In physics, a vapor (

American English American English, sometimes called United States English or U.S. English, is the set of variety (linguistics), varieties of the English language native to the United States. English is the Languages of the United States, most widely spoken lan ...

) or vapour (

British English British English (BrE, en-GB, or BE) is, according to Lexico, Oxford Dictionaries, "English language, English as used in Great Britain, as distinct from that used elsewhere". More narrowly, it can refer specifically to the English language in ...

and

Canadian English Canadian English (CanE, CE, en-CA) encompasses the varieties of English native to Canada. According to the 2016 census, English was the first language of 19.4 million Canadians or 58.1% of the total population; the remainder spoke French ( ...

; see spelling differences) is a substance in the

gas Gas is one of the four fundamental states of matter (the others being solid, liquid, and plasma). A pure gas may be made up of individual atoms (e.g. a noble gas like neon), elemental molecules made from one type of atom (e.g. oxygen), or ...

phase at a

temperature Temperature is a physical quantity that expresses quantitatively the perceptions of hotness and coldness. Temperature is measured with a thermometer. Thermometers are calibrated in various temperature scales that historically have relied o ...

lower than its

critical temperature Critical or Critically may refer to: *Critical, or critical but stable, medical states **Critical, or intensive care medicine *Critical juncture, a discontinuous change studied in the social sciences. *Critical Software, a company specializing in ...

,R. H. Petrucci, W. S. Harwood, and F. G. Herring, ''General Chemistry'', Prentice-Hall, 8th ed. 2002, p. 483–86. which means that the vapor can be condensed to a

liquid A liquid is a nearly incompressible fluid that conforms to the shape of its container but retains a (nearly) constant volume independent of pressure. As such, it is one of the four fundamental states of matter (the others being solid, gas, a ...

by increasing the

pressure Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country and e ...

on it without reducing the temperature. A vapor is different from an

aerosol An aerosol is a suspension (chemistry), suspension of fine solid particles or liquid Drop (liquid), droplets in air or another gas. Aerosols can be natural or Human impact on the environment, anthropogenic. Examples of natural aerosols are fog o ...

. An aerosol is a suspension of tiny particles of liquid, solid, or both within a gas. For example, water has a critical temperature of , which is the highest temperature at which liquid water can exist. In the

atmosphere An atmosphere () is a layer of gas or layers of gases that envelop a planet, and is held in place by the gravity of the planetary body. A planet retains an atmosphere when the gravity is great and the temperature of the atmosphere is low. A s ...

at ordinary temperatures gaseous water (known as

water vapor (99.9839 °C) , - , Boiling point , , - , specific gas constant , 461.5 J/( kg·K) , - , Heat of vaporization , 2.27 MJ/kg , - , Heat capacity , 1.864 kJ/(kg·K) Water vapor, water vapour or aqueous vapor is the gaseous pha ...

) will condense into a liquid if its

partial pressure In a mixture of gases, each constituent gas has a partial pressure which is the notional pressure of that constituent gas as if it alone occupied the entire volume of the original mixture at the same temperature. The total pressure of an ideal gas ...

is increased sufficiently. A vapor may co-exist with a liquid (or a solid). When this is true, the two phases will be in equilibrium, and the gas-partial pressure will be equal to the equilibrium

vapor pressure Vapor pressure (or vapour pressure in English-speaking countries other than the US; see spelling differences) or equilibrium vapor pressure is defined as the pressure exerted by a vapor in thermodynamic equilibrium with its condensed phases ...

of the liquid (or solid).

Properties

''Vapor'' refers to a gas phase at a temperature where the same substance can also exist in the

solid Solid is one of the State of matter#Four fundamental states, four fundamental states of matter (the others being liquid, gas, and Plasma (physics), plasma). The molecules in a solid are closely packed together and contain the least amount o ...

state, below the

of the substance. (For example, water has a critical temperature of 374 °C (647 K), which is the highest temperature at which liquid water can exist.) If the vapor is in contact with a liquid or solid phase, the two phases will be in a state of equilibrium. The term ''gas'' refers to a compressible fluid phase. Fixed gases are gases for which no liquid or solid can form at the temperature of the gas, such as air at typical ambient temperatures. A liquid or solid does not have to boil to release a vapor. Vapor is responsible for the familiar processes of

cloud In meteorology, a cloud is an aerosol consisting of a visible mass of miniature liquid droplets, frozen crystals, or other particles suspended in the atmosphere of a planetary body or similar space. Water or various other chemicals may co ...

formation and

condensation Condensation is the change of the state of matter from the gas phase into the liquid phase, and is the reverse of vaporization. The word most often refers to the water cycle. It can also be defined as the change in the state of water vapor to ...

. It is commonly employed to carry out the physical processes of

distillation Distillation, or classical distillation, is the process of separation process, separating the components or substances from a liquid mixture by using selective boiling and condensation, usually inside an apparatus known as a still. Dry distilla ...

and headspace extraction from a liquid sample prior to

gas chromatography Gas chromatography (GC) is a common type of chromatography used in analytical chemistry for separating and analyzing compounds that can be vaporized without decomposition. Typical uses of GC include testing the purity of a particular substance, ...

