Tokyoite is a rare

barium Barium is a chemical element with the symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element. Th ...

manganese Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy use ...

vanadate In chemistry, a vanadate is an anionic coordination complex of vanadium. Often vanadate refers to oxoanions of vanadium, most of which exist in its highest oxidation state of +5. The complexes and are referred to as hexacyanovanadate(III) and no ...

mineral with the

chemical formula In chemistry, a chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, ...

: Ba₂(Mn³⁺,Fe³⁺)OH(VO₄)₂. It is the manganese analogue of the iron rich gamagarite and the barium analogue of the lead vanadate, brackebuschite. It occurs in low-grade

metamorphosed Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock (protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, causin ...

sedimentary manganese

ore deposit Ore is natural rock or sediment that contains one or more valuable minerals, typically containing metals, that can be mined, treated and sold at a profit.Encyclopædia Britannica. "Ore". Encyclopædia Britannica Online. Retrieved 7 April 2 ...

s associated with

hyalophane Hyalophane or jaloallofane is a crystalline mineral, part of the feldspar group of tectosilicates. It is considered a barium-rich potassium feldspar. Its chemical formula is , and it has a hardness of 6 to . The name ''hyalophane'' comes from the ...

braunite Braunite is a silicate mineral containing both di- and tri- valent manganese with the chemical formula: Mn2+Mn3+6 SiO4 Common impurities include iron, calcium, boron, barium, titanium, aluminium, and magnesium. Braunite forms grey/black tetragon ...

and tamaite. It was first reported for an occurrence in the Shiromaru Mine, Okutama, Tama district,

Tokyo Prefecture Tokyo (; ja, 東京, , ), officially the Tokyo Metropolis ( ja, 東京都, label=none, ), is the capital and List of cities in Japan, largest city of Japan. Formerly known as Edo, its metropolitan area () is the most populous in the world, ...

Kantō region The is a geographical area of Honshu, the largest island of Japan. In a common definition, the region includes the Greater Tokyo Area and encompasses seven prefectures: Gunma, Tochigi, Ibaraki, Saitama, Tokyo, Chiba and Kanagawa. Slight ...

Honshu Island , historically called , is the largest and most populous island of Japan. It is located south of Hokkaidō across the Tsugaru Strait, north of Shikoku across the Inland Sea, and northeast of Kyūshū across the Kanmon Straits. The island sep ...

Japan Japan ( ja, 日本, or , and formally , ''Nihonkoku'') is an island country in East Asia. It is situated in the northwest Pacific Ocean, and is bordered on the west by the Sea of Japan, while extending from the Sea of Okhotsk in the north ...

and approved by the IMA in 2003. It has been found in two mines in

Italy Italy ( it, Italia ), officially the Italian Republic, ) or the Republic of Italy, is a country in Southern Europe. It is located in the middle of the Mediterranean Sea, and its territory largely coincides with the homonymous geographical re ...

and one in

, for which it was named.

References

Vanadate minerals Monoclinic minerals {{oxide-mineral-stub