Benitoite () is a rare blue

barium Barium is a chemical element with the symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element. Th ...

titanium Titanium is a chemical element with the symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in ...

cyclosilicate Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, silica (silicon dioxide, ) is usually consid ...

, found in hydrothermally altered

serpentinite Serpentinite is a rock composed predominantly of one or more serpentine group minerals, the name originating from the similarity of the texture of the rock to that of the skin of a snake. Serpentinite has been called ''serpentine'' or ''ser ...

. It forms in low temperature, high pressure environments typical of

subduction Subduction is a geological process in which the oceanic lithosphere is recycled into the Earth's mantle at convergent boundaries. Where the oceanic lithosphere of a tectonic plate converges with the less dense lithosphere of a second plate, the ...

zones at

convergent plate boundaries A convergent boundary (also known as a destructive boundary) is an area on Earth where two or more lithospheric plates collide. One plate eventually slides beneath the other, a process known as subduction. The subduction zone can be defined by a ...

. Benitoite fluoresces under short wave

ultraviolet light Ultraviolet (UV) is a form of electromagnetic radiation with wavelength from 10 nm (with a corresponding frequency around 30 PHz) to 400 nm (750 THz), shorter than that of visible light, but longer than X-rays. UV radiation i ...

, appearing bright blue to bluish white in color. The more rarely seen clear to white benitoite crystals fluoresce red under long-wave UV light. It was discovered in 1907 by prospector James M. Couch in the San Benito Mountains roughly halfway between

San Francisco San Francisco (; Spanish language, Spanish for "Francis of Assisi, Saint Francis"), officially the City and County of San Francisco, is the commercial, financial, and cultural center of Northern California. The city proper is the List of Ca ...

and

Los Angeles Los Angeles ( ; es, Los Ángeles, link=no , ), often referred to by its initials L.A., is the largest city in the state of California and the second most populous city in the United States after New York City, as well as one of the world' ...

. Due to its similar color, Couch originally believed it to be

sapphire Sapphire is a precious gemstone, a variety of the mineral corundum, consisting of aluminium oxide () with trace amounts of elements such as iron, titanium, chromium, vanadium, or magnesium. The name sapphire is derived via the Latin "sapphir ...

, a variety of

corundum Corundum is a crystalline form of aluminium oxide () typically containing traces of iron, titanium, vanadium and chromium. It is a rock-forming mineral. It is a naturally transparent material, but can have different colors depending on the pres ...

. In 1909, a sample was sent to the

University of California, Berkeley The University of California, Berkeley (UC Berkeley, Berkeley, Cal, or California) is a public land-grant research university in Berkeley, California. Established in 1868 as the University of California, it is the state's first land-grant u ...

, where mineralogist Dr. George D. Louderback realized it was a previously unknown mineral. Corundum (sapphire) has a defined Mohs hardness of 9, while benitoite is much softer. He named it ''benitoite'' for its occurrence near the headwaters of the

San Benito River The San Benito River is a long river flowing northwesterly between the Diablo Range and the Gabilan Range, on the Central Coast of California.U.S. Geological Survey. National Hydrography Dataset high-resolution flowline dataThe National Map acces ...

San Benito County San Benito County (; ''San Benito'', Spanish for "St. Benedict"), officially the County of San Benito, is a county located in the Coast Range Mountains of the U.S. state of California. As of the 2020 census, the population was 64,209. The coun ...

California California is a U.S. state, state in the Western United States, located along the West Coast of the United States, Pacific Coast. With nearly 39.2million residents across a total area of approximately , it is the List of states and territori ...

. Benitoite occurs in a number of isolated locations globally, but gemstone quality material has only been found in California at the Benito Gem Mine where it was first discovered. It has been correctly identified in

Montana Montana () is a state in the Mountain West division of the Western United States. It is bordered by Idaho to the west, North Dakota and South Dakota to the east, Wyoming to the south, and the Canadian provinces of Alberta, British Columbi ...