. The constituent

molecule A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and bioch ...

s of a vapor possess vibrational, rotational, and translational motion. These motions are considered in the

kinetic theory of gases Kinetic (Ancient Greek: κίνησις “kinesis”, movement or to move) may refer to: * Kinetic theory, describing a gas as particles in random motion * Kinetic energy, the energy of an object that it possesses due to its motion Art and enter ...

Vapor pressure

The

is the equilibrium pressure from a liquid or a solid at a specific temperature. The equilibrium vapor pressure of a liquid or solid is not affected by the amount of contact with the liquid or solid interface. The

normal boiling point The boiling point of a substance is the temperature at which the vapor pressure of a liquid equals the pressure surrounding the liquid and the liquid changes into a vapor. The boiling point of a liquid varies depending upon the surrounding envir ...

of a liquid is the

at which the vapor pressure is equal to normal atmospheric pressure. For two-phase systems (e.g., two liquid phases), the vapor pressure of the individual phases are equal. In the absence of stronger inter-species attractions between like-like or like-unlike molecules, the vapor pressure follows Raoult's law, which states that the

of each component is the product of the vapor pressure of the pure component and its mole fraction in the mixture. The total vapor pressure is the sum of the component partial pressures.

Examples

Crepuscular Rays Beam through the Mist Blown from Takkakaw Falls

Perfume Perfume (, ; french: parfum) is a mixture of fragrant essential oils or aroma compounds (fragrances), fixatives and solvents, usually in liquid form, used to give the human body, animals, food, objects, and living-spaces an agreeable scent. Th ...

s contain chemicals that vaporize at different temperatures and at different rate in scent accords, known as

note Note, notes, or NOTE may refer to: Music and entertainment * Musical note, a pitched sound (or a symbol for a sound) in music * ''Notes'' (album), a 1987 album by Paul Bley and Paul Motian * ''Notes'', a common (yet unofficial) shortened version ...

s. *

Atmospheric An atmosphere () is a layer of gas or layers of gases that envelop a planet, and is held in place by the gravity of the planetary body. A planet retains an atmosphere when the gravity is great and the temperature of the atmosphere is low. A s ...

is found near the earth's surface, and may condense into small liquid droplets and form meteorological phenomena, such as

fog Fog is a visible aerosol consisting of tiny water droplets or ice crystals suspended in the air at or near the Earth's surface. Reprint from Fog can be considered a type of low-lying cloud usually resembling stratus, and is heavily influ ...

mist Mist is a phenomenon caused by small droplets of water suspended in the cold air, usually by condensation. Physically, it is an example of a dispersion. It is most commonly seen where water vapor in warm, moist air meets sudden cooling, such a ...

, and haar. *

Mercury-vapor lamp A mercury-vapor lamp is a gas-discharge lamp that uses an electric arc through vaporized mercury to produce light. The arc discharge is generally confined to a small fused quartz arc tube mounted within a larger soda lime or borosilicate glass ...

s and

sodium vapor lamp A sodium-vapor lamp is a gas-discharge lamp that uses sodium in an excited state to produce light at a characteristic wavelength near 589 nm. Two varieties of such lamps exist: low pressure and high pressure. Low-pressure sodium lamps are ...

s produce light from atoms in

excited state In quantum mechanics, an excited state of a system (such as an atom, molecule or nucleus) is any quantum state of the system that has a higher energy than the ground state (that is, more energy than the absolute minimum). Excitation refers to a ...

s. *

Flammable liquid A flammable liquid is a liquid which can be easily ignited in air at ambient temperatures, i.e. it has a flash point at or below nominal threshold temperatures defined by a number of national and international standards organisations. The Occupat ...

s do not burn when ignited. It is the vapor cloud above the liquid that will burn if the vapor's concentration is between the

lower flammable limit Lower flammability limit (LFL), usually expressed in volume per cent, is the lower end of the concentration range over which a flammable mixture of gas or vapour in air can be ignited at a given temperature and pressure. The flammability range is de ...

(LFL) and upper flammable limit (UFL), of the flammable liquid.

E-cigarettes An electronic cigarette is an electronic device that simulates tobacco smoking. It consists of an atomizer, a power source such as a battery, and a container such as a cartridge or tank. Instead of smoke, the user inhales vapor. As such ...

produce

s, not vapors.

Measuring vapor

Since it is in the gas phase, the amount of vapor present is quantified by the

of the gas. Also, vapors obey the

barometric formula The barometric formula, sometimes called the ''exponential atmosphere'' or ''isothermal atmosphere'', is a formula used to model how the pressure (or density) of the air changes with altitude. The pressure drops approximately by 11.3 pascals pe ...

in a gravitational field, just as conventional atmospheric gases do.

References

{{Authority control Gases Pressure Chemical properties ca:Vapour fr:Vapeur gl:Vapour

Properties

Vapor pressure

Examples

Measuring vapor

See also

References