White phosphorus munitions are weapons that use one of the common
allotrope
Allotropy or allotropism () is the property of some chemical elements to exist in two or more different forms, in the same physical state, known as allotropes of the elements. Allotropes are different structural modifications of an element: the ...
s of the
chemical element
A chemical element is a species of atoms that have a given number of protons in their nuclei, including the pure substance consisting only of that species. Unlike chemical compounds, chemical elements cannot be broken down into simpler sub ...
phosphorus
Phosphorus is a chemical element with the symbol P and atomic number 15. Elemental phosphorus exists in two major forms, white phosphorus and red phosphorus, but because it is highly reactive, phosphorus is never found as a free element on Ear ...
.
White phosphorus
Elemental phosphorus can exist in several allotropes, the most common of which are white and red solids. Solid violet and black allotropes are also known. Gaseous phosphorus exists as diphosphorus and atomic phosphorus.
White phosphorus
White ...
is used in
smoke
Smoke is a suspension of airborne particulates and gases emitted when a material undergoes combustion or pyrolysis, together with the quantity of air that is entrained or otherwise mixed into the mass. It is commonly an unwanted by-product ...
,
illumination, and
incendiary munitions, and is commonly the burning element of
tracer ammunition
Tracer ammunition (AMO) (Tracers) are bullets or cannon-caliber projectiles that are built with a small pyrotechnic charge in their base. When fired, the pyrotechnic composition is ignited by the burning powder and burns very brightly, making t ...
.
Other common names for white phosphorus munitions include ''WP'' and the slang terms ''Willie Pete'' and ''Willie Peter'', which are derived from ''William Peter'', the
World War II phonetic alphabet rendering of the letters ''WP''. White phosphorus is
pyrophoric
A substance is pyrophoric (from grc-gre, πυροφόρος, , 'fire-bearing') if it ignites spontaneously in air at or below (for gases) or within 5 minutes after coming into contact with air (for liquids and solids). Examples are organolith ...
(it is ignited by contact with air); burns fiercely; and can ignite cloth, fuel, ammunition, and other combustibles.
In addition to its offensive capabilities, white phosphorus is a highly efficient smoke-producing agent, reacting with air to produce an immediate blanket of
phosphorus pentoxide
Phosphorus pentoxide is a chemical compound with molecular formula P4 O10 (with its common name derived from its empirical formula, P2O5). This white crystalline solid is the anhydride of phosphoric acid. It is a powerful desiccant and dehydra ...
vapour. Smoke-producing white phosphorus munitions are very common, particularly as smoke grenades for
infantry
Infantry is a military specialization which engages in ground combat on foot. Infantry generally consists of light infantry, mountain infantry, motorized infantry & mechanized infantry, airborne infantry, air assault infantry, and marine i ...
, loaded in defensive
grenade launcher
A grenade launcher is a weapon that fires a specially-designed large-caliber projectile, often with an explosive, smoke or gas warhead. Today, the term generally refers to a class of dedicated firearms firing unitary grenade cartridges. The mos ...
s on
tank
A tank is an armoured fighting vehicle intended as a primary offensive weapon in front-line ground combat. Tank designs are a balance of heavy firepower, strong armour, and good battlefield mobility provided by tracks and a powerful engin ...
s and other armoured vehicles, and in the
ammunition
Ammunition (informally ammo) is the material fired, scattered, dropped, or detonated from any weapon or weapon system. Ammunition is both expendable weapons (e.g., bombs, missiles, grenades, land mines) and the component parts of other weap ...
allotment for
artillery
Artillery is a class of heavy military ranged weapons that launch munitions far beyond the range and power of infantry firearms. Early artillery development focused on the ability to breach defensive walls and fortifications during siege ...
and
mortars
Mortar may refer to:
* Mortar (weapon), an indirect-fire infantry weapon
* Mortar (masonry), a material used to fill the gaps between blocks and bind them together
* Mortar and pestle, a tool pair used to crush or grind
* Mortar, Bihar, a villag ...
. These create
smoke screen
A smoke screen is smoke released to mask the movement or location of military units such as infantry, tanks, aircraft, or ships.
