) is a city and municipality in Wallonia, Belgium. It is both the capital of the province of Namur and of Wallonia, hosting the Parliament of Wallonia, the Government of Wallonia and its administration. Namur ...
in
Wallonia Wallonia (; french: Wallonie ), or ; nl, Wallonië ; wa, Waloneye or officially the Walloon Region (french: link=no, Région wallonne),; nl, link=no, Waals gewest; wa, link=no, Redjon walone is one of the three regions of Belgium—al ...
(Belgium) in the late 15th century, being introduced to England in 1491. The fuel used in these was invariably charcoal. The successful substitution of coke for charcoal is widely attributed to English inventor Abraham Darby in 1709. The efficiency of the process was further enhanced by the practice of preheating the combustion air (
hot blast Hot blast refers to the preheating of air blown into a blast furnace or other metallurgical process. As this considerably reduced the fuel consumed, hot blast was one of the most important technologies developed during the Industrial Revolution. ...
), patented by Scottish inventor
James Beaumont Neilson James Beaumont Neilson (22 June 1792 – 18 January 1865) was a Scottish inventor whose hot-blast process greatly increased the efficiency of smelting iron. Life He was the son of the engineer Walter Neilson, a millwright and later engin ...
in 1828.


China

Archaeological evidence shows that bloomeries appeared in China around 800 BC. Originally it was thought that the Chinese started casting iron right from the beginning, but this theory has since been debunked by the discovery of 'more than ten' iron digging implements found in the tomb of Duke Jing of Qin (d. 537 BC), whose tomb is located in
Fengxiang County Fengxiang District (), formerly, Fengxiang County and its ancient name is Yong county (雍县), is a district administered by Baoji City in the west of Shaanxi province, China. The county covers an area of and as of 2004 had a population of 510, ...
,
Shaanxi Shaanxi (alternatively Shensi, see § Name) is a landlocked province of China. Officially part of Northwest China, it borders the province-level divisions of Shanxi (NE, E), Henan (E), Hubei (SE), Chongqing (S), Sichuan (SW), Gansu (W), Ning ...
(a museum exists on the site today). There is however no evidence of the bloomery in China after the appearance of the blast furnace and cast iron. In China, blast furnaces produced cast iron, which was then either converted into finished implements in a cupola furnace, or turned into wrought iron in a fining hearth. Although
cast iron Cast iron is a class of iron–carbon alloys with a carbon content more than 2%. Its usefulness derives from its relatively low melting temperature. The alloy constituents affect its color when fractured: white cast iron has carbide impuriti ...
farm tools and weapons were widespread in China by the 5th century BC, employing workforces of over 200 men in iron smelters from the 3rd century onward, the earliest blast furnaces constructed were attributed to the
Han Dynasty The Han dynasty (, ; ) was an imperial dynasty of China (202 BC – 9 AD, 25–220 AD), established by Liu Bang (Emperor Gao) and ruled by the House of Liu. The dynasty was preceded by the short-lived Qin dynasty (221–207 BC) and a war ...
in the 1st century AD.Ebrey, p. 30. These early furnaces had clay walls and used
phosphorus Phosphorus is a chemical element with the symbol P and atomic number 15. Elemental phosphorus exists in two major forms, white phosphorus and red phosphorus, but because it is highly reactive, phosphorus is never found as a free element on Ea ...
-containing minerals as a
flux Flux describes any effect that appears to pass or travel (whether it actually moves or not) through a surface or substance. Flux is a concept in applied mathematics and vector calculus which has many applications to physics. For transport ph ...
. Chinese blast furnaces ranged from around two to ten meters in height, depending on the region. The largest ones were found in modern
Sichuan Sichuan (; zh, c=, labels=no, ; zh, p=Sìchuān; alternatively romanized as Szechuan or Szechwan; formerly also referred to as "West China" or "Western China" by Protestant missions) is a province in Southwest China occupying most of the ...
and
Guangdong Guangdong (, ), alternatively romanized as Canton or Kwangtung, is a coastal province in South China on the north shore of the South China Sea. The capital of the province is Guangzhou. With a population of 126.01 million (as of 2020) ...
, while the 'dwarf" blast furnaces were found in Dabieshan. In construction, they are both around the same level of technological sophistication The effectiveness of the Chinese human and horse powered blast furnaces was enhanced during this period by the engineer
Du Shi Du Shi (, d. 38''Book of Later Han'', vol. 31Crespigny, 183.) was a Chinese hydrologist, inventor, mechanical engineer, metallurgist, and politician of the Eastern Han Dynasty. Du Shi is credited with being the first to apply hydraulic power (i. ...
(c. AD 31), who applied the power of
waterwheel A water wheel is a machine for converting the energy of flowing or falling water into useful forms of power, often in a watermill. A water wheel consists of a wheel (usually constructed from wood or metal), with a number of blades or bucke ...
s to
piston A piston is a component of reciprocating engines, reciprocating pumps, gas compressors, hydraulic cylinders and pneumatic cylinders, among other similar mechanisms. It is the moving component that is contained by a cylinder and is made gas-tig ...
-
bellows A bellows or pair of bellows is a device constructed to furnish a strong blast of air. The simplest type consists of a flexible bag comprising a pair of rigid boards with handles joined by flexible leather sides enclosing an approximately airtigh ...
in forging cast iron. Early water-driven reciprocators for operating blast furnaces were built according to the structure of horse powered reciprocators that already existed. That is, the circular motion of the wheel, be it horse driven or water driven, was transferred by the combination of a
belt drive A belt is a loop of flexible material used to link two or more rotating shafts mechanically, most often parallel. Belts may be used as a source of motion, to transmit power efficiently or to track relative movement. Belts are looped over pulleys ...
, a crank-and-connecting-rod, other
connecting rods A connecting rod, also called a 'con rod', is the part of a piston engine which connects the piston to the crankshaft. Together with the crank, the connecting rod converts the reciprocating motion of the piston into the rotation of the crankshaf ...
, and various shafts, into the reciprocal motion necessary to operate a push bellow.. Donald Wagner suggests that early blast furnace and cast iron production evolved from furnaces used to melt
bronze Bronze is an alloy consisting primarily of copper, commonly with about 12–12.5% tin and often with the addition of other metals (including aluminium, manganese, nickel, or zinc) and sometimes non-metals, such as phosphorus, or metalloids such ...
. Certainly, though, iron was essential to military success by the time the
State of Qin Qin () was an ancient Chinese state during the Zhou dynasty. Traditionally dated to 897 BC, it took its origin in a reconquest of western lands previously lost to the Rong; its position at the western edge of Chinese civilization permitted e ...
had unified China (221 BC). Usage of the blast and cupola furnace remained widespread during the
Song A song is a musical composition intended to be performed by the human voice. This is often done at distinct and fixed pitches (melodies) using patterns of sound and silence. Songs contain various forms, such as those including the repetitio ...
and Tang Dynasties. By the 11th century, the
Song Dynasty The Song dynasty (; ; 960–1279) was an imperial dynasty of China that began in 960 and lasted until 1279. The dynasty was founded by Emperor Taizu of Song following his usurpation of the throne of the Later Zhou. The Song conquered the rest ...
Chinese iron industry made a switch of resources from
charcoal Charcoal is a lightweight black carbon residue produced by strongly heating wood (or other animal and plant materials) in minimal oxygen to remove all water and volatile constituents. In the traditional version of this pyrolysis process, cal ...
to coke in casting iron and steel, sparing thousands of acres of woodland from felling. This may have happened as early as the 4th century AD. The primary advantage of the early blast furnace was in large scale production and making iron implements more readily available to peasants. Cast iron is more brittle than wrought iron or steel, which required additional fining and then cementation or co-fusion to produce, but for menial activities such as farming it sufficed. By using the blast furnace, it was possible to produce larger quantities of tools such as ploughshares more efficiently than the bloomery. In areas where quality was important, such as warfare, wrought iron and steel were preferred. Nearly all Han period weapons are made of wrought iron or steel, with the exception of axe-heads, of which many are made of cast iron. Blast furnaces were also later used to produce
gunpowder Gunpowder, also commonly known as black powder to distinguish it from modern smokeless powder, is the earliest known chemical explosive. It consists of a mixture of sulfur, carbon (in the form of charcoal) and potassium nitrate (saltpeter). Th ...
weapons such as cast iron bomb shells and cast iron
cannon A cannon is a large-caliber gun classified as a type of artillery, which usually launches a projectile using explosive chemical propellant. Gunpowder ("black powder") was the primary propellant before the invention of smokeless powder during ...
s during the
Song dynasty The Song dynasty (; ; 960–1279) was an imperial dynasty of China that began in 960 and lasted until 1279. The dynasty was founded by Emperor Taizu of Song following his usurpation of the throne of the Later Zhou. The Song conquered the rest ...
.


