Aragonite is a
carbonate mineral
Carbonate minerals are those minerals containing the carbonate ion, .
Carbonate divisions Anhydrous carbonates
*Calcite group: trigonal
** Calcite CaCO3
** Gaspéite (Ni,Mg,Fe2+)CO3
** Magnesite MgCO3
**Otavite CdCO3
** Rhodochrosite MnCO3
...
, one of the three most common naturally occurring
crystal forms of
calcium carbonate, (the other forms being the
mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2 ...
s
calcite
Calcite is a carbonate mineral and the most stable polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on the Mohs scale of mineral hardness, based on scratc ...
and
vaterite). It is formed by biological and physical processes, including precipitation from marine and freshwater environments.
The
crystal lattice
In geometry and crystallography, a Bravais lattice, named after , is an infinite array of discrete points generated by a set of discrete translation operations described in three dimensional space by
: \mathbf = n_1 \mathbf_1 + n_2 \mathbf_2 + n ...
of aragonite differs from that of calcite, resulting in a different crystal shape, an
orthorhombic crystal system
In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic lattices result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular prism with ...
with
acicular crystal. Repeated
twinning results in pseudo-hexagonal forms. Aragonite may be columnar or fibrous, occasionally in branching
helictitic forms called ''flos-ferri'' ("flowers of iron") from their association with the
ores at the
Carinthian
Carinthia (german: Kärnten ; sl, Koroška ) is the southernmost Austrian state, in the Eastern Alps, and is noted for its mountains and lakes. The main language is German. Its regional dialects belong to the Southern Bavarian group. Carint ...
iron mines.
Occurrence
The
type location for aragonite is
Molina de Aragón in the
Province of Guadalajara in
Castilla-La Mancha,
Spain
, image_flag = Bandera de España.svg
, image_coat = Escudo de España (mazonado).svg
, national_motto = '' Plus ultra'' (Latin)(English: "Further Beyond")
, national_anthem = (English: "Royal March")
, ...
, for which it was named in 1797.
Aragonite is found in this locality as cyclic twins inside gypsum and marls of the
Keuper
The Keuper is a lithostratigraphic unit (a sequence of rock strata) in the subsurface of large parts of west and central Europe. The Keuper consists of dolomite, shales or claystones and evaporites that were deposited during the Middle and Lat ...
facies of the
Triassic
The Triassic ( ) is a geologic period and system which spans 50.6 million years from the end of the Permian Period 251.902 million years ago ( Mya), to the beginning of the Jurassic Period 201.36 Mya. The Triassic is the first and shortest per ...
. This type of aragonite deposit is very common in Spain, and there are also some in France.
[
An aragonite cave, the Ochtinská Aragonite Cave, is situated in ]Slovakia
Slovakia (; sk, Slovensko ), officially the Slovak Republic ( sk, Slovenská republika, links=no ), is a landlocked country in Central Europe. It is bordered by Poland to the north, Ukraine to the east, Hungary to the south, Austria to the ...
.
In the US, aragonite in the form of stalactite
A stalactite (, ; from the Greek 'stalaktos' ('dripping') via
''stalassein'' ('to drip') is a mineral formation that hangs from the ceiling of caves, hot springs, or man-made structures such as bridges and mines. Any material that is soluble ...
s and "cave flowers" ( anthodite) is known from Carlsbad Caverns and other caves. For a few years in the early 1900s, aragonite was mined at Aragonite, Utah (now a ghost town).
Massive deposits of oolitic aragonite sand are found on the seabed in the Bahamas
The Bahamas (), officially the Commonwealth of The Bahamas, is an island country within the Lucayan Archipelago of the West Indies in the North Atlantic. It takes up 97% of the Lucayan Archipelago's land area and is home to 88% of the a ...
.
Aragonite is the high pressure polymorph of calcium carbonate. As such, it occurs in high pressure metamorphic rocks such as those formed at subduction zones.
