Zircon () is a

mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ...

belonging to the group of

nesosilicate Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, silica (silicon dioxide, ) is usually cons ...

s and is a source of the metal

zirconium Zirconium is a chemical element with the symbol Zr and atomic number 40. The name ''zirconium'' is taken from the name of the mineral zircon, the most important source of zirconium. The word is related to Persian '' zargun'' (zircon; ''zar-gun'' ...

. Its chemical name is zirconium(IV) silicate, and its corresponding chemical formula is Zr SiO₄. An

empirical formula In chemistry, the empirical formula of a chemical compound is the simplest whole number ratio of atoms present in a compound. A simple example of this concept is that the empirical formula of sulfur monoxide, or SO, would simply be SO, as is t ...

showing some of the range of substitution in zircon is (Zr_1–y, REE_y)(SiO₄)_1–x(OH)_4x–y. Zircon precipitates from silicate melts and has relatively high concentrations of high field strength incompatible elements. For example,

hafnium Hafnium is a chemical element with the symbol Hf and atomic number 72. A lustrous, silvery gray, tetravalent transition metal, hafnium chemically resembles zirconium and is found in many zirconium minerals. Its existence was predicted by D ...

is almost always present in quantities ranging from 1 to 4%. The

crystal structure In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions or molecules in a crystalline material. Ordered structures occur from the intrinsic nature of the constituent particles to form symmetric patterns t ...

of zircon is

tetragonal In crystallography, the tetragonal crystal system is one of the 7 crystal systems. Tetragonal crystal lattices result from stretching a cubic lattice along one of its lattice vectors, so that the cube becomes a rectangular prism with a squar ...

crystal system In crystallography, a crystal system is a set of point groups (a group of geometric symmetries with at least one fixed point). A lattice system is a set of Bravais lattices. Space groups are classified into crystal systems according to their poi ...

. The natural color of zircon varies between colorless, yellow-golden, red, brown, blue, and green. The name derives from the Persian ''zargun'', meaning "gold-hued". This word is changed into " jargoon", a term applied to light-colored zircons. The English word "zircon" is derived from ''Zirkon'', which is the German adaptation of this word. Yellow, orange, and red zircon is also known as " hyacinth", from the flower '' hyacinthus'', whose name is of

Ancient Greek Ancient Greek includes the forms of the Greek language used in ancient Greece and the ancient world from around 1500 BC to 300 BC. It is often roughly divided into the following periods: Mycenaean Greek (), Dark Ages (), the Archaic p ...

origin.

Properties

Zircon is common in the crust of Earth. It occurs as a common

accessory mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...

igneous rock Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rock is formed through the cooling and solidification of magma or l ...

s (as primary crystallization products), in

metamorphic rock Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock ( protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, cau ...

s and as detrital grains in

sedimentary rock Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particle ...

s. Large zircon crystals are rare. Their average size in

granite Granite () is a coarse-grained ( phaneritic) intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly cools and solidifies und ...

rocks is about , but they can also grow to sizes of several cm, especially in

mafic A mafic mineral or rock is a silicate mineral or igneous rock rich in magnesium and iron. Most mafic minerals are dark in color, and common rock-forming mafic minerals include olivine, pyroxene, amphibole, and biotite. Common mafic rocks includ ...

pegmatite A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic co ...

s and

carbonatite Carbonatite () is a type of intrusive or extrusive igneous rock defined by mineralogic composition consisting of greater than 50% carbonate minerals. Carbonatites may be confused with marble and may require geochemical verification. Carbonatit ...

s. Zircon is fairly hard (with a Mohs hardness of 7.5) and chemically stable, and so is highly resistant to weathering. It also is resistant to heat, so that detrital zircon grains are sometimes preserved in igneous rocks formed from melted sediments. Its resistance to weathering, together with its relatively high specific gravity (4.68), make it an important component of the heavy mineral fraction of sandstones. Because of their

uranium Uranium is a chemical element with the symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium is weakly ...

and

thorium Thorium is a weakly radioactive metallic chemical element with the symbol Th and atomic number 90. Thorium is silvery and tarnishes black when it is exposed to air, forming thorium dioxide; it is moderately soft and malleable and has a high ...

content, some zircons undergo metamictization. Connected to internal radiation damage, these processes partially disrupt the crystal structure and partly explain the highly variable properties of zircon. As zircon becomes more and more modified by internal radiation damage, the density decreases, the crystal structure is compromised, and the color changes. Zircon occurs in many colors, including reddish brown, yellow, green, blue, gray, and colorless. The color of zircons can sometimes be changed by heat treatment. Common brown zircons can be transformed into colorless and blue zircons by heating to . In geological settings, the development of pink, red, and purple zircon occurs after hundreds of millions of years, if the crystal has sufficient trace elements to produce

color centers An F center or Farbe center (from the original German ''Farbzentrum'', where ''Farbe'' means ''color'' and ''zentrum'' means center) is a type of crystallographic defect in which an anionic vacancy in a crystal lattice is occupied by one or more un ...

