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The TAS classification can be used to assign names to many common types of volcanic rocks based upon the relationships between the combined alkali content and the silica content. These chemical parameters are useful, because the relative proportions of alkalis and silica play an important role in determining actual mineralogy and normative mineralogy. The classification appears to be and can be simple to use for rocks that have been chemically analyzed. Except for the following quotation from Johannsen (1937), this entry is based upon Le Maitre and others (2002).


Use of the TAS classification

TAS stands for Total Alkali Silica. Before using the TAS or any other classification, however, the following words of Johannsen (1937) should be kept in mind. :''Many and peculiar are the classifications that have been proposed for igneous rocks. Their variability depends in part upon the purpose for which each was intended, and in part upon the difficulties arising from the characters of the rocks themselves. The trouble is not with the classifications but with nature which did not make things right. … Rocks must be classified in order to compare them with others, previously described, of similar composition and appearance. If this cannot be done on a genetic basis, then an artificial system must answer in order to serve as a card index to rock descriptions. Although this may be an evil thing, it is, at least, the least of several evils.'' The subtitle of the classification chapter by Johannsen (1937) is "Chacun a son goût" (to each his own taste). Furthermore, as discussed in considerable detail by Le Maitre and others (2002), the classification cannot be applied to all volcanic rocks. Certain rocks cannot be named using the diagram. For others, additional chemical, mineralogic, or textural criteria must be used, as for
lamprophyre Lamprophyres () are uncommon, small-volume ultrapotassic igneous rocks primarily occurring as dikes, lopoliths, laccoliths, stocks, and small intrusions. They are alkaline silica- undersaturated mafic or ultramafic rocks with high magnesium ...
s. The TAS classification should be applied only to rocks for which the mineral mode cannot be determined (otherwise, use a scheme based on mineralogy, such as the
QAPF diagram A QAPF diagram is a double ternary diagram which is used to classify igneous rocks based on mineralogic composition. The acronym QAPF stands for " Quartz, Alkali feldspar, Plagioclase, Feldspathoid (Foid)". These are the mineral groups us ...
or one of the other diagrams presented in the entry for
igneous rock Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rock is formed through the cooling and solidification of magma o ...
s). Before classifying rocks using the TAS diagram, the chemical analyses must be recalculated to 100% excluding water and carbon dioxide.


The TAS diagram

The names provided by Le Maitre et al. (2002) for fields in the TAS diagram are listed below. B (
Basalt Basalt (; ) is an aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the surface of a rocky planet or moon. More than 90 ...
) (Use normative mineralogy to subdivide) O1 (
Basaltic andesite Basaltic andesite is a volcanic rock that is intermediate in composition between basalt and andesite. It is composed predominantly of augite and plagioclase. Basaltic andesite can be found in volcanoes around the world, including in Central Am ...
) O2 (
Andesite Andesite () is a volcanic rock of intermediate composition. In a general sense, it is the intermediate type between silica-poor basalt and silica-rich rhyolite. It is fine-grained (aphanitic) to porphyritic in texture, and is composed predo ...
) O3 (
Dacite Dacite () is a volcanic rock formed by rapid solidification of lava that is high in silica and low in alkali metal oxides. It has a fine-grained ( aphanitic) to porphyritic texture and is intermediate in composition between andesite and rhyo ...
) R (
Rhyolite Rhyolite ( ) is the most silica-rich of volcanic rocks. It is generally glassy or fine-grained (aphanitic) in texture, but may be porphyritic, containing larger mineral crystals ( phenocrysts) in an otherwise fine-grained groundmass. The miner ...
) T (
Trachyte Trachyte () is an extrusive igneous rock composed mostly of alkali feldspar. It is usually light-colored and aphanitic (fine-grained), with minor amounts of mafic minerals, and is formed by the rapid cooling of lava enriched with silica and al ...
or Trachydacite) (Use normative mineralogy to decide) Ph (
Phonolite Phonolite is an uncommon extrusive rock, of intermediate chemical composition between felsic and mafic, with texture ranging from aphanitic (fine-grained) to porphyritic (mixed fine- and coarse-grained). Phonolite is a variation of the igneous ...
) S1 ( Trachybasalt) *Sodic and potassic variants are
Hawaiite Hawaiite is an olivine basalt with a composition between alkali basalt and mugearite. It was first used as a name for some lavas found on the island of Hawaii. It occurs during the later stages of volcanic activity on oceanic islands such as Ha ...
and Potassic Trachybasalt S2 (Basaltic trachyandesite) *Sodic and potassic variants are
Mugearite Mugearite () is a type of oligoclase-bearing basalt, comprising olivine, apatite, and opaque oxides. The main feldspar in mugearite is oligoclase. Mugearite is a sodium-rich member of the alkaline magma series. In the TAS classification of volc ...
and Shoshonite S3 (
Trachyandesite Trachyandesite is an extrusive igneous rock with a composition between trachyte and andesite. It has little or no free quartz, but is dominated by sodic plagioclase and alkali feldspar. It is formed from the cooling of lava enriched i ...
*Sodic and potassic variants are
Benmoreite Benmoreite is a silica-undersaturated volcanic rock of intermediate composition. It is a sodium-rich variety of trachyandesite and belongs to the alkalic suite of igneous rocks. Nepheline benmoreite An origin by fractionation from basanite thr ...
and Latite Pc ( Picrobasalt) U1 (
Basanite Basanite () is an igneous, volcanic ( extrusive) rock with aphanitic to porphyritic texture. It is composed mostly of feldspathoids, pyroxenes, olivine, and plagioclase and forms from magma low in silica and enriched in alkali metal oxides tha ...
or Tephrite) (Use normative mineralogy to decide) U2 ( Phonotephrite) U3 ( Tephriphonolite) F ( Foidite) (Name according to dominant
feldspathoid The feldspathoids are a group of tectosilicate minerals which resemble feldspars but have a different structure and much lower silica content. They occur in rare and unusual types of igneous rocks, and are usually not found in rocks containing ...
when possible. Melilitites also plot in this area and can be distinguished by additional chemical criteria.) *Sodic as used above means that Na2O - 2 is greater than K2O, and potassic that Na2O - 2 is less than K2O. Yet other names have been applied to rocks particularly rich in either sodium or potassium (as are ultrapotassic igneous rocks).


References

*Albert Johannsen, A Descriptive Petrography of the Igneous Rocks. Volume 1, Introduction, Textures, Classifications, and Glossary. The University of Chicago Press, Chicago, Illinois, 1937. *R. W. Le Maitre (editor), A. Streckeisen, B. Zanettin, M. J. Le Bas, B. Bonin, P. Bateman, G. Bellieni, A. Dudek, S. Efremova, J. Keller, J. Lamere, P. A. Sabine, R. Schmid, H. Sorensen, and A. R. Woolley, Igneous Rocks: A Classification and Glossary of Terms, Recommendations of the International Union of Geological Sciences, Subcommission of the Systematics of Igneous Rocks. Cambridge University Press, 2002. {{DEFAULTSORT:Tas Classification Igneous petrology Igneous rocks