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Taconite () is a variety of iron formation, an
iron Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in ...
-bearing (over 15% iron)
sedimentary rock Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particles ...
, in which the iron minerals are interlayered with
quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical f ...
,
chert Chert () is a hard, fine-grained sedimentary rock composed of microcrystalline or cryptocrystalline quartz, the mineral form of silicon dioxide (SiO2). Chert is characteristically of biological origin, but may also occur inorganically as a ...
, or
carbonate A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word ''carbonate'' may also refer to a carbonate ester, an organic compound containing the carbonate ...
. The name "taconyte" was coined by Horace Vaughn Winchell (1865–1923) – son of
Newton Horace Winchell Newton Horace Winchell (17 December 1839 – 2 May 1914) was an American geologist chiefly notable for his six-volume work ''The Geology of Minnesota: Final Report of the Geological and Natural History Survey of Minnesota'', which was prepared ...
, the
Minnesota Minnesota () is a state in the upper midwestern region of the United States. It is the 12th largest U.S. state in area and the 22nd most populous, with over 5.75 million residents. Minnesota is home to western prairies, now given over t ...
State Geologist – during their pioneering investigations of the
Precambrian The Precambrian (or Pre-Cambrian, sometimes abbreviated pꞒ, or Cryptozoic) is the earliest part of Earth's history, set before the current Phanerozoic Eon. The Precambrian is so named because it preceded the Cambrian, the first period of th ...
Biwabik Iron Formation of northeastern Minnesota. He believed the sedimentary rock sequence hosting the iron-formation was correlative with the
Taconic orogeny The Taconic orogeny was a mountain building period that ended 440 million years ago and affected most of modern-day New England. A great mountain chain formed from eastern Canada down through what is now the Piedmont of the East coast of the Unit ...
of New England, and referred to the unfamiliar and as-yet-unnamed iron-bearing rock as the 'taconic rock' or ''taconyte''. Following development of high grade direct shipping
iron ore Iron ores are rocks and minerals from which metallic iron can be economically extracted. The ores are usually rich in iron oxides and vary in color from dark grey, bright yellow, or deep purple to rusty red. The iron is usually found in the ...
deposits on the Mesabi Range, containing up to 65% iron and as little as 1.25%
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is ...
, miners termed the unaltered iron-formation wall rock taconite. The iron content of taconite is generally 30% to 35%, and the silica content generally around 45%. Iron in 'taconite' is commonly present as magnetite, iron silicates, and iron-bearing carbonates, and locally martite (hematite) formed by oxidation of magnetite. Horizons containing magnetite as the dominant mineral have been extensively mined since 1955 to produce iron ore pellets; the term 'taconite' has consequently been colloquially adapted to describe the magnetite iron-formation ores (''taconite iron ore''), the mining, milling, magnetic separation, and agglomerating process (''taconite process''), and the product iron ore pellets (''taconite pellets'').


History

In the late 19th and early 20th centuries, the United States was mining such an abundance of
iron ore Iron ores are rocks and minerals from which metallic iron can be economically extracted. The ores are usually rich in iron oxides and vary in color from dark grey, bright yellow, or deep purple to rusty red. The iron is usually found in the ...
of high quality that taconite was considered an uneconomic waste product. By the end of
World War II World War II or the Second World War, often abbreviated as WWII or WW2, was a world war that lasted from 1939 to 1945. It involved the World War II by country, vast majority of the world's countries—including all of the great power ...
, however, much of the high-grade iron ore in the
United States The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country Continental United States, primarily located in North America. It consists of 50 U.S. state, states, a Washington, D.C., ...
had been exhausted. Taconite became valued as a new source of the metal.