Medieval Europe

The simplest
forge A forge is a type of hearth used for heating metals, or the workplace (smithy) where such a hearth is located. The forge is used by the smith to heat a piece of metal to a temperature at which it becomes easier to shape by forging, or to the ...
, known as the Corsican, was used prior to the advent of Christianity. Examples of improved bloomeries are the (sometimes called wolf-furnace), which remained until the beginning of the 19th century. Instead of using natural draught, air was pumped in by a ''
trompe A trompe is a water-powered air compressor, commonly used before the advent of the electric-powered compressor. A trompe is somewhat like an airlift pump working in reverse. Trompes were used to provide compressed air for bloomery furnaces ...
'', resulting in better quality iron and an increased capacity. This pumping of air in with bellows is known as ''cold blast'', and it increases the
fuel efficiency Fuel efficiency is a form of thermal efficiency, meaning the ratio of effort to result of a process that converts chemical potential energy contained in a carrier (fuel) into kinetic energy or work. Overall fuel efficiency may vary per device, w ...
of the bloomery and improves yield. They can also be built bigger than natural draught bloomeries.


Oldest European blast furnaces

The oldest known blast furnaces in the West were built in Dürstel in
Switzerland ). Swiss law does not designate a ''capital'' as such, but the federal parliament and government are installed in Bern, while other federal institutions, such as the federal courts, are in other cities (Bellinzona, Lausanne, Luzern, Neuchâtel ...
, the Märkische
Sauerland The Sauerland () is a rural, hilly area spreading across most of the south-eastern part of North Rhine-Westphalia, in parts heavily forested and, apart from the major valleys, sparsely inhabited. The Sauerland is the largest tourist region in ...
in Germany, and at
Lapphyttan Lapphyttan or Lapphyttejarn in Norberg Municipality, Sweden, may be regarded as the type site for the Medieval Blast Furnace. Its date is probably between 1150 and 1350. It produced cast iron, which was then fined to make ferritic wrought iron ...
in
Sweden Sweden, formally the Kingdom of Sweden,The United Nations Group of Experts on Geographical Names states that the country's formal name is the Kingdom of SwedenUNGEGN World Geographical Names, Sweden./ref> is a Nordic country located on ...
, where the complex was active between 1205 and 1300. At Noraskog in the Swedish parish of Järnboås, traces of even earlier blast furnaces have been found, possibly from around 1100. These early blast furnaces, like the
Chinese Chinese can refer to: * Something related to China * Chinese people, people of Chinese nationality, citizenship, and/or ethnicity **''Zhonghua minzu'', the supra-ethnic concept of the Chinese nation ** List of ethnic groups in China, people of v ...
examples, were very inefficient compared to those used today. The iron from the Lapphyttan complex was used to produce balls of wrought iron known as osmonds, and these were traded internationally – a possible reference occurs in a treaty with
Novgorod Veliky Novgorod ( rus, links=no, Великий Новгород, t=Great Newtown, p=vʲɪˈlʲikʲɪj ˈnovɡərət), also known as just Novgorod (), is the largest city and administrative centre of Novgorod Oblast, Russia. It is one of the ol ...
from 1203 and several certain references in accounts of English customs from the 1250s and 1320s. Other furnaces of the 13th to 15th centuries have been identified in Westphalia. The technology required for blast furnaces may have either been transferred from China, or may have been an indigenous innovation. Al-Qazvini in the 13th century and other travellers subsequently noted an iron industry in the Alburz Mountains to the south of the
Caspian Sea The Caspian Sea is the world's largest inland body of water, often described as the world's largest lake or a full-fledged sea. An endorheic basin, it lies between Europe and Asia; east of the Caucasus, west of the broad steppe of Central Asi ...
. This is close to the
silk route The Silk Road () was a network of Eurasian trade routes active from the second century BCE until the mid-15th century. Spanning over 6,400 kilometers (4,000 miles), it played a central role in facilitating economic, cultural, political, and reli ...
, so that the use of technology derived from China is conceivable. Much later descriptions record blast furnaces about three metres high. As the
Varangian The Varangians (; non, Væringjar; gkm, Βάραγγοι, ''Várangoi'';Varangian
" Online Etymo ...
Rus' people The Rusʹ (Old East Slavic: Рѹсь; Belarusian, Russian, Rusyn, and Ukrainian: Русь; Old Norse: '' Garðar''; Greek: Ῥῶς, ''Rhos'') were a people in early medieval eastern Europe. The scholarly consensus holds that they were orig ...
from
Scandinavia Scandinavia; Sámi languages: /. ( ) is a subregion in Northern Europe, with strong historical, cultural, and linguistic ties between its constituent peoples. In English usage, ''Scandinavia'' most commonly refers to Denmark, Norway, and Swed ...
traded with the Caspian (using their
Volga trade route In the Middle Ages, the Volga trade route connected Northern Europe and Northwestern Russia with the Caspian Sea and the Sasanian Empire, via the Volga River. The Rus used this route to trade with Muslim countries on the southern shores of the ...
), it is possible that the technology reached Sweden by this means. The step from
bloomery A bloomery is a type of metallurgical furnace once used widely for smelting iron from its oxides. The bloomery was the earliest form of smelter capable of smelting iron. Bloomeries produce a porous mass of iron and slag called a ''bloom''. ...
to true blast furnace is not big. Simply just building a bigger furnace and using bigger bellows to increase the volume of the blast and hence the amount of oxygen leads inevitably into higher temperatures, bloom melting into liquid iron, and cast iron flowing from the smelters. The Vikings are known to have used double bellows, which greatly increases the volumetric flow of the blast. The Caspian region may also have been the source for the design of the furnace at
Ferriere Ferriere ( lij, E Ferrër; Piacentino: ) is a ''comune'' (municipality) in the Province of Piacenza in the Italian region Emilia-Romagna, located about west of Bologna and about southwest of Piacenza, in the Val Nure of the Ligurian Apennine ...
, described by
Filarete Antonio di Pietro Aver(u)lino (; – ), known as Filarete (; from grc, φιλάρετος, meaning "lover of excellence"), was a Florentine Renaissance architect, sculptor, medallist, and architectural theorist. He is perhaps best remembered for ...
, involving a water-powered bellows at in
Valdidentro Valdidentro is a ''comune'' (municipality) in the Province of Sondrio in the Italian region Lombardy, located about northeast of Milan and about northeast of Sondrio, in the upper Alta Valtellina on the border with Switzerland. It is the se ...
in northern Italy in 1226. In a two-stage process the molten iron was tapped twice a day into water, thereby granulating it.


Cistercian contributions

The General Chapter of the Cistercian monks spread some technological advances across Europe. This may have included the blast furnace, as the Cistercians are known to have been skilled
metallurgists Metallurgy is a domain of materials science and engineering that studies the physical and chemical behavior of metallic elements, their inter-metallic compounds, and their mixtures, which are known as alloys. Metallurgy encompasses both the sci ...
.Woods, p. 34. According to Jean Gimpel, their high level of industrial technology facilitated the diffusion of new techniques: "Every monastery had a model factory, often as large as the church and only several feet away, and waterpower drove the machinery of the various industries located on its floor." Iron ore deposits were often donated to the monks along with forges to extract the iron, and after a time surpluses were offered for sale. The Cistercians became the leading iron producers in
Champagne Champagne (, ) is a sparkling wine originated and produced in the Champagne wine region of France under the rules of the appellation, that demand specific vineyard practices, sourcing of grapes exclusively from designated places within it, sp ...
, France, from the mid-13th century to the 17th century,Gimpel, p. 67. also using the
phosphate In chemistry, a phosphate is an anion, salt, functional group or ester derived from a phosphoric acid. It most commonly means orthophosphate, a derivative of orthophosphoric acid . The phosphate or orthophosphate ion is derived from phospho ...
-rich slag from their furnaces as an agricultural
fertilizer A fertilizer (American English) or fertiliser (British English; see spelling differences) is any material of natural or synthetic origin that is applied to soil or to plant tissues to supply plant nutrients. Fertilizers may be distinct from ...
. Archaeologists are still discovering the extent of Cistercian technology.Woods, p. 36. At
Laskill Laskill is a small hamlet in Bilsdale, 5 miles (8 km) north-west of Helmsley, North Yorkshire, England, on the road from Helmsley to Stokesley and is located within the North York Moors National Park. Archaeological investigations h ...
, an outstation of
Rievaulx Abbey Rievaulx Abbey was a Cistercian abbey in Rievaulx, near Helmsley, in the North York Moors National Park, North Yorkshire, England. It was one of the great abbeys in England until it was seized in 1538 under Henry VIII during the Dissolut ...
and the only medieval blast furnace so far identified in
Britain Britain most often refers to: * The United Kingdom, a sovereign state in Europe comprising the island of Great Britain, the north-eastern part of the island of Ireland and many smaller islands * Great Britain, the largest island in the United King ...
, the slag produced was low in iron content.Woods, p. 37. Slag from other furnaces of the time contained a substantial concentration of iron, whereas Laskill is believed to have produced cast iron quite efficiently.David Derbyshire
'Henry "Stamped Out Industrial Revolution"'
, ''
The Daily Telegraph ''The Daily Telegraph'', known online and elsewhere as ''The Telegraph'', is a national British daily broadsheet newspaper published in London by Telegraph Media Group and distributed across the United Kingdom and internationally. It was fo ...
'' (21 June 2002); cited by Woods.
Its date is not yet clear, but it probably did not survive until
Henry VIII Henry VIII (28 June 149128 January 1547) was King of England from 22 April 1509 until his death in 1547. Henry is best known for his six marriages, and for his efforts to have his first marriage (to Catherine of Aragon) annulled. His disagr ...
's Dissolution of the Monasteries in the late 1530s, as an agreement (immediately after that) concerning the "smythes" with the
Earl of Rutland Earl () is a rank of the nobility in the United Kingdom. The title originates in the Old English word ''eorl'', meaning "a man of noble birth or rank". The word is cognate with the Scandinavian form ''jarl'', and meant "chieftain", particular ...
in 1541 refers to blooms. Nevertheless, the means by which the blast furnace spread in medieval Europe has not finally been determined.


Origin and spread of early modern blast furnaces

Due to the increased demand for iron for casting cannons, the blast furnace came into widespread use in France in the mid 15th century. The direct ancestor of those used in France and England was in the Namur region, in what is now Wallonia (Belgium). From there, they spread first to the
Pays de Bray The Pays de Bray (, literally ''Land of Bray'') is a small (about 750 km²) natural region of France situated to the north-east of Rouen, straddling the French departments of the Seine-Maritime and the Oise (historically divided among the P ...
on the eastern boundary of
Normandy Normandy (; french: link=no, Normandie ; nrf, Normaundie, Nouormandie ; from Old French , plural of ''Normant'', originally from the word for "northman" in several Scandinavian languages) is a geographical and cultural region in Northwestern ...
and from there to the
Weald The Weald () is an area of South East England between the parallel chalk escarpments of the North and the South Downs. It crosses the counties of Hampshire, Surrey, Sussex and Kent. It has three separate parts: the sandstone "High Weald" in the ...
of
Sussex Sussex (), from the Old English (), is a historic county in South East England that was formerly an independent medieval Anglo-Saxon kingdom. It is bounded to the west by Hampshire, north by Surrey, northeast by Kent, south by the English C ...
, where the first furnace (called Queenstock) in
Buxted Buxted is a village and civil parish in the Wealden district of East Sussex in England. The parish is situated on the Weald, north of Uckfield; the settlements of Five Ash Down, Heron's Ghyll and High Hurstwood are included within its boundarie ...
was built in about 1491, followed by one at Newbridge in
Ashdown Forest Ashdown Forest is an ancient area of open heathland occupying the highest sandy ridge-top of the High Weald Area of Outstanding Natural Beauty. It is situated some south of London in the county of East Sussex, England. Rising to an elevation o ...
in 1496. They remained few in number until about 1530 but many were built in the following decades in the Weald, where the iron industry perhaps reached its peak about 1590. Most of the pig iron from these furnaces was taken to
finery forge A finery forge is a forge used to produce wrought iron from pig iron by decarburization in a process called "fining" which involved liquifying cast iron in a fining hearth and removing carbon from the molten cast iron through oxidation. Finery ...
s for the production of
bar iron Wrought iron is an iron alloy with a very low carbon content (less than 0.08%) in contrast to that of cast iron (2.1% to 4%). It is a semi-fused mass of iron with fibrous slag inclusions (up to 2% by weight), which give it a wood-like "grain" ...
. The first British furnaces outside the Weald appeared during the 1550s, and many were built in the remainder of that century and the following ones. The output of the industry probably peaked about 1620, and was followed by a slow decline until the early 18th century. This was apparently because it was more economic to import iron from
Sweden Sweden, formally the Kingdom of Sweden,The United Nations Group of Experts on Geographical Names states that the country's formal name is the Kingdom of SwedenUNGEGN World Geographical Names, Sweden./ref> is a Nordic country located on ...
and elsewhere than to make it in some more remote British locations. Charcoal that was economically available to the industry was probably being consumed as fast as the wood to make it grew. The first blast furnace in Russia opened in 1637 near Tula and was called the Gorodishche Works. The blast furnace spread from there to central Russia and then finally to the
Urals The Ural Mountains ( ; rus, Ура́льские го́ры, r=Uralskiye gory, p=ʊˈralʲskʲɪjə ˈɡorɨ; ba, Урал тауҙары) or simply the Urals, are a mountain range that runs approximately from north to south through western ...
.


