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Wad is an old mining term for any black manganese
oxide An oxide () is a chemical compound that contains at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion of oxygen, an O2– (molecular) ion. with oxygen in the oxidation state of −2. Most of the E ...
or hydroxide mineral-rich rock in the oxidized zone of various ore deposits. Typically closely associated with various iron oxides. Specific mineral varieties include
pyrolusite Pyrolusite is a mineral consisting essentially of manganese dioxide ( Mn O2) and is important as an ore of manganese.. It is a black, amorphous appearing mineral, often with a granular, fibrous, or columnar structure, sometimes forming reniform ...
, lithiophorite,
nsutite Nsutite is a manganese oxide mineral with formula: ( Mn4+1−xMn2+x O2-2x(O H)2x where x = 0.06-0.07).http://www.webmineral.com/data/Nsutite.shtml Webmineral data It is found in most large manganese deposits and was first discovered in Nsuta, Ghan ...
, takanelite and vernadite.Wad on Mindat.org
/ref> Wad can be considered to be the manganese equivalent to the iron
mineraloid A mineraloid is a naturally occurring mineral-like substance that does not demonstrate crystallinity. Mineraloids possess chemical compositions that vary beyond the generally accepted ranges for specific minerals. For example, obsidian is an amor ...
limonite Limonite () is an iron ore consisting of a mixture of hydrated iron(III) oxide-hydroxides in varying composition. The generic formula is frequently written as FeO(OH)·H2O, although this is not entirely accurate as the ratio of oxide to hydroxid ...
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References

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External links

{{EB1911 poster, Wad Oxide minerals