. Color in this red or pink series is annealed in geological conditions above temperatures of around . Structurally, zircon consists of parallel chains of alternating silica tetrahedra (silicon ions in fourfold coordination with oxygen ions) and zirconium ions, with the large zirconium ions in eightfold coordination with oxygen ions.

Applications

Zircon is mainly consumed as an

opacifier An opacifier is a substance added to a material in order to make the ensuing system opaque. An example of a chemical opacifier is titanium dioxide (TiO2), which is used as an opacifier in paints, in paper, and in plastics. It has very high refract ...

, and has been known to be used in the decorative ceramics industry. It is also the principal precursor not only to metallic

, although this application is small, but also to all compounds of zirconium including

zirconium dioxide Zirconium dioxide (), sometimes known as zirconia (not to be confused with zircon), is a white crystalline oxide of zirconium. Its most naturally occurring form, with a monoclinic crystalline structure, is the mineral baddeleyite. A dopant s ...

(), an important

refractory In materials science, a refractory material or refractory is a material that is resistant to decomposition by heat, pressure, or chemical attack, and retains strength and form at high temperatures. Refractories are polycrystalline, polyphase ...

oxide with a melting point of . Other applications include use in refractories and foundry casting and a growing array of specialty applications as

zirconia Zirconium dioxide (), sometimes known as zirconia (not to be confused with zircon), is a white crystalline oxide of zirconium. Its most naturally occurring form, with a monoclinic crystalline structure, is the mineral baddeleyite. A dopant stab ...

and zirconium chemicals, including in nuclear fuel rods, catalytic fuel converters and in water and air purification systems. Zircon is one of the key minerals used by geologists for

geochronology Geochronology is the science of determining the age of rocks, fossils, and sediments using signatures inherent in the rocks themselves. Absolute geochronology can be accomplished through radioactive isotopes, whereas relative geochronology is p ...

. Zircon is a part of the ZTR index to classify highly- weathered

sediment Sediment is a naturally occurring material that is broken down by processes of weathering and erosion, and is subsequently transported by the action of wind, water, or ice or by the force of gravity acting on the particles. For example, sa ...

As gemstone

Transparent zircon is a well-known form of semi-precious gemstone, favored for its high

specific gravity Relative density, or specific gravity, is the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for liquids is nearly always measured with respect to water (molecule), wa ...

(between 4.2 and 4.86) and adamantine luster. Because of its high

refractive index In optics, the refractive index (or refraction index) of an optical medium is a dimensionless number that gives the indication of the light bending ability of that medium. The refractive index determines how much the path of light is bent, o ...

(1.92) it has sometimes been used as a substitute for

diamond Diamond is a solid form of the element carbon with its atoms arranged in a crystal structure called diamond cubic. Another solid form of carbon known as graphite is the chemically stable form of carbon at room temperature and pressure, ...

, though it does not display quite the same play of color as a diamond. Zircon is the heaviest of any gem, readily sinking in even highly viscous liquids. Its

Mohs hardness The Mohs scale of mineral hardness () is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material. The scale was introduced in 1812 by the ...

is between that of quartz and topaz, at 7.5 on the 10 point scale, though below that of the similar manmade stone

cubic zirconia Cubic zirconia (CZ) is the cubic crystalline form of zirconium dioxide (ZrO2). The synthesized material is hard and usually colorless, but may be made in a variety of different colors. It should not be confused with zircon, which is a zircon ...

