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Explosive material An explosive (or explosive material) is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An exp ...
s are produced in numerous physical forms for their use in mining, engineering, or military applications. The different physical forms and fabrication methods are grouped together in several use forms of explosives. Explosives are sometimes used in their pure forms, but most common applications transform or modify them. These use forms are commonly categorized as:


Castings

Castings, or castable explosives, are explosive materials or mixtures in which at least one component can be safely melted at a temperature which is safe to handle the other components, and which are normally produced by casting or pouring the molten mixture or material into a form or use container. In modern usage,
Trinitrotoluene Trinitrotoluene (), more commonly known as TNT, more specifically 2,4,6-trinitrotoluene, and by its preferred IUPAC name 2-methyl-1,3,5-trinitrobenzene, is a chemical compound with the formula C6H2(NO2)3CH3. TNT is occasionally used as a reage ...
or TNT is the basic meltable explosive used in essentially all castable explosives. Other ingredients found in modern castable explosives include: * Active, energetic or explosive ingredients: **
Aluminum powder Aluminium powder is powdered aluminium. This was originally produced by mechanical means using a stamp mill to create flakes. Subsequently, a process of spraying molten aluminium to create a powder of droplets was developed by E. J. Hall in the ...
**
Ammonium nitrate Ammonium nitrate is a chemical compound with the chemical formula . It is a white crystalline salt consisting of ions of ammonium and nitrate. It is highly soluble in water and hygroscopic as a solid, although it does not form hydrates. It is ...
**
Ammonium picrate Dunnite, also known as Explosive D or systematically as ammonium picrate, is an explosive developed in 1906 by US Army Major Beverly W. Dunn, who later served as the chief inspector of the Bureau of Transportation Explosives. Ammonium picrate is ...
**
Barium nitrate Barium nitrate is the inorganic compound with the chemical formula Ba( NO3)2. It, like most barium salts, is colorless, toxic, and water-soluble. It burns with a green flame and is an oxidizer; the compound is commonly used in pyrotechnics. Man ...
** EDNA ** HMX **
Lead nitrate Lead(II) nitrate is an inorganic compound with the chemical formula Pb( NO3)2. It commonly occurs as a colourless crystal or white powder and, unlike most other lead(II) salts, is soluble in water. Known since the Middle Ages by the name plumbum ...
**
PETN Pentaerythritol tetranitrate (PETN), also known as PENT, PENTA, (ПЕНТА, primarily in Russian) TEN, corpent, or penthrite (or, rarely and primarily in German, as nitropenta), is an explosive material. It is the nitrate ester of pentaerythri ...
** Sodium picrate **
RDX RDX (abbreviation of "Research Department eXplosive") or hexogen, among other names, is an organic compound with the formula (O2N2CH2)3. It is a white solid without smell or taste, widely used as an explosive. Chemically, it is classified as a n ...
**
Tetryl 2,4,6-Trinitrophenylmethylnitramine commonly referred to as tetryl ( C7 H5 N5 O8) is an explosive compound used to make detonators and explosive booster charges. Tetryl is a nitramine booster explosive, though its use has been largely superseded ...
* Inert ingredients **
Boric acid Boric acid, more specifically orthoboric acid, is a compound of boron, oxygen, and hydrogen with formula . It may also be called hydrogen borate or boracic acid. It is usually encountered as colorless crystals or a white powder, that dissolves ...
