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Zinc mining is the process by which mineral forms of the metal
zinc Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodi ...
are extracted from the earth through
mining Mining is the extraction of valuable minerals or other geological materials from the Earth, usually from an ore body, lode, vein, seam, reef, or placer deposit. The exploitation of these deposits for raw material is based on the economic ...
. A zinc mine is a mine that produces
zinc Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodi ...
minerals in ore as its primary product. Common co-products in zinc ores include minerals of
lead Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cu ...
and
silver Silver is a chemical element with the symbol Ag (from the Latin ', derived from the Proto-Indo-European ''h₂erǵ'': "shiny" or "white") and atomic number 47. A soft, white, lustrous transition metal, it exhibits the highest electrical ...
. Other mines may produce zinc minerals as a by-product of the production of ores containing more valuable minerals or metals, such as
gold Gold is a chemical element with the symbol Au (from la, aurum) and atomic number 79. This makes it one of the higher atomic number elements that occur naturally. It is a bright, slightly orange-yellow, dense, soft, malleable, and ductile me ...
, silver or
copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkis ...
. Mined ore is processed, usually on site, to produce one or more metal-rich concentrates, then transported to a zinc smelter for production of zinc metal. Global zinc mine production in 2020 was estimated to be 12 million tonnes. The largest producers were China (35%), Australia (12%),
Peru , image_flag = Flag of Peru.svg , image_coat = Escudo nacional del Perú.svg , other_symbol = Great Seal of the State , other_symbol_type = National seal , national_motto = "Firm and Happy f ...
(10%),
India India, officially the Republic of India (Hindi: ), is a country in South Asia. It is the seventh-largest country by area, the second-most populous country, and the most populous democracy in the world. Bounded by the Indian Ocean on the so ...
(6.0%), United States (5.6%) and Mexico (5.0%), with Australia having the largest reserves. The world's largest zinc mine is the Red Dog open-pit zinc-lead-silver mine in
Alaska Alaska ( ; russian: Аляска, Alyaska; ale, Alax̂sxax̂; ; ems, Alas'kaaq; Yup'ik: ''Alaskaq''; tli, Anáaski) is a state located in the Western United States on the northwest extremity of North America. A semi-exclave of the U.S. ...
, with 4.2% of world production. Major zinc mine operators include
Vedanta Resources Vedanta Resources Limited is an Indian diversified mining company headquartered in London, United Kingdom. It is the largest mining and non-ferrous metals company in India and has mining operations in Australia and Zambia and oil and gas oper ...
, Glencore,
BHP BHP Group Limited (formerly known as BHP Billiton) is an Australian multinational mining, metals, natural gas petroleum public company that is headquartered in Melbourne, Victoria, Australia. The Broken Hill Proprietary Company was founded ...
,
Teck Resources Teck Resources Limited, known as Teck Cominco until late 2008, is a diversified natural resources company headquartered in Vancouver, British Columbia, that is engaged in mining and mineral development, including coal for the steelmaking indust ...
, Sumitomo, Nexa Resources, Boliden AB, and
China Minmetals China Minmetals Corporation is a Chinese metals and mineral trading company headquartered in Beijing. It is a state-owned corporation under direct supervision of the State-owned Assets Supervision and Administration Commission (SASAC). China Min ...
.


History

Zinc deposits have been exploited for thousands of years, with the oldest zinc mine, located in
Rajasthan Rajasthan (; lit. 'Land of Kings') is a state in northern India. It covers or 10.4 per cent of India's total geographical area. It is the largest Indian state by area and the seventh largest by population. It is on India's northwestern s ...
, India established nearly 2000 years BP. Pure zinc production occurred in the 9th century AD while, earlier in antiquity zinc was primarily utilized in the alloying of copper to produce
brass Brass is an alloy of copper (Cu) and zinc (Zn), in proportions which can be varied to achieve different mechanical, electrical, and chemical properties. It is a substitutional alloy: atoms of the two constituents may replace each other wit ...
. This is because the isolation of zinc metal from its ore poses a unique challenge. At the temperature zinc is released from its ore it also vaporizes into a gas, and if the furnace is not airtight, the gaseous zinc reacts with the air to form
zinc oxide Zinc oxide is an inorganic compound with the formula . It is a white powder that is insoluble in water. ZnO is used as an additive in numerous materials and products including cosmetics, food supplements, rubbers, plastics, ceramics, glass, cement ...
. Metallic zinc smelting occurred in 9th century BC in India, followed soon by China 300 years later, and In Europe by 1738 AD. The methods of smelting in China and India were most likely independently developed, while the method of smelting developed in Europe was likely derived by the Indian method. The primary modern use for zinc is for coating iron and steel in order to prevent its corrosion, with nearly half of worldwide zinc production going towards that purpose. Approximately 20% of the world's zinc is used in the production of brass, where zinc is alloyed with copper in between ratios of 20-40% zinc. Of the remaining 30% of the global production of zinc, half is used in the production of zinc alloys, where zinc is combined with varying amounts of
aluminium Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...
, and
magnesium Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ta ...
. The remaining zinc is used in various other industries from agriculture as a fertilizer and human consumption as a supplement.


