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The terms active packaging, intelligent packaging, smart packaging and connected packaging refer to
packaging Packaging is the science, art and technology of enclosing or protecting products for distribution, storage, sale, and use. Packaging also refers to the process of designing, evaluating, and producing packages. Packaging can be described as a c ...
systems used with
food Food is any substance consumed by an organism for nutritional support. Food is usually of plant, animal, or fungal origin, and contains essential nutrients, such as carbohydrates, fats, proteins, vitamins, or minerals. The substance is in ...
s,
pharmaceutical A medication (also called medicament, medicine, pharmaceutical drug, medicinal drug or simply drug) is a drug used to diagnose, cure, treat, or prevent disease. Drug therapy ( pharmacotherapy) is an important part of the medical field and ...
s, and several other types of products. They help extend shelf life, monitor freshness, display information on quality, improve safety, and improve
convenience Convenient procedures, products and services are those intended to increase ease in accessibility, save resources (such as time, effort and energy) and decrease frustration. A modern convenience is a labor-saving device, service or substance ...
. The terms are closely related. ''Active packaging'' usually means having active functions beyond the inert passive containment and protection of the product. ''Intelligent'' and ''smart'' packaging usually involve the ability to sense or measure an attribute of the product, the inner atmosphere of the package, or the shipping environment. This information can be communicated to users or can trigger active packaging functions. Programmable matter,
smart material Smart materials, also called intelligent or responsive materials, are designed materials that have one or more properties that can be significantly changed in a controlled fashion by external stimuli, such as stress, moisture, electric or magnetic ...
s, etc. can be employed in packages. Depending on the working definitions, some traditional types of packaging might be considered as "active" or "intelligent". More often, the terms are used with new technologically advanced systems:
microelectronics Microelectronics is a subfield of electronics. As the name suggests, microelectronics relates to the study and manufacture (or microfabrication) of very small electronic designs and components. Usually, but not always, this means micrometre- ...
,
computer applications A computer is a machine that can be programmed to carry out sequences of arithmetic or logical operations (computation) automatically. Modern digital electronic computers can perform generic sets of operations known as programs. These progr ...
,
nanotechnology Nanotechnology, also shortened to nanotech, is the use of matter on an atomic, molecular, and supramolecular scale for industrial purposes. The earliest, widespread description of nanotechnology referred to the particular technological goal ...
, etc.


Moisture control

For many years, desiccants have been used to control the water vapor in a closed package. A desiccant is a hygroscopic substance usually in a porous pouch or
sachet A sachet is a small scented cloth bag filled with herbs, potpourri, or aromatic ingredients.Oster, p. 54 A sachet is also a small porous bag or packet containing a material intended to interact with its atmosphere; for example, desiccants ...
which is placed inside a sealed package. They have been used to reduce corrosion of machinery and electronics and to extend the
shelf life Shelf life is the length of time that a commodity may be stored without becoming unfit for use, consumption, or sale. In other words, it might refer to whether a commodity should no longer be on a pantry shelf (unfit for use), or no longer on a ...
of moisture-sensitive foods. With pharmaceutical packages, a common method is to include a small packet of dessicant in a bottle. Other methods of including desiccants attached to the inner surface or in the material have recently been developed.


