Tolyltriazole
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Tolyltriazole is a mixture of
isomer In chemistry, isomers are molecules or polyatomic ions with identical molecular formulae – that is, same number of atoms of each element – but distinct arrangements of atoms in space. Isomerism is existence or possibility of isomers. Iso ...
s or congeners that differ from
benzotriazole Benzotriazole (BTA) is a heterocyclic compound with the chemical formula C6H5N3. Its five-membered ring contains three consecutive nitrogen atoms. This bicyclic compound may be viewed as fused rings of the aromatic compounds benzene and triazole. ...
by the addition of one methyl group attached somewhere on the benzene ring. "The term tolyltriazole (CAS 29385-43-1) generally efers tothe commercial mixture composed of approximately equal amounts of 4- and 5-methylbenzotriazole, with small quantities of heir_respective_7-_and_6-methyl_ heir_respective_7-_and_6-methyl_tautomers">tautomer.html"_;"title="heir_respective_7-_and_6-methyl_tautomer">heir_respective_7-_and_6-methyl_tautomers.Benzotriazole_and_Tolyltriazole:_Evaluation_of_health_hazards_and_proposal_of_health-based_quality_criteria_for_soil_and_drinking_water
_Environmental_Project_No._1526,_2006,_2013,_The_Danish_Environmental_Protection_Agency,_ISBN_9_7_8-87-93026-81-0


_Structure


_Synthesis_and_reactions

Synthesis_is_much_like_that_of_benzotriazole_ Benzotriazole_(BTA)_is_a_heterocyclic_compound_with_the_chemical_formula_C6H5N3._Its_five-membered_ring_contains_three_consecutive_nitrogen_atoms._This_bicyclic_compound_may_be_viewed_as_fused_rings_of_the_aromatic_compounds_benzene_and_triazole.__...
,_but_starting_with_methyl-''o''-phenylenediamine_instead_of_o-Phenylenediamine.html" ;"title="tautomers.html" ;"title="tautomer.html" ;"title="heir respective 7- and 6-methyl tautomer">heir respective 7- and 6-methyl tautomers">tautomer.html" ;"title="heir respective 7- and 6-methyl tautomer">heir respective 7- and 6-methyl tautomers.Benzotriazole and Tolyltriazole: Evaluation of health hazards and proposal of health-based quality criteria for soil and drinking water
Environmental Project No. 1526, 2006, 2013, The Danish Environmental Protection Agency, ISBN 9 7 8-87-93026-81-0


Structure


Synthesis and reactions

Synthesis is much like that of
benzotriazole Benzotriazole (BTA) is a heterocyclic compound with the chemical formula C6H5N3. Its five-membered ring contains three consecutive nitrogen atoms. This bicyclic compound may be viewed as fused rings of the aromatic compounds benzene and triazole. ...
, but starting with methyl-''o''-phenylenediamine instead of o-Phenylenediamine">''o''-phenylenediamine. Isomers of methyl-''o''-phenylenediamine include 3-methyl-''o''-phenylenediamine, 4-methyl-''o''-phenylenediamine, and N-methyl-''o''-phenylenediamine (not involved here).


Applications

Tolyltriazole has uses similar to benzotriazole, but has better solubility in some organic solvents.


Corrosion inhibitor


Environmental relevance


Related compounds


References

Benzotriazoles Chelating agents Conservation and restoration materials Corrosion inhibitors {{Organic-compound-stub