Walter Heitler
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Walter Heinrich Heitler (; 2 January 1904 – 15 November 1981) was a German physicist who made contributions to quantum electrodynamics and
quantum field theory In theoretical physics, quantum field theory (QFT) is a theoretical framework that combines classical field theory, special relativity, and quantum mechanics. QFT is used in particle physics to construct physical models of subatomic particles and ...
. He brought chemistry under quantum mechanics through his theory of valence bonding.


Education

In 1922, Heitler began his study of physics at the Karlsruhe Technische Hochschule, in 1923 at the Humboldt University of Berlin, and in 1924 at the
Ludwig Maximilian University of Munich The Ludwig Maximilian University of Munich (simply University of Munich or LMU; german: Ludwig-Maximilians-Universität München) is a public research university in Munich, Germany. It is Germany's sixth-oldest university in continuous operatio ...
(LMU), where he studied under both
Arnold Sommerfeld Arnold Johannes Wilhelm Sommerfeld, (; 5 December 1868 – 26 April 1951) was a German theoretical physicist who pioneered developments in atomic and quantum physics, and also educated and mentored many students for the new era of theoretica ...
and Karl Herzfeld. The latter was his thesis advisor when he obtained his doctorate in 1926; Herzfeld taught courses in theoretical physics and one in physical chemistry, and in Sommerfeld's absence often took over his classes. From 1926 to 1927, he was a
Rockefeller Foundation The Rockefeller Foundation is an American private foundation and philanthropic medical research and arts funding organization based at 420 Fifth Avenue, New York City. The second-oldest major philanthropic institution in America, after the Carneg ...
Fellow for postgraduate research with Niels Bohr at the Institute for Theoretical Physics at the University of Copenhagen and with Erwin Schrödinger at the University of Zurich. He then became an assistant to
Max Born Max Born (; 11 December 1882 – 5 January 1970) was a German physicist and mathematician who was instrumental in the development of quantum mechanics. He also made contributions to solid-state physics and optics and supervised the work of a n ...
at the Institute for Theoretical Physics at the University of Göttingen. Heitler completed his
Habilitation Habilitation is the highest university degree, or the procedure by which it is achieved, in many European countries. The candidate fulfills a university's set criteria of excellence in research, teaching and further education, usually including a ...
, under Born, in 1929, and then remained as a
Privatdozent ''Privatdozent'' (for men) or ''Privatdozentin'' (for women), abbreviated PD, P.D. or Priv.-Doz., is an academic title conferred at some European universities, especially in German-speaking countries, to someone who holds certain formal qualific ...
until 1933. In that year, he was let go by the university because he was Jewish.Uta Schäfer-Richter, Jörg Klein (1992), p. 93
/ref> At the time Heitler received his doctorate, three Institutes for Theoretical Physics formed a consortium which worked on the key problems of the day, such as atomic and molecular structure, and exchanged both scientific information and personnel in their scientific quests. These institutes were located at the LMU, under
Arnold Sommerfeld Arnold Johannes Wilhelm Sommerfeld, (; 5 December 1868 – 26 April 1951) was a German theoretical physicist who pioneered developments in atomic and quantum physics, and also educated and mentored many students for the new era of theoretica ...
, the University of Göttingen, under
Max Born Max Born (; 11 December 1882 – 5 January 1970) was a German physicist and mathematician who was instrumental in the development of quantum mechanics. He also made contributions to solid-state physics and optics and supervised the work of a n ...
, and the University of Copenhagen, under Niels Bohr. Furthermore, Werner Heisenberg and Born had just recently published their trilogy of papers which launched the matrix mechanics formulation of quantum mechanics. Also, in early 1926, Erwin Schrödinger, at the University of Zurich, began to publish his quintet of papers which launched the wave mechanics formulation of quantum mechanics and showed that the wave mechanics and matrix mechanics formulations were equivalent. These papers immediately put the personnel at the leading theoretical physics institutes onto applying these new tools to understanding atomic and molecular structure. It was in this environment that Heitler went on his Rockefeller Foundations Fellowship, leaving LMU and within a period of two years going to do research and study with the leading figures of the day in theoretical physics, Bohr's personnel in Copenhagen, Schrödinger in Zurich, and Born in Göttingen. In Zurich, with Fritz London, Heitler applied the new quantum mechanics to deal with the saturable, nondynamic forces of attraction and repulsion, i.e., exchange forces, of the hydrogen molecule. Their valence bond treatment of this problem, was a landmark in that it brought chemistry under quantum mechanics. Furthermore, their work greatly influenced chemistry through
Linus Pauling Linus Carl Pauling (; February 28, 1901August 19, 1994) was an American chemist, biochemist, chemical engineer, peace activist, author, and educator. He published more than 1,200 papers and books, of which about 850 dealt with scientific top ...
, who had just received his doctorate and on a
Guggenheim Fellowship Guggenheim Fellowships are grants that have been awarded annually since by the John Simon Guggenheim Memorial Foundation to those "who have demonstrated exceptional capacity for productive scholarship or exceptional creative ability in the ar ...
visited Heitler and London in Zurich. Pauling spent much of his career studying the nature of the chemical bond. The application of quantum mechanics to chemistry would be a prominent theme in Heitler's career. While Heitler was at Göttingen, Adolf Hitler came to power in 1933. With the rising prominence of anti-Semitism under Hitler, Born took it upon himself to take the younger Jewish generation under his wing. In doing so, Born arranged for Heitler to get a position that year as a Research Fellow at the University of Bristol, with Nevill Francis Mott.Mott
– Bristol Physics in the 1930s


