Voronkovite is a very rare mineralMindat, Voronkovite, http://www.mindat.org/min-32199.html of the

eudialyte group Eudialyte group is a group of complex trigonal zircono- and, more rarely, titanosilicate minerals with general formula (1)N(2)N(3)N(4)N(5)sub>3 (1a)M(1b)sub>3M(2)3M(4)Z3 i24O72'4X2, where N(1) and N(2) and N(3) and N(5) = Na+ and more rarely H3 ...

with the chemical formula .Khomyakov, A.P., Nechelyustov, G.N., and Rastsvetaeva, R.K., 2010, Voronkovite, , a new mineral species of the eudialyte group from the Lovozero alkaline pluton, Kola Peninsula, Russia. Geology of Ore Deposits 51(8), 750–756 The formula is based on the simplified original one; it does not show the presence of cyclic silicate groups, but two M3- and M4-site silicon atoms are shown separately (basing on the nomenclature of the eudialyte groupJohnsen, O., Ferraris, G., Gault, R.A., Grice, D.G., Kampf, A.R., and Pekov, I.V., 2003. The nomenclature of eudialyte-group minerals. The Canadian Mineralogist 41, 785–794). Voronkovite has lowered symmetry (space group ''R''3, instead of more specific for the group ''R''3''m'' one), similarly to some other eudialyte-group members:

aqualite Aqualite is a very rare mineral of the eudialyte group, with formula (H3O)8(Na,K,Sr)5Ca6Zr3SiSi(Si24O66)(OH)9Cl.Khomyakov, A. P., Nechelyustov, G. N., and Rastsvetaeva, R. K., 2007: Aqualite, a new mineral species of the eudialyte group from the In ...

labyrinthite Labyrinthite is a very rare mineral of the eudialyte group.Mindat, http://www.mindat.org/min-27420.html When compared to other species in the group, its structure is extremely complex - with over 100 sites and about 800 cations and anions - hence ...

oneillite Oneillite is a rare mineral of the eudialyte group with the chemical formula .Mindat, Oneillite, http://www.mindat.org/min-11029.htmlJohnsen, O., Grice, J.D., and Gault, R.A., 1999. Oneillite: a new Ca-deficient and ''REE''-rich member of the eud ...

and raslakite. The specific feature of voronkovite is, among others, strong enrichment in sodium.

Occurrence and association

Voronkovite comes from an ultra-alkaline

pegmatite A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic com ...

of Mt. Alluaiv, Lovozero Massif,

Kola Peninsula sjd, Куэлнэгк нёа̄ррк , image_name= Kola peninsula.png , image_caption= Kola Peninsula as a part of Murmansk Oblast , image_size= 300px , image_alt= , map_image= Murmansk in Russia.svg , map_caption = Location of Murmansk Oblas ...

Russia Russia (, , ), or the Russian Federation, is a List of transcontinental countries, transcontinental country spanning Eastern Europe and North Asia, Northern Asia. It is the List of countries and dependencies by area, largest country in the ...

. It occurs with aegirine, lomonosovite,

manganoneptunite Neptunite is a silicate mineral with the formula K Na2 Li( Fe2+, Mn2+)2 Ti2 Si8 O24. With increasing manganese it forms a series with mangan-neptunite. Watatsumiite is the variety with vanadium replacing the titanium in the formula. It was fi ...

microcline Microcline (KAlSi3O8) is an important igneous rock-forming tectosilicate mineral. It is a potassium-rich alkali feldspar. Microcline typically contains minor amounts of sodium. It is common in granite and pegmatites. Microcline forms during slow ...

nepheline Nepheline, also called nephelite (), is a rock-forming mineral in the feldspathoid groupa silica-undersaturated aluminosilicate, Na3 K Al4 Si4 O16, that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmatites ...

, shkatulkalite,

sodalite Sodalite ( ) is a tectosilicate mineral with the formula , with royal blue varieties widely used as an wikt:ornamental, ornamental gemstone. Although massive sodalite samples are opaque, crystals are usually transparent to translucent. Sodalite i ...

, terskite,

sphalerite Sphalerite (sometimes spelled sphaelerite) is a sulfide mineral with the chemical formula . It is the most important ore of zinc. Sphalerite is found in a variety of deposit types, but it is primarily in Sedimentary exhalative deposits, sedimen ...

and vuonnemite.

Notes on chemistry

Voronkovite has additional impurities, not given in the formula. They include

strontium Strontium is the chemical element with the symbol Sr and atomic number 38. An alkaline earth metal, strontium is a soft silver-white yellowish metallic element that is highly chemically reactive. The metal forms a dark oxide layer when it is ex ...

fluorine Fluorine is a chemical element with the symbol F and atomic number 9. It is the lightest halogen and exists at standard conditions as a highly toxic, pale yellow diatomic gas. As the most electronegative reactive element, it is extremely reacti ...

potassium Potassium is the chemical element with the symbol K (from Neo-Latin ''kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmosphe ...

lanthanum Lanthanum is a chemical element with the symbol La and atomic number 57. It is a soft, ductile, silvery-white metal that tarnishes slowly when exposed to air. It is the eponym of the lanthanide series, a group of 15 similar elements between lantha ...

neodymium Neodymium is a chemical element with the symbol Nd and atomic number 60. It is the fourth member of the lanthanide series and is considered to be one of the rare-earth metals. It is a hard, slightly malleable, silvery metal that quickly tarnishes i ...

(at the Mn site),

niobium Niobium is a chemical element with chemical symbol Nb (formerly columbium, Cb) and atomic number 41. It is a light grey, crystalline, and ductile transition metal. Pure niobium has a Mohs hardness rating similar to pure titanium, and it has sim ...

, and minor

hafnium Hafnium is a chemical element with the symbol Hf and atomic number 72. A lustrous, silvery gray, tetravalent transition metal, hafnium chemically resembles zirconium and is found in many zirconium minerals. Its existence was predicted by Dmitri M ...

and

aluminium Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...

References

Cyclosilicates Sodium minerals Cerium minerals Calcium minerals Manganese minerals Iron minerals Zirconium minerals Trigonal minerals Minerals in space group 146 Minerals described in 2009 {{silicate-mineral-stub