Corrosion

Corrosion inhibitor In chemistry, a corrosion inhibitor or anti-corrosive is a chemical compound that, when added to a liquid or gas, decreases the corrosion rate of a material, typically a metal or an alloy, that comes into contact with the fluid. The effectiveness ...
s can be applied to items to help prevent
rust Rust is an iron oxide, a usually reddish-brown oxide formed by the reaction of iron and oxygen in the catalytic presence of water or air moisture. Rust consists of hydrous iron(III) oxides (Fe2O3·nH2O) and iron(III) oxide-hydroxide (FeO( ...
and
corrosion Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engi ...
. Volatile corrosion inhibitors (VCI) or vapor phase corrosion inhibitors can be provided inside a package in a pouch or can be incorporated in a saturated overwrap of special paper or plastic film. Many of these are organic salts that condense on the metal to resist corrosion. Some films also have VCI emitting capability. Films are available with copper ions in the polymer structure, These neutralize the corrosive gas in a package and deter rust. VCIs create a neutral environment in the packaging. It works on the principle of difference in
vapour pressure Vapor pressure (or vapour pressure in English-speaking countries other than the US; see spelling differences) or equilibrium vapor pressure is defined as the pressure exerted by a vapor in thermodynamic equilibrium with its condensed phase ...
and causes reaction with metals and non-metals, and with moisture to prevent corrosion. There are different forms of VCIs available, such as papers,
plastic Plastics are a wide range of synthetic or semi-synthetic materials that use polymers as a main ingredient. Their plasticity makes it possible for plastics to be moulded, extruded or pressed into solid objects of various shapes. This adapta ...
s,
HDPE High-density polyethylene (HDPE) or polyethylene high-density (PEHD) is a thermoplastic polymer produced from the monomer ethylene. It is sometimes called "alkathene" or "polythene" when used for HDPE pipes. With a high strength-to-density ratio, ...
papers, oils,
foam Foams are materials formed by trapping pockets of gas in a liquid or solid. A bath sponge and the head on a glass of beer are examples of foams. In most foams, the volume of gas is large, with thin films of liquid or solid separating the ...
s, chips, aluminum barrier foils,
bubble Bubble, Bubbles or The Bubble may refer to: Common uses * Bubble (physics), a globule of one substance in another, usually gas in a liquid ** Soap bubble * Economic bubble, a situation where asset prices are much higher than underlying fund ...
, and emitters that can prevent corrosion at many stages.


Metal chelation

Trace
transition metal In chemistry, a transition metal (or transition element) is a chemical element in the d-block of the periodic table (groups 3 to 12), though the elements of group 12 (and less often group 3) are sometimes excluded. They are the elements that can ...
s in foods, especially
iron Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in ...
, can induce oxidative degradation of many food components, especially lipids, and cause quality changes of the products. Metal- chelating active packaging materials are made by immobilizing metal-chelating active compounds onto traditional active packaging material. The surface immobilized metal-chelating compounds can scavenge the transition metals from the product and enhance the oxidative stability of the product. The metal-chelating active packaging technology is also
antioxidant Antioxidants are compounds that inhibit oxidation, a chemical reaction that can produce free radicals. This can lead to polymerization and other chain reactions. They are frequently added to industrial products, such as fuels and lubrica ...
active packaging that will extend the shelf-life of consumer products by controlling the oxidation. The metal-chelating active packaging technology is known to be able to remove synthetic food preservatives (e.g.
EDTA Ethylenediaminetetraacetic acid (EDTA) is an aminopolycarboxylic acid with the formula H2N(CH2CO2H)2sub>2. This white, water-soluble solid is widely used to bind to iron (Fe2+/Fe3+) and calcium ions (Ca2+), forming water-soluble complexes ev ...
) from the food product. This technology can be used to address the increasing consumer demand for additive free and 'clean' label food products.


Oxygen control

Oxygen scavengers or oxygen absorbers help remove oxygen from a closed package. Some are small packets or sachets containing powdered iron: as the iron rusts, oxygen is removed from the surrounding atmosphere. Newer systems are on cards or can be built into package films or molded structures. In addition, the physical characteristics of the packaging itself (
oxygen transmission rate Oxygen transmission rate (OTR) is the measurement of the amount of oxygen gas that passes through a substance over a given period. It is mostly carried out on non-porous materials, where the mode of transport is diffusion, but there are a growing nu ...
- OTR) can dictate how effective an oxygen absorber can be, and how long it will stay effective. Packaging with a low OTR will let less oxygen in the closed package through the polymer barrier itself.