Coke blast furnaces

In 1709, at
Coalbrookdale Coalbrookdale is a village in the Ironbridge Gorge in Shropshire, England, containing a settlement of great significance in the history of iron ore smelting. It lies within the civil parish called the Gorge. This is where iron ore was first sm ...
in Shropshire, England, Abraham Darby began to fuel a blast furnace with coke instead of
charcoal Charcoal is a lightweight black carbon residue produced by strongly heating wood (or other animal and plant materials) in minimal oxygen to remove all water and volatile constituents. In the traditional version of this pyrolysis process, cal ...
. Coke's initial advantage was its lower cost, mainly because making coke required much less labor than cutting trees and making charcoal, but using coke also overcame localized shortages of wood, especially in Britain and on the Continent. Metallurgical grade coke will bear heavier weight than charcoal, allowing larger furnaces. A disadvantage is that coke contains more impurities than charcoal, with sulfur being especially detrimental to the iron's quality. Coke's impurities were more of a problem before hot blast reduced the amount of coke required and before furnace temperatures were hot enough to make slag from limestone free flowing. (Limestone ties up sulfur. Manganese may also be added to tie up sulfur.) Coke iron was initially only used for
foundry A foundry is a factory that produces metal castings. Metals are cast into shapes by melting them into a liquid, pouring the metal into a mold, and removing the mold material after the metal has solidified as it cools. The most common metals pr ...
work, making pots and other cast iron goods. Foundry work was a minor branch of the industry, but Darby's son built a new furnace at nearby Horsehay, and began to supply the owners of
finery forge A finery forge is a forge used to produce wrought iron from pig iron by decarburization in a process called "fining" which involved liquifying cast iron in a fining hearth and removing carbon from the molten cast iron through oxidation. Finery ...
s with coke pig iron for the production of bar iron. Coke pig iron was by this time cheaper to produce than charcoal pig iron. The use of a coal-derived fuel in the iron industry was a key factor in the British
Industrial Revolution The Industrial Revolution was the transition to new manufacturing processes in Great Britain, continental Europe, and the United States, that occurred during the period from around 1760 to about 1820–1840. This transition included going f ...
. Darby's original blast furnace has been archaeologically excavated and can be seen in situ at Coalbrookdale, part of the
Ironbridge Gorge The Ironbridge Gorge is a deep gorge, containing the River Severn in Shropshire, England. It was first formed by a glacial overflow from the long drained away Lake Lapworth, at the end of the last ice age. The deep exposure of the rocks cut ...
Museums. Cast iron from the furnace was used to make
girder A girder () is a support beam used in construction. It is the main horizontal support of a structure which supports smaller beams. Girders often have an I-beam cross section composed of two load-bearing ''flanges'' separated by a stabilizing ...
s for the world's first iron bridge in 1779.
The Iron Bridge The Iron Bridge is a cast iron arch bridge that crosses the River Severn in Shropshire, England. Opened in 1781, it was the first major bridge in the world to be made of cast iron. Its success inspired the widespread use of cast iron as a str ...
crosses the
River Severn , name_etymology = , image = SevernFromCastleCB.JPG , image_size = 288 , image_caption = The river seen from Shrewsbury Castle , map = RiverSevernMap.jpg , map_size = 288 , map_c ...
at Coalbrookdale and remains in use for pedestrians.


Steam-powered blast

The steam engine was applied to power blast air, overcoming a shortage of water power in areas where coal and iron ore were located. This was first done at Coalbrookdale where a
steam engine A steam engine is a heat engine that performs mechanical work using steam as its working fluid. The steam engine uses the force produced by steam pressure to push a piston back and forth inside a cylinder. This pushing force can be trans ...
replaced a horse-powered pump in 1742. Such engines were used to pump water to a reservoir above the furnace. The first engines used to blow cylinders directly was supplied by
Boulton and Watt Boulton & Watt was an early British engineering and manufacturing firm in the business of designing and making marine and stationary steam engines. Founded in the English West Midlands around Birmingham in 1775 as a partnership between the Engl ...
to John Wilkinson's New Willey Furnace. This powered a cast iron blowing cylinder, which had been invented by his father Isaac Wilkinson. He patented such cylinders in 1736, to replace the leather bellows, which wore out quickly. Isaac was granted a second patent, also for blowing cylinders, in 1757. The steam engine and cast iron blowing cylinder led to a large increase in British iron production in the late 18th century.


Hot blast

Hot blast Hot blast refers to the preheating of air blown into a blast furnace or other metallurgical process. As this considerably reduced the fuel consumed, hot blast was one of the most important technologies developed during the Industrial Revolution. ...
was the single most important advance in fuel efficiency of the blast furnace and was one of the most important technologies developed during the
Industrial Revolution The Industrial Revolution was the transition to new manufacturing processes in Great Britain, continental Europe, and the United States, that occurred during the period from around 1760 to about 1820–1840. This transition included going f ...
. Hot blast was patented by
James Beaumont Neilson James Beaumont Neilson (22 June 1792 – 18 January 1865) was a Scottish inventor whose hot-blast process greatly increased the efficiency of smelting iron. Life He was the son of the engineer Walter Neilson, a millwright and later engin ...
at
Wilsontown Ironworks The ruins of the Wilsontown Ironworks are located near the village of Forth in Lanarkshire in Scotland, approximately to the south east of Glasgow. The works were founded by the three Wilson brothers in 1779, and operated until 1842. The works ...
in Scotland in 1828. Within a few years of the introduction, hot blast was developed to the point where fuel consumption was cut by one-third using coke or two-thirds using coal, while furnace capacity was also significantly increased. Within a few decades, the practice was to have a "stove" as large as the furnace next to it into which the waste gas (containing CO) from the furnace was directed and burnt. The resultant heat was used to preheat the air blown into the furnace.Birch, pp. 181–189. Hot blast enabled the use of raw
anthracite Anthracite, also known as hard coal, and black coal, is a hard, compact variety of coal that has a submetallic luster. It has the highest carbon content, the fewest impurities, and the highest energy density of all types of coal and is the high ...
coal, which was difficult to light, to the blast furnace. Anthracite was first tried successfully by George Crane at Ynyscedwyn Ironworks in south Wales in 1837. It was taken up in America by the
Lehigh Crane Iron Company The Lehigh Crane Iron Company (later simply the Crane Iron Company) was a major ironmaking firm in the Lehigh Valley from its founding in 1839 until its sale in 1899. It was founded under the patronage of Josiah White and Erskine Hazard, and fin ...
at
Catasauqua, Pennsylvania Catasauqua, referred to colloquially as Catty, is a borough in Lehigh County, Pennsylvania. Catasauqua's population was 6,518 at the 2020 census. It is a suburb of Allentown in the Lehigh Valley, which had a population of 861,899 and was the 68th ...
, in 1839. Anthracite use declined when very high capacity blast furnaces requiring coke were built in the 1870s.