Arkansas Arkansas ( ) is a landlocked state in the South Central United States. It is bordered by Missouri to the north, Tennessee and Mississippi to the east, Louisiana to the south, and Texas and Oklahoma to the west. Its name is from the Osage ...

Japan Japan ( ja, 日本, or , and formally , ''Nihonkoku'') is an island country in East Asia. It is situated in the northwest Pacific Ocean, and is bordered on the west by the Sea of Japan, while extending from the Sea of Okhotsk in the north ...

, and

Australia Australia, officially the Commonwealth of Australia, is a Sovereign state, sovereign country comprising the mainland of the Australia (continent), Australian continent, the island of Tasmania, and numerous List of islands of Australia, sma ...

although they formed under slightly different conditions and only grow large enough to be considered an accessory mineral. In 1985 benitoite was named as the official state gem of

. Non-gem crystals of benitoite can have a very rare, six-pointed twinned form.

Associated minerals and locations

Benitoite typically occurs with an unusual set of minerals, along with minerals that make up its host rock. Frequently associated minerals include:

natrolite Natrolite is a tectosilicate mineral species belonging to the zeolite group. It is a hydrated sodium and aluminium silicate with the formula . The type locality is Hohentwiel, Hegau, Germany. It was named natrolite by Martin Heinrich Klaproth i ...

neptunite Neptunite is a silicate mineral with the formula K Na2 Li( Fe2+, Mn2+)2 Ti2 Si8 O24. With increasing manganese it forms a series with mangan-neptunite. Watatsumiite is the variety with vanadium replacing the titanium in the formula. It was fir ...

, joaquinite, serpentine and

albite Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula . It is a tectosilicate. I ...

. Benitoite is a rare mineral found in very few locations including San Benito County, California,

and

. In the San Benito occurrence, it is found in

veins Veins are blood vessels in humans and most other animals that carry blood towards the heart. Most veins carry deoxygenated blood from the tissues back to the heart; exceptions are the pulmonary and umbilical veins, both of which carry oxygenated b ...

within

glaucophane Glaucophane is the name of a mineral and a mineral group belonging to the sodic amphibole supergroup of the double chain inosilicates, with the chemical formula ☐Na2(Mg3Al2)Si8O22(OH)2. Glaucophane crystallizes in the monoclinic system. Name G ...

schist Schist ( ) is a medium-grained metamorphic rock showing pronounced schistosity. This means that the rock is composed of mineral grains easily seen with a low-power hand lens, oriented in such a way that the rock is easily split into thin flakes o ...

within a

body. In Japan, the mineral occurs in a magnesio-

riebeckite Riebeckite is a sodium-rich member of the amphibole group of silicate minerals, chemical formula Na2(Fe2+3Fe3+2)Si8O22(OH)2. It forms a solid solution series with magnesioriebeckite. It crystallizes in the monoclinic system, usually as long prisma ...

quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...

phlogopite Phlogopite is a yellow, greenish, or reddish-brown member of the mica family of phyllosilicates. It is also known as magnesium mica. Phlogopite is the magnesium endmember of the biotite solid solution series, with the chemical formula KMg3AlSi3O ...

dike Dyke (UK) or dike (US) may refer to: General uses * Dyke (slang), a slang word meaning "lesbian" * Dike (geology), a subvertical sheet-like intrusion of magma or sediment * Dike (mythology), ''Dikē'', the Greek goddess of moral justice * Dikes ...

cutting a serpentinite body.Handbook of Mineralogy
/ref> File:benitoite09.jpg, Blue benitoite crystals on white natrolite, Dallas Gem Mine, San Benito Co., California, US File:Benitoite, UVL.jpg, Benitoite crystals under UV light

References

{{reflist, 25em Cyclosilicates Gemstones Titanium minerals Hexagonal minerals Minerals in space group 188 Barium minerals Luminescent minerals Geology of San Benito County, California Geology of California Symbols of California