Smoke screens are commonly deployed either by a canister (such as a grenade) or generated by a vehicle (such as ...
s to mask friendly forces' movement, position,
infrared
Infrared (IR), sometimes called infrared light, is electromagnetic radiation (EMR) with wavelengths longer than those of visible light. It is therefore invisible to the human eye. IR is generally understood to encompass wavelengths from around ...
signatures, and shooting positions. They are often called ''smoke/marker rounds'' for their use in marking points of interest, such as a light mortar to designate a target for artillery spotters.
Early use
White phosphorus was used by
Fenian
The word ''Fenian'' () served as an umbrella term for the Irish Republican Brotherhood (IRB) and their affiliate in the United States, the Fenian Brotherhood, secret political organisations in the late 19th and early 20th centuries dedicated ...
(Irish nationalist) arsonists in the 19th century in a formulation that became known as "Fenian fire".
The phosphorus would be in a solution of
carbon disulfide
Carbon disulfide (also spelled as carbon disulphide) is a neurotoxic, colorless, volatile liquid with the formula and structure . The compound is used frequently as a building block in organic chemistry as well as an industrial and chemical non ...
; when the carbon disulfide evaporates, the phosphorus bursts into flames.
The same formula was also used in arson in Australia.
World War I, the inter-war period and World War II
The
British Army
The British Army is the principal land warfare force of the United Kingdom, a part of the British Armed Forces along with the Royal Navy and the Royal Air Force. , the British Army comprises 79,380 regular full-time personnel, 4,090 Gurk ...
introduced the first factory-built white phosphorus grenades in late 1916 during the
First World War
World War I (28 July 1914 11 November 1918), often abbreviated as WWI, was one of the deadliest global conflicts in history. Belligerents included much of Europe, the Russian Empire, the United States, and the Ottoman Empire, with fightin ...
. During the war, white phosphorus mortar bombs, shells, rockets, and grenades were used extensively by
American
American(s) may refer to:
* American, something of, from, or related to the United States of America, commonly known as the "United States" or "America"
** Americans, citizens and nationals of the United States of America
** American ancestry, pe ...
,
Commonwealth
A commonwealth is a traditional English term for a political community founded for the common good. Historically, it has been synonymous with "republic". The noun "commonwealth", meaning "public welfare, general good or advantage", dates from the ...
, and, to a lesser extent,
Japanese
Japanese may refer to:
* Something from or related to Japan, an island country in East Asia
* Japanese language, spoken mainly in Japan
* Japanese people, the ethnic group that identifies with Japan through ancestry or culture
** Japanese diaspor ...
forces, in both smoke-generating and antipersonnel roles. The
Royal Air Force
The Royal Air Force (RAF) is the United Kingdom's air and space force. It was formed towards the end of the First World War on 1 April 1918, becoming the first independent air force in the world, by regrouping the Royal Flying Corps (RFC) and ...
based
in Iraq also used white phosphorus bombs in
Anbar Province during the
Iraqi revolt of 1920
The Iraqi revolt against the British, also known as the 1920 Iraqi Revolt or the Great Iraqi Revolution, started in Baghdad in the summer of 1920 with mass demonstrations by Iraqis, including protests by embittered officers from the old Ottoman ...
.
Among the many social groups protesting the war and conscription at the time, at least one, the
Industrial Workers of the World
The Industrial Workers of the World (IWW), members of which are commonly termed "Wobblies", is an international labor union that was founded in Chicago in 1905. The origin of the nickname "Wobblies" is uncertain. IWW ideology combines genera ...
in Australia, used Fenian fire.
In the interwar years, the
US Army
The United States Army (USA) is the land service branch of the United States Armed Forces. It is one of the eight U.S. uniformed services, and is designated as the Army of the United States in the U.S. Constitution.Article II, section 2, cla ...
trained using white phosphorus, by artillery shell and air bombardment.