Modern applications of the blast furnace


Iron blast furnaces

The blast furnace remains an important part of modern iron production. Modern furnaces are highly efficient, including
Cowper stove A regenerative heat exchanger, or more commonly a regenerator, is a type of heat exchanger where heat from the hot fluid is intermittently stored in a thermal storage medium before it is transferred to the cold fluid. To accomplish this the hot fl ...
s to pre-heat the blast air and employ recovery systems to extract the heat from the hot gases exiting the furnace. Competition in industry drives higher production rates. The largest blast furnace in the world is in South Korea, with a volume around . It can produce around of iron per year. This is a great increase from the typical 18th-century furnaces, which averaged about per year. Variations of the blast furnace, such as the Swedish electric blast furnace, have been developed in countries which have no native coal resources. According to
Global Energy Monitor Global Energy Monitor (GEM) is a San Francisco-based non-governmental organization which catalogs fossil fuel and renewable energy projects worldwide. GEM shares information in support of clean energy and its data and reports on energy trends ...
the blast furnace is likely to become obsolete to meet climate change objectives of reducing carbon dioxide emission, but
BHP BHP Group Limited (formerly known as BHP Billiton) is an Australian multinational mining, metals, natural gas petroleum public company that is headquartered in Melbourne, Victoria, Australia. The Broken Hill Proprietary Company was founded ...
disagrees. An alternative process involving
direct reduced iron Direct reduced iron (DRI), also called sponge iron, is produced from the direct reduction of iron ore (in the form of lumps, pellets, or fines) into iron by a reducing gas or elemental carbon produced from natural gas or coal. Many ores are suit ...
is likely to succeed it, but this also needs to use a blast furnace to melt the iron and remove the
gangue In mining, gangue () is the commercially worthless material that surrounds, or is closely mixed with, a wanted mineral in an ore deposit. It is thus distinct from overburden, which is the waste rock or materials overlying an ore or mineral body t ...
(impurities) unless the ore is very high quality.


Oxygen blast furnace

The oxygen blast furnace (OBF) process has been extensively studied theoretically because of the potentials of promising energy conservation and CO2 emission reduction. This type may be the most suitable for use with CCS.the main blast furnace has of three levels of reduction zones reduction zone (523–973k),slag formation zone (1073–1273k), combustion zone (1773–1873k)


Lead blast furnaces

Blast furnaces are currently rarely used in copper smelting, but modern lead smelting blast furnaces are much shorter than iron blast furnaces and are rectangular in shape.R J Sinclair, ''The Extractive Metallurgy of Lead'' (The Australasian Institute of Mining and Metallurgy: Melbourne, 2009), 75. The overall shaft height is around 5 to 6 m.R J Sinclair, ''The Extractive Metallurgy of Lead'' (The Australasian Institute of Mining and Metallurgy: Melbourne, 2009), 77. Modern lead blast furnaces are constructed using water-cooled steel or copper jackets for the walls, and have no refractory linings in the side walls. The base of the furnace is a hearth of refractory material (bricks or castable refractory). Lead blast furnaces are often open-topped rather than having the charging bell used in iron blast furnaces. The blast furnace used at the
Nyrstar Nyrstar is a global multi-metals business, with a market leading position in zinc and lead and growing positions in other base and precious metals, such as copper, gold and silver. Nyrstar has mining and smelting operations located in Europe, North ...
Port Pirie Port Pirie is a small city on the east coast of the Spencer Gulf in South Australia, north of the state capital, Adelaide. The city has an expansive history which dates back to 1845. Port Pirie was the first proclaimed regional city in South A ...
lead smelter differs from most other lead blast furnaces in that it has a double row of tuyeres rather than the single row normally used. The lower shaft of the furnace has a chair shape with the lower part of the shaft being narrower than the upper. The lower row of tuyeres being located in the narrow part of the shaft. This allows the upper part of the shaft to be wider than the standard.


Zinc blast furnaces (Imperial Smelting Furnaces)

The blast furnaces used in the Imperial Smelting Process ("ISP") were developed from the standard lead blast furnace, but are fully sealed.R J Sinclair, ''The Extractive Metallurgy of Lead'' (The Australasian Institute of Mining and Metallurgy: Melbourne, 2009), 89. This is because the zinc produced by these furnaces is recovered as metal from the vapor phase, and the presence of oxygen in the off-gas would result in the formation of zinc oxide. Blast furnaces used in the ISP have a more intense operation than standard lead blast furnaces, with higher air blast rates per m2 of hearth area and a higher coke consumption. Zinc production with the ISP is more expensive than with electrolytic zinc plants, so several smelters operating this technology have closed in recent years. However, ISP furnaces have the advantage of being able to treat zinc concentrates containing higher levels of lead than can electrolytic zinc plants.


Manufacture of stone wool

Stone wool or
rock wool Mineral wool is any fibrous material formed by spinning or drawing molten mineral or rock materials such as slag and ceramics. Applications of mineral wool include thermal insulation (as both structural insulation and pipe insulation), filt ...
is a spun mineral
fibre Fiber or fibre (from la, fibra, links=no) is a natural or artificial substance that is significantly longer than it is wide. Fibers are often used in the manufacture of other materials. The strongest engineering materials often incorporate ...
used as an insulation product and in
hydroponic Hydroponics is a type of horticulture and a subset of hydroculture which involves growing plants, usually crops or medicinal plants, without soil, by using water-based mineral nutrient solutions in aqueous solvents. Terrestrial or aquatic plant ...
s. It is manufactured in a blast furnace fed with
diabase Diabase (), also called dolerite () or microgabbro, is a mafic, holocrystalline, subvolcanic rock equivalent to volcanic basalt or plutonic gabbro. Diabase dikes and sills are typically shallow intrusive bodies and often exhibit fine-grained ...
rock which contains very low levels of metal oxides. The resultant slag is drawn off and spun to form the rock wool product. Very small amounts of metals are also produced which are an unwanted
by-product A by-product or byproduct is a secondary product derived from a production process, manufacturing process or chemical reaction; it is not the primary product or service being produced. A by-product can be useful and marketable or it can be consid ...
.