Methods of extraction

Zinc is mined both at the surface and at depth. Surface mining of zinc, typically used for oxide ores, while underground mining yields
zinc sulfide Zinc sulfide (or zinc sulphide) is an inorganic compound with the chemical formula of ZnS. This is the main form of zinc found in nature, where it mainly occurs as the mineral sphalerite. Although this mineral is usually black because of various ...
ores. Some of the common methods of zinc mining are open pit mining, open stope, and cut and fill mining:
Open-pit mining Open-pit mining, also known as open-cast or open-cut mining and in larger contexts mega-mining, is a surface mining technique of extracting rock or minerals from the earth from an open-air pit, sometimes known as a borrow. This form of mini ...
: Surface mining involves the removal of waste rock from above an ore deposit before it can be extracted. Once the waste overburden is removed, ore and waste are then mined in parallel, primarily using track-mounted excavators and rubber-tired trucks. In smaller scale operations, front loaders may be used. Open Stope mining: This is a method of underground mining where ore bodies are completely removed leaving sizeable caverns (stopes) within the mine. Open stope mining leaves these caverns with no additional bracing or external support, instead the cavern walls are supported by random pillars of ore which have not been removed. Cut and Fill stoping: A method of underground mining which removes ore from below the deposit. The stope is then filled with waste rock to replace the mined out ore to support the stope walls, and to provide an elevated floor for the miners and equipment to further extract ore from the deposit.


Production

Global mine production of zinc in 2019 was 12.9 million tonnes, a 0.9% increase from 2018, with the increase primarily attributed to increased output from zinc mines located in Australia and
South Africa South Africa, officially the Republic of South Africa (RSA), is the Southern Africa, southernmost country in Africa. It is bounded to the south by of coastline that stretch along the Atlantic Ocean, South Atlantic and Indian Oceans; to the ...
. In 2020 production of zinc is expected to rise 3.7% to 13.99 million tonnes, with the increase due to increased production of zinc by China and India. In 2019 global demand for refined zinc exceeded supply and resulted in a deficit of 0.178 million tonnes, while in 2020 there is an expected surplus of 0.192 million tonnes. Major zinc producing countries ranked by their output for 2019 are as follows:


Environmental impact

Research conducted in the health of the benthic macroinvertebrate populations in the mining areas of southeastern Missouri, a US state, have yielded a wealth of information on the effect of zinc mining and its effect on its local environment. Fish and Crayfish populations in localities near mining sites have been observed to be much lower than other populations found in reference sites; with the crayfish possessing metal concentrations within their tissues at a much greater concentration than their reference counterparts. Other investigation into the effect of the health of mussel populations that reside near lead-zinc mining areas have found that the populations residing near mining areas possessed reduced biomass, and were less specious than those found in their reference sites. Plant tissue have been reported to possess concentrations of metals 10-60% higher than reference. Macroinvertebrate assessments of localities immediately downstream of mining activity have observed a reduction in biotic condition 10-58% and with the ecosystem having an impaired ability to support its populations when compared to other reference sites. Benthic macro-invertebrates such as crayfish and mussels represent a pathway for
biomagnification Biomagnification, also known as bioamplification or biological magnification, is any concentration of a toxin, such as pesticides, in the tissues of tolerant organisms at successively higher levels in a food chain. This increase can occur as a ...
, where the concentration of noxious materials within organisms at higher trophic levels accumulates as a result of consuming contaminated prey. In addition, benthic macroinvertebrate populations are frequently used as indicators of overall ecosystem health. Assessment of soil samples from agricultural areas near a lead-zinc mining region in Guangxi, China have observed a "Serious pollution level" of zinc in the soils of the paddy fields relatively close to the mining area and a "Moderate pollution level" in the aerated fields relatively further away. The research also indicated that as a result of their Nemerow synthetic index assessment, the region under study is not fit for agricultural purposes. Other investigation into the effect of zinc mining on agricultural soils in the
Heilongjiang Heilongjiang () formerly romanized as Heilungkiang, is a province in northeast China. The standard one-character abbreviation for the province is (). It was formerly romanized as "Heilungkiang". It is the northernmost and easternmost province ...
Province of China has found that the soils were "moderately contaminated" and a significant reduction in the population and diversity of the bacterial assemblages within the soils and reduced activity of soil enzymes. The activity of the bacteria and enzymes aid plant matter in the uptake of nutrients, decompose decaying matter, and other ecosystem interactions. Their reduction and impaired effectiveness result in poorer agricultural productivity.


Zinc mines

The world's ten largest zinc producing mines (by tonnes of zinc) are:


See also

* Zinc mining in the United States


References

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