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Valleriite is an uncommon
sulfide mineral The sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide (S22−) as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenides, the tellurides, the ...
(hydroxysulfide) of iron and copper with formula: or . It is an opaque, soft, bronze-yellow to brown mineral which occurs as nodules or encrustations.


Discovery and occurrence

Valleriite was first described in 1870 from an occurrence in Västmanland,
Sweden Sweden, formally the Kingdom of Sweden,The United Nations Group of Experts on Geographical Names states that the country's formal name is the Kingdom of SwedenUNGEGN World Geographical Names, Sweden./ref> is a Nordic country located on ...
. It was named for Swedish chemist
Johan Gottschalk Wallerius Johan Gottschalk Wallerius (11 July 1709 – 16 November 1785) was a Swedish chemist and mineralogist. Biography Wallerius was born at Stora Mellösa in Närke (now Örebro County), Sweden. He was a son of provost Erik Nilsson Wallerius and hi ...
(Vallerius) (1709–1785). Valleriite occurs in
dunite Dunite (), also known as olivinite (not to be confused with the mineral olivenite), is an intrusive igneous rock of ultramafic composition and with phaneritic (coarse-grained) texture. The mineral assemblage is greater than 90% olivine, with mi ...
s and
chromitite Chromitite is an igneous cumulate rock composed mostly of the mineral chromite. It is found in layered intrusions such as the Bushveld Igneous Complex in South Africa, the Stillwater igneous complex in Montana and the Ring of Fire discovery in O ...
s replacing
chalcopyrite Chalcopyrite ( ) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mo ...
in
Cyprus Cyprus ; tr, Kıbrıs (), officially the Republic of Cyprus,, , lit: Republic of Cyprus is an island country located south of the Anatolian Peninsula in the eastern Mediterranean Sea. Its continental position is disputed; while it is geo ...
. In
Phalaborwa Phalaborwa (translated to English as ''better than the south; phala'' means ''better than and borwa'' means ''south'') is a town in the Mopani District Municipality, Limpopo province, South Africa. It is located near the confluence of the Ga-Sela ...
,
South Africa South Africa, officially the Republic of South Africa (RSA), is the southernmost country in Africa. It is bounded to the south by of coastline that stretch along the South Atlantic and Indian Oceans; to the north by the neighbouring countri ...
it occurs as replacement of
magnetite Magnetite is a mineral and one of the main iron ores, with the chemical formula Fe2+Fe3+2O4. It is one of the oxides of iron, and is ferrimagnetic; it is attracted to a magnet and can be magnetized to become a permanent magnet itself. With the ...
in a
carbonatite Carbonatite () is a type of intrusive rock, intrusive or extrusive rock, extrusive igneous rock defined by mineralogic composition consisting of greater than 50% carbonate minerals. Carbonatites may be confused with marble and may require geoche ...
. It occurs as replacements of copper and nickel phases in
serpentinite Serpentinite is a rock composed predominantly of one or more serpentine group minerals, the name originating from the similarity of the texture of the rock to that of the skin of a snake. Serpentinite has been called ''serpentine'' or ''ser ...
s and other altered
ultramafic rock Ultramafic rocks (also referred to as ultrabasic rocks, although the terms are not wholly equivalent) are igneous and meta-igneous rocks with a very low silica content (less than 45%), generally >18% MgO, high FeO, low potassium, and are composed ...
s.


References

Copper minerals Iron minerals Magnesium minerals Aluminium minerals Sulfide minerals Trigonal minerals Minerals in space group 166 Minerals described in 1870 {{sulfide-mineral-stub