**
Calcium chloride Calcium chloride is an inorganic compound, a salt with the chemical formula . It is a white crystalline solid at room temperature, and it is highly soluble in water. It can be created by neutralising hydrochloric acid with calcium hydroxide. Ca ...
**
Wax Waxes are a diverse class of organic compounds that are lipophilic, malleable solids near ambient temperatures. They include higher alkanes and lipids, typically with melting points above about 40 °C (104 °F), melting to give low ...
**
Silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...
, often in the form of
silica fume Silica fume, also known as microsilica, (CAS number 69012-64-2, EINECS number 273-761-1) is an amorphous (non-crystalline) polymorph of silicon dioxide, silica. It is an ultrafine powder collected as a by-product of the silicon and ferrosilicon a ...
(
Cab-o-sil Fumed silica (CAS number 112945-52-5), also known as pyrogenic silica because it is produced in a flame, consists of microscopic droplets of amorphous silica fused into branched, chainlike, three-dimensional secondary particles which then agglom ...
for example) Common castable explosives include: *
Amatol Amatol is a highly explosive material made from a mixture of TNT and ammonium nitrate. The British name originates from the words ammonium and toluene (the precursor of TNT). Similar mixtures (one part dinitronaphthalene and seven parts ammoniu ...
*
Baratol Baratol is an explosive made of a mixture of TNT and barium nitrate, with a small quantity (about 1%) of paraffin wax used as a phlegmatizing agent. TNT typically makes up 25% to 33% of the mixture. Because of the high density of barium nitrate, B ...
* Boracitol *
Composition B Composition B, colloquially Comp B, is an explosive consisting of castable mixtures of RDX and TNT. It is used as the main explosive filling in artillery projectiles, rockets, land mines, hand grenades and various other munitions. It was also use ...
*
Cyclotol Cyclotol is an explosive consisting of castable mixtures of RDX and TNT. It is related to the more common Composition B, which is roughly 60% RDX and 40% TNT; various compositions of Cyclotol contain from 65% to 80% RDX. Typical ranges are from 60/ ...
*
Octol {{Short description, A high explosive mixture consisting of HMX and TNT Octol is a melt-castable, high explosive mixture consisting of HMX and TNT in different weight proportions. Composition Two formulations are commonly used: * 70% HMX & 30% T ...
*
Pentolite Pentolite is a composite high explosive used for military and civilian purposes, e.g., warheads and booster charges. It is made of pentaerythritol tetranitrate (PETN) phlegmatized with trinitrotoluene (TNT) by melt casting.B. M. Dobratz & P. C. Cr ...
* Plumbatol *
Tritonal Tritonal is a mixture of 80% Trinitrotoluene, TNT and 20% aluminium Powder (substance), powder, used in several types of ordnance such as air-dropped bombs. The aluminium improves the total heat output and hence Impulse (physics), impulse of the ...
*
Torpex Torpex is a secondary explosive, 50% more powerful than TNT by mass. Torpex comprises 42% RDX, 40% TNT and 18% powdered aluminium. It was used in the Second World War from late 1942, at which time some used the names Torpex and RDX interchangeab ...
*
IMX-101 IMX-101 is a high-performance insensitive high explosive composite mixture developed by BAE Systems and the United States Army to replace TNT in artillery shells, starting as soon as 2011. IMX stands for "Insensitive Munitions eXplosives", which ...