Atmosphere

With some products, such as
cheese Cheese is a dairy product produced in wide ranges of flavors, textures, and forms by coagulation of the milk protein casein. It comprises proteins and fat from milk, usually the milk of cows, buffalo, goats, or sheep. During productio ...
, it has long been common to flush the package with
nitrogen Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at se ...
prior to sealing: the inert nitrogen is absorbed into the cheese, allowing a tight
shrink film Shrink may refer to: Common meanings * Miniaturization *Shrink, a slang term for: ** a psychiatrist ** a psychoanalyst ** a psychologist Arts, entertainment, and media * ''Shrink'' (album), album by German indie rock/electronica group The Notw ...
package. The nitrogen removes oxygen and interacts with the cheese to make the package functional. More recently, other mixtures of gas have been used inside the package to extend the shelf life. The gas mixture depends on the specific product and its degradation mechanisms. Some package components have been developed that incorporate active chemistry to help maintain certain atmospheres in packages. Oxygen scavengers,
carbon dioxide generator A carbon dioxide generator or CO2 generator is a machine used to enhance carbon dioxide levels in order to promote plant growth in greenhouses or other enclosed areas. Carbon dioxide generators have been used to help grow marijuana.Karen LovetMarch ...
s, ethanol generators, etc. are available to help keep the atmosphere in a package at specified conditions.


Temperature monitor

Some temperature indicators give a visual signal that a specified temperature has been exceeded. Others, Time temperature indicators, signal when a critical accumulation of temperature deviation over time has been exceeded. When the mechanism of the indicator is tuned to the mechanism of product degradation, these can provide valuable signals for consumers. Digital temperature data loggers record the temperatures encountered throughout the shipment. This data can be used to predict product degradation and help determine if the product is suited for normal sale or if expedited sale is required. They also determine the time of the temperature excess: this can be used to direct corrective action. Thermochromic inks are sometimes used to signal temperature excess or change. Some are reversible while others have a permanent change of color. These can be used alone or with other packaging functions such as
barcode A barcode or bar code is a method of representing data in a visual, machine-readable form. Initially, barcodes represented data by varying the widths, spacings and sizes of parallel lines. These barcodes, now commonly referred to as linear or o ...
s. The inks can also signal a desired temperature for consumers. For example, one type of beer can has ink that graphically shows when an ideal drinking temperature is achieved.


Controlling package temperatures

For critical vaccines, insulated shipping containers are passive packaging to help control the temperatures fluctuations seen even with a controlled
cold chain A cold chain is a low temperature-controlled supply chain network. An unbroken cold chain is an uninterrupted series of refrigerated production, storage and distribution activities, along with associated equipment and logistics, which maintain qu ...
. In addition, gel packs are often used to keep the temperature of the contents within specified acceptable temperature ranges. Some newer packages have the ability to heat or cool the product for the consumer. These have segregated compartments where exothermic or endothermic reactions provide the desired effect. Self-heating cans are available for several products.


Dispensing

Some packages have closures or other dispensing systems that change the contents from a liquid to an
aerosol An aerosol is a suspension of fine solid particles or liquid droplets in air or another gas. Aerosols can be natural or anthropogenic. Examples of natural aerosols are fog or mist, dust, forest exudates, and geyser steam. Examples of anthropogen ...
. These are used for products ranging from precision
inhaler An inhaler (also known as a puffer, pump or allergy spray) is a medical device used for delivering medicines into the lungs through the work of a person's breathing. This allows medicines to be delivered to and absorbed in the lungs, which prov ...
s for medications to spray bottles of household cleaners. Some dispensing packages for two-part
epoxy Epoxy is the family of basic components or cured end products of epoxy resins. Epoxy resins, also known as polyepoxides, are a class of reactive prepolymers and polymers which contain epoxide groups. The epoxide functional group is also co ...
adhesives do more than passively contain the two components. When dispensed, some packages meter and mix the two components so the adhesive is fully functioning at the point of application. The ability of a package to fully empty or dispense a viscous liquid is somewhat dependent on the
surface energy In surface science, surface free energy (also interfacial free energy or surface energy) quantifies the disruption of intermolecular bonds that occurs when a surface is created. In solid-state physics, surfaces must be intrinsically less ener ...
of the inner walls of the container. The use of
superhydrophobic Ultrahydrophobic (or superhydrophobic) surfaces are highly hydrophobic, i.e., extremely difficult to wet. The contact angles of a water droplet on an ultrahydrophobic material exceed 150°. This is also referred to as the lotus effect, after the ...
surfaces is useful but can be further improved by using new lubricant-impregnated surfaces.


