Valentinite is an antimony oxide mineral with formula Sb₂ O₃. Valentinite crystallizes in the

orthorhombic In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic lattices result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular prism with a r ...

system and typically forms as radiating clusters of

euhedral Euhedral crystals (also known as idiomorphic or automorphic crystals) are those that are well-formed, with sharp, easily recognised faces. The opposite is anhedral (also known as '' xenomorphic'' or ''allotriomorphic''): a rock with an anhedra ...

crystals or as fibrous masses. It is colorless to white with occasional shades or tints of yellow and red. It has a

Mohs hardness The Mohs scale of mineral hardness () is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material. The scale was introduced in 1812 by th ...

of 2.5 to 3 and a

specific gravity Relative density, or specific gravity, is the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for liquids is nearly always measured with respect to water (molecule), wa ...

of 5.76.Pradyot Patnaik. ''Handbook of Inorganic Chemicals''. McGraw-Hill, 2002, Valentinite occurs as a

weathering Weathering is the deterioration of rocks, soils and minerals as well as wood and artificial materials through contact with water, atmospheric gases, and biological organisms. Weathering occurs ''in situ'' (on site, with little or no movement), ...

product of

stibnite Stibnite, sometimes called antimonite, is a sulfide mineral with the formula Sb2 S3. This soft grey material crystallizes in an orthorhombic space group. It is the most important source for the metalloid antimony. The name is derived from the ...

and other antimony minerals. It is dimorphous with the isometric antimony oxide senarmontite.

Historical data

Valentinite is a mineral named in the middle of the 19th century in honour of

Basilius Valentinus Basil Valentine is the Anglicised version of the name Basilius Valentinus, ostensibly a 15th-century alchemist, possibly Canon of the Benedictine Priory of Saint Peter in Erfurt, Germany but more likely a pseudonym used by one or several 16th-ce ...

, a writer on

alchemy Alchemy (from Arabic: ''al-kīmiyā''; from Ancient Greek: χυμεία, ''khumeía'') is an ancient branch of natural philosophy, a philosophical and protoscientific tradition that was historically practiced in China, India, the Muslim world, ...

. He is the supposed author of the first book to give a detailed description of antimony and its compounds. From the contents of the book it is also obvious that Valentinus was familiar with the synthetic preparation of antimony trioxide, which was called 'the antimony flower'. Valentinite was first described in 1845 for an occurrence in the Les Chalanches Mine,

Allemond Allemond (; spelled Allemont by the local council) is a commune in the Isère department in the Auvergne-Rhône-Alpes region of south-eastern France. The inhabitants of the commune are known as ''Allemondins'' or ''Allemondines'' Geography Al ...

, Isère,

Auvergne-Rhône-Alpes Auvergne-Rhône-Alpes (ARA; ; frp, Ôvèrgne-Rôno-Ârpes; oc, Auvèrnhe Ròse Aups; it, Alvernia-Rodano-Alpi) is a region in southeast-central France created by the 2014 territorial reform of French regions; it resulted from the merger of Au ...

France France (), officially the French Republic ( ), is a country primarily located in Western Europe. It also comprises of Overseas France, overseas regions and territories in the Americas and the Atlantic Ocean, Atlantic, Pacific Ocean, Pac ...

. The first description of its occurrence in the region of

Příbram Příbram (; german: Freiberg in Böhmen, ''Przibram'', or ''Pribram'', in 1939–1945 ''Pibrans'') is a town in the Central Bohemian Region of the Czech Republic. It has about 32,000 inhabitants. It is well known for its mining history, and more ...

Bohemia Bohemia ( ; cs, Čechy ; ; hsb, Čěska; szl, Czechy) is the westernmost and largest historical region of the Czech Republic. Bohemia can also refer to a wider area consisting of the historical Lands of the Bohemian Crown ruled by the Bohem ...

comes roughly from the same time. This particular locality at one time produced the very best crystals of this mineral. The largest crystals found there measured up to 3 cm. Grouped in rich druses, they developed in

vein Veins are blood vessels in humans and most other animals that carry blood towards the heart. Most veins carry deoxygenated blood from the tissues back to the heart; exceptions are the pulmonary and umbilical veins, both of which carry oxygenated b ...

cavities with

galena Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver. Galena is one of the most abundant and widely distributed sulfide minerals. It cryst ...

Occurrence

Valentinite is a

product of

hydrothermal Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...

antimony-bearing veins, where it forms as a secondary mineral through

oxidation Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a d ...

in the upper parts of the deposits. It occurs associated with

, native antimony, stibiconite, cervantite,

kermesite Kermesite or antimony oxysulfide is also known as red antimony (Sb2S2O) . The mineral's color ranges from cherry red to a dark red to a black. Kermesite is the result of partial oxidation between stibnite (Sb2S3) and other antimony oxides such a ...

and

tetrahedrite Tetrahedrite is a copper antimony sulfosalt mineral with formula: . It is the antimony endmember of the continuous solid solution series with arsenic-bearing tennantite. Pure endmembers of the series are seldom if ever seen in nature. Of the two, ...

. A rich deposit of valentinite has been found in the

Constantine Constantine most often refers to: * Constantine the Great, Roman emperor from 306 to 337, also known as Constantine I *Constantine, Algeria, a city in Algeria Constantine may also refer to: People * Constantine (name), a masculine given name ...

province of

Algeria ) , image_map = Algeria (centered orthographic projection).svg , map_caption = , image_map2 = , capital = Algiers , coordinates = , largest_city = capital , relig ...

. This is the only deposit where it is mined as an

ore Ore is natural rock or sediment that contains one or more valuable minerals, typically containing metals, that can be mined, treated and sold at a profit.Encyclopædia Britannica. "Ore". Encyclopædia Britannica Online. Retrieved 7 Apr ...

, with 83% antimony. In all other locations it occurs in negligible quantities.

References

{{reflist Antimony minerals Oxide minerals Orthorhombic minerals Minerals in space group 56

Historical data

Occurrence

See also

References