Polymer bonded

Polymer-bonded explosives, also known as Plastic-bonded explosives or simply PBX, are a relatively solid and inflexible explosive form containing a powdered explosive material and a polymer (plastic) binder. These are usually carefully mixed, often with a very thin coating of the polymer onto the powder grains of the explosive material, and then hot pressed to form dense solid blocks of PBX material. There are numerous PBX explosives, mostly based on
RDX RDX (abbreviation of "Research Department eXplosive") or hexogen, among other names, is an organic compound with the formula (O2N2CH2)3. It is a white solid without smell or taste, widely used as an explosive. Chemically, it is classified as a n ...
, HMX, or
TATB TATB, triaminotrinitrobenzene or 2,4,6-triamino-1,3,5-trinitrobenzene is an aromatic explosive, based on the basic six-carbon benzene ring structure with three nitro functional groups (NO2) and three amine (NH2) groups attached, alternating aroun ...
explosive materials. An extensive but by no means complete list of PBX materials is in the main
Polymer-bonded explosive Polymer-bonded explosives, also called PBX or plastic-bonded explosives, are explosive materials in which explosive powder is bound together in a matrix using small quantities (typically 5–10% by weight) of a synthetic polymer. PBXs are normally ...
article. The major naming systems for PBX use: * LX-# (
Lawrence Livermore National Laboratory Lawrence Livermore National Laboratory (LLNL) is a federal research facility in Livermore, California, United States. The lab was originally established as the University of California Radiation Laboratory, Livermore Branch in 1952 in response ...
developed PBXes) * PBX #### (
Los Alamos National Laboratory Los Alamos National Laboratory (often shortened as Los Alamos and LANL) is one of the sixteen research and development laboratories of the United States Department of Energy (DOE), located a short distance northwest of Santa Fe, New Mexico, ...
developed PBXes) * PBXN-# (
United States Navy The United States Navy (USN) is the maritime service branch of the United States Armed Forces and one of the eight uniformed services of the United States. It is the largest and most powerful navy in the world, with the estimated tonnage ...
developed PBXes) LX numbers range from 1 to 17. PBX system numbers start around 9000 and use numerous scattered numbers between there and 9700. Some commonly known PBXes are: * LX-17 *
PBX 9502 Polymer-bonded explosives, also called PBX or plastic-bonded explosives, are explosive materials in which explosive powder is bound together in a matrix using small quantities (typically 5–10% by weight) of a synthetic polymer. PBXs are normally ...
*
PBX 9404 Polymer-bonded explosives, also called PBX or plastic-bonded explosives, are explosive materials in which explosive powder is bound together in a matrix using small quantities (typically 5–10% by weight) of a synthetic polymer. PBXs are normally ...
* LX-11 *
LX-14 LX-14 and LX-14-0 are polymer-bonded explosives developed by Lawrence Livermore National Laboratory and used in nuclear weapons in the United States. Ingredients LX-14 is made of HMX HMX, also called octogen, is a powerful and relatively in ...
PBXes are notable for their use in modern
Nuclear weapons A nuclear weapon is an explosive device that derives its destructive force from nuclear reactions, either fission (fission bomb) or a combination of fission and fusion reactions (thermonuclear bomb), producing a nuclear explosion. Both bomb ...
. Modern US and British nuclear warheads nearly all use insensitive PBX types using only
TATB TATB, triaminotrinitrobenzene or 2,4,6-triamino-1,3,5-trinitrobenzene is an aromatic explosive, based on the basic six-carbon benzene ring structure with three nitro functional groups (NO2) and three amine (NH2) groups attached, alternating aroun ...
explosive, to increase safety in case of accidents.


Putties, aka Plastic explosives

Technically known as putties, but more commonly
Plastic explosives Plastic explosive is a soft and hand-moldable solid form of explosive material. Within the field of explosives engineering, plastic explosives are also known as putty explosives or blastics. Plastic explosives are especially suited for explos ...
, these mixtures are a thick, flexible, moldable solid material that can be shaped and will retain that shape after forming, much like
clay Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4). Clays develop plasticity when wet, due to a molecular film of water surrounding the clay par ...
. Putties normally contain mostly
RDX RDX (abbreviation of "Research Department eXplosive") or hexogen, among other names, is an organic compound with the formula (O2N2CH2)3. It is a white solid without smell or taste, widely used as an explosive. Chemically, it is classified as a n ...
explosive, but may include some
PETN Pentaerythritol tetranitrate (PETN), also known as PENT, PENTA, (ПЕНТА, primarily in Russian) TEN, corpent, or penthrite (or, rarely and primarily in German, as nitropenta), is an explosive material. It is the nitrate ester of pentaerythri ...
(Semtex, for example). Some common putties are: * C4 * (Now-obsolete)
Composition C The Composition C family is a family of related US-specified plastic explosives consisting primarily of RDX. All can be moulded by hand for use in demolition work and packed by hand into shaped charge devices. Variants have different proportions a ...
*
Semtex Semtex is a general-purpose plastic explosive containing RDX and Pentaerythritol tetranitrate, PETN. It is used in commercial blasting, demolition, and in certain military applications. Semtex was developed and manufactured in Czechoslovakia, or ...
* PE-4


