Tlapallite is a rare and complex

tellurate In chemistry tellurate is a compound containing an oxyanion of tellurium where tellurium has an oxidation number of +6. In the naming of inorganic compounds it is a suffix that indicates a polyatomic anion with a central tellurium atom.

mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...

with the chemical formula . It has a Moh's hardness of 3 and it is green in colour. It was named after the

Nahua The Nahuas () are a group of the indigenous people of Mexico, El Salvador, Guatemala, Honduras, and Nicaragua. They comprise the largest indigenous group in Mexico and second largest in El Salvador. The Mexica (Aztecs) were of Nahua ethnicity, a ...

word "Tlalpalli", which translates to paint, referring to the paint-like habit of the mineral. Its formula and crystal structure were redefined in 2019, showing it contained a mixed-valence phyllotellurate layer .

Occurrence

It was discovered in 1972 the Bambollita mine (La Oriental), Moctezuma, Municipio de Moctezuma,

Sonora Sonora (), officially Estado Libre y Soberano de Sonora ( en, Free and Sovereign State of Sonora), is one of the 31 states which, along with Mexico City, comprise the Administrative divisions of Mexico, Federal Entities of Mexico. The state is d ...

Mexico Mexico (Spanish: México), officially the United Mexican States, is a country in the southern portion of North America. It is bordered to the north by the United States; to the south and west by the Pacific Ocean; to the southeast by Guatema ...

, a mine known for its tellurium deposits, and it was approved by the IMA in 1977. Here, it is found as thin paint-like crusts on rock fractures and next to thin veins running through

rhyolite Rhyolite ( ) is the most silica-rich of volcanic rocks. It is generally glassy or fine-grained (aphanitic) in texture, but may be porphyritic, containing larger mineral crystals (phenocrysts) in an otherwise fine-grained groundmass. The mineral ...

. It is often found as a thin film on

quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...

sericite Sericite is the name given to very fine, ragged grains and aggregates of white (colourless) micas, typically made of muscovite, illite, or paragonite. Sericite is produced by the alteration of orthoclase or plagioclase feldspars in areas that hav ...

calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...

baryte Baryte, barite or barytes ( or ) is a mineral consisting of barium sulfate ( Ba S O4). Baryte is generally white or colorless, and is the main source of the element barium. The ''baryte group'' consists of baryte, celestine (strontium sulfate), ...

, but it also forms botryoidal aggregates. It is often found alone, but may be associated with other minerals, especially

carlfriesite Carlfriesite is a rare tellurium mineral with the formula Ca Te4+2 Te6+ O8, or more simplified: CaTe3O8. It has a Moh's hardness of 3.5 and it occurs in various shades of yellow, ranging from bright yellow to a light buttery color. It was named ...

. It has also been found in the emerald mine in Tombstone District,

Cochise County Cochise County () is a county in the southeastern corner of the U.S. state of Arizona. It is named after the Native American chief Cochise. The population was 125,447 at the 2020 census. The county seat is Bisbee and the most populous city is ...

, Arizona in the

United States The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country primarily located in North America. It consists of 50 states, a federal district, five major unincorporated territorie ...

. The habit of the mineral suggests it precipitates from rapidly drying acid solutions. It seems to form in the transitory phase when other

tellurium Tellurium is a chemical element with the symbol Te and atomic number 52. It is a brittle, mildly toxic, rare, silver-white metalloid. Tellurium is chemically related to selenium and sulfur, all three of which are chalcogens. It is occasionally fou ...

minerals, like

tlalocite Tlalocite is a rare and complex tellurate mineral with the formula Cu10 Zn6( Te O4)2( Te O3)( O H)25 Cl · 27 H2O. It has a Mohