Tellurium Tetrabromide
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Tellurium tetrabromide ( Te Br4) is an
inorganic In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemist ...
chemical compound A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) containing atoms from more than one chemical element held together by chemical bonds. A molecule consisting of atoms of only one element ...
. It has a similar tetrameric structure to TeCl4.''Inorganic Chemistry'',Egon Wiberg, Arnold Frederick Holleman Elsevier 2001 It can be made by reacting bromine and tellurium. In the vapour TeBr4 dissociates: :TeBr4 → TeBr2 + Br2 It is a conductor when molten, dissociating into the ions TeBr3+ and Br. When dissolved in
benzene Benzene is an organic chemical compound with the molecular formula C6H6. The benzene molecule is composed of six carbon atoms joined in a planar ring with one hydrogen atom attached to each. Because it contains only carbon and hydrogen atoms, ...
and
toluene Toluene (), also known as toluol (), is a substituted aromatic hydrocarbon. It is a colorless, water-insoluble liquid with the smell associated with paint thinners. It is a mono-substituted benzene derivative, consisting of a methyl group (CH3) at ...
, TeBr4 is present as the unionized tetramer Te4Br16. In solvents with donor properties such as
acetonitrile Acetonitrile, often abbreviated MeCN (methyl cyanide), is the chemical compound with the formula and structure . This colourless liquid is the simplest organic nitrile (hydrogen cyanide is a simpler nitrile, but the cyanide anion is not clas ...
, CH3CN ionic complexes are formed which make the solution conducting: :TeBr4 + 2CH3CN → (CH3CN)2TeBr3+ + Br


References

Bromides Tellurium halides Tellurium(IV) compounds Chalcohalides {{inorganic-compound-stub