RFID

Radio-frequency identification Radio-frequency identification (RFID) uses electromagnetic fields to automatically Automatic identification system, identify and Tracking system, track tags attached to objects. An RFID system consists of a tiny radio transponder, a radio receiver ...
chips are becoming more common with the introduction of smart labels that are used to track and trace packages and
unit load The term unit load refers to the size of an assemblage into which a number of individual items are combined for ease of storage and handling, for example a pallet load represents a unit load which can be moved easily with a pallet jack or fork ...
s throughout distribution. Newer developments include recording the temperature history of shipments and other intelligent packaging functions. RFID can be integrated into labels: Smart labels.


Security

A variety of
security printing Security printing is the field of the printing industry that deals with the printing of items such as banknotes, cheques, passports, tamper-evident labels, security tapes, product authentication, stock certificates, postage stamps and identity ...
methods,
security hologram Security holograms are labels with a hologram printed onto it for sale security reasons. Holograms on security labels are very difficult to forge because they are replicated from a master hologram which requires expensive, specialized and technol ...
s, and specialized
label A label (as distinct from signage) is a piece of paper, plastic film, cloth, metal, or other material affixed to a container or product, on which is written or printed information or symbols about the product or item. Information printed ...
s are available to help confirm that the product in the package is not
counterfeit To counterfeit means to imitate something authentic, with the intent to steal, destroy, or replace the original, for use in illegal transactions, or otherwise to deceive individuals into believing that the fake is of equal or greater value tha ...
. RFID chips are being used in this application also.
Electronic article surveillance Electronic article surveillance is a technological method for preventing shoplifting from retail stores, pilferage of books from libraries or removal of properties from office buildings. Special tags are fixed to merchandise; these tags are remove ...
(on the product or on the package) is used to help counter shoplifting.


Microwave packaging

Metallised film Metallised films (or metallized films) are polymer films coated with a thin layer of metal, usually aluminium. They offer the glossy metallic appearance of an aluminium foil at a reduced weight and cost. Metallised films are widely used for decorati ...
s are used as a
susceptor A susceptor is a material used for its ability to absorb electromagnetic energy and convert it to heat (which in some cases is re-emitted as infrared thermal radiation). The electromagnetic energy is typically radiofrequency or microwave radiation ...
for cooking in
microwave oven A microwave oven (commonly referred to as a microwave) is an electric oven that heats and cooks food by exposing it to electromagnetic radiation in the microwave frequency range. This induces polar molecules in the food to rotate and produce ...
s. These increase the heating capacity and help make foods crisp and brown. Plastic microwavable containers are also used for microwave cooking.


Shock and vibration

Shock detector A shock detector, shock indicator, or impact monitor is a device which indicates whether a physical shock or impact has occurred. These usually have a binary output (go/no-go) and are sometimes called ''shock overload devices''. Shock detect ...
s have been available for many years. These are attached to the package or to the product in the package to determine if an excessive shock has been encountered. The mechanisms of these ''shock overload'' devices have been spring-mass systems, magnets, drops of red dDye, and several others. Recently, digital shock and vibration data loggers have been available to more accurately record the shocks and vibrations of shipment. These are used to monitor critical shipments to determine if extra inspection and calibration is required. They are also used to monitor the types of shocks and vibrations encountered in transit for use in package testing in a laboratory.