Rubberized

Rubberized explosives are flat sheets of solid but flexible material, a mixture of a powdered explosive (commonly
RDX RDX (abbreviation of "Research Department eXplosive") or hexogen, among other names, is an organic compound with the formula (O2N2CH2)3. It is a white solid without smell or taste, widely used as an explosive. Chemically, it is classified as a n ...
or
PETN Pentaerythritol tetranitrate (PETN), also known as PENT, PENTA, (ПЕНТА, primarily in Russian) TEN, corpent, or penthrite (or, rarely and primarily in German, as nitropenta), is an explosive material. It is the nitrate ester of pentaerythri ...
) and a synthetic or natural rubber compound. Rubberized sheet explosives are commonly used for
explosive welding Explosion welding (EXW) is a solid state (solid-phase) process where welding is accomplished by accelerating one of the components at extremely high velocity through the use of chemical explosives. This process is often used to clad carbon st ...
and for various other industrial and military applications. Rubberized explosives can be cut to specific shape, bent around solid surfaces, glued or taped in place, or simply laid on relatively flat surfaces. Some common rubberized explosives include: *
Detasheet Detasheet is a flexible rubberized explosive, somewhat similar to plastic explosives, originally manufactured by DuPont. Its ingredients are PETN with nitrocellulose and a binder. Properties It was manufactured in thin flexible sheets with a ...
- a discontinued
DuPont DuPont de Nemours, Inc., commonly shortened to DuPont, is an American multinational chemical company first formed in 1802 by French-American chemist and industrialist Éleuthère Irénée du Pont de Nemours. The company played a major role in ...
product now manufactured by The Ensign-Bickford Aerospace & Defense Company ** Deta Flex - a DuPont military version of Detasheet ** LX-02-1 - a DuPont Deta Flex variant used by the
US Department of Energy The United States Department of Energy (DOE) is an executive department of the U.S. federal government that oversees U.S. national energy policy and manages the research and development of nuclear power and nuclear weapons in the United State ...
nuclear weapons programs *
Primasheet Primasheet is a rubberized sheet explosive identical to Detasheet. Manufactured by Ensign-Bickford Aerospace & Defense Company Primasheet comes in two varieties: Primasheet 1000 is PETN based and Primasheet 2000 is RDX based. Both are waterproof ...
- current Ensign-Bickford product line ** Primasheet 1000 - Primasheet 1000 using
PETN Pentaerythritol tetranitrate (PETN), also known as PENT, PENTA, (ПЕНТА, primarily in Russian) TEN, corpent, or penthrite (or, rarely and primarily in German, as nitropenta), is an explosive material. It is the nitrate ester of pentaerythri ...
** Primasheet 2000 - Primasheet 2000 using
RDX RDX (abbreviation of "Research Department eXplosive") or hexogen, among other names, is an organic compound with the formula (O2N2CH2)3. It is a white solid without smell or taste, widely used as an explosive. Chemically, it is classified as a n ...


Extrudable

Extrudable explosives are an extremely viscous liquid, similar in properties to
silicone A silicone or polysiloxane is a polymer made up of siloxane (−R2Si−O−SiR2−, where R = organic group). They are typically colorless oils or rubber-like substances. Silicones are used in sealants, adhesives, lubricants, medicine, cooking ...
based
caulk Caulk or, less frequently, caulking is a material used to seal joints or seams against leakage in various structures and piping. The oldest form of caulk consisted of fibrous materials driven into the wedge-shaped seams between boards on w ...
ing materials used in construction. It is used in similar ways - stored in a container, then extruded out a nozzle into thin cracks, holes, or along surfaces. Some extrudable explosives can then be hardened using a heat curing process. Others will remain a viscous fluid permanently. Common extrudable explosives include: * Setting extrudables ** LX-13 ** XTX-8003 ** XTX-8004 * Non-setting extrudables ** Demex-400


