Waxes are a diverse class of
organic compound
In chemistry, organic compounds are generally any chemical compounds that contain carbon-hydrogen or carbon-carbon bonds. Due to carbon's ability to catenate (form chains with other carbon atoms), millions of organic compounds are known. The ...
s that are
lipophilic
Lipophilicity (from Greek λίπος "fat" and φίλος "friendly"), refers to the ability of a chemical compound to dissolve in fats, oils, lipids, and non-polar solvents such as hexane or toluene. Such non-polar solvents are themselves lipop ...
,
malleable
Ductility is a mechanical property commonly described as a material's amenability to drawing (e.g. into wire). In materials science, ductility is defined by the degree to which a material can sustain plastic deformation under tensile stres ...
solids near ambient temperatures. They include
higher alkanes
Higher alkanes are alkanes having nine or more carbon atoms. Nonane is the lightest alkane to have a flash point above 25 °C, and is not classified as dangerously flammable.
The term ''higher alkanes'' is sometimes used literally as "alkanes ...
and
lipid
Lipids are a broad group of naturally-occurring molecules which includes fats, waxes, sterols, fat-soluble vitamins (such as vitamins A, D, E and K), monoglycerides, diglycerides, phospholipids, and others. The functions of lipids include ...
s, typically with
melting point
The melting point (or, rarely, liquefaction point) of a substance is the temperature at which it changes state from solid to liquid. At the melting point the solid and liquid phase exist in equilibrium. The melting point of a substance depends ...
s above about 40 °C (104 °F), melting to give low
viscosity
The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water.
Viscosity quantifies the inte ...
liquids. Waxes are
insoluble
In chemistry, solubility is the ability of a substance, the solute, to form a solution with another substance, the solvent. Insolubility is the opposite property, the inability of the solute to form such a solution.
The extent of the solubil ...
in water but soluble in nonpolar organic solvents such as
hexane
Hexane () is an organic compound, a straight-chain alkane with six carbon atoms and has the molecular formula C6H14.
It is a colorless liquid, odorless when pure, and with boiling points approximately . It is widely used as a cheap, relatively ...
,
benzene
Benzene is an organic chemical compound with the molecular formula C6H6. The benzene molecule is composed of six carbon atoms joined in a planar ring with one hydrogen atom attached to each. Because it contains only carbon and hydrogen atoms, ...
and
chloroform
Chloroform, or trichloromethane, is an organic compound with chemical formula, formula Carbon, CHydrogen, HChlorine, Cl3 and a common organic solvent. It is a colorless, strong-smelling, dense liquid produced on a large scale as a precursor to ...
. Natural waxes of different types are produced by plants and animals and occur in
petroleum
Petroleum, also known as crude oil, or simply oil, is a naturally occurring yellowish-black liquid mixture of mainly hydrocarbons, and is found in geological formations. The name ''petroleum'' covers both naturally occurring unprocessed crud ...
.
Chemistry
![MODOCeroline](https://upload.wikimedia.org/wikipedia/commons/b/b5/MODOCeroline.jpg)
Waxes are organic compounds that characteristically consist of long
aliphatic
In organic chemistry, hydrocarbons ( compounds composed solely of carbon and hydrogen) are divided into two classes: aromatic compounds and aliphatic compounds (; G. ''aleiphar'', fat, oil). Aliphatic compounds can be saturated, like hexane, or ...
alkyl
In organic chemistry, an alkyl group is an alkane missing one hydrogen.
The term ''alkyl'' is intentionally unspecific to include many possible substitutions.
An acyclic alkyl has the general formula of . A cycloalkyl is derived from a cycloalk ...
chains, although aromatic compounds may also be present. Natural waxes may contain unsaturated bonds and include various
functional group
In organic chemistry, a functional group is a substituent or moiety in a molecule that causes the molecule's characteristic chemical reactions. The same functional group will undergo the same or similar chemical reactions regardless of the rest ...
s such as
fatty acids
In chemistry, particularly in biochemistry, a fatty acid is a carboxylic acid with an aliphatic chain, which is either saturated or unsaturated. Most naturally occurring fatty acids have an unbranched chain of an even number of carbon atoms, f ...
,
primary
Primary or primaries may refer to:
Arts, entertainment, and media Music Groups and labels
* Primary (band), from Australia
* Primary (musician), hip hop musician and record producer from South Korea
* Primary Music, Israeli record label
Works
* ...
and
secondary alcohol
In chemistry, an alcohol is a type of organic compound that carries at least one hydroxyl () functional group bound to a saturated carbon atom. The term ''alcohol'' originally referred to the primary alcohol ethanol (ethyl alcohol), which is ...
s,
ketones
In organic chemistry, a ketone is a functional group with the structure R–C(=O)–R', where R and R' can be a variety of carbon-containing substituents. Ketones contain a carbonyl group –C(=O)– (which contains a carbon-oxygen double bon ...
