Vertex Model
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A vertex model is a type of
statistical mechanics In physics, statistical mechanics is a mathematical framework that applies statistical methods and probability theory to large assemblies of microscopic entities. Sometimes called statistical physics or statistical thermodynamics, its applicati ...
model A model is an informative representation of an object, person, or system. The term originally denoted the plans of a building in late 16th-century English, and derived via French and Italian ultimately from Latin , . Models can be divided in ...
in which the Boltzmann weights are associated with a vertex in the model (representing an
atom Atoms are the basic particles of the chemical elements. An atom consists of a atomic nucleus, nucleus of protons and generally neutrons, surrounded by an electromagnetically bound swarm of electrons. The chemical elements are distinguished fr ...
or particle). This contrasts with a nearest-neighbour model, such as the
Ising model The Ising model (or Lenz–Ising model), named after the physicists Ernst Ising and Wilhelm Lenz, is a mathematical models in physics, mathematical model of ferromagnetism in statistical mechanics. The model consists of discrete variables that r ...
, in which the energy, and thus the Boltzmann weight of a statistical microstate is attributed to the bonds connecting two neighbouring particles. The energy associated with a vertex in the lattice of particles is thus dependent on the state of the bonds which connect it to adjacent vertices. It turns out that every solution of the
Yang–Baxter equation In physics, the Yang–Baxter equation (or star–triangle relation) is a consistency equation which was first introduced in the field of statistical mechanics. It depends on the idea that in some scattering situations, particles may preserve their ...
with spectral parameters in a tensor product of
vector space In mathematics and physics, a vector space (also called a linear space) is a set (mathematics), set whose elements, often called vector (mathematics and physics), ''vectors'', can be added together and multiplied ("scaled") by numbers called sc ...
s V\otimes V yields an exactly-solvable vertex model. Although the model can be applied to various
geometries Geometry is a branch of mathematics concerned with questions of shape, size, relative position of figures, and the properties of space. Geometry is one of the oldest mathematical sciences. Types, methodologies, and terminologies of geometry. ...
in any number of dimensions, with any number of possible states for a given bond, the most fundamental examples occur for two dimensional lattices, the simplest being a
square lattice In mathematics, the square lattice is a type of lattice in a two-dimensional Euclidean space. It is the two-dimensional version of the integer lattice, denoted as . It is one of the five types of two-dimensional lattices as classified by their ...
where each bond has two possible states. In this model, every particle is connected to four other particles, and each of the four bonds adjacent to the particle has two possible states, indicated by the direction of an arrow on the bond. In this model, each vertex can adopt 2^4 possible configurations. The
energy Energy () is the physical quantity, quantitative physical property, property that is transferred to a physical body, body or to a physical system, recognizable in the performance of Work (thermodynamics), work and in the form of heat and l ...
for a given vertex can be given by \varepsilon_^, with a state of the lattice is an assignment of a state of each bond, with the total energy of the state being the sum of the vertex energies. As the energy is often divergent for an infinite lattice, the model is studied for a finite lattice as the lattice approaches infinite size. Periodic or domain wall
boundary condition In the study of differential equations, a boundary-value problem is a differential equation subjected to constraints called boundary conditions. A solution to a boundary value problem is a solution to the differential equation which also satis ...
s may be imposed on the model.


