Wurtzite is a

zinc Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodi ...

and

iron Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...

sulfide mineral The sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide (S22−) as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenides, the tellurides, the ...

with the chemical formula , a less frequently encountered structural polymorph form of

sphalerite Sphalerite (sometimes spelled sphaelerite) is a sulfide mineral with the chemical formula . It is the most important ore of zinc. Sphalerite is found in a variety of deposit types, but it is primarily in Sedimentary exhalative deposits, sedimen ...

. The iron content is variable up to eight percent.Palache, Charles, Harry Berman & Clifford Frondel (1944), ''The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana,'' Yale University 1837-1892, Volume I: Elements, Sulfides, Sulfosalts, Oxides. John Wiley and Sons, Inc., New York. 7th edition, revised and enlarged, pp. 226-228. It is trimorphous with matraite and sphalerite. It occurs in

hydrothermal Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...

deposits associated with sphalerite,

pyrite The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Iron, FeSulfur, S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic Luster (mineralogy), lust ...

chalcopyrite Chalcopyrite ( ) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mo ...

barite Baryte, barite or barytes ( or ) is a mineral consisting of barium sulfate ( Ba S O4). Baryte is generally white or colorless, and is the main source of the element barium. The ''baryte group'' consists of baryte, celestine (strontium sulfate), ...

and

marcasite The mineral marcasite, sometimes called “white iron pyrite”, is iron sulfide (FeS2) with orthorhombic crystal structure. It is physically and crystallographically distinct from pyrite, which is iron sulfide with cubic crystal structure. Both ...

. It also occurs in low-temperature

clay Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4). Clays develop plasticity when wet, due to a molecular film of water surrounding the clay par ...

ironstone Ironstone is a sedimentary rock, either deposited directly as a ferruginous sediment or created by chemical replacement, that contains a substantial proportion of an iron ore compound from which iron (Fe) can be smelted commercially. Not to be con ...

concretion A concretion is a hard, compact mass of matter formed by the precipitation of mineral cement within the spaces between particles, and is found in sedimentary rock or soil. Concretions are often ovoid or spherical in shape, although irregular ...

s. It was first described in 1861 for an occurrence in the San José Mine, Oruro City, Cercado Province,

Oruro Department Oruro (; Quechua: ''Uru Uru''; Aymara: ''Ururu'') is a department of Bolivia, with an area of . Its capital is the city of Oruro. According to the 2012 census, the Oruro department had a population of 494,178. Provinces of Oruro The departme ...

Bolivia , image_flag = Bandera de Bolivia (Estado).svg , flag_alt = Horizontal tricolor (red, yellow, and green from top to bottom) with the coat of arms of Bolivia in the center , flag_alt2 = 7 × 7 square p ...

, and named for French chemist

Charles-Adolphe Wurtz Charles Adolphe Wurtz (; 26 November 181710 May 1884) was an Alsatian French chemist. He is best remembered for his decades-long advocacy for the atomic theory and for ideas about the structures of chemical compounds, against the skeptical opinio ...

. It has widespread distribution. In Europe it is reported from

Příbram Příbram (; german: Freiberg in Böhmen, ''Przibram'', or ''Pribram'', in 1939–1945 ''Pibrans'') is a town in the Central Bohemian Region of the Czech Republic. It has about 32,000 inhabitants. It is well known for its mining history, and more ...

Czech Republic The Czech Republic, or simply Czechia, is a landlocked country in Central Europe. Historically known as Bohemia, it is bordered by Austria to the south, Germany to the west, Poland to the northeast, and Slovakia to the southeast. The ...

;

Hesse Hesse (, , ) or Hessia (, ; german: Hessen ), officially the State of Hessen (german: links=no, Land Hessen), is a States of Germany, state in Germany. Its capital city is Wiesbaden, and the largest urban area is Frankfurt. Two other major histor ...

Germany Germany,, officially the Federal Republic of Germany, is a country in Central Europe. It is the second most populous country in Europe after Russia, and the most populous member state of the European Union. Germany is situated betwe ...