,
aldehydes
In organic chemistry, an aldehyde () is an organic compound containing a functional group with the structure . The functional group itself (without the "R" side chain) can be referred to as an aldehyde but can also be classified as a formyl group ...
and fatty acid
ester
In chemistry, an ester is a compound derived from an oxoacid (organic or inorganic) in which at least one hydroxyl group () is replaced by an alkoxy group (), as in the substitution reaction of a carboxylic acid and an alcohol. Glycerides ar ...
s. Synthetic waxes often consist of
homologous series
In organic chemistry, a homologous series is a sequence of compounds with the same functional group and similar chemical properties in which the members of the series can be branched or unbranched, or differ by molecular formula of and molecu ...
of long-chain aliphatic hydrocarbons (
alkane
In organic chemistry, an alkane, or paraffin (a historical trivial name that also has other meanings), is an acyclic saturated hydrocarbon. In other words, an alkane consists of hydrogen and carbon atoms arranged in a tree structure in which ...
s or paraffins) that lack
functional group
In organic chemistry, a functional group is a substituent or moiety in a molecule that causes the molecule's characteristic chemical reactions. The same functional group will undergo the same or similar chemical reactions regardless of the rest ...
s.
[
]
Plant and animal waxes
Waxes are synthesized by many plants and animals. Those of animal origin typically consist of wax ester
A wax ester (WE) is an ester of a fatty acid and a fatty alcohol. Wax esters comprise the main components of three commercially important waxes: carnauba wax, candelilla wax, and beeswax..
Wax esters are formed by combining one fatty acid with o ...
s derived from a variety of fatty acids and carboxylic alcohols. In waxes of plant origin, characteristic mixtures of unesterified hydrocarbons may predominate over esters.[ The composition depends not only on species, but also on geographic location of the organism.
]
Animal waxes
The best-known animal wax is beeswax
Beeswax (''cera alba'') is a natural wax produced by honey bees of the genus ''Apis''. The wax is formed into scales by eight wax-producing glands in the abdominal segments of worker bees, which discard it in or at the hive. The hive workers ...
used in constructing the honeycomb
A honeycomb is a mass of Triangular prismatic honeycomb#Hexagonal prismatic honeycomb, hexagonal prismatic Beeswax, wax cells built by honey bees in their beehive, nests to contain their larvae and stores of honey and pollen.
beekeeping, Beekee ...
s of beehives, but other insects also secrete waxes. A major component of beeswax is myricyl palmitate which is an ester
In chemistry, an ester is a compound derived from an oxoacid (organic or inorganic) in which at least one hydroxyl group () is replaced by an alkoxy group (), as in the substitution reaction of a carboxylic acid and an alcohol. Glycerides ar ...
of triacontanol
1-Triacontanol (''n''-triacontanol) is a fatty alcohol of the general formula C30H62O, also known as melissyl alcohol or myricyl alcohol. It is found in plant cuticle waxes and in beeswax. Triacontanol is a growth stimulant for many plants, mo ...
and palmitic acid
Palmitic acid (hexadecanoic acid in IUPAC nomenclature) is a fatty acid with a 16-carbon chain. It is the most common saturated fatty acid found in animals, plants and microorganisms.Gunstone, F. D., John L. Harwood, and Albert J. Dijkstra. The Li ...
. Its melting point is 62-65 °C. Spermaceti
Spermaceti is a waxy substance found in the head cavities of the sperm whale (and, in smaller quantities, in the oils of other whales). Spermaceti is created in the spermaceti organ inside the whale's head. This organ may contain as much as of ...
occurs in large amounts in the head oil of the sperm whale
The sperm whale or cachalot (''Physeter macrocephalus'') is the largest of the toothed whales and the largest toothed predator. It is the only living member of the genus ''Physeter'' and one of three extant species in the sperm whale famil ...
. One of its main constituents is cetyl palmitate
Hexadecyl hexadecanoate, also known as Cetyl palmitate, is the ester derived from hexadecanoic acid and hexadecanol. This white waxy solid is the primary constituent of spermaceti, the once highly prized wax found in the skull of sperm whales.Wi ...
, another ester of a fatty acid
In chemistry, particularly in biochemistry, a fatty acid is a carboxylic acid with an aliphatic chain, which is either saturated or unsaturated. Most naturally occurring fatty acids have an unbranched chain of an even number of carbon atoms, fr ...
and a fatty alcohol
Fatty alcohols (or long-chain alcohols) are usually high-molecular-weight, straight-chain primary alcohols, but can also range from as few as 4–6 carbons to as many as 22–26, derived from natural fats and oils. The precise chain length varies ...
. Lanolin
Lanolin (from Latin 'wool', and 'oil'), also called wool yolk, wool wax, or wool grease, is a wax secreted by the sebaceous glands of wool-bearing animals. Lanolin used by humans comes from domestic sheep breeds that are raised specifically fo ...
is a wax obtained from wool, consisting of esters of sterol
Sterol is an organic compound with formula , whose molecule is derived from that of gonane by replacement of a hydrogen atom in position 3 by a hydroxyl group. It is therefore an alcohol of gonane. More generally, any compounds that contain the go ...
s.[Wilhelm Riemenschneider1 and Hermann M. Bolt "Esters, Organic" Ullmann's Encyclopedia of Industrial Chemistry, 2005, Wiley-VCH, Weinheim. ]
Plant waxes
Plants secrete waxes into and on the surface of their cuticles
A cuticle (), or cuticula, is any of a variety of tough but flexible, non-mineral outer coverings of an organism, or parts of an organism, that provide protection. Various types of "cuticle" are non- homologous, differing in their origin, structu ...
as a way to control evaporation, wettability and hydration.[ The ]epicuticular wax
Epicuticular wax is a coating of wax covering the outer surface of the plant cuticle in land plants. It may form a whitish film or bloom on leaves, fruits and other plant organs. Chemically, it consists of hydrophobic organic compounds, mainly str ...
es of plants are mixtures of substituted long-chain aliphatic hydrocarbons, containing alkanes, alkyl esters, fatty acids, primary and secondary alcohols, diol
A diol is a chemical compound containing two hydroxyl groups ( groups). An aliphatic diol is also called a glycol. This pairing of functional groups is pervasive, and many subcategories have been identified.