Discussion

For a given state of the lattice, the Boltzmann weight can be written as the product over the vertices of the Boltzmann weights of the corresponding vertex states : \exp(-\beta \varepsilon(\mbox)) = \prod_\mbox \exp(-\beta \varepsilon_^) where the Boltzmann weights for the vertices are written : R_^ = \exp(-\beta \varepsilon_^), and the ''i'', ''j'', ''k'', ''l'' range over the possible statuses of each of the four edges attached to the vertex. The vertex states of adjacent vertices must satisfy compatibility conditions along the connecting edges (bonds) in order for the state to be admissible. The
probability Probability is a branch of mathematics and statistics concerning events and numerical descriptions of how likely they are to occur. The probability of an event is a number between 0 and 1; the larger the probability, the more likely an e ...
of the system being in any given state at a particular time, and hence the properties of the system are determined by the partition function, for which an analytic form is desired. : \mathbb = \sum_\mbox \exp(-\beta \varepsilon(\mbox)) where ''β'' = 1/''kT'', ''T'' is
temperature Temperature is a physical quantity that quantitatively expresses the attribute of hotness or coldness. Temperature is measurement, measured with a thermometer. It reflects the average kinetic energy of the vibrating and colliding atoms making ...
and ''k'' is the
Boltzmann constant The Boltzmann constant ( or ) is the proportionality factor that relates the average relative thermal energy of particles in a ideal gas, gas with the thermodynamic temperature of the gas. It occurs in the definitions of the kelvin (K) and the ...
. The probability that the system is in any given state (
microstate A microstate or ministate is a sovereign state having a very small population or land area, usually both. However, the meanings of "state" and "very small" are not well-defined in international law. Some recent attempts to define microstates ...
) is given by : \frac so that the average value of the energy of the system is given by : \langle \varepsilon \rangle = \frac = kT^2 \frac \ln \mathbb In order to evaluate the partition function, firstly examine the states of a row of vertices. The external edges are free variables, with summation over the internal bonds. Hence, form the row partition function : T_^ = \sum_ R_^ R_^ \cdots R_^ This can be reformulated in terms of an auxiliary ''n''-dimensional vector space ''V'', with a basis \, and R \in End(V \otimes V) as : R(v_i \otimes v_j) = \sum_ R_^ v_k \otimes v_\ell and T \in End(V \otimes V^) as : T(v_ \otimes v_ \otimes \cdots \otimes v_) = \sum_ T_^ v_ \otimes v_ \otimes \cdots \otimes v_ thereby implying that ''T'' can be written as : T = R_\cdots R_ R_ , where the indices indicate the factors of the
tensor product In mathematics, the tensor product V \otimes W of two vector spaces V and W (over the same field) is a vector space to which is associated a bilinear map V\times W \rightarrow V\otimes W that maps a pair (v,w),\ v\in V, w\in W to an element of ...
V \otimes V^ on which ''R'' operates. Summing over the states of the bonds in the first row with the periodic boundary conditions i_1 = i'_1, gives : (\operatorname_(T))_^, where \tau = \operatorname_(T) is the row-transfer matrix. By summing the contributions over two rows, the result is : (\operatorname_(T))_^ (\operatorname_(T))_^ . which upon summation over the vertical bonds connecting the first two rows gives:((\operatorname_(T))^2)_^ for ''M'' rows, this gives : ((\operatorname_(T))^M)_^ and then applying the periodic boundary conditions to the vertical columns, the partition function can be expressed in terms of the transfer matrix \tau as : \mathbb= \operatorname_(\tau^M) \sim \lambda_^M where \lambda_ is the largest
eigenvalue In linear algebra, an eigenvector ( ) or characteristic vector is a vector that has its direction unchanged (or reversed) by a given linear transformation. More precisely, an eigenvector \mathbf v of a linear transformation T is scaled by a ...
of \tau. The approximation follows from the fact that the eigenvalues of \tau^M are the eigenvalues of \tau to the power of ''M'', and as M \rightarrow \infty, the power of the largest eigenvalue becomes much larger than the others. As the
trace Trace may refer to: Arts and entertainment Music * ''Trace'' (Son Volt album), 1995 * ''Trace'' (Died Pretty album), 1993 * Trace (band), a Dutch progressive rock band * ''The Trace'' (album), by Nell Other uses in arts and entertainment * ...
is the sum of the eigenvalues, the problem of calculating \mathbb reduces to the problem of finding the maximum eigenvalue of \tau. This in itself is another field of study. However, a standard approach to the problem of finding the largest eigenvalue of \tau is to find a large family of operators which commute with \tau. This implies that the
eigenspace In linear algebra, an eigenvector ( ) or characteristic vector is a Vector (mathematics and physics), vector that has its direction (geometry), direction unchanged (or reversed) by a given linear map, linear transformation. More precisely, an e ...
s are common, and restricts the possible space of solutions. Such a family of commuting operators is usually found by means of the
Yang–Baxter equation In physics, the Yang–Baxter equation (or star–triangle relation) is a consistency equation which was first introduced in the field of statistical mechanics. It depends on the idea that in some scattering situations, particles may preserve their ...
, which thus relates statistical mechanics to the study of
quantum group In mathematics and theoretical physics, the term quantum group denotes one of a few different kinds of noncommutative algebras with additional structure. These include Drinfeld–Jimbo type quantum groups (which are quasitriangular Hopf algebra ...
s.