Aragonite forms naturally in almost all mollusk
Mollusca is the second-largest phylum of invertebrate animals after the Arthropoda, the members of which are known as molluscs or mollusks (). Around 85,000 extant species of molluscs are recognized. The number of fossil species is e ...
shells, and as the calcareous endoskeleton of warm- and cold-water coral
Corals are marine invertebrates within the class Anthozoa of the phylum Cnidaria. They typically form compact colonies of many identical individual polyps. Coral species include the important reef builders that inhabit tropical oceans and se ...
s (Scleractinia
Scleractinia, also called stony corals or hard corals, are marine animals in the phylum Cnidaria that build themselves a hard skeleton. The individual animals are known as polyps and have a cylindrical body crowned by an oral disc in which a ...
). Several serpulids have aragonitic tubes. Because the mineral deposition in mollusk shells is strongly biologically controlled, some crystal forms are distinctively different from those of inorganic aragonite. In some mollusks, the entire shell is aragonite; in others, aragonite forms only discrete parts of a bimineralic shell (aragonite plus calcite).[ The nacreous layer of the aragonite ]fossil
A fossil (from Classical Latin , ) is any preserved remains, impression, or trace of any once-living thing from a past geological age. Examples include bones, shells, exoskeletons, stone imprints of animals or microbes, objects preserved ...
shells of some extinct ammonite
Ammonoids are a group of extinct marine mollusc animals in the subclass Ammonoidea of the class Cephalopoda. These molluscs, commonly referred to as ammonites, are more closely related to living coleoids (i.e., octopuses, squid and cuttlefis ...
s forms an iridescent
Iridescence (also known as goniochromism) is the phenomenon of certain surfaces that appear to gradually change color as the angle of view or the angle of illumination changes. Examples of iridescence include soap bubbles, feathers, butterfl ...
material called ammolite.
Aragonite also forms naturally in the endocarp of ''Celtis occidentalis
''Celtis occidentalis'', commonly known as the common hackberry, is a large deciduous tree native to North America. It is also known as the nettletree, sugarberry, beaverwood, northern hackberry, and American hackberry. It is a moderately long ...
''.
Aragonite also forms in the ocean inorganic precipitates called marine cements (in the sediment
Sediment is a naturally occurring material that is broken down by processes of weathering and erosion, and is subsequently transported by the action of wind, water, or ice or by the force of gravity acting on the particles. For example, sand ...
) or as free crystals (in the water column).
Inorganic precipitation of aragonite in caves can occur in the form of speleothem
A speleothem (; ) is a geological formation by mineral deposits that accumulate over time in natural caves. Speleothems most commonly form in calcareous caves due to carbonate dissolution reactions. They can take a variety of forms, dependi ...
s. Aragonite is common in serpentinites where magnesium-rich pore solutions apparently inhibit calcite growth and promote aragonite precipitation.
Aragonite is metastable at the low pressures near the Earth's surface and is thus commonly replaced by calcite in fossils. Aragonite older than the Carboniferous
The Carboniferous ( ) is a geologic period and system of the Paleozoic that spans 60 million years from the end of the Devonian Period million years ago ( Mya), to the beginning of the Permian Period, million years ago. The name ''Carboniferou ...
is essentially unknown. It can also be synthesized by adding a calcium chloride
Calcium chloride is an inorganic compound, a salt with the chemical formula . It is a white crystalline solid at room temperature, and it is highly soluble in water. It can be created by neutralising hydrochloric acid with calcium hydroxide.
Ca ...
solution to a sodium carbonate
Sodium carbonate, , (also known as washing soda, soda ash and soda crystals) is the inorganic compound with the formula Na2CO3 and its various hydrates. All forms are white, odourless, water-soluble salts that yield moderately alkaline solutions ...
solution at temperatures above or in water-ethanol mixtures at ambient temperatures.
