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Volcanic glass is the
amorphous
In condensed matter physics and materials science, an amorphous solid (or non-crystalline solid, glassy solid) is a solid that lacks the long-range order that is characteristic of a crystal.
Etymology
The term comes from the Greek ''a'' ("wi ...
(uncrystallized) product of rapidly cooling
magma
Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natural sa ...
. Like all types of
glass
Glass is a non-crystalline, often transparent, amorphous solid that has widespread practical, technological, and decorative use in, for example, window panes, tableware, and optics. Glass is most often formed by rapid cooling (quenching) of ...
, it is a
state of matter
In physics, a state of matter is one of the distinct forms in which matter can exist. Four states of matter are observable in everyday life: solid, liquid, gas, and plasma. Many intermediate states are known to exist, such as liquid crystal ...
intermediate between the closely packed, highly ordered array of a
crystal
A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macro ...
and the highly disordered array of
liquid
A liquid is a nearly incompressible fluid that conforms to the shape of its container but retains a (nearly) constant volume independent of pressure. As such, it is one of the four fundamental states of matter (the others being solid, gas, a ...
. Volcanic glass may refer to the interstitial material, or
matrix
Matrix most commonly refers to:
* ''The Matrix'' (franchise), an American media franchise
** ''The Matrix'', a 1999 science-fiction action film
** "The Matrix", a fictional setting, a virtual reality environment, within ''The Matrix'' (franchis ...
, in an
aphanitic
Aphanites (adj. ''aphanitic''; ) are igneous rocks that are so fine-grained that their component mineral crystals are not visible to the naked eye (in contrast to phanerites, in which the crystals are visible to the unaided eye). This geolog ...
(fine-grained)
volcanic rock
Volcanic rock (often shortened to volcanics in scientific contexts) is a rock formed from lava erupted from a volcano. In other words, it differs from other igneous rock by being of volcanic origin. Like all rock types, the concept of volcanic ...
, or to any of several types of vitreous
igneous rock
Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main The three types of rocks, rock types, the others being Sedimentary rock, sedimentary and metamorphic rock, metamorphic. Igneous rock ...
s.
Origin
Volcanic glass is formed when
magma
Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natural sa ...
is rapidly cooled. Magma rapidly cooled to below its normal crystallization temperature becomes a
supercooled liquid, and, with further rapid cooling, this becomes an amorphous solid. The change from supercooled liquid to glass occurs at a temperature called the glass transition temperature, which depends on both cooling rate and the amount of water dissolved in the magma. Magma rich in silica and poor in dissolved water is most easily cooled rapidly enough to form volcanic glass. As a result,
rhyolite
Rhyolite ( ) is the most silica-rich of volcanic rocks. It is generally glassy or fine-grained (aphanitic) in texture, but may be porphyritic, containing larger mineral crystals (phenocrysts) in an otherwise fine-grained groundmass. The mineral ...
magmas, which are high in silica, can produced
tephra
Tephra is fragmental material produced by a volcanic eruption regardless of composition, fragment size, or emplacement mechanism.
Volcanologists also refer to airborne fragments as pyroclasts. Once clasts have fallen to the ground, they rem ...
composed entirely of volcanic glass and may also form glassy
lava flows.
[ ]Ash
Ash or ashes are the solid remnants of fires. Specifically, ''ash'' refers to all non-aqueous, non- gaseous residues that remain after something burns. In analytical chemistry, to analyse the mineral and metal content of chemical samples, ash ...
-flow tuff
Tuff is a type of rock made of volcanic ash ejected from a vent during a volcanic eruption. Following ejection and deposition, the ash is lithified into a solid rock. Rock that contains greater than 75% ash is considered tuff, while rock cont ...
s typically consist of countless microscopic shards of volcanic glass. Basalt
Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...
, which is low in silica, forms glass only with difficulty, so that basalt tephra almost always contains at least some crystalline material (''quench crystals''). The glass transition temperature of basalt is about .[
The mechanisms controlling formation of volcanic glass are further illustrated by the two forms of basaltic glass, ]tachylite
Tachylite ( ; also spelled tachylyte) is a form of basaltic volcanic glass. This glass is formed naturally by the rapid cooling of molten basalt. It is a type of mafic igneous rock that is decomposable by acids and readily fusible. The color ...
and sideromelane
Sideromelane is a vitreous basaltic volcanic glass, usually occurring in palagonite tuff, for which it is characteristic. It is a less common form of tachylite, with which it usually occurs together; however it lacks the iron oxide crystals di ...
. Tachylite is opaque to transmitted light because of the abundance of tiny oxide mineral crystals suspended in the glass. Sideromelane is partially transparent because it contains much fewer crystals. Sideromelane is abundant only in eruptions where basalt magma has been very rapidly cooled by contact with water, such as phreatomagmatic eruptions
Phreatomagmatic eruptions are volcanic eruptions resulting from interaction between magma and water. They differ from exclusively magmatic eruptions and phreatic eruptions. Unlike phreatic eruptions, the products of phreatomagmatic eruptions conta ...
. Basaltic volcanic glass is also present in pillow lava
Pillow lavas are lavas that contain characteristic pillow-shaped structures that are attributed to the extrusion of the lava underwater, or ''subaqueous extrusion''. Pillow lavas in volcanic rock are characterized by thick sequences of discont ...
s.