Career

At Bristol, Heitler was a Research Fellow of the Academic Assistance Council, in the H. H. Wills Physics Laboratory. At Bristol, among other things, he worked on
quantum field theory In theoretical physics, quantum field theory (QFT) is a theoretical framework that combines classical field theory, special relativity, and quantum mechanics. QFT is used in particle physics to construct physical models of subatomic particles and ...
and quantum electrodynamics on his own, as well as in collaboration with other scientific refugees from Hitler, such as Hans Bethe and Herbert Fröhlich, who also left Germany in 1933. With Bethe, he published a paper on pair production of gamma rays in the Coulomb field of an atomic nucleus, in which they developed the Bethe-Heitler formula for Bremsstrahlung. In 1936, Heitler published his major work on quantum electrodynamics, ''The Quantum Theory of Radiation'', which marked the direction for future developments in quantum theory. The book appeared in many editions and printings and has been translated into Russian. Heitler also contributed to the understanding of cosmic rays, as well as predicted the existence of the electrically neutral pi meson. While developing the theory of cosmic ray showers in 1937, he became aware of the latest experimental work in the field: the observation of cosmic ray interactions in Nuclear emulsion by Austrian physicists Marietta Blau and Hertha Wambacher. He mentioned this to Bristol colleague
Cecil Powell Cecil Frank Powell, FRS (5 December 1903 – 9 August 1969) was a British physicist, and Nobel Prize in Physics laureate for heading the team that developed the photographic method of studying nuclear processes and for the resulting discovery of ...
, saying that the method appeared so straightforward that 'even a theoretician might be able also to do it'. This intrigued Powell, and he convinced theoretician Heitler to travel to Switzerland with a batch of llford emulsions and expose them on the Jungfraujoch at 3500m. In a letter to 'Nature' in August 1939, Heitler and Powell were able to confirm the observations of Blau and Wambacher. Thus Heitler had some influence in setting
Cecil Powell Cecil Frank Powell, FRS (5 December 1903 – 9 August 1969) was a British physicist, and Nobel Prize in Physics laureate for heading the team that developed the photographic method of studying nuclear processes and for the resulting discovery of ...
on the first step of his path to the 1950 Nobel Prize in Physics, "for his development of the photographic method of studying nuclear processes and his discoveries regarding mesons made with this method". After the fall of France in 1940, Heitler was briefly interned on the Isle of Man for several months.Moore, 1992, p. 368. Heitler remained at Bristol eight years, until 1941, when he became a professor at the Dublin Institute for Advanced Studies, which was arranged there by Erwin Schrödinger, Director of the School for Theoretical Physics.Heitler
– Irish University Science
He has been described as the "unsung hero of DIAS in the 1940s". At Dublin, Heitler's work with H. W. Peng on radiation damping theory and the meson scattering process resulted in the Heitler-Peng integral equation. During his stay in Dublin he lived at 21 Seapark Road, Clontarf, down the road from Erwin Schrödinger. During the 1942–1943 academic year, Heitler gave a course on elementary wave mechanics, during which W. S. E. Hickson took notes and prepared a finished copy. These notes were the basis for Heitler's book ''Elementary Wave Mechanics: Introductory Course of Lectures'', first published in 1943. A new edition was published as ''Elementary Wave Mechanics'' in 1945. This version was revised and republished many times, as well as being translated into French and Italian and published in 1949 and in German in 1961. A further revised version appeared as ''Elementary Wave Mechanics With Applications to Quantum Chemistry'' in 1956, as well as in German in 1961. Schrödinger resigned as Director of the School for Theoretical Physics in 1946, but stayed at Dublin, whereupon Heitler became Director. Heitler stayed at Dublin until 1949, when he accepted a position as Ordinarius Professor for Theoretical Physics and Director of the Institute for Theoretical Physics at the University of Zurich, where he remained until 1974, when he retired. In 1958, Heitler held the Lorentz Chair for Theoretical Physics at the University of Leiden. While in Zurich, after some years, he began writing on the philosophical relationship of science to religion. His books were published in German, English, and French.


