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Vantablack is a brand name for a class of super-black coatings with total hemispherical reflectances (THR) below 1.5% in the visible spectrum. The coatings were invented by Ben Jensen, who first publicly unveiled them in July 2014, and commercialised by the scientific team from Surrey NanoSystems. The original Vantablack coating was grown from a chemical vapour deposition process (CVD) and is claimed to be the "world's darkest material", absorbing up to 99.965% of visible light perpendicular to the material at 663 nm. The coatings are unique in that they are not only super-black but that they retain uniform light absorption from almost all viewing angles. Original CVD Vantablack is no longer manufactured for commercial applications as it has been superseded by Vantablack spray coatings that offer similar optical performance in key parts of the electromagnetic spectrum. The name is a combination of the acronym ''VANTA'' ( vertically aligned nanotube arrays) and the color ''black''. Vantablack coatings are very costly, and cannot be supplied to private individuals, and samples are only available for applications considered "valid" by the supplier.


Properties

CVD Vantablack is composed of a forest of vertical
carbon nanotubes A scanning tunneling microscopy image of a single-walled carbon nanotube Rotating single-walled zigzag carbon nanotube A carbon nanotube (CNT) is a tube made of carbon with diameters typically measured in nanometers. ''Single-wall carbon na ...
"grown" on a substrate using a modified
chemical vapor deposition Chemical vapor deposition (CVD) is a vacuum deposition method used to produce high quality, and high-performance, solid materials. The process is often used in the semiconductor industry to produce thin films. In typical CVD, the wafer (subst ...
process. When light strikes Vantablack, instead of bouncing off, it becomes trapped and is continually deflected amongst the tubes, eventually becoming absorbed and dissipating as heat. CVD Vantablack was an improvement over similar substances developed at the time. Vantablack absorbs up to 99.965% of visible light and can be created at .
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had previously developed a similar substance that was grown at , so it required materials to be more heat resistant than Vantablack. Darker materials are possible: in 2019, MIT engineers developed a CVD material which reflects a tenth of the amount of light that Vantablack reflects. The
outgassing Outgassing (sometimes called offgassing, particularly when in reference to indoor air quality) is the release of a gas that was dissolved, trapped, frozen, or absorbed in some material. Outgassing can include sublimation and evaporation (which ...
and particle fallout levels of Vantablack are low compared to similar substances, which makes it more commercially viable. Vantablack also has greater resistance to mechanical vibration, and has greater thermal stability.


Development

Early development was carried out at the National Physical Laboratory in the UK; the term "Vanta" was coined some time later. Vertically aligned nanotube arrays are sold by several firms, including NanoLab, Santa Barbara Infrared and others. The Vantablack name is trademarked by Surrey NanoSystems Limited,Surrey NanoSystems: Home
/ref> and has been referenced in three patents registered in the
United States Patent and Trademark Office The United States Patent and Trademark Office (USPTO) is an agency in the U.S. Department of Commerce that serves as the national patent office and trademark registration authority for the United States. The USPTO's headquarters are in Alex ...
.


Applications

As one of the darkest materials, Vantablack has many potential applications, such as preventing
stray light Stray light is light in an optical system, which was not intended in the design. The light may be from the intended source, but follow paths other than intended, or it may be from a source other than the intended source. This light will often set a ...
from entering telescopes, and improving the performance of
infrared camera Infrared (IR), sometimes called infrared light, is electromagnetic radiation (EMR) with wavelengths longer than those of visible light. It is therefore invisible to the human eye. IR is generally understood to encompass wavelengths from around ...
s both on Earth and in space. In addition to directly growing aligned
carbon nanotube A scanning tunneling microscopy image of a single-walled carbon nanotube Rotating single-walled zigzag carbon nanotube A carbon nanotube (CNT) is a tube made of carbon with diameters typically measured in nanometers. ''Single-wall carbon na ...
s, Vantablack is made into two sprayable paints with randomly oriented nanotubes, Vantablack S-VIS and Vantablack S-IR with better infrared absorption than the former. These paints require a special license, a temperature of 100–280 °C, and vacuum post-processing. Surrey NanoSystems also markets a line of non-nanotube sprayable paints known as Vantablack VBx that are even easier to apply.


Artistic and decorative use

Vantablack S-VIS, a sprayable paint that uses randomly aligned carbon nanotubes and very high levels of absorption from ultraviolet to the terahertz spectrum, has been exclusively licensed to
Anish Kapoor Sir Anish Mikhail Kapoor (born 12 March 1954) is a British-Indian sculptor specializing in installation art and conceptual art. Born in Mumbai, Kapoor attended the elite all-boys Indian boarding school The Doon School, before moving to the UK t ...
's studio for artistic use. Nanolab, a
Waltham, Massachusetts Waltham ( ) is a city in Middlesex County, Massachusetts, United States, and was an early center for the labor movement as well as a major contributor to the American Industrial Revolution. The original home of the Boston Manufacturing Company, ...
-based carbon nanotube manufacturer, partnered with
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artist Jason Chase to release a nanotube-based black paint called Singularity Black. During the first showing of the colour, Chase, alluding to Vantablack, stated that "its possibilities have been stunted by not being available to experiment with", and Singularity Black's release was important to create access. The manufacturer claims that Vantablack is subject to
export control Export control is legislation that regulates the export of goods, software and technology. Some items could potentially be useful for purposes that are contrary to the interest of the exporting country. These items are considered to be ''controlled ...
s by the UK, and due to its physical requirements and thermal characteristics, the original Vantablack is not practical for use in many types of art. Vantablack VBx2, a variant of the non-nanotube Vantablack VBx that is optimized for large area spraying, was used in a "Vantablack pavilion" at the
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. BMW unveiled an X6 concept with Vantablack paint at the
Frankfurt Auto Show The International Motor Show Germany or International Mobility Show Germany, in German known as the ''Internationale Automobil-Ausstellung'' (''IAA'' – International Automobile Exhibition), is one of the world's largest mobility shows. It cons ...
in September 2019; however, the company does not plan on producing the color on production models of the X6. French musician Gesaffelstein used Vantablack VBx2 as part of his stage decoration during his Coachella 2019 performance. RTFKT used Vantablack as a colorway for their sneaker, the RTFKT x Nike Air Force 1 - Genesis, in their Clone X Forging SZN 1 collection. It was previewed in December 2022 and scheduled for release in June 2023.


Commercial production

The first orders were delivered in July 2014. In 2015, production was scaled up to meet demand in the
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and
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sectors.


See also

* * *


References


External links


Surrey NanoSystems
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* {{Anish Kapoor Carbon nanotubes 2014 introductions Shades of black Chemical substances British inventions