Of the cooling mechanisms responsible for forming volcanic glass, the most effective is quenching by water, followed by cooling by entrained air in an eruption column
An eruption column or eruption plume is a cloud of super-heated Volcanic ash, ash and tephra suspended in volcanic gas, gases emitted during an explosive volcanic eruption. The volcanic materials form a vertical column or Plume (fluid dynamics), ...
. The least effective mechanism is cooling at the bottom of a flow in contact with the ground.
Types
Most commonly, ''volcanic glass'' refers to ''obsidian
Obsidian () is a naturally occurring volcanic glass formed when lava extrusive rock, extruded from a volcano cools rapidly with minimal crystal growth. It is an igneous rock.
Obsidian is produced from felsic lava, rich in the lighter elements s ...
'', a rhyolitic
Rhyolite ( ) is the most silica-rich of volcanic rocks. It is generally glassy or fine-grained (aphanitic) in texture, but may be porphyritic, containing larger mineral crystals (phenocrysts) in an otherwise fine-grained groundmass. The mineral ...
glass with high silica
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is ...
(SiO2) content.
Other types of volcanic glass include the following:
* Pumice
Pumice (), called pumicite in its powdered or dust form, is a volcanic rock that consists of highly vesicular rough-textured volcanic glass, which may or may not contain crystals. It is typically light-colored. Scoria is another vesicular v ...
, which is considered a glass because it has no crystal structure.
* Apache tears
Apache tears are rounded pebbles of obsidian or "obsidianites" composed of black or dark-colored natural volcanic glass, usually of rhyolitic composition and bearing conchoidal fracture. Also known by the lithologic term marekanite, this vari ...
, a kind of nodular obsidian.
* Tachylite
Tachylite ( ; also spelled tachylyte) is a form of basaltic volcanic glass. This glass is formed naturally by the rapid cooling of molten basalt. It is a type of mafic igneous rock that is decomposable by acids and readily fusible. The color ...
(also spelled tachylyte), a basalt
Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...
ic glass with relatively low silica content.
* Sideromelane
Sideromelane is a vitreous basaltic volcanic glass, usually occurring in palagonite tuff, for which it is characteristic. It is a less common form of tachylite, with which it usually occurs together; however it lacks the iron oxide crystals di ...
, a less common form of tachylyte.
* Palagonite
Palagonite is an alteration product from the interaction of water with volcanic glass of chemical composition similar to basalt. Palagonite can also result from the interaction between water and basalt melt. The water flashes to steam on contact w ...
, an alteration product of basaltic glass.
* Hyaloclastite
Hyaloclastite is a volcanoclastic accumulation or breccia consisting of glass (from the Greek ''hyalus'') fragments (clasts) formed by quench fragmentation of lava flow surfaces during submarine or subglacial extrusion. It occurs as thin margin ...
, a hydrated tuff-like breccia of sideromelane and palagonite.
* Pele's hair, threads or fibers of volcanic glass, usually basaltic.
* Pele's tears
Pele's tears (closest Hawaiian translation: "nā waimaka o pele") are small pieces of solidified lava drops formed when airborne particles of molten material fuse into tearlike drops of volcanic glass. Pele's tears are jet black in color and are ...
, tear-like drops of volcanic glass, usually basaltic.
* Limu o Pele
Limu o Pele or Pele's seaweed ( Hawaiian, literally "seaweed of Pele" after Pele the Hawaiian fire goddess of volcanoes) is a geological term for thin sheets and subsequently shattered flakes of brownish-green to near-colorless volcanic glass lav ...
(Pele's seaweed), thin sheets and flakes of brownish-green to near-clear volcanic glass, usually basaltic.
Alteration
Volcanic glass is chemically unstable and readily decomposes. Water molecules readily react with the open, disordered structure of volcanic glass, removing soluble cations from the glass and precipitating secondary (''authigenic
Authigenesis is the process whereby a mineral or sedimentary rock deposit is generated where it is found or observed. Such deposits are described as authigenic. Authigenic sedimentary minerals form during sedimentation by precipitation or recrys ...
'') minerals. As a result, lithification
Lithification (from the Ancient Greek word ''lithos'' meaning 'rock' and the Latin-derived suffix ''-ific'') is the process in which sediments compact under pressure, expel connate fluids, and gradually become solid rock. Essentially, lithificatio ...
of volcanic ash is one of the fastest low-temperature lithification processes. Alteration of volcanic glass at mid-ocean ridges
A mid-ocean ridge (MOR) is a seafloor mountain system formed by plate tectonics. It typically has a depth of about and rises about above the deepest portion of an ocean basin. This feature is where seafloor spreading takes place along a diverg ...
may have contributed significantly to the formation of massive sulfide deposits Massive sulfide deposits are ore deposits that have significant stratiform ore body, ore bodies consisting mainly of sulfide minerals. Most massive sulfide ore deposits have other portions that are not massive, including stringer or feeder zones be ...
, and alteration of volcanic ash beds formed economically important zeolite
Zeolites are microporous, crystalline aluminosilicate materials commonly used as commercial adsorbents and catalysts. They mainly consist of silicon, aluminium, oxygen, and have the general formula ・y where is either a metal ion or H+. These p ...
and bentonite
Bentonite () is an absorbent swelling clay consisting mostly of montmorillonite (a type of smectite) which can either be Na-montmorillonite or Ca-montmorillonite. Na-montmorillonite has a considerably greater swelling capacity than Ca-mon ...
deposits.
References
{{DEFAULTSORT:Volcanic Glass
Volcanology
Glass in nature
Volcanic rocks