The most common industrial diol is e ...
s, ketones and aldehydes.[EA Baker (1982) Chemistry and morphology of plant epicuticular waxes. In The Plant Cuticle. Ed. DF Cutler, KL Alvin, CE Price. Academic Press. ]
From the commercial perspective, the most important plant wax is carnauba wax
Carnauba (; pt, carnaúba ), also called Brazil wax and palm wax, is a wax of the leaves of the carnauba palm ''Copernicia prunifera'' (synonym: ''Copernicia cerifera''), a plant native to and grown only in the northeastern Brazilian states of C ...
, a hard wax obtained from the Brazilian palm ''Copernicia prunifera
''Copernicia prunifera'' or the carnaúba palm or carnaubeira palm () is a species of palm tree native to northeastern Brazil (mainly the states of Ceará, Piauí, Maranhão, Rio Grande do Norte and Bahia). Known by many as 'tree of life' becaus ...
''. Containing the ester myricyl cerotate, it has many applications, such as confectionery and other food coatings, car and furniture polish, floss coating, and surfboard wax
Surfboard wax (also known as surfwax) is a formulation of natural and/or synthetic wax for application to the deck of a surfboard, bodyboard, or skimboard, to keep the surfer from slipping off the board when paddling out or riding a wave. It is al ...
. Other more specialized vegetable waxes include jojoba oil
Jojoba oil is the liquid produced in the seed of the ''Simmondsia chinensis'' ( jojoba) plant, a shrub, which is native to southern Arizona, southern California, and northwestern Mexico. The oil makes up approximately 50% of the jojoba seed by w ...
, candelilla wax
Candelilla wax is a wax derived from the leaves of the small Candelilla shrub native to northern Mexico and the southwestern United States, '' Euphorbia antisyphilitica'', from the family ''Euphorbiaceae''. It is yellowish-brown, hard, brittle, a ...
and ouricury wax
Ouricury wax is a brown-colored wax obtained from the leaves of a Brazilian feather palm '' Syagrus coronata'' by scraping the leaf surface.
Harvesting
Harvesting ouricury wax is more difficult than harvesting carnauba wax, as ouricury wax does n ...
.
Modified plant and animal waxes
Plant and animal based waxes or oils can undergo selective chemical modifications to produce waxes with more desirable properties than are available in the unmodified starting material. This approach has relied on green chemistry approaches including olefin metathesis and enzymatic reactions and can be used to produce waxes from inexpensive starting materials like vegetable oils.
Petroleum derived waxes
Although many natural waxes contain esters, paraffin waxes are hydrocarbons, mixtures of alkanes usually in a homologous series
In organic chemistry, a homologous series is a sequence of compounds with the same functional group and similar chemical properties in which the members of the series can be branched or unbranched, or differ by molecular formula of and molecu ...
of chain lengths. These materials represent a significant fraction of petroleum. They are refined by vacuum distillation
Vacuum distillation is distillation performed under reduced pressure, which allows the purification of compounds not readily distilled at ambient pressures or simply to save time or energy. This technique separates compounds based on differences i ...
. Paraffin waxes are mixtures of saturated n- and iso- alkanes, naphthenes, and alkyl- and naphthene-substituted aromatic compounds. A typical alkane paraffin wax chemical composition comprises hydrocarbons with the general formula C''n''H2''n''+2, such as hentriacontane
Hentriacontane, also called ''untriacontane'', is a solid, long-chain alkane hydrocarbon with the structural formula CH3(CH2)29CH3. It is the main component of Paraffin wax.
It is found in a variety of plants, including peas (''Pisum sativum''), ...
, C31H64. The degree of branching has an important influence on the properties. Microcrystalline wax
Microcrystalline waxes are a type of wax produced by de-oiling petrolatum, as part of the petroleum refining process. In contrast to the more familiar paraffin wax which contains mostly unbranched alkanes, microcrystalline wax contains a higher per ...
is a lesser produced petroleum based wax that contains higher percentage of isoparaffinic (branched) hydrocarbons and naphthenic hydrocarbons.
Millions of tons of paraffin waxes are produced annually. They are used in foods (such as chewing gum and cheese wrapping), in candles and cosmetics, as non-stick and waterproofing coatings and in polishes.
Montan wax
Montan wax
Montan wax, also known as lignite wax or OP wax, is a hard wax obtained by solvent extraction of certain types of lignite or brown coal. Commercially viable deposits exist in only a few locations, including Amsdorf, Germany, and in the Ione Ba ...
is a fossilized wax extracted from coal and lignite
Lignite, often referred to as brown coal, is a soft, brown, combustible, sedimentary rock formed from naturally compressed peat. It has a carbon content around 25–35%, and is considered the lowest rank of coal due to its relatively low heat ...