Modern iron process

Modern furnaces are equipped with an array of supporting facilities to increase efficiency, such as ore storage yards where barges are unloaded. The raw materials are transferred to the stockhouse complex by ore bridges, or rail hoppers and ore transfer cars. Rail-mounted scale cars or computer controlled weight hoppers weigh out the various raw materials to yield the desired hot metal and slag chemistry. The raw materials are brought to the top of the blast furnace via a
skip Skip or Skips may refer to: Acronyms * SKIP (Skeletal muscle and kidney enriched inositol phosphatase), a human gene * Simple Key-Management for Internet Protocol * SKIP of New York (Sick Kids need Involved People), a non-profit agency aiding ...
car powered by winches or conveyor belts.American Iron and Steel Institute (2005)
How a Blast Furnace Works
steel.org.
There are different ways in which the raw materials are charged into the blast furnace. Some blast furnaces use a "double bell" system where two "bells" are used to control the entry of raw material into the blast furnace. The purpose of the two bells is to minimize the loss of hot gases in the blast furnace. First, the raw materials are emptied into the upper or small bell which then opens to empty the charge into the large bell. The small bell then closes, to seal the blast furnace, while the large bell rotates to provide specific distribution of materials before dispensing the charge into the blast furnace. A more recent design is to use a "bell-less" system. These systems use multiple hoppers to contain each raw material, which is then discharged into the blast furnace through valves. These valves are more accurate at controlling how much of each constituent is added, as compared to the skip or conveyor system, thereby increasing the efficiency of the furnace. Some of these bell-less systems also implement a discharge chute in the throat of the furnace (as with the Paul Wurth top) in order to precisely control where the charge is placed. The iron making blast furnace itself is built in the form of a tall structure, lined with
refractory In materials science, a refractory material or refractory is a material that is resistant to decomposition by heat, pressure, or chemical attack, and retains strength and form at high temperatures. Refractories are polycrystalline, polyphase, ...
brick, and profiled to allow for expansion of the charged materials as they heat during their descent, and subsequent reduction in size as melting starts to occur. Coke,
limestone Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms when ...
flux, and iron ore (iron oxide) are charged into the top of the furnace in a precise filling order which helps control gas flow and the chemical reactions inside the furnace. Four "uptakes" allow the hot, dirty gas high in carbon monoxide content to exit the furnace throat, while "bleeder valves" protect the top of the furnace from sudden gas pressure surges. The coarse particles in the exhaust gas settle in the "dust catcher" and are dumped into a railroad car or truck for disposal, while the gas itself flows through a
venturi scrubber A venturi scrubber is designed to effectively use the energy from a high-velocity inlet gas stream to atomize the liquid being used to scrub the gas stream. This type of technology is a part of the group of air pollution controls collectively refe ...
and/or electrostatic precipitators and a gas cooler to reduce the temperature of the cleaned gas. The "casthouse" at the bottom half of the furnace contains the bustle pipe, water cooled copper tuyeres and the equipment for casting the liquid iron and slag. Once a "taphole" is drilled through the refractory clay plug, liquid iron and slag flow down a trough through a "skimmer" opening, separating the iron and slag. Modern, larger blast furnaces may have as many as four tapholes and two casthouses. Once the pig iron and slag has been tapped, the taphole is again plugged with refractory clay. The
tuyere A tuyere or tuyère (; ) is a tube, nozzle or pipe through which air is blown into a furnace or hearth.W. K. V. Gale, The iron and Steel industry: a dictionary of terms (David and Charles, Newton Abbot 1972), 216–217. Air or oxygen is in ...
s are used to implement a
hot blast Hot blast refers to the preheating of air blown into a blast furnace or other metallurgical process. As this considerably reduced the fuel consumed, hot blast was one of the most important technologies developed during the Industrial Revolution. ...
, which is used to increase the efficiency of the blast furnace. The hot blast is directed into the furnace through water-cooled copper nozzles called tuyeres near the base. The hot blast temperature can be from 900 °C to 1300 °C (1600 °F to 2300 °F) depending on the stove design and condition. The temperatures they deal with may be 2000 °C to 2300 °C (3600 °F to 4200 °F).
Oil An oil is any nonpolar chemical substance that is composed primarily of hydrocarbons and is hydrophobic (does not mix with water) & lipophilic (mixes with other oils). Oils are usually flammable and surface active. Most oils are unsaturated ...
,
tar Tar is a dark brown or black viscous liquid of hydrocarbons and free carbon, obtained from a wide variety of organic materials through destructive distillation. Tar can be produced from coal, wood, petroleum, or peat. "a dark brown or black b ...
,
natural gas Natural gas (also called fossil gas or simply gas) is a naturally occurring mixture of gaseous hydrocarbons consisting primarily of methane in addition to various smaller amounts of other higher alkanes. Low levels of trace gases like carbon di ...
, powdered
coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when dead ...
and
oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as well ...
can also be injected into the furnace at tuyere level to combine with the coke to release additional energy and increase the percentage of reducing gases present which is necessary to increase productivity. The exhaust gasses of a blast furnace are generally cleaned in the
dust collector A dust collector is a system used to enhance the quality of air released from industrial and commercial processes by collecting dust and other impurities from air or gas. Designed to handle high-volume dust loads, a dust collector system consists ...
– such as an
inertia Inertia is the idea that an object will continue its current motion until some force causes its speed or direction to change. The term is properly understood as shorthand for "the principle of inertia" as described by Newton in his first law ...
l separator, a
baghouse A baghouse, also known as a baghouse filter, bag filter, or fabric filter is an air pollution control device and dust collector that removes particulates or gas released from commercial processes out of the air. Power plants, steel mills, pharmace ...
, or an
electrostatic precipitator An electrostatic precipitator (ESP) is a filterless device that removes fine particles, like dust and smoke, from a flowing gas using the force of an induced electrostatic charge minimally impeding the flow of gases through the unit. In con ...
. Each type of dust collector has strengths and weaknesses – some collect fine particles, some coarse particles, some collect electrically charged particles. Effective exhaust clearing relies on multiple stages of treatment. Waste heat is usually collected from the exhaust gases, for example by the use of a
Cowper stove A regenerative heat exchanger, or more commonly a regenerator, is a type of heat exchanger where heat from the hot fluid is intermittently stored in a thermal storage medium before it is transferred to the cold fluid. To accomplish this the hot fl ...
, a variety of
heat exchanger A heat exchanger is a system used to transfer heat between a source and a working fluid. Heat exchangers are used in both cooling and heating processes. The fluids may be separated by a solid wall to prevent mixing or they may be in direct contac ...
. The IEA Green House Gas R&D Programme (IEAGHG) has shown that in an integrated steel plant, 70% of the is directly from the blast furnace gas (BFG). It is possible to use carbon capture technology on the BFG before the BFG goes on to be used for heat exchange processes within the plant. In 2000, the IEAGHG estimated using that chemical absorption to capture BFG would cost $35/t of (an additional $8–20/t of would be required for transportation and storage). This would make the entire steel production process in a plant 15–20% more expensive.


