Vanadium tetrachloride is the inorganic compound with the formula V Cl₄. This bright red liquid serves as a useful reagent for the preparation of other vanadium compounds.

Synthesis, bonding, basic properties

With one more valence electron than

diamagnetic Diamagnetic materials are repelled by a magnetic field; an applied magnetic field creates an induced magnetic field in them in the opposite direction, causing a repulsive force. In contrast, paramagnetic and ferromagnetic materials are attracted ...

TiCl₄, VCl₄ is a

paramagnetic Paramagnetism is a form of magnetism whereby some materials are weakly attracted by an externally applied magnetic field, and form internal, induced magnetic fields in the direction of the applied magnetic field. In contrast with this behavior, ...

liquid. It is one of only a few paramagnetic compounds that is liquid at room temperature. VCl₄ is prepared by chlorination of vanadium metal. VCl₅ does not form in this reaction; Cl₂ lacks the oxidizing power to attack VCl₄. VCl₅ can however be prepared indirectly from VF₅ at −78 °C. In contrast, the heavier analogues NbCl₅ and TaCl₅ are stable and not particularly oxidizing. VF₅ can be prepared directly by fluorination of vanadium metal, reflecting the increased oxidizing power of F₂ vs Cl₂. Indicative of its oxidizing power, VCl₄ releases Cl₂ at its boiling point (standard pressure) to afford VCl₃.

Reactions

Consistent with its high oxidizing power, VCl₄ reacts with HBr at -50 °C to produce VBr₃. The reaction proceeds via VBr₄, which releases Br₂ during warming to room temperature. :2 VCl₄ + 8 HBr → 2 VBr₃ + 8 HCl + Br₂ VCl₄ forms

adduct An adduct (from the Latin ''adductus'', "drawn toward" alternatively, a contraction of "addition product") is a product of a direct addition of two or more distinct molecules, resulting in a single reaction product containing all atoms of all co ...

s with many donor ligands, for example, VCl₄(

THF Tetrahydrofuran (THF), or oxolane, is an organic compound with the formula (CH2)4O. The compound is classified as heterocyclic compound, specifically a cyclic ether. It is a colorless, water- miscible organic liquid with low viscosity. It is ...

)₂. It is the precursor to

vanadocene dichloride Vanadocene dichloride is an organometallic complex with formula (hapticity, ''η''5-cyclopentadienyl, C5H5)2VCl2 (commonly abbreviated as Cp2VCl2). It is a structural analogue of titanocene dichloride but with vanadium(IV) instead of titanium(IV). ...

Organic chemistry

In organic synthesis, VCl₄ is used for the

oxidative coupling Oxidative coupling in chemistry is a coupling reaction of two molecular entities through an oxidative process. Usually oxidative couplings are catalysed by a transition metal complex like in classical cross-coupling reactions, although the underl ...

of phenols. For example, it converts

phenol Phenol (also called carbolic acid) is an aromatic organic compound with the molecular formula . It is a white crystalline solid that is volatile. The molecule consists of a phenyl group () bonded to a hydroxy group (). Mildly acidic, it ...

into a mixture of 4,4'-, 2,4'-, and 2,2'-

biphenol In organic chemistry, a biphenol refers to compounds with the formula (C6H4OH)2. Such compounds formally result from the coupling of two phenols. {{short description, Chemical compound Three symmetrical isomers of biphenol exist: * 2,2'-Biphenol ...

s: :2 C₆H₅OH + 2 VCl₄ → HOC₆H₄–C₆H₄OH + 2 VCl₃ + 2 HCl

Applications

VCl₄ is a catalyst for the polymerization of alkenes, especially those useful in the rubber industry. The underlying technology is related to Ziegler–Natta catalysis, which involves the intermediacy of vanadium alkyls.

Safety considerations

VCl₄ is a volatile, aggressive oxidant that readily hydrolyzes to release

HCl HCL may refer to: Science and medicine * Hairy cell leukemia, an uncommon and slowly progressing B cell leukemia * Harvard Cyclotron Laboratory, from 1961 to 2002, a proton accelerator used for research and development * Hollow-cathode lamp, a spe ...

References

{{Chlorides Vanadium(IV) compounds Chlorides Metal halides Reagents for organic chemistry