. It is very hard, reflecting the high concentration of saturated fatty acid
In chemistry, particularly in biochemistry, a fatty acid is a carboxylic acid with an aliphatic chain, which is either saturated or unsaturated. Most naturally occurring fatty acids have an unbranched chain of an even number of carbon atoms, fr ...
s and alcohols. Although dark brown and odorous, they can be purified and bleached to give commercially useful products.
Polyethylene and related derivatives
, about 200 million kilograms of polyethylene waxes were consumed annually.[
Polyethylene waxes are manufactured by one of three methods:
# The direct polymerization of ethylene, potentially including co-monomers also;
# The thermal degradation of high molecular weight polyethylene resin;
# The recovery of low molecular weight fractions from high molecular weight resin production.
Each production technique generates products with slightly different properties. Key properties of low molecular weight polyethylene waxes are viscosity, density and melt point.
Polyethylene waxes produced by means of degradation or recovery from polyethylene resin streams contain very low molecular weight materials that must be removed to prevent volatilization and potential fire hazards during use. Polyethylene waxes manufactured by this method are usually stripped of low molecular weight fractions to yield a flash point >500°F (>260°C). Many polyethylene resin plants produce a low molecular weight stream often referred to as Low Polymer Wax (LPW). LPW is unrefined and contains volatile oligomers, corrosive catalyst and may contain other foreign material and water. Refining of LPW to produce a polyethylene wax involves removal of oligomers and hazardous catalyst. Proper refining of LPW to produce polyethylene wax is especially important when being used in applications requiring FDA or other regulatory certification.
]
Uses
Waxes are mainly consumed industrially as components of complex formulations, often for coatings. The main use of polyethylene and polypropylene waxes is in the formulation of colourants for plastics. Waxes confer matting effects (i.e., to confer non-glossy finishes) and wear resistance to paints. Polyethylene waxes are incorporated into inks in the form of dispersions to decrease friction. They are employed as release agent
A release agent (also mold release agent, release coating, or mold release coating) is a chemical used to prevent other materials from bonding to surfaces. It can provide a solution in processes involving mold release, die-cast release, plastic re ...
s, find use as slip agents in furniture, and confer corrosion resistance.[Uwe Wolfmeier, Mr. Hans Schmidt, Franz-Leo Heinrichs, Georg Michalczyk, Wolfgang Payer, Wolfram Dietsche, Klaus Boehlke, Gerd Hohner, Josef Wildgruber "Waxes" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2002. .]
Candles
Waxes such as paraffin wax
Paraffin wax (or petroleum wax) is a soft colorless solid derived from petroleum, coal, or oil shale that consists of a mixture of hydrocarbon molecules containing between 20 and 40 carbon atoms. It is solid at room temperature and begins to m ...
or beeswax
Beeswax (''cera alba'') is a natural wax produced by honey bees of the genus ''Apis''. The wax is formed into scales by eight wax-producing glands in the abdominal segments of worker bees, which discard it in or at the hive. The hive workers ...
, and hard fats such as tallow
Tallow is a rendering (industrial), rendered form of beef or mutton fat, primarily made up of triglycerides.
In industry, tallow is not strictly defined as beef or mutton fat. In this context, tallow is animal fat that conforms to certain techn ...
are used to make candle
A candle is an ignitable wick embedded in wax, or another flammable solid substance such as tallow, that provides light, and in some cases, a fragrance. A candle can also provide heat or a method of keeping time.
A person who makes candles i ...
s, used for lighting and decoration. Another fuel type used in candle manufacturing includes soy
The soybean, soy bean, or soya bean (''Glycine max'') is a species of legume native to East Asia, widely grown for its edible bean, which has numerous uses.
Traditional unfermented food uses of soybeans include soy milk, from which tofu and ...
. Soy wax is made by the hydrogenation process using soybean oil.
Wax products
Waxes are used as finishes and coatings for wood products. Beeswax is frequently used as a lubricant on drawer slides where wood to wood contact occurs.
Other uses
Sealing wax
Sealing wax is a wax material of a seal which, after melting, hardens quickly (to paper, parchment, ribbons and wire, and other material) forming a bond that is difficult to separate without noticeable tampering. Wax is used to verify something su ...
was used to close important documents in the Middle Ages
In the history of Europe, the Middle Ages or medieval period lasted approximately from the late 5th to the late 15th centuries, similar to the post-classical period of global history. It began with the fall of the Western Roman Empire a ...
. Wax tablet
A wax tablet is a tablet made of wood and covered with a layer of wax, often linked loosely to a cover tablet, as a "double-leaved" diptych. It was used as a reusable and portable writing surface in Antiquity and throughout the Middle Ages. C ...
s were used as writing surfaces. There were different types of wax in the Middle Ages, namely four kinds of wax (Ragusan Ragusan may refer to:
* citizen of the Republic of Ragusa
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, population_estimate ...
, Montenegro
)
, image_map = Europe-Montenegro.svg
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, official_languages = M ...
, Byzantine
The Byzantine Empire, also referred to as the Eastern Roman Empire or Byzantium, was the continuation of the Roman Empire primarily in its eastern provinces during Late Antiquity and the Middle Ages, when its capital city was Constantinopl ...