(9). Zircons may sometimes lose their inherent color after long exposure to bright sunlight, which is unusual in a gemstone. It is immune to acid attack except by sulfuric acid and then only when ground into a fine powder. Most gem-grade zircons show a high degree of

birefringence Birefringence is the optical property of a material having a refractive index that depends on the polarization and propagation direction of light. These optically anisotropic materials are said to be birefringent (or birefractive). The birefrin ...

which, on stones cut with a table and pavilion cuts (i.e., nearly all cut stones), can be seen as the apparent doubling-up of the latter when viewed through the former, and this characteristic can be used to distinguish them from diamonds and cubic zirconias (CZ) as well as soda-lime glass, none of which show this characteristic. However, some zircons from Sri Lanka display only weak or no birefringence at all, and some other Sri Lanka stones may show clear birefringence in one place and little or none in another part of the same cut stone. Other gemstones also display birefringence, so while the presence of this characteristic may help distinguish a given zircon from a diamond or a CZ, it will not help distinguish it from, for example, a

topaz Topaz is a silicate mineral of aluminium and fluorine with the chemical formula Al Si O( F, OH). It is used as a gemstone in jewelry and other adornments. Common topaz in its natural state is colorless, though trace element impurities can ma ...

gemstone. The high specific gravity of zircon, however, can usually separate it from any other gem and is simple to test. Also, birefringence depends on the cut of the stone in relation to its optical axis. If a zircon is cut with this axis perpendicular to its table, birefringence may be reduced to undetectable levels unless viewed with a jeweler's

loupe A loupe ( ) is a simple, small magnification device used to see small details more closely. They generally have higher magnification than a magnifying glass, and are designed to be held or worn close to the eye. A loupe does not have an attached h ...

or other magnifying optics. The highest grade zircons are cut to minimize birefringence. The value of a zircon gem depends largely on its color, clarity, and size. Prior to World War II, blue zircons (the most valuable color) were available from many gemstone suppliers in sizes between 15 and 25 carats; since then, stones even as large as 10 carats have become very scarce, especially in the most desirable color varieties. Synthetic zircons have been created in laboratories but they are only of scientific interest and are never encountered in the jewellery trade. Zircons are sometimes imitated by

spinel Spinel () is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula in the cubic crystal system. Its name comes from the Latin word , which means ''spine'' in reference to its pointed crystals. Properties ...

and synthetic

sapphire Sapphire is a precious gemstone, a variety of the mineral corundum, consisting of aluminium oxide () with trace amounts of elements such as iron, titanium, chromium, vanadium, or magnesium. The name sapphire is derived via the Latin "sap ...

, but are not difficult to distinguish from them with simple tools.

Occurrence

Zircon is a common accessory to trace mineral constituent of all kinds of igneous rocks, but particularly

and

felsic In geology, felsic is a modifier describing igneous rocks that are relatively rich in elements that form feldspar and quartz.Marshak, Stephen, 2009, ''Essentials of Geology,'' W. W. Norton & Company, 3rd ed. It is contrasted with mafic rocks, wh ...

igneous rocks. Due to its hardness, durability and chemical inertness, zircon persists in sedimentary deposits and is a common constituent of most sands. Zircon can occasionally be found as a trace mineral in

ultrapotassic igneous rocks Ultrapotassic igneous rocks are a class of rare, volumetrically minor and generally ultramafic or mafic silica-depleted igneous rocks. Ultrapotassic rocks are defined by molar K2 O/ Na2O >3 in much of the scientific literature. In other papers wr ...

such as

kimberlite Kimberlite is an igneous rock and a rare variant of peridotite. It is most commonly known to be the main host matrix for diamonds. It is named after the town of Kimberley in South Africa, where the discovery of an diamond called the Star of S ...

s, carbonatites, and lamprophyre, owing to the unusual magma genesis of these rocks. Zircon forms economic concentrations within

heavy mineral sands ore deposits Heavy mineral sands are a class of ore deposit which is an important source of zirconium, titanium, thorium, tungsten, rare-earth elements, the industrial minerals diamond, sapphire, garnet, and occasionally precious metals or gemstones. Heavy ...

, within certain

s, and within some rare alkaline volcanic rocks, for example the Toongi Trachyte, Dubbo, New South Wales Australia in association with the zirconium-hafnium minerals eudialyte and armstrongite. Australia leads the world in zircon mining, producing 37% of the world total and accounting for 40% of world EDR (

economic demonstrated resources Geoscience Australia is an agency of the Australian Government. It carries out geoscientific research. The agency is the government's technical adviser on all aspects of geoscience, and custodian of the geographic and geological data and knowle ...

) for the mineral. South Africa is Africa's main producer, with 30% of world production, second after Australia.

Radiometric dating

Zircon has played an important role during the evolution of

radiometric dating Radiometric dating, radioactive dating or radioisotope dating is a technique which is used to date materials such as rocks or carbon, in which trace radioactive impurities were selectively incorporated when they were formed. The method compares t ...