Antimicrobial control

Some engineered packaging films contain
enzyme Enzymes () are proteins that act as biological catalysts by accelerating chemical reactions. The molecules upon which enzymes may act are called substrates, and the enzyme converts the substrates into different molecules known as products ...
s, antimicrobial agents, scavengers, natural pigments and other active components to help control food degradation and extend shelf life and safety. The mechanism focuses on preventing the growth of pathogenic or spoilage microorganisms


QR Codes

QR Codes are often used on packaging to provide additional information on the product via a smartphone scan. With digital printers, unit-level QR Codes can become the equivalent of a unique identifier or URL for each packaging, and enable other interactions with consumers such as providing specific information on product
traceability Traceability is the capability to trace something. In some cases, it is interpreted as the ability to verify the history, location, or application of an item by means of documented recorded identification. Other common definitions include the capab ...
, or deploying loyalty programs. Unit-level QR Codes are easy to counterfeit if additional security features are not used, but the scan data generated can be used for active brand protection. A digital watermark or
secure graphic A copy detection pattern (CDP) or graphical code is a small random or pseudo-random digital image which is printed on documents, labels or products for counterfeit detection. Authentication is made by scanning the printed CDP using an image s ...
can be inserted into the QR Code to make it copy-sensitive and let consumers authenticate products with a higher security level. The GS1 digital link is a standard for embedding GS1 standardised product identifiers into the unique identifier, which allows the same QR Code (or other data carrier) to provide information to consumers, retailers and supply chain.


Other developments

Edible films have been developed to allow consumers to eat the package along with the product. Special packaging has been developed for shipping organs which keeps them alive during extended shipments. The organs are alive and fresh for transplanting. Several packages used by Canadian cannabis corporations use active packaging to monitor THC levels throughout the production process. This is being implemented in order to ensure consistency between products to improve supply chain management as well as offer consumers improved value of purchase.


Regulations

Active packaging is often designed to interact with the contents of the package. Thus extra care is often needed for active or smart packagings that are
food contact materials Food contact materials are materials that are intended to be in contact with food. These can be things that are quite obvious like a glass or a can for soft drinks as well as machinery in a food factory or a coffee machine. Food contact materia ...
. Food packagers take extra care with some types of active packaging. For example, when the oxygen atmosphere in a package is reduced for extending shelf life, controls for
anaerobic bacteria An anaerobic organism or anaerobe is any organism that does not require molecular oxygen for growth. It may react negatively or even die if free oxygen is present. In contrast, an aerobic organism (aerobe) is an organism that requires an oxygenat ...
need to be considered. Also when a controlled atmosphere reduces the appearance of food degradation, consumers need to retain a means of determining whether actual degradation is present.


See also

*
Automatic identification and data capture Automatic identification and data capture (AIDC) refers to the methods of automatically identifying objects, collecting data about them, and entering them directly into computer systems, without human involvement. Technologies typically considered ...
*
Electronic article surveillance Electronic article surveillance is a technological method for preventing shoplifting from retail stores, pilferage of books from libraries or removal of properties from office buildings. Special tags are fixed to merchandise; these tags are remove ...
*
Scavenger (chemistry) A scavenger in chemistry is a chemical substance added to a mixture in order to remove or de-activate impurities and unwanted reaction products, for example oxygen, to make sure that they will not cause any unfavorable reactions. Their use is wide- ...
*
Security printing Security printing is the field of the printing industry that deals with the printing of items such as banknotes, cheques, passports, tamper-evident labels, security tapes, product authentication, stock certificates, postage stamps and identity ...
* Self-heating food packaging *
Smart material Smart materials, also called intelligent or responsive materials, are designed materials that have one or more properties that can be significantly changed in a controlled fashion by external stimuli, such as stress, moisture, electric or magnetic ...


References


Further reading

* Yam, K. L., "Encyclopedia of Packaging Technology", John Wiley & Sons, 2009, * Brody, A. L., "Active Packaging for Food Applications", CRC Press, 2001 * Kerry, J, and Butler, P, "Smart Packaging Technologies for Fast Moving Consumer Goods", Wiley, * Sabotka, I.; Junge, S.; Mandel, A.; Seibt, M.: "Smart Packaging - Intelligente Verpackung mit Mehrwert", in: Henning, J. (Publ.): "Verpackungstechnik", Beuth Verlag Berlin/Germany, 2014, {{packaging Food preservation Packaging