Production

To process taconite, the ore is ground into a fine powder, the magnetite is separated from the gangue by strong magnets, and the powdered iron concentrate is combined with a binder such as bentonite clay and limestone as a
flux Flux describes any effect that appears to pass or travel (whether it actually moves or not) through a surface or substance. Flux is a concept in applied mathematics and vector calculus which has many applications to physics. For transport ...
. As a last step, it is rolled into pellets about 10 millimeters in diameter that contain about 65% iron. The pellets are fired at a very high temperature to harden them and make them durable. This is to ensure that the
blast furnace A blast furnace is a type of metallurgical furnace used for smelting to produce industrial metals, generally pig iron, but also others such as lead or copper. ''Blast'' refers to the combustion air being "forced" or supplied above atmospheri ...
charge remains porous enough to allow heated gas to pass through and react with the pelletized ore. Firing the pellet
oxidize Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or ...
s the magnetite (Fe3O4) to
hematite Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
(Fe2O3), an
exothermic In thermodynamics, an exothermic process () is a thermodynamic process or reaction that releases energy from the system to its surroundings, usually in the form of heat, but also in a form of light (e.g. a spark, flame, or flash), electricity ...
reaction that reduces the cost of pelletizing the concentrate. E. W. Davis of the
University of Minnesota The University of Minnesota, formally the University of Minnesota, Twin Cities, (UMN Twin Cities, the U of M, or Minnesota) is a public land-grant research university in the Twin Cities of Minneapolis and Saint Paul, Minnesota, United States. ...
Mines Experiment Station is credited with developing the pelletizing process. Since the commercial development of this process in the
Lake Superior Lake Superior in central North America is the largest freshwater lake in the world by surface areaThe Caspian Sea is the largest lake, but is saline, not freshwater. and the third-largest by volume, holding 10% of the world's surface fresh wa ...
region in the 1950s, the term "taconite" has been used globally to refer to iron ores amenable to upgrading by similar processes. Major producers of iron ore pellets from taconite in North America include Iron Ore Company of Canada, Cliffs Natural Resources, Inc., U.S. Steel, and
ArcelorMittal ArcelorMittal S.A. is a Luxembourgian multinational steel manufacturing corporation headquartered in Luxembourg City. It was formed in 2006 from the takeover and merger of Arcelor by Indian-owned Mittal Steel. ArcelorMittal is the second ...
. These processed taconite-ore pellets are also referred to as "taconite". Because this is the form that is typically transported by rail and ship, and cargo of these is often discussed, this usage of the term is very common."Taconite"
Department of Natural Resources
The
Mesabi Iron Range The Mesabi Iron Range is a mining district in northeastern Minnesota following an elongate trend containing large deposits of iron ore. It is the largest of four major iron ranges in the region collectively known as the Iron Range of Minnesot ...
region of the American state of Minnesota is a major production area. The taconite iron ore pellets are hauled by
railroad Rail transport (also known as train transport) is a means of transport that transfers passengers and goods on wheeled vehicles running on rails, which are incorporated in tracks. In contrast to road transport, where the vehicles run on a prep ...
to the ports of Silver Bay, Two Harbors and the Twin Ports of
Duluth, Minnesota , settlement_type = City , nicknames = Twin Ports (with Superior, Wisconsin, Superior), Zenith City , motto = , image_skyline = , image_caption = Clockwise from top: Downtown Dul ...
, and
Superior, Wisconsin , native_name_lang = oj , nickname = , total_type = , motto = , image_skyline = Tower Avenue.jpg , imagesize = , image_caption = Downtown Superior , ima ...
, all on
Lake Superior Lake Superior in central North America is the largest freshwater lake in the world by surface areaThe Caspian Sea is the largest lake, but is saline, not freshwater. and the third-largest by volume, holding 10% of the world's surface fresh wa ...
. The docks at Escanaba, Michigan, on Lake Michigan, also ship taconite from the Marquette iron range in Michigan, and occasionally ore from Minnesota is hauled by rail there.
Marquette, Michigan Marquette ( ) is a city in Marquette County in the U.S. state of Michigan. The population was 20,629 at the 2020 United States Census, which makes it the largest city in the Upper Peninsula. Marquette serves as the seat of government of Marque ...
, also has a taconite dock that loads bulk freighters with ore from the Marquette iron range. The ore is generally shipped by lake freighters to locations on the lower
Great Lakes The Great Lakes, also called the Great Lakes of North America, are a series of large interconnected freshwater lakes in the mid-east region of North America that connect to the Atlantic Ocean via the Saint Lawrence River. There are five lakes ...
. Many steelmaking centers are near
Lake Erie Lake Erie ( "eerie") is the fourth largest lake by surface area of the five Great Lakes in North America and the eleventh-largest globally. It is the southernmost, shallowest, and smallest by volume of the Great Lakes and therefore also ha ...
. Due to increased international demand, taconite is shipped to Mexico and China.
Future Work
The SS ''
Edmund Fitzgerald SS ''Edmund Fitzgerald'' was an American Great Lakes freighter that sank in Lake Superior during a storm on November 10, 1975, with the loss of the entire crew of 29 men. When launched on June 7, 1958, she was the largest ship on North America ...
,'' which sank in
Lake Superior Lake Superior in central North America is the largest freshwater lake in the world by surface areaThe Caspian Sea is the largest lake, but is saline, not freshwater. and the third-largest by volume, holding 10% of the world's surface fresh wa ...
on November 10, 1975, was carrying about 26,116 long tons of taconite pellets.


