Triazene is an
unsaturated inorganic compound
In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemist ...
having the chemical formula
N3 H3. It has one
double bond
In chemistry, a double bond is a covalent bond between two atoms involving four bonding electrons as opposed to two in a single bond. Double bonds occur most commonly between two carbon atoms, for example in alkenes. Many double bonds exist betw ...
and is the second-simplest member of the azene class of hydronitrogen compounds, after
diimide
Diimide, also called diazene or diimine, is a compound having the formula (NH)2. It exists as two geometric isomers, ''E'' (''trans'') and ''Z'' (''cis''). The term diazene is more common for organic derivatives of diimide. Thus, azobenzene is ...
.
Triazenes
Triazenes are organic compounds that contain the functional group −N(R)−N=N− (where R is H, alkyl, aryl). Some anti-cancer medications and dyes are triazenes. Formally, triazenes are related to the unstable triazene, H2N−N=NH. The relat ...
are a class of organic compounds containing the
functional group
In organic chemistry, a functional group is a substituent or moiety in a molecule that causes the molecule's characteristic chemical reactions. The same functional group will undergo the same or similar chemical reactions regardless of the rest ...
-N(H)-N=N-. Triazene, possibly along with its
isomer
In chemistry, isomers are molecules or polyatomic ions with identical molecular formulae – that is, same number of atoms of each element – but distinct arrangements of atoms in space. Isomerism is existence or possibility of isomers.
Iso ...
triimide (HNNHNH), has been synthesized in electron-irradiated ices of
ammonia
Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous was ...
and ammonia/
dinitrogen and detected in the gas phase after
sublimation.
[Forstel, Tsegaw, Maksyutenko, Mebel, Sander, & Kaiser. "On the formation of N3H3 isomers in irradiated ammonia bearing ices: Triazene (H2NNNH) or Triimide (HNHNNH)", ''ChemPhysChem'', 2016, 17, 2726.]
References
External links
*
IUPAC
The International Union of Pure and Applied Chemistry (IUPAC ) is an international federation of National Adhering Organizations working for the advancement of the chemical sciences, especially by developing nomenclature and terminology. It is ...
Gold Book
The International Union of Pure and Applied Chemistry publishes many books which contain its complete list of definitions. The definitions are divided into seven "colour books": Gold, Green, Blue, Purple, Orange, White, and Red. There is also an e ...
br>
definition
{{Hydrides by group
Nitrogen hydrides