, and Bulgaria
Bulgaria (; bg, България, Bǎlgariya), officially the Republic of Bulgaria,, ) is a country in Southeast Europe. It is situated on the eastern flank of the Balkans, and is bordered by Romania to the north, Serbia and North Macedon ...
n), "ordinary" waxes from Spain
, image_flag = Bandera de España.svg
, image_coat = Escudo de España (mazonado).svg
, national_motto = ''Plus ultra'' (Latin)(English: "Further Beyond")
, national_anthem = (English: "Royal March")
, i ...
, Poland
Poland, officially the Republic of Poland, is a country in Central Europe. It is divided into 16 administrative provinces called voivodeships, covering an area of . Poland has a population of over 38 million and is the fifth-most populous ...
, and Riga
Riga (; lv, Rīga , liv, Rīgõ) is the capital and largest city of Latvia and is home to 605,802 inhabitants which is a third of Latvia's population. The city lies on the Gulf of Riga at the mouth of the Daugava river where it meets the Ba ...
, unrefined waxes and colored waxes (red, white, and green). Waxes are used to make wax paper
Waxed paper (also wax paper, waxpaper, or paraffin paper) is paper that has been made moisture-proof and grease-proof through the application of wax.
The practice of oiling parchment or paper in order to make it semi-translucent or moisture-pro ...
, impregnating and coating paper and card to waterproof it or make it resistant to staining, or to modify its surface properties. Waxes are also used in shoe polish
Shoe polish (or boot polish) is a waxy paste, cream, or liquid that is used to polish, shine, and waterproof leather shoes or boots to extend the footwear's life and restore its appearance. Shoe polishes are distinguished by their textures, ...
es, wood polish
Wood finishing refers to the process of refining or protecting a wooden surface, especially in the production of furniture where typically it represents between 5 and 30% of manufacturing costs.
Finishing is the final step of the manufacturing ...
es, and automotive polishes, as mold release agent
A release agent (also mold release agent, release coating, or mold release coating) is a chemical used to prevent other materials from bonding to surfaces. It can provide a solution in processes involving mold release, die-cast release, plastic ...
s in mold making, as a coating for many cheese
Cheese is a dairy product produced in wide ranges of flavors, textures, and forms by coagulation of the milk protein casein. It comprises proteins and fat from milk, usually the milk of cows, buffalo, goats, or sheep. During production, ...
s, and to waterproof
Waterproofing is the process of making an object or structure waterproof or water-resistant so that it remains relatively unaffected by water or resisting the ingress of water under specified conditions. Such items may be used in wet environme ...
leather and fabric. Wax has been used since antiquity as a temporary, removable model in lost-wax casting
Lost-wax casting (also called "investment casting", "precision casting", or ''cire perdue'' which has been adopted into English from the French, ) is the process by which a duplicate metal sculpture (often silver, gold, brass, or bronze) is ...
of gold
Gold is a chemical element with the symbol Au (from la, aurum) and atomic number 79. This makes it one of the higher atomic number elements that occur naturally. It is a bright, slightly orange-yellow, dense, soft, malleable, and ductile met ...
, silver
Silver is a chemical element with the Symbol (chemistry), symbol Ag (from the Latin ', derived from the Proto-Indo-European wikt:Reconstruction:Proto-Indo-European/h₂erǵ-, ''h₂erǵ'': "shiny" or "white") and atomic number 47. A soft, whi ...
and other materials.
Wax with colorful pigments added has been used as a medium in encaustic painting
Encaustic painting, also known as hot wax painting, is a form of painting that involves a heated wax medium to which colored pigments have been added. The molten mix is applied to a surface—usually prepared wood, though canvas and other mat ...
, and is used today in the manufacture of crayon
A crayon (or wax pastel) is a stick of pigmented wax used for writing or drawing. Wax crayons differ from pastels, in which the pigment is mixed with a dry binder such as gum arabic, and from oil pastels, where the binder is a mixture of wax an ...
s, china markers and colored pencil
A pencil () is a writing or drawing implement with a solid pigment core in a protective casing that reduces the risk of core breakage, and keeps it from marking the user's hand.
Pencils create marks by physical abrasion, leaving a trail ...
s. Carbon paper
Carbon paper (originally carbonic paper) consists of sheets of paper which create one or more copies simultaneously with the creation of an original document when inscribed by a typewriter or ballpoint pen.
History
In 1801, Pellegrino Turri, ...
, used for making duplicate typewritten
A typewriter is a mechanical or electromechanical machine for typing characters. Typically, a typewriter has an array of keys, and each one causes a different single character to be produced on paper by striking an inked ribbon selective ...
documents was coated with carbon black
Carbon black (subtypes are acetylene black, channel black, furnace black, lamp black and thermal black) is a material produced by the incomplete combustion of coal and coal tar, vegetable matter, or petroleum products, including fuel oil, fluid ...
suspended in wax, typically montan wax
Montan wax, also known as lignite wax or OP wax, is a hard wax obtained by solvent extraction of certain types of lignite or brown coal. Commercially viable deposits exist in only a few locations, including Amsdorf, Germany, and in the Ione Ba ...
