Vinyl ester resin, or often just vinyl ester, is a resin produced by the esterification of an

epoxy Epoxy is the family of basic components or cured end products of epoxy resins. Epoxy resins, also known as polyepoxides, are a class of reactive prepolymers and polymers which contain epoxide groups. The epoxide functional group is also coll ...

resin with

acrylic Acrylic may refer to: Chemicals and materials * Acrylic acid, the simplest acrylic compound * Acrylate polymer, a group of polymers (plastics) noted for transparency and elasticity * Acrylic resin, a group of related thermoplastic or thermosett ...

methacrylic acid Methacrylic acid, abbreviated MAA, is an organic compound. This colorless, viscous liquid is a carboxylic acid with an acrid unpleasant odor. It is soluble in warm water and miscible with most organic solvents. Methacrylic acid is produced indu ...

s. The "vinyl" groups refer to these ester substituents, which are prone to polymerize and thus an inhibitor is usually added. The diester product is then dissolved in a reactive solvent, such as

styrene Styrene () is an organic compound with the chemical formula C6H5CH=CH2. This derivative of benzene is a colorless oily liquid, although aged samples can appear yellowish. The compound evaporates easily and has a sweet smell, although high concen ...

, to approximately 35–45 percent content by weight. Polymerization is initiated by

free radical A daughter category of ''Ageing'', this category deals only with the biological aspects of ageing. Ageing Ailments of unknown cause Biogerontology Biological processes Causes of death Cellular processes Gerontology Life extension Metabo ...

s, which are generated by UV-irradiation or peroxides. 352px, Bis-GMA a typical "vinyl ester" derived from bisphenol A diglycidyl ether. This thermosetting polymer, thermoset material can be used as an alternative to polyester and

materials as the

thermoset polymer matrix A thermoset polymer matrix is a synthetic polymer reinforcement where polymers act as binder or matrix to secure in place incorporated particulates, fibres or other reinforcements. They were first developed for structural applications, such as gla ...

composite material A composite material (also called a composition material or shortened to composite, which is the common name) is a material which is produced from two or more constituent materials. These constituent materials have notably dissimilar chemical or ...

s, where its characteristics, strengths, and bulk cost are intermediate between polyester and epoxy. Vinyl ester has lower resin viscosity (approx. 200 cps) than polyester (approx. 500cps) and epoxy (approx. 900cps).

Uses

In homebuilt airplanes, the

Glasair Glasair Aviation USA, LLC is a Chinese-owned aircraft manufacturer based in Arlington, Washington that produces the Glasair and Sportsman 2+2 line of homebuilt aircraft. More than 3000 Glasair kits have been delivered worldwide. History Tom ...

and

Glastar The Glasair GlaStar (sometimes Glastar) is an American amateur-built aircraft that was designed by Tom Hamilton and produced by Stoddard-Hamilton Aircraft and later Glasair Aviation. It was first flown in 1994 and was superseded in production ...

kit planes made extensive use of vinylester

fiberglass Fiberglass (American English) or fibreglass (Commonwealth English) is a common type of fiber-reinforced plastic using glass fiber. The fibers may be randomly arranged, flattened into a sheet called a chopped strand mat, or woven into glass cloth ...

-reinforced structures. It is a common resin in the marine industry due to its corrosion resistance and ability to withstand water absorption. Vinyl ester resin is extensively used to manufacture

FRP tanks and vessels FRP ( Fibreglass Reinforced Plastics, also known as GRP, or Glass Reinforced Plastics) is a modern composite material of construction for chemical plant equipment like tanks and vessels. Chemical equipment that range in size from less than a metre ...

as per

BS4994 BS4994 (formally: British Standard 4994:1987) is the "specification for the design and construction of vessels and storage tanks in reinforced plastics". It specifies a code of practice for use by manufacturers of such containers. With the publicat ...

. For laminating process, vinyl ester is usually initiated with methyl ethyl ketone peroxide. It has greater strength and mechanical properties than polyester and less than epoxy resin. Renewable precursors to vinyl ester resins have been developed. Vinyl resins are often used in repair materials and laminating because they are waterproof and reliable.

Bisphenol A Bisphenol A (BPA) is a chemical compound primarily used in the manufacturing of various plastics. It is a colourless solid which is soluble in most common organic solvents, but has very poor solubility in water. BPA is produced on an industrial s ...

is a precursor in production of major classes of

resins In polymer chemistry and materials science, resin is a solid or highly viscous substance of plant or synthetic origin that is typically convertible into polymers. Resins are usually mixtures of organic compounds. This article focuses on natu ...

, including the vinyl ester resins along with

resins and

polycarbonate Polycarbonates (PC) are a group of thermoplastic polymers containing carbonate groups in their chemical structures. Polycarbonates used in engineering are strong, tough materials, and some grades are optically transparent. They are easily work ...

. This application usually begins with alkylation of BPA with

epichlorohydrin Epichlorohydrin (abbreviated ECH) is an organochlorine compound and an epoxide. Despite its name, it is not a halohydrin. It is a colorless liquid with a pungent, garlic-like odor, moderately soluble in water, but miscible with most polar organi ...

References

* ResinNavigator.org'
Epoxy-based vinyl esters benefits
Plastics Synthetic resins Thermosetting plastics {{polymer-stub