In 1940, when the Nazi invasion of
Great Britain
Great Britain is an island in the North Atlantic Ocean off the northwest coast of continental Europe. With an area of , it is the largest of the British Isles, the largest European island and the ninth-largest island in the world. It is ...
seemed imminent, the phosphorus firm of
Albright and Wilson
Albright and Wilson was founded in 1856 as a United Kingdom manufacturer of potassium chlorate and white phosphorus for the match industry. For much of its first 100 years of existence, phosphorus-derived chemicals formed the majority of its prod ...
suggested that the
British government
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, image = HM Government logo.svg
, image_size = 220px
, image2 = Royal Coat of Arms of the United Kingdom (HM Government).svg
, image_size2 = 180px
, caption = Royal Arms
, date_es ...
use a material similar to Fenian fire in several expedient incendiary weapons. The only one fielded was the ''
Grenade, No. 76'' or ''Special Incendiary Phosphorus grenade'', which consisted of a glass bottle filled with a mixture similar to Fenian fire, plus some
latex
Latex is an emulsion (stable dispersion) of polymer microparticles in water. Latexes are found in nature, but synthetic latexes are common as well.
In nature, latex is found as a milky fluid found in 10% of all flowering plants (angiosperms ...
. It came in two versions, one with a red cap intended to be thrown by hand, and a slightly stronger bottle with a green cap, intended to be launched from the
Northover projector
The Projector, 2.5 inch—more commonly known as the Northover Projector—was an ''ad hoc'' anti-tank weapon used by the British Army and Home Guard during the Second World War.
With a German invasion of Great Britain seeming likely after ...
, a crude launcher using
black powder
Gunpowder, also commonly known as black powder to distinguish it from modern smokeless powder, is the earliest known chemical explosive. It consists of a mixture of sulfur, carbon (in the form of charcoal) and potassium nitrate (saltpeter). Th ...
as a propellant. These were improvised anti-tank weapons, hastily fielded in 1940 when the British were awaiting
a potential German invasion after losing the bulk of their modern armaments in the
Dunkirk evacuation
The Dunkirk evacuation, codenamed Operation Dynamo and also known as the Miracle of Dunkirk, or just Dunkirk, was the evacuation of more than 338,000 Allied soldiers during the Second World War from the beaches and harbour of Dunkirk, in the ...
.
At the start of the Normandy campaign, 20% of American 81 mm mortar ammunition consisted of M57 point-detonating bursting smoke rounds using WP filler. At least five American
Medal of Honor
The Medal of Honor (MOH) is the United States Armed Forces' highest military decoration and is awarded to recognize American soldiers, sailors, marines, airmen, guardians and coast guardsmen who have distinguished themselves by acts of valor. ...
citations mention their recipients using M15 white phosphorus
hand grenade
A grenade is an explosive weapon typically thrown by hand (also called hand grenade), but can also refer to a shell (explosive projectile) shot from the muzzle of a rifle (as a rifle grenade) or a grenade launcher. A modern hand grenade genera ...
s to clear enemy positions, and in the 1944
liberation of Cherbourg alone, a single US mortar battalion, the 87th, fired 11,899 white phosphorus rounds into the city. The US Army and
Marines
Marines, or naval infantry, are typically a military force trained to operate in littoral zones in support of naval operations. Historically, tasks undertaken by marines have included helping maintain discipline and order aboard the ship (refle ...
used M2 and M328 WP shells in mortars. White phosphorus was widely used by Allied soldiers for breaking up German attacks and creating havoc among enemy troop concentrations during the latter part of the war.
US
Sherman tank
}
The M4 Sherman, officially Medium Tank, M4, was the most widely used medium tank by the United States and Western Allies in World War II. The M4 Sherman proved to be reliable, relatively cheap to produce, and available in great numbers. It w ...
s carried the M64, a 75mm white phosphorus round intended for screening and artillery spotting, but tank crews found it useful against German tanks such as the
Panther
Panther may refer to:
Large cats
*Pantherinae, the cat subfamily that contains the genera ''Panthera'' and ''Neofelis''
**'' Panthera'', the cat genus that contains tigers, lions, jaguars and leopards.
*** Jaguar (''Panthera onca''), found in So ...
that their APC ammunition could not penetrate at long range. Smoke from rounds fired directly at German tanks would be used to blind them, allowing the Shermans to close to a range where their armour-piercing rounds were effective. In addition, due to the turret ventilation systems sucking in fumes, German crews would sometimes be forced to abandon their vehicle: this proved particularly effective against inexperienced crews who, on seeing smoke inside the turret, would assume their tank had caught fire. Smoke was also used for "silhouetting" enemy vehicles, with rounds dropped behind them to produce a better contrast for gunnery.