Integrability

Definition: A vertex model is ''integrable'' if, \forall \mu, \nu, \exists \lambda such that : R_(\lambda)R_(\mu)R_(\nu) = R_(\nu)R_(\mu)R_(\lambda) This is a parameterized version of the Yang–Baxter equation, corresponding to the possible dependence of the vertex energies, and hence the Boltzmann weights ''R'' on external parameters, such as temperature, external fields, etc. The integrability condition implies the following relation. Proposition: For an integrable vertex model, with \lambda, \mu and \nu defined as above, then : R(\lambda)(1 \otimes T(\mu))(T(\nu) \otimes 1) = (T(\nu) \otimes 1)(1 \otimes T(\mu))R(\lambda) as
endomorphism In mathematics, an endomorphism is a morphism from a mathematical object to itself. An endomorphism that is also an isomorphism is an automorphism. For example, an endomorphism of a vector space is a linear map , and an endomorphism of a g ...
s of V \otimes V \otimes V^, where R(\lambda) acts on the first two vectors of the tensor product. It follows by multiplying both sides of the above equation on the right by R(\lambda)^ and using the cyclic property of the trace operator that the following corollary holds. Corollary: For an integrable vertex model for which R(\lambda) is invertible \forall \lambda, the transfer matrix \tau(\mu) commutes with \tau(\nu), \ \forall \mu, \nu. This illustrates the role of the Yang–Baxter equation in the solution of solvable lattice models. Since the transfer matrices \tau commute for all \lambda, \nu, the eigenvectors of \tau are common, and hence independent of the parameterization. It is a recurring theme which appears in many other types of statistical mechanical models to look for these commuting transfer matrices. From the definition of ''R'' above, it follows that for every solution of the Yang–Baxter equation in the tensor product of two ''n''-dimensional vector spaces, there is a corresponding 2-dimensional solvable vertex model where each of the bonds can be in the possible states \, where ''R'' is an endomorphism in the space spanned by \, 1 \leq a,b \leq n . This motivates the classification of all the finite-dimensional irreducible
representations ''Representations'' is an interdisciplinary journal in the humanities published quarterly by the University of California Press. The journal was established in 1983 and is the founding publication of the New Historicism movement of the 1980s. It ...
of a given Quantum algebra in order to find solvable models corresponding to it.


Notable vertex models

* Six-vertex model *: *
Eight-vertex model In statistical mechanics, the eight-vertex model is a generalization of the ice-type model, ice-type (six-vertex) models. It was discussed by T. Bill Sutherland and C. Fan & F. Y. Wu, and solved by Rodney Baxter in the zero-field case. Description ...
*:
Nineteen-vertex model
(Izergin-Korepin model) A. G. Izergin and V. E. Korepin, The inverse scattering method approach to the quantum Shabat-Mikhailov model. ''Communications in Mathematical Physics'', 79, 303 (1981)
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References

{{reflist Statistical mechanics Lattice models