Environmental impact

The results showed that
global warming In common usage, climate change describes global warming—the ongoing increase in global average temperature—and its effects on Earth's climate system. Climate change in a broader sense also includes previous long-term changes to E ...
potential and acidification potential were the most significant environmental impacts. On average producing a tonne of steel emits 1.8 tonnes of . However, a steel mill using a top gas recycling blast furnace (TGRBF) producing a tonne of steel will emit 0.8 to 1.3 tonnes of depending upon the recycle rate of the TGRBF.


Decommissioned blast furnaces as museum sites

For a long time, it was normal procedure for a decommissioned blast furnace to be demolished and either be replaced with a newer, improved one, or to have the entire site demolished to make room for follow-up use of the area. In recent decades, several countries have realized the value of blast furnaces as a part of their industrial history. Rather than being demolished, abandoned steel mills were turned into museums or integrated into multi-purpose parks. The largest number of preserved historic blast furnaces exists in Germany; other such sites exist in Spain, France, the Czech Republic,
Great Britain Great Britain is an island in the North Atlantic Ocean off the northwest coast of continental Europe. With an area of , it is the largest of the British Isles, the largest European island and the ninth-largest island in the world. It is ...
. Japan,
Luxembourg Luxembourg ( ; lb, Lëtzebuerg ; french: link=no, Luxembourg; german: link=no, Luxemburg), officially the Grand Duchy of Luxembourg, ; french: link=no, Grand-Duché de Luxembourg ; german: link=no, Großherzogtum Luxemburg is a small land ...
,
Poland Poland, officially the Republic of Poland, is a country in Central Europe. It is divided into 16 administrative provinces called voivodeships, covering an area of . Poland has a population of over 38 million and is the fifth-most populou ...
,
Romania Romania ( ; ro, România ) is a country located at the crossroads of Central, Eastern, and Southeastern Europe. It borders Bulgaria to the south, Ukraine to the north, Hungary to the west, Serbia to the southwest, Moldova to the east, and ...
,
Mexico Mexico (Spanish: México), officially the United Mexican States, is a country in the southern portion of North America. It is bordered to the north by the United States; to the south and west by the Pacific Ocean; to the southeast by Guatema ...
,
Russia Russia (, , ), or the Russian Federation, is a transcontinental country spanning Eastern Europe and Northern Asia. It is the largest country in the world, with its internationally recognised territory covering , and encompassing one-eight ...
and the
United States The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country primarily located in North America. It consists of 50 states, a federal district, five major unincorporated territo ...
.


Gallery

File:Alto horno antiguo Sestao.jpg, Abandoned blast furnace in
Sestao Sestao is a town and municipality of 27,296 inhabitants located in the province of Biscay, in the autonomous community of Basque Country, northern Spain. It is in the left bank of the Estuary of Bilbao and part of Bilbao's metropolitan area. Ses ...
, Spain. The furnace itself is inside the central girderwork. File:Old blast furnace gas cleaning plant 2012-05-02.jpg, Part of the gas cleaning system of a blast furnace in
Monclova Monclova (), is a city and the seat of the surrounding municipality of the same name in the northern Mexican state of Coahuila. According to the 2015 census, the city had 231,107 inhabitants. Its metropolitan area has 381,432 inhabitants and ...
, Mexico. This one is about to be de-commissioned and replaced.


See also

*
Basic oxygen furnace Basic oxygen steelmaking (BOS, BOP, BOF, or OSM), also known as Linz-Donawitz steelmaking or the oxygen converter processBrock and Elzinga, p. 50. is a method of primary steelmaking in which carbon-rich molten pig iron is made into steel. Blowing ...
* Blast furnace zinc smelting process *
Crucible steel Crucible steel is steel made by melting pig iron (cast iron), iron, and sometimes steel, often along with sand, glass, ashes, and other fluxes, in a crucible. In ancient times steel and iron were impossible to melt using charcoal or coal fir ...
* Extraction of iron *
Water gas Water gas is a kind of fuel gas, a mixture of carbon monoxide and hydrogen. It is produced by "alternately hot blowing a fuel layer okewith air and gasifying it with steam". The caloric yield of this is about 10% of a modern syngas plant. Fu ...
, produced by a "steam blast" * FINEX *
Flodin process The Flodin process is a direct reduction process for manufacturing modern iron and steel, developed by Gustaf Henning Flodin from Sweden and patented in 1924. It has been used in Norway, Sweden, and the United States. Using a specially constructe ...
*
Ironworks and steelworks in England An ironworks or iron works is an industrial plant where iron is smelted and where heavy iron and steel products are made. The term is both singular and plural, i.e. the singular of ''ironworks'' is ''ironworks''. Ironworks succeeded bloomeri ...
, which covers ironworks of all kinds. * Shaft furnace breather


References


Bibliography

* * * * * * *


External links


American Iron and Steel InstituteBlast Furnace animation Extensive picture gallery about all methods of making and shaping of iron and steel in North America and Europe. In German and English.Schematic diagram of blast furnace and Cowper stove
{{DEFAULTSORT:Blast Furnace Industrial furnaces Industrial Revolution Metallurgy Chinese inventions Steelmaking Smelting Firing techniques Industrial buildings