; and

Liskeard Liskeard ( ; kw, Lyskerrys) is a small ancient stannary and market town in south-east Cornwall, South West England. It is situated approximately 20 miles (32 km) west of Plymouth, west of the Devon border, and 12 miles (20 km) eas ...

Cornwall Cornwall (; kw, Kernow ) is a historic county and ceremonial county in South West England. It is recognised as one of the Celtic nations, and is the homeland of the Cornish people. Cornwall is bordered to the north and west by the Atlantic ...

England England is a country that is part of the United Kingdom. It shares land borders with Wales to its west and Scotland to its north. The Irish Sea lies northwest and the Celtic Sea to the southwest. It is separated from continental Europe b ...

. In the US it is reported from

Litchfield County, Connecticut Litchfield County is in northwestern Connecticut. As of the 2020 census, the population was 185,186. The county was named after Lichfield, in England. Litchfield County has the lowest population density of any county in Connecticut and is the ...

; Butte,

Silver Bow County, Montana Silver Bow County is a county in the U.S. state Montana. As of the 2020 census, the population was 35,133. Its county seat is Butte. In 1977, the city and county governments consolidated to form the single entity of Butte-Silver Bow. Additional ...

; at Frisco,

Beaver County, Utah Beaver County is a county in west central Utah, United States. As of the 2010 United States Census, the population was 6,629. Its county seat and largest city is Beaver. The county was named for the abundance of beaver in the area. History Ex ...

; and from the Joplin district,

Jasper County, Missouri Jasper County is located in the southwest portion of the U.S. state of Missouri. As of the 2020 census, the population was 122,761. Its county seat is Carthage, and its largest city is Joplin. The county was organized in 1841 and named for W ...

Wurtzite structure

The wurtzite group includes

cadmoselite Cadmoselite is a rare cadmium selenide mineral with chemical formula CdSe. Cadmoselite crystallizes in the Hexagonal (crystal system), hexagonal system and occurs as black to pale grey opaque crystals and grains.http://rruff.geo.arizona.edu/doclib/h ...

(CdSe),

greenockite Greenockite is a rare cadmium bearing metal sulfide mineral consisting of cadmium sulfide (CdS) in crystalline form. Greenockite crystallizes in the hexagonal system. It occurs as massive encrustations and as hemimorphic six-sided pyramidal cryst ...

(CdS), mátraite (ZnS), and

rambergite Rambergite is a manganese sulfide mineral with formula . It has been found in anoxic marine sediments, rich in organic matter of the Gotland Deep, Baltic Sea and also in skarn in the Garpenberg area, Dalarna, Sweden. It was named after the mine ...

(MnS), in addition to wurtzite. Its

crystal structure In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions or molecules in a crystal, crystalline material. Ordered structures occur from the intrinsic nature of the constituent particles to form symmetric pat ...

is called the

wurtzite crystal structure In crystallography, the hexagonal crystal family is one of the six crystal families, which includes two crystal systems (hexagonal and trigonal) and two lattice systems (hexagonal and rhombohedral). While commonly confused, the trigonal crystal ...

, to which it lends its name. This structure is a member of the

hexagonal In geometry, a hexagon (from Greek , , meaning "six", and , , meaning "corner, angle") is a six-sided polygon. The total of the internal angles of any simple (non-self-intersecting) hexagon is 720°. Regular hexagon A '' regular hexagon'' has ...

crystal system In crystallography, a crystal system is a set of point groups (a group of geometric symmetries with at least one fixed point). A lattice system is a set of Bravais lattices. Space groups are classified into crystal systems according to their po ...

and consists of tetrahedrally coordinated

and

sulfur Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula ...

atoms that are stacked in an ABABABABAB pattern.

The unit cell parameters of wurtzite are (-2H polytype): *''a'' = ''b'' = 3.81 Å = 381 pm *''c'' = 6.23 Å = 623 pm *V = 78.41 Å³ *Z = 2

References

External links

The Mineral Wurtzite
* {{Cite NIE, wstitle=Wurtzite, year=1905 , short=x Sulfide minerals Zinc minerals Iron minerals Hexagonal minerals Minerals in space group 186 Minerals described in 1861 ja:閃亜鉛鉱#ウルツ鉱

Wurtzite structure

See also

References

External links