, but has largely been superseded by photocopier
A photocopier (also called copier or copy machine, and formerly Xerox machine, the generic trademark) is a machine that makes copies of documents and other visual images onto paper or plastic film quickly and cheaply. Most modern photocopiers u ...
s and computer printer
In computing, a printer is a peripheral machine which makes a persistent representation of graphics or text, usually on paper. While most output is human-readable, bar code printers are an example of an expanded use for printers. Differ ...
s. In another context, lipstick
Lipstick is a cosmetic product used to apply coloration and texture to lips, often made of wax and oil. Different pigments are used to produce color, and minerals such as silica may be used to provide texture. The use of lipstick dates back to ...
and mascara
Mascara is a cosmetic commonly used to enhance the upper and lower eyelashes. It is used to darken, thicken, lengthen, and/or define the eyelashes. Normally in one of three forms—liquid, powder, or cream—the modern mascara product has vario ...
are blends of various fats and waxes colored with pigments, and both beeswax
Beeswax (''cera alba'') is a natural wax produced by honey bees of the genus ''Apis''. The wax is formed into scales by eight wax-producing glands in the abdominal segments of worker bees, which discard it in or at the hive. The hive workers ...
and lanolin
Lanolin (from Latin 'wool', and 'oil'), also called wool yolk, wool wax, or wool grease, is a wax secreted by the sebaceous glands of wool-bearing animals. Lanolin used by humans comes from domestic sheep breeds that are raised specifically fo ...
are used in other cosmetics
Cosmetics are constituted mixtures of chemical compounds derived from either natural sources, or synthetically created ones. Cosmetics have various purposes. Those designed for personal care and skin care can be used to cleanse or protect ...
. Ski wax
Ski wax is a material applied to the bottom of snow runners, including skis, snowboards, and toboggans, to improve their coefficient of friction performance under varying snow conditions. The two main types of wax used on skis are glide waxes and ...
is used in skiing
Skiing is the use of skis to glide on snow. Variations of purpose include basic transport, a recreational activity, or a competitive winter sport. Many types of competitive skiing events are recognized by the International Olympic Committee (IO ...
and snowboarding
Snowboarding is a recreational and competitive activity that involves descending a snow-covered surface while standing on a snowboard that is almost always attached to a rider's feet. It features in the Winter Olympic Games and Winter Paralympi ...
. Also, the sports of surfing and skateboarding
Skateboarding is an extreme sport, action sport originating in the United States that involves riding and performing tricks using a skateboard, as well as a recreational activity, an art form, an entertainment industry Profession, job, and a ...
often use wax to enhance the performance.
Some waxes are considered food-safe and are used to coat wooden cutting boards and other items that come into contact with food. Beeswax or coloured synthetic wax is used to decorate Easter egg
Easter eggs, also called Paschal eggs, are eggs that are decorated for the Christian feast of Easter, which celebrates the resurrection of Jesus. As such, Easter eggs are common during the season of Eastertide (Easter season). The oldest tr ...
s in Romania
Romania ( ; ro, România ) is a country located at the crossroads of Central Europe, Central, Eastern Europe, Eastern, and Southeast Europe, Southeastern Europe. It borders Bulgaria to the south, Ukraine to the north, Hungary to the west, S ...
, Ukraine
Ukraine ( uk, Україна, Ukraïna, ) is a country in Eastern Europe. It is the second-largest European country after Russia, which it borders to the east and northeast. Ukraine covers approximately . Prior to the ongoing Russian inv ...
, Poland
Poland, officially the Republic of Poland, is a country in Central Europe. It is divided into 16 administrative provinces called voivodeships, covering an area of . Poland has a population of over 38 million and is the fifth-most populous ...
, Lithuania
Lithuania (; lt, Lietuva ), officially the Republic of Lithuania ( lt, Lietuvos Respublika, links=no ), is a country in the Baltic region of Europe. It is one of three Baltic states and lies on the eastern shore of the Baltic Sea. Lithuania ...
and the Czech Republic
The Czech Republic, or simply Czechia, is a landlocked country in Central Europe. Historically known as Bohemia, it is bordered by Austria to the south, Germany to the west, Poland to the northeast, and Slovakia to the southeast. The ...
. Paraffin wax
Paraffin wax (or petroleum wax) is a soft colorless solid derived from petroleum, coal, or oil shale that consists of a mixture of hydrocarbon molecules containing between 20 and 40 carbon atoms. It is solid at room temperature and begins to m ...
is used in making chocolate covered sweets.
Wax is also used in wax bullet
A wax bullet is a non-lethal projectile made of wax material — often paraffin wax or some mixture of waxes and other substances that produce the desired consistency — that mimics the external ballistics but not the terminal effects of real bu ...
s, which are used as simulation aids.
Specific examples
Animal waxes
* Beeswax
Beeswax (''cera alba'') is a natural wax produced by honey bees of the genus ''Apis''. The wax is formed into scales by eight wax-producing glands in the abdominal segments of worker bees, which discard it in or at the hive. The hive workers ...
- produced by honey bee
A honey bee (also spelled honeybee) is a eusocial flying insect within the genus ''Apis'' of the bee clade, all native to Afro-Eurasia. After bees spread naturally throughout Africa and Eurasia, humans became responsible for the current co ...
s
* Chinese wax Chinese wax is a white to yellowish-white, gelatinous, crystalline water-insoluble substance obtained from the wax secreted by certain insects.
It resembles spermaceti but is harder, more friable, and with a higher melting point. Two scale insects ...