Quote

*''Physics eats chemistry with a spoon.''


Honours

* 1943 – Fellow of the
Royal Irish Academy The Royal Irish Academy (RIA; ga, Acadamh Ríoga na hÉireann), based in Dublin, is an academic body that promotes study in the sciences, humanities and social sciences. It is Ireland's premier List of Irish learned societies, learned socie ...
* 1948 – Fellow of the Royal Society of London * 1954 – Honorary Doctor of Science (DSc.) of the National University of Ireland * 1968 – Deutsche Physikalische Gesellschaft Max-Planck Medal * 1969 – Marcel Benoist Prize * 1979 – Gold Medal of the Humboldt Gesellschaft


Books


Physics

*Walter Heitler ''Elementary Wave Mechanics: Introductory Course of Lectures'' Notes taken and prepared by W.S.E. Hickson (Oxford, 1943) *Walter Heitler ''Elementary Wave Mechanics'' (Oxford, 1945, 1946, 1948, 1950) *Walter Heitler ''The Quantum Theory of Radiation'' (Clarendon Press, 1936, 1944, 1947, 1949, 1950, 1953, 1954, 1957, 1960, 1966, 1970) **Reprinted by Dover Publications in 1984. *Walter Heitler ''14 Offprints: 1928-1947'' (1947) *Walter Heitler ''Eléments de Mécanique Ondulatoire'' (Presses Universitaires de France, PUF, Paris, 1949, 1964) *Walter Heitler ''Elementi di Meccanica Ondulatoria'' con presentazione di R.Ciusa (Zuffi, Bologna,1949) *Walter Heitler ''Elementary Wave Mechanics With Applications to Quantum Chemistry'' (Oxford University, 1956, 1958, 1961, 1969) *Walter Heitler ''The Quantum Theory of Radiation ussian Translation' (Moscow, 1956) *Walter Heitler ''Lectures on Problems Connected with the Finite Size of Elementary Particles (Tata Institute of Fundamental Research. Lectures on mathematics and physics. Physics)'' (Tata Institute of Fundamental Research, 1961) *Walter Heitler and Klaus Müller ''Elementare Wellenmechanik'' (Vieweg, 1961) *Walter Heitler ''Elementare Wellenmechanik. Mit Anwendung auf die Quantenchemie'' (Vieweg Friedr. & Sohn Ver, 1961) * Walter Heitler ''Wahrheit und Richtigkeit in den exakten Wissenschaften. Abhandlungen der mathematisch- naturwissenschaftlichen Klasse. Jahrgang 1972. Nr. 3.'' (Akademie der Wissenschaften und der Literatur. Mainz, Verlag der Akademie der Wissenschaften und der Literatur, Kommission bei Franz Steiner Verlag, Wiesbaden, 1972) *Walter Heitler ''Über die Komplementarität von lebloser und lebender Materie. Abhandlungen der Mathematisch-Naturwissenschaftlichen Klasse, Jahrg. 1976, Nr. 1'' (Mainz, Verlag der Akademie der Wissenschaften und der Literatur, Kommission bei F. Steiner, 1976)