Later uses
White phosphorus munitions were used extensively by US forces in
Vietnam
Vietnam or Viet Nam ( vi, Việt Nam, ), officially the Socialist Republic of Vietnam,., group="n" is a country in Southeast Asia, at the eastern edge of mainland Southeast Asia, with an area of and population of 96 million, making i ...
and by Russian forces in the
and
Second Chechen War
The Second Chechen War (russian: Втора́я чече́нская война́, ) took place in Chechnya and the border regions of the North Caucasus between the Russia, Russian Federation and the Chechen Republic of Ichkeria, from Augus ...
. White phosphorus grenades were used by the US in Vietnam to destroy
Viet Cong
,
, war = the Vietnam War
, image = FNL Flag.svg
, caption = The flag of the Viet Cong, adopted in 1960, is a variation on the flag of North Vietnam. Sometimes the lower stripe was green.
, active ...
tunnel complexes as they would burn up all oxygen and suffocate the enemy soldiers sheltering inside. British soldiers also made extensive use of white phosphorus grenades during the
Falklands War
The Falklands War ( es, link=no, Guerra de las Malvinas) was a ten-week undeclared war between Argentina and the United Kingdom in 1982 over two British dependent territories in the South Atlantic: the Falkland Islands and its territorial de ...
to clear out
Argentine
Argentines (mistakenly translated Argentineans in the past; in Spanish (masculine) or (feminine)) are people identified with the country of Argentina. This connection may be residential, legal, historical or cultural. For most Argentines, s ...
positions as the peaty soil they were constructed on tended to lessen the impact of fragmentation grenades. According to
GlobalSecurity.org
GlobalSecurity.org is an American nonpartisan, independent, nonprofit organization that serves as a think tank, and research and consultancy group. Focus
The site is focused on national and international security issues; military analysis, syste ...
, during the
Battle of Grozny during the
in
Chechnya
Chechnya ( rus, Чечня́, Chechnyá, p=tɕɪtɕˈnʲa; ce, Нохчийчоь, Noxçiyçö), officially the Chechen Republic,; ce, Нохчийн Республика, Noxçiyn Respublika is a republic of Russia. It is situated in the ...
, every fourth or fifth Russian artillery or mortar shell fired was a smoke or white phosphorus shell.
Use by US forces in Iraq
In April 2004, during the
First Battle of Fallujah
The First Battle of Fallujah, code-named Operation Vigilant Resolve, was an operation against militants in Fallujah as well as an attempt to apprehend or kill the perpetrators of the killing of four U.S. contractors in March 2004.
The chief ca ...
, Darrin Mortenson of California's ''
North County Times
The ''North County Times'' was a local newspaper in San Diego's North County. It was headquartered in Escondido. The final publisher was Peter York.
It was formed in 1995 from the merger of the ''North County Blade-Citizen'' of Oceanside (fo ...
'' reported that US forces had used white phosphorus as an
incendiary weapon
Incendiary weapons, incendiary devices, incendiary munitions, or incendiary bombs are weapons designed to start fires or destroy sensitive equipment using fire (and sometimes used as anti-personnel weaponry), that use materials such as napalm, th ...
while "never knowing what the targets were or what damage the resulting explosions caused". Embedded with the
2nd Battalion,
1st Marine Regiment
The 1st Marine Regiment is an infantry regiment of the United States Marine Corps based at Marine Corps Base Camp Pendleton, California. The regiment is under the command of the 1st Marine Division and the I Marine Expeditionary Force. The 1st ...