Taconite and human health

Beginning in 1955, Reserve Mining Company discharged crushed waste rock (tailings) from their Silver Bay, Minnesota processing plant into Lake Superior. The tailings contained 40% of the
amphibole Amphibole () is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is ...
group mineral series
cummingtonite Cummingtonite ( ) is a metamorphic amphibole with the chemical composition , magnesium iron silicate hydroxide. Monoclinic cummingtonite is compositionally similar and polymorphic with orthorhombic anthophyllite, which is a much more common fo ...
- grunerite, which may form asbestiform particles. A small fraction of the fine-grained tailings were shown to widely disperse along the western shore of Lake Superior, the source of drinking water for a number of cities; for example, tests of Duluth, Minnesota's water supply showed 100 billion fibers per liter of water. There was no epidemiological proof whether these particles caused cancer or were safe. On April 20, 1974, the U.S. District Court judge Miles Lord ruled that the drinking water and Lake Superior must be protected from the asbestos-like particles. The Reserve Mine was forced to begin disposing of tailing wastes on the land, and to implement air pollution control equipment, instead of discharging them directly to Lake Superior. This became one of the costliest pollution prevention cases in U.S. history. Government-funded studies have found no adverse health effects from drinking Lake Superior water. A 2003 study of taconite miners concluded that the most likely cause of 14 of the 17 cases of
mesothelioma Mesothelioma is a type of cancer that develops from the thin layer of tissue that covers many of the internal organs (known as the mesothelium). The most common area affected is the lining of the lungs and chest wall. Less commonly the lining ...
among miners on the iron range was contact with
asbestos Asbestos () is a naturally occurring fibrous silicate mineral. There are six types, all of which are composed of long and thin fibrous crystals, each fibre being composed of many microscopic "fibrils" that can be released into the atmosphere b ...
. Since that study was concluded, 35 more Iron Range miners have been diagnosed with the disease. Mesothelioma occurs at twice the expected rate among the population of the northeastern region of Minnesota, including the Iron Range. Spurred by the 2003 study, the Minnesota Department of Health (MDH) studied the relationship of fibrous minerals in taconite and taconite dust, and lung conditions similar to
asbestosis Asbestosis is long-term inflammation and scarring of the lungs due to asbestos fibers. Symptoms may include shortness of breath, cough, wheezing, and chest tightness. Complications may include lung cancer, mesothelioma, and pulmonary heart ...
, pleural mesothelioma and other
pleural The pleural cavity, pleural space, or interpleural space is the potential space between the pleurae of the pleural sac that surrounds each lung. A small amount of serous pleural fluid is maintained in the pleural cavity to enable lubrication b ...
conditions which occur following asbestos exposure. Because these conditions can be triggered by industrial asbestos, which was used in taconite mining and processing, as well as other industrial facilities in northeastern Minnesota, the study attempted to determine what, if any, influence naturally occurring fibrous minerals in taconite may have played. The lengthy epidemiological study of Minnesota iron miners concluded in December 2014 that those working 30 years in the iron mines and living to be 80 years old had a lifetime chance of having a mesothelioma of 3.33 cases per thousand such workers, more than double the background rate of 1.44 cases per thousand people living to 80 years old.


See also

* * {{annotated link, Banded iron formation


References


Further reading

* Davis, Edward W., ''Pioneering With Taconite''. St. Paul: Minnesota Historical Society Press, 1964. * Erie Mining Company History Project Team, ''Taconite, New Life for Minnesota's Iron Range: The History of Erie Mining Company''. Duluth: St. Louis County Historical Society, 2019. * Manuel, Jeffrey T., “Mr. Taconite: Edward W. Davis and the Promotion of Low-Grade Iron Ore, 1913–1955,” ''Technology and Culture,'' 54 (April 2013), 317–45. * Manuel, Jeffrey T., ''Taconite Dreams: The Struggle to Sustain Mining on Minnesota's Iron Range, 1915-2000''. Minneapolis: University of Minnesota Press, 2015.


External links


"Taconite"
Minnesota Department of Natural Resources

Geography

Silver Bay, Minnesota Official Website Economic geology Geology of Minnesota Iron(II,III) minerals Iron mining Mining in Minnesota Sedimentary rocks