Water Subsidies

Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as a solvent). It is vital for all known forms of life, despite not providing food, energy or organic micronutrients. Its chemical formula, H₂O, indicates that each of its molecules contains one oxygen and two hydrogen atoms, connected by covalent bonds. The hydrogen atoms are attached to the oxygen atom at an angle of 104.45°. "Water" is also the name of the liquid state of H₂O at standard temperature and pressure.

A number of natural states of water exist. It forms precipitation in the form of rain and aerosols in the form of fog. Clouds consist of suspended droplets of water and ice, its solid state. When finely divided, crystalline ice may precipitate in the form of snow. The gaseous state of water is steam or water vapor.

Water covers about 71% of the Earth's surface, with seas and oceans making up most of the water volume on earth (about 96.5%). Small portions of water occur as groundwater (1.7%), in the glaciers and the ice caps of Antarctica and Greenland (1.7%), and in the air as vapor, clouds (consisting of ice and liquid water suspended in air), and precipitation (0.001%). Water moves continually through the water cycle of evaporation, transpiration (evapotranspiration), condensation, precipitation, and runoff, usually reaching the sea.

Water plays an important role in the world economy. Approximately 70% of the freshwater used by humans goes to agriculture. Fishing in salt and fresh water bodies has been, and continues to be a major source of food for many parts of the world, providing 6.5% of global protein. Much of the long-distance trade of commodities (such as oil, natural gas, and manufactured products) is transported by boats through seas, rivers, lakes, and canals. Large quantities of water, ice, and steam are used for cooling and heating, in industry and homes. Water is an excellent solvent for a wide variety of substances both mineral and organic; as such it is widely used in industrial processes, and in cooking and washing. Water, ice and snow are also central to many sports and other forms of entertainment, such as swimming, pleasure boating, boat racing, surfing, sport fishing, diving, ice skating and skiing.

Etymology

The word ''water'' comes from Old English , from Proto-Germanic *''watar'' (source also of Old Saxon , Old Frisian , Dutch , Old High German , German , , Gothic (), from Proto-Indo-European *''wod-or'', suffixed form of root *''wed-'' ("water"; "wet"). Also cognate, through the Indo-European root, with Greek (, from Ancient Greek , ''hýdōr,'' whence English "hydro-"), Russian (), Irish , and Albanian .

History

Properties

Water () is a polar inorganic compound. At room temperature it is a tasteless and odorless liquid, nearly colorless with a hint of blue. This simplest hydrogen chalcogenide is by far the most studied chemical compound and is described as the "universal solvent" for its ability to dissolve many substances. This allows it to be the "solvent of life": indeed, water as found in nature almost always includes various dissolved substances, and special steps are required to obtain chemically pure water. Water is the only common substance to exist as a solid, liquid, and gas in normal terrestrial conditions.

States

Along with ''oxidane'', ''water'' is one of the two official names for the chemical compound ; it is also the liquid phase of . The other two common states of matter of water are the solid phase, ice, and the gaseous phase, water vapor or steam. The addition or removal of heat can cause phase transitions: freezing (water to ice), melting (ice to water), vaporization (water to vapor), condensation (vapor to water), sublimation (ice to vapor) and deposition (vapor to ice).

Density

Water differs from most liquids in that it becomes less dense as it freezes. In 1 atm pressure, it reaches its maximum density of at , or almost at almost . The density of ice is , an expansion of 9%. This expansion can exert enormous pressure, bursting pipes and cracking rocks.

In a lake or ocean, water at sinks to the bottom, and ice forms on the surface, floating on the liquid water. This ice insulates the water below, preventing it from freezing solid. Without this protection, most aquatic organisms residing in lakes would perish during the winter.

Magnetism

Water is a diamagnetic material. Though interaction is weak, with superconducting magnets it can attain a notable interaction.

Phase transitions

At a pressure of one atmosphere (atm), ice melts or water freezes (solidifies) at ) and water boils or vapor condenses at . However, even below the boiling point, water can change to vapor at its surface by evaporation (vaporization throughout the liquid is known as boiling). Sublimation and deposition also occur on surfaces. For example, frost is deposited on cold surfaces while snowflakes form by deposition on an aerosol particle or ice nucleus. In the process of freeze-drying, a food is frozen and then stored at low pressure so the ice on its surface sublimates.

The melting and boiling points depend on pressure. A good approximation for the rate of change of the melting temperature with pressure is given by the Clausius–Clapeyron relation:

$\frac = \frac,$

where $v_\text$ and $v_\text$ are the molar volumes of the liquid and solid phases, and $L_\text$ is the molar latent heat of melting. In most substances, the volume increases when melting occurs, so the melting temperature increases with pressure. However, because ice is less dense than water, the melting temperature decreases. In glaciers, pressure melting can occur under sufficiently thick volumes of ice, resulting in subglacial lakes.

The Clausius-Clapeyron relation also applies to the boiling point, but with the liquid/gas transition the vapor phase has a much lower density than the liquid phase, so the boiling point increases with pressure. Water can remain in a liquid state at high temperatures in the deep ocean or underground. For example, temperatures exceed in Old Faithful, a geyser in Yellowstone National Park. In hydrothermal vents, the temperature can exceed .

At sea level, the boiling point of water is . As atmospheric pressure decreases with altitude, the boiling point decreases by 1 °C every 274 meters. High-altitude cooking takes longer than sea-level cooking. For example, at , cooking time must be increased by a fourth to achieve the desired result. (Conversely, a pressure cooker can be used to decrease cooking times by raising the boiling temperature.)
In a vacuum, water will boil at room temperature.

Triple and critical points

On a pressure/temperature phase diagram