Science and religion

*Walter Heitler ''Der Mensch und die naturwissenschaftliche Erkenntnis'' (Vieweg Friedr. & Sohn Ver, 1961, 1962, 1964, 1966, 1984) *Walter Heitler ''Man and Science'' (Oliver and Boyd, 1963) *Walter Heitler ''Die Frage nach dem Sinn der Evolution'' (Herder, 1969) *Walter Heitler ''Naturphilosophische Streifzüge'' (Vieweg Friedr. & Sohn Ver, 1970, 1984) *Walter Heitler ''Naturwissenschaft ist Geisteswissenschaft'' (Zürich : Verl. die Waage, 1972) *K. Rahner, H.R. Schlette, B. Welte, R. Affemann, D. Savramis, W. Heitler ''Gott in dieser Zeit'' (C. H. Beck, 1972) *Walter Heitler ''Die Natur und das Göttliche'' (Klett & Balmer; 1. Aufl edition, 1974) *Walter Heitler ''Gottesbeweise? Und weitere Vorträge'' (1977) *Walter Heitler ''La Nature et Le Divin'' (A la Baconniere, 1977) *Walter Heitler ''Schöpfung, die Öffnung der Naturwissenschaft zum Göttlichen'' (Verlag der Arche, 1979) *Walter Heitler ''Schöpfung als Gottesbeweis. Die Öffnung der Naturwissenschaft zum Göttlichen'' (1979)


References


Bibliography


Key Participants: Walter Heitler
– ''Linus Pauling and the Nature of the Chemical Bond: A Documentary History''

by
John Heilbron John Lewis Heilbron (born 17 March 1934, San Francisco) is an American historian of science best known for his work in the history of physics and the history of astronomy. He is Professor of History and Vice-Chancellor Emeritus (Vice-Chancellor 19 ...
(18 March 1963. Archives for the History of Quantum Physics) * L. O'Raifeartaigh and G. Rasche: Walter Heitler 1904–81, in ''Creators of Mathematics, The Irish Connection'', ed. Ken Houston, University College Dublin Press, 2000. *Nancy Thorndike Greenspan, " The End of the Certain World: The Life and Science of Max Born" (Basic Books, 2005) . * Mehra, Jagdish, and Helmut Rechenberg ''The Historical Development of Quantum Theory. Volume 5 Erwin Schrödinger and the Rise of Wave Mechanics. Part 1 Schrödinger in Vienna and Zurich 1887–1925.'' (Springer, 2001) * Jammer, Max ''The Conceptual Development of Quantum Mechanics'' (McGraw-Hill, 1966) *Moore, Walte
''Schrödinger: Life and Thought''
(Cambridge, 1992)


External links

* * {{DEFAULTSORT:Heitler, Walter 1904 births 1981 deaths Fellows of the Royal Society 20th-century German physicists Ludwig Maximilian University of Munich alumni Jewish emigrants from Nazi Germany to the United Kingdom Academics of the University of Bristol Jewish physicists Winners of the Max Planck Medal Academics of the Dublin Institute for Advanced Studies