. Zircons contain trace amounts of

and

(from 10 ppm up to 1 wt%) and can be dated using several modern analytical techniques. Because zircons can survive geologic processes like

erosion Erosion is the action of surface processes (such as water flow or wind) that removes soil, rock, or dissolved material from one location on the Earth's crust, and then transports it to another location where it is deposited. Erosion is di ...

, transport, even high-grade

metamorphism Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of ...

, they contain a rich and varied record of geological processes. Currently, zircons are typically dated by uranium-lead (U-Pb), fission-track,

cathodoluminescence Cathodoluminescence is an optical and electromagnetic phenomenon in which electrons impacting on a luminescent material such as a phosphor, cause the emission of photons which may have wavelengths in the visible spectrum. A familiar example is th ...

, and U+Th/He techniques. For instance, imaging the cathodoluminescence emission from fast electrons can be used as a prescreening tool for high-resolution secondary-ion-mass spectrometry (SIMS) to image the zonation pattern and identify regions of interest for isotope analysis. This is done using an integrated cathodoluminescence and scanning electron microscope. Zircons in sedimentary rock can identify the sediment source. Zircons from

Jack Hills The Jack Hills are a range of hills in Mid West Western Australia. They are best known as the source of the oldest material of terrestrial origin found to date: Hadean zircons that formed around 4.39 billion years ago. These zircons have enable ...

in the Narryer Gneiss Terrane,

Yilgarn Craton The Yilgarn Craton is a large craton that constitutes the bulk of the Western Australian land mass. It is bounded by a mixture of sedimentary basins and Proterozoic fold and thrust belts. Zircon grains in the Jack Hills, Narryer Terrane have b ...

Western Australia Western Australia (commonly abbreviated as WA) is a state of Australia occupying the western percent of the land area of Australia excluding external territories. It is bounded by the Indian Ocean to the north and west, the Southern Ocean to ...

, have yielded U-Pb ages up to 4.404 billion years, interpreted to be the age of crystallization, making them the oldest minerals so far dated on Earth. In addition, the

oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as we ...

isotopic compositions of some of these zircons have been interpreted to indicate that more than 4.4 billion years ago there was already water on the surface of the Earth. This interpretation is supported by additional trace element data, but is also the subject of debate. In 2015, "remains of

biotic life Biotic material or biological derived material is any material that originates from living organisms. Most such materials contain carbon and are capable of decay. The earliest life on Earth arose at least 3.5 billion years ago.Schopf, JW, Kudrya ...

" were found in 4.1-billion-year-old rocks in the Jack Hills of Western Australia. According to one of the researchers, "If

life Life is a quality that distinguishes matter that has biological processes, such as Cell signaling, signaling and self-sustaining processes, from that which does not, and is defined by the capacity for Cell growth, growth, reaction to Stimu ...

arose relatively quickly on

Earth Earth is the third planet from the Sun and the only astronomical object known to harbor life. While large volumes of water can be found throughout the Solar System, only Earth sustains liquid surface water. About 71% of Earth's surf ...

... then it could be common in the

universe The universe is all of space and time and their contents, including planets, stars, galaxies, and all other forms of matter and energy. The Big Bang theory is the prevailing cosmological description of the development of the universe. A ...

Similar minerals

Hafnon (),

xenotime Xenotime is a rare-earth phosphate mineral, the major component of which is yttrium orthophosphate ( Y P O4). It forms a solid solution series with chernovite-(Y) ( Y As O4) and therefore may contain trace impurities of arsenic, as well as si ...

(), béhierite, schiavinatoite (),

thorite Thorite, (Th,U)SiO4, is a rare nesosilicate of thorium that crystallizes in the tetragonal system and is isomorphous with zircon and hafnon. It is the most common mineral of thorium and is nearly always strongly radioactive. It was named in 18 ...

(), and coffinite () all share the same crystal structure (^IVX ^IVY O₄, ^IIIX ^VY O₄ in the case of xenotime) as zircon.

Gallery

Image:Zircon.GIF, Crystal structure of zircon Image:Zirconcrystal-model.png, Unit cell of zircon Image:Zirkon 372.jpg, Scanning electron microscope image of zircon Image:Zircon-tuc1001a.jpg, Unusual olive-green zircon Image:Zircon-j08-23a.jpg, Cluster of three compound crystals of zircon

References

External links

Geochemistry of old zircons

GIA Gem Encyclopedia - Zircon
Online articles and information on zircon history, lore, and research
Zircon Industry Association
{{Authority control Zirconium minerals Nesosilicates Refractory materials Gemstones Tetragonal minerals Minerals in space group 141 Luminescent minerals