Binary

Binary explosives A binary explosive or two-component explosive is an explosive consisting of two components, neither of which is explosive by itself, which have to be mixed in order to become explosive. Examples of common binary explosives include Oxyliquit (liqui ...
are cap-sensitive (detonatable with a standard #8
blasting cap A detonator, frequently a blasting cap, is a device used to trigger an explosive device. Detonators can be chemically, mechanically, or electrically initiated, the last two being the most common. The commercial use of explosives uses electri ...
) two-part explosives mixtures, shipped separately and combined at the use site. Many of these mixtures are based on
Ammonium nitrate Ammonium nitrate is a chemical compound with the chemical formula . It is a white crystalline salt consisting of ions of ammonium and nitrate. It is highly soluble in water and hygroscopic as a solid, although it does not form hydrates. It is ...
as an oxidizer plus a volatile fuel, but unlike
ANFO ANFO ( ) (or AN/FO, for ammonium nitrate/fuel oil) is a widely used bulk industrial explosive. It consists of 94% porous prilled ammonium nitrate (NH4NO3) (AN), which acts as the oxidizing agent and absorbent for the fuel, and 6% number 2 fue ...
(ammonium nitrate fuel oil explosive) these binaries can be detonated by blasting caps. ANFO requires high explosive boosters to detonate it. Most binary explosives are a slurry after mixing, but some form a fluid with solid components dissolved into liquid ones. Some common binary explosives include: * Kinestik (ammonium nitrate/
nitromethane Nitromethane, sometimes shortened to simply "nitro", is an organic compound with the chemical formula . It is the simplest organic nitro compound. It is a polar liquid commonly used as a solvent in a variety of industrial applications such as in ...
) * Tannerite (ammonium nitrate/aluminum) * Kinepouch * Kinepak * Boulder-Busters * Marine Pac * ASTRO-PAK The historical but now uncommon
Astrolite {{no footnotes, date=December 2016 Astrolite is the trade name of a family of explosives, invented by chemist Gerald Hurst in the 1960s during his employment with the Atlas Powder Company. The Astrolite family consists of two compounds, Astrolite G ...
explosive is also a binary explosive. This category is somewhat unusual in that a single explosives researcher,
Gerald Hurst Gerald "Jerry" Hurst (June 16, 1937 – March 11, 2015) was an American chemist and fire investigator. Before becoming noted for arson investigations, Hurst designed explosives for warfare, invented a binary explosive device known as Kinepak and d ...
, was responsible for inventing and developing most of the explosive mixtures now in use.Astrolite usenet posts archived at Yarchive
accessed 2008-12-28


Blasting agents

Blasting agents are explosive materials or mixtures which are not detonatable by standard #8
blasting cap A detonator, frequently a blasting cap, is a device used to trigger an explosive device. Detonators can be chemically, mechanically, or electrically initiated, the last two being the most common. The commercial use of explosives uses electri ...
s. The best known blasting agent is
ANFO ANFO ( ) (or AN/FO, for ammonium nitrate/fuel oil) is a widely used bulk industrial explosive. It consists of 94% porous prilled ammonium nitrate (NH4NO3) (AN), which acts as the oxidizing agent and absorbent for the fuel, and 6% number 2 fue ...
explosive, a mixture containing primarily
ammonium nitrate Ammonium nitrate is a chemical compound with the chemical formula . It is a white crystalline salt consisting of ions of ammonium and nitrate. It is highly soluble in water and hygroscopic as a solid, although it does not form hydrates. It is ...
with a small quantity (typically around 6%) of fuel oil, most commonly
diesel fuel Diesel fuel , also called diesel oil, is any liquid fuel specifically designed for use in a diesel engine, a type of internal combustion engine in which fuel ignition takes place without a spark as a result of compression of the inlet air and t ...
. Other fuels and additives are used as well. While ANFO is often made on-site using fertilizer grade ammonium nitrate, blasting agents can also be purchased in prepackaged form, usually in metal or cardboard cylinders. Some brand names of packaged blasting agents include: * Nitramon * Nitramite * Pellite * Carbomite * Vibronite * Dynatex * Hydratol * Anoil


Dynamites

It is usually sold in the form of a stick roughly eight inches (20 cm) long and one inch (2.5 cm) in diameter but other sizes also exist. Dynamite is considered a "high explosive", which means it detonates rather than deflagrates. The chief uses of dynamite used to be in construction, mining and demolition. However, newer explosives and techniques have replaced dynamite in many applications. Dynamite is still used, mainly as bottom charge or in underwater blasting.


References

{{Reflist Explosives engineering