Physical properties
Aragonite is not the thermodynamically stable phase of calcium carbonate at any pressure below about at any temperature. Aragonite nonetheless frequently forms in near-surface environments at ambient temperatures. The difference in stability between aragonite and calcite, as measured by the Gibbs free energy of formation, is small, and effects of grain size and impurities can be important. The formation of aragonite at temperatures and pressures where calcite should be the stable polymorph may be an example of Ostwald's step rule, where a less stable phase is the first to form. The presence of magnesium
Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ...
ions may inhibit calcite formation in favor of aragonite. Once formed, aragonite tends to alter to calcite
Calcite is a carbonate mineral and the most stable polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on the Mohs scale of mineral hardness, based on scratc ...
on scales of 107 to 108 years.
The mineral vaterite, also known as μ-CaCO3, is another phase of calcium carbonate that is metastable at ambient conditions typical of Earth's surface, and decomposes even more readily than aragonite.
Uses
In aquaria, aragonite is considered essential for the replication of reef conditions. Aragonite provides the materials necessary for much sea life and also keeps the pH of the water close to its natural level, to prevent the dissolution of biogenic
A biogenic substance is a product made by or of life forms. While the term originally was specific to metabolite compounds that had toxic effects on other organisms, it has developed to encompass any constituents, secretions, and metabolites of p ...
calcium carbonate.
Aragonite has been successfully tested for the removal of pollutants like zinc
Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodi ...
, cobalt
Cobalt is a chemical element with the symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. The free element, p ...
and lead
Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cut, ...
from contaminated wastewaters.
Claims that magnetic water treatment can reduce scaling, by converting calcite to aragonite, have been met with skepticism,[
] but continue to be investigated.
Gallery
Aragonite crystal - Los Molinillos, Ceunca, Spain - 4x3.6x3.5cm 100g.jpg, Aragonite crystal from Los Molinillos, Ceunca, Spain
Aragonite 2 Enguidanos.jpg, Aragonite crystals from Cuenca, Castile-La Mancha, Spain
Aragonite - Pantoja, Toledo, Castile-La Mancha, Spain.jpg, Aragonite crystal cluster from Spain
Image:BaculitesSuturesAragonite.jpg, Remnant biogenic aragonite (thin, rainbow-colored shell) on the ammonite '' Baculites'' (Pierre Shale
The Pierre Shale is a geologic formation or series in the Upper Cretaceous which occurs east of the Rocky Mountains in the Great Plains, from Pembina Valley in Canada to New Mexico.
The Pierre Shale was described by Fielding Bradford Meek, Meek a ...
, Late Cretaceous
The Cretaceous ( ) is a geological period that lasted from about 145 to 66 million years ago (Mya). It is the third and final period of the Mesozoic Era, as well as the longest. At around 79 million years, it is the longest geological period of ...
, South Dakota)
Aragonite layers in a blue mussel shell.jpg, Scanning electron microscope image of aragonite layers in the nacre
Nacre ( , ), also known as mother of pearl, is an organicinorganic composite material produced by some molluscs as an inner shell layer; it is also the material of which pearls are composed. It is strong, resilient, and iridescent.
Nacre is ...
of a blue mussel (''Mytilus edulis'')
Aragonit_-_Fluorescence.gif, Fluorescence of aragonite
See also
* Aragonite sea
An aragonite sea contains aragonite and high-magnesium calcite as the primary inorganic calcium carbonate precipitates. The chemical conditions of the seawater must be notably high in magnesium content relative to calcium (high Mg/Ca ratio) for ...
* Ikaite, CaCO3·6H2O
* Monohydrocalcite, CaCO3·H2O
* Nacre
Nacre ( , ), also known as mother of pearl, is an organicinorganic composite material produced by some molluscs as an inner shell layer; it is also the material of which pearls are composed. It is strong, resilient, and iridescent.
Nacre is ...
, otherwise known as "Mother-of-Pearl"
References
External links
The Ochtinska Aragonite Cave in Slovakia
Kosovo Caves Aragonite Formations
{{Authority control
Calcium minerals
Carbonate minerals
Cave minerals
Aragonite group
Orthorhombic minerals
Minerals in space group 62
Luminescent minerals
Evaporite