, Mortenson described a Marine mortar team using a mixture of white phosphorus and high explosives to shell a cluster of buildings where Iraqi insurgents had been spotted throughout the week. In November 2004, during the
Second Battle of Fallujah
The Second Battle of Fallujah, codenamed Operation al-Fajr ( ar, الفجر, ) and Operation Phantom Fury, was an American-led offensive of the Iraq War that lasted roughly 6 weeks, starting 7th November, 2004. Marking the highest point of the ...
, ''
Washington Post
''The Washington Post'' (also known as the ''Post'' and, informally, ''WaPo'') is an American daily newspaper published in Washington, D.C. It is the most widely circulated newspaper within the Washington metropolitan area and has a large nati ...
'' reporters embedded with Task Force 2-2,
Regimental Combat Team 7 stated that they witnessed artillery guns firing white phosphorus projectiles, which "create a screen of fire that cannot be extinguished with water. Insurgents reported being attacked with a substance that melted their skin, a reaction consistent with white phosphorous burns."
The same article also reported, "The corpses of the mujaheddin which we received were burned, and some corpses were melted."
[ The March/April 2005 issue of an official Army publication called ''Field Artillery Magazine'' reported that "White phosphorus proved to be an effective and versatile munition and a potent psychological weapon against the insurgents in trench lines and spider holes. ... We fired 'shake and bake' missions at the insurgents using W.P. hite phosphorusto flush them out and H.E. igh explosivesto take them out".]
The documentary ''Fallujah, The Hidden Massacre
''Fallujah, The Hidden Massacre'' is a documentary film by Sigfrido Ranucci and Maurizio Torrealta which first aired on Italy's RAI state television network on November 8, 2005. The film documents the use of chemical weapons, particularly the us ...
'', produced by RAI TV
RAI – Radiotelevisione italiana (; commercially styled as Rai since 2000; known until 1954 as Radio Audizioni Italiane) is the national public broadcasting company of Italy, owned by the Ministry of Economy and Finance. RAI operates many ter ...
and released 8 November 2005, showed video and photos purporting to be of Fallujah combatants and also civilians, including women and children, who had died of burns caused by white phosphorus during the Second Battle of Fallujah.[ ]George Monbiot
George Joshua Richard Monbiot ( ; born 27 January 1963) is a British writer known for his environmental and political activism. He writes a regular column for ''The Guardian'' and is the author of a number of books.
Monbiot grew up in Oxfordsh ...
, a British writer for the ''Guardian'', disputed these claims, stating that while he was not "qualified to determine someone's cause of death", there was no evidence that white phosphorus was used against civilians and that "we don't yet know" how the people shown in the documentary had died.
The US Embassy in Rome denied that US troops had used white phosphorus as a weapon. On 15 November 2005, the US ambassador to the UK, Robert H. Tuttle, wrote to ''The Independent
''The Independent'' is a British online newspaper. It was established in 1986 as a national morning printed paper. Nicknamed the ''Indy'', it began as a broadsheet and changed to tabloid format in 2003. The last printed edition was publis ...
'' also denying that the United States used white phosphorus as a weapon in Fallujah, but later that same day US Department of Defense spokesman Lieutenant Colonel Barry Venable confirmed to the BBC #REDIRECT BBC #REDIRECT BBC
Here i going to introduce about the best teacher of my life b BALAJI sir. He is the precious gift that I got befor 2yrs . How has helped and thought all the concept and made my success in the 10th board exam. ...
...
that US forces had used white phosphorus as an incendiary weapon there, in order to drive combatants out of dug-in positions.
On 22 November 2005, the Iraqi government stated it would investigate the use of white phosphorus in the battle of Fallujah. On 30 November 2005, a BBC article included an image of WP being fired from helicopters in the air above Fallujah and quoted General
that white phosphorus munitions were a "legitimate tool of the military" used to illuminate targets and create smokescreens, saying "It is not a chemical weapon. It is an incendiary. And it is well within the law of war to use those weapons as they're being used, for marking and for screening". The article wrote that "If it comes into contact with human skin, white phosphorus can ignite and burn down to the bone if it is not exhausted or extinguished."
said that white phosphorus would probably fall into the category of chemical weapons if it was used directly against people.