- produced by the scale insect
Scale insects are small insects of the order Hemiptera, suborder Sternorrhyncha. Of dramatically variable appearance and extreme sexual dimorphism, they comprise the infraorder Coccomorpha which is considered a more convenient grouping than the ...
''Ceroplastes ceriferus''
* Lanolin
Lanolin (from Latin 'wool', and 'oil'), also called wool yolk, wool wax, or wool grease, is a wax secreted by the sebaceous glands of wool-bearing animals. Lanolin used by humans comes from domestic sheep breeds that are raised specifically fo ...
(wool wax) - from the sebaceous gland
A sebaceous gland is a microscopic exocrine gland in the skin that opens into a hair follicle to secrete an oily or waxy matter, called sebum, which lubricates the hair and skin of mammals. In humans, sebaceous glands occur in the greatest number ...
s of sheep
Sheep or domestic sheep (''Ovis aries'') are domesticated, ruminant mammals typically kept as livestock. Although the term ''sheep'' can apply to other species in the genus ''Ovis'', in everyday usage it almost always refers to domesticated s ...
* Shellac
Shellac () is a resin secreted by the female lac bug on trees in the forests of India and Thailand. It is processed and sold as dry flakes and dissolved in alcohol to make liquid shellac, which is used as a brush-on colorant, food glaze and ...
wax - from the lac insect
''Kerriidae'' is a family of scale insects, commonly known as lac insects or lac scales. Some members of the genera ''Metatachardia'', ''Tachardiella'', ''Austrotacharidia'', ''Afrotachardina'', ''Tachardina'', and ''Kerria'' are raised for comme ...
''Kerria lacca
''Kerria lacca'' is a species of insect in the family Kerriidae, the lac insects. These are in the superfamily Coccoidea, the scale insects. This species is perhaps the most commercially important lac insect, being a main source of lac, a resin w ...
''
* Spermaceti
Spermaceti is a waxy substance found in the head cavities of the sperm whale (and, in smaller quantities, in the oils of other whales). Spermaceti is created in the spermaceti organ inside the whale's head. This organ may contain as much as of ...
- from the head cavities and blubber of the sperm whale
The sperm whale or cachalot (''Physeter macrocephalus'') is the largest of the toothed whales and the largest toothed predator. It is the only living member of the genus ''Physeter'' and one of three extant species in the sperm whale famil ...
Vegetable waxes
* Bayberry wax
Bayberry wax is an aromatic green vegetable wax. It is removed from the surface of the fruit of the bayberry (wax-myrtle) shrub (ex. ''Myrica cerifera'') by boiling the fruits in water and skimming the wax from the surface of the water. It is made ...
- from the surface wax of the fruits
In botany, a fruit is the seed-bearing structure in flowering plants that is formed from the ovary after flowering.
Fruits are the means by which flowering plants (also known as angiosperms) disseminate their seeds. Edible fruits in particula ...
of the bayberry shrub, ''Myrica faya
''Myrica faya'' (firetree, faya or haya; syn. ''Morella faya'' (Ait.) Wilbur) is a species of ''Myrica'', native to Macaronesia (the Azores, Madeira, and the Canary Islands), and possibly also western coastal mainland Portugal.
Description
It i ...
''
* Candelilla wax
Candelilla wax is a wax derived from the leaves of the small Candelilla shrub native to northern Mexico and the southwestern United States, '' Euphorbia antisyphilitica'', from the family ''Euphorbiaceae''. It is yellowish-brown, hard, brittle, a ...
- from the Mexican shrubs ''Euphorbia cerifera
''Euphorbia antisyphilitica'' is a species of flowering plant in the spurge family Euphorbiaceae. It is native to the Trans-Pecos of Texas and southern New Mexico in the United States as well as Chihuahua, Coahuila, Hidalgo, and Querétaro in M ...
'' and ''Euphorbia antisyphilitica
''Euphorbia antisyphilitica'' is a species of flowering plant in the spurge family Euphorbiaceae. It is native to the Trans-Pecos of Texas and southern New Mexico in the United States as well as Chihuahua, Coahuila, Hidalgo, and Querétaro in Me ...
''
* Carnauba wax
Carnauba (; pt, carnaúba ), also called Brazil wax and palm wax, is a wax of the leaves of the carnauba palm ''Copernicia prunifera'' (synonym: ''Copernicia cerifera''), a plant native to and grown only in the northeastern Brazilian states of C ...
- from the leaves of the Carnauba palm, '' Copernicia cerifera''
* Castor wax
Castor wax, also called hydrogenated castor oil, is an opaque, white vegetable wax. It is produced by the hydrogenation of pure castor oil often in the presence of a nickel catalyst to increase the rate of reaction. The hydrogenation of castor oil ...
- catalytically hydrogenated castor oil
Castor oil is a vegetable oil pressed from castor beans.
It is a colourless or pale yellow liquid with a distinct taste and odor. Its boiling point is and its density is 0.961 g/cm3. It includes a mixture of triglycerides in which about ...
* Esparto wax - a byproduct of making paper from esparto grass
Esparto, halfah grass, or esparto grass is a fiber produced from two species of perennial grasses of north Africa, Spain and Portugal. It is used for crafts, such as cords, basketry, and espadrilles. ''Stipa tenacissima'' and ''Lygeum spartum' ...
, (''Macrochloa tenacissima'')
* Japan wax Japan wax (木蝋 ''Mokurō''), also known as sumac wax, sumach wax, vegetable wax, China green tallow, and Japan tallow, is a pale-yellow, waxy, water-insoluble solid with a gummy feel, obtained from the berries of certain sumacs native to Japan an ...
- a vegetable triglyceride
A triglyceride (TG, triacylglycerol, TAG, or triacylglyceride) is an ester derived from glycerol and three fatty acids (from ''tri-'' and ''glyceride'').
Triglycerides are the main constituents of body fat in humans and other vertebrates, as w ...
(not a true wax), from the berries of ''Rhus'' and ''Toxicodendron'' species
* Jojoba oil
Jojoba oil is the liquid produced in the seed of the ''Simmondsia chinensis'' ( jojoba) plant, a shrub, which is native to southern Arizona, southern California, and northwestern Mexico. The oil makes up approximately 50% of the jojoba seed by w ...
- a liquid wax ester
A wax ester (WE) is an ester of a fatty acid and a fatty alcohol. Wax esters comprise the main components of three commercially important waxes: carnauba wax, candelilla wax, and beeswax..
Wax esters are formed by combining one fatty acid with o ...
, from the seed of ''Simmondsia chinensis''.
* Ouricury wax
Ouricury wax is a brown-colored wax obtained from the leaves of a Brazilian feather palm '' Syagrus coronata'' by scraping the leaf surface.
Harvesting
Harvesting ouricury wax is more difficult than harvesting carnauba wax, as ouricury wax does n ...
- from the Brazilian feather palm, ''Syagrus coronata
''Syagrus coronata'', commonly known as the ouricury palm, aricuri palm, or licuri palm, is a species of palm tree that is native to eastern Brazil, ranging from the southern part of the state of Pernambuco, into the state of Bahia, south to the ...
''.
* Rice bran wax - obtained from rice
Rice is the seed of the grass species ''Oryza sativa'' (Asian rice) or less commonly ''Oryza glaberrima
''Oryza glaberrima'', commonly known as African rice, is one of the two domesticated rice species. It was first domesticated and grown i ...
bran
Bran, also known as miller's bran, is the hard outer layers of Cereal, cereal grain. It consists of the combined aleurone and pericarp. Corn (maize) bran also includes the pedicel (tip cap). Along with cereal germ, germ, it is an integral pa ...
(''Oryza sativa'')
* Soy wax
Soy candles are candles made from soy wax, which is a processed form of soybean oil. They are usually container candles, because soy wax typically has a lower melting point than traditional waxes, but can also be made into pillar candles if ce ...
- from soybean oil
* Tallow Tree wax - from the seeds of the tallow tree ''Triadica sebifera''.
Mineral waxes
* Ceresin
Ceresin (also cerin, cerasin, cerosin, ceresin wax or ceresine) is a wax derived from ozokerite by a purifying process.
The purifying process of the ozokerite commonly comprises a treatment with heat and sulfuric acid, but other processes are al ...
waxes
* Montan wax
Montan wax, also known as lignite wax or OP wax, is a hard wax obtained by solvent extraction of certain types of lignite or brown coal. Commercially viable deposits exist in only a few locations, including Amsdorf, Germany, and in the Ione Ba ...
- extracted from lignite
Lignite, often referred to as brown coal, is a soft, brown, combustible, sedimentary rock formed from naturally compressed peat. It has a carbon content around 25–35%, and is considered the lowest rank of coal due to its relatively low heat ...
and brown coal
Lignite, often referred to as brown coal, is a soft, brown, combustible, sedimentary rock formed from naturally compressed peat. It has a carbon content around 25–35%, and is considered the lowest rank of coal due to its relatively low heat ...
* Ozocerite - found in lignite beds
* Peat waxes
Petroleum waxes
* Paraffin wax
Paraffin wax (or petroleum wax) is a soft colorless solid derived from petroleum, coal, or oil shale that consists of a mixture of hydrocarbon molecules containing between 20 and 40 carbon atoms. It is solid at room temperature and begins to m ...
- made of long-chain alkane
In organic chemistry, an alkane, or paraffin (a historical trivial name that also has other meanings), is an acyclic saturated hydrocarbon. In other words, an alkane consists of hydrogen and carbon atoms arranged in a tree structure in which ...
hydrocarbon
In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or ex ...
s
* Microcrystalline wax
Microcrystalline waxes are a type of wax produced by de-oiling petrolatum, as part of the petroleum refining process. In contrast to the more familiar paraffin wax which contains mostly unbranched alkanes, microcrystalline wax contains a higher per ...
- with very fine crystalline structure
See also
* Slip melting point
* Wax acid
{{Expand German, Wachssäuren, date=June 2016
The wax acids are a subgroup of saturated unbranched alkanoic acids. The frontier between fatty acids and wax acids is fluid. It often begins at 22 carbon atoms.
The members are:
* Behenic acid C-22
* ...
* Wax argument
The wax argument or the ball of wax example is a thought experiment that René Descartes created in the second of his ''Meditations on First Philosophy''. He devised it to analyze what properties are essential for bodies, show how uncertain our kno ...
or the "ball of wax example", is a thought experiment originally articulated by Renė Descartes.
References
External links
Waxes
{{Authority control
Petroleum products
Plant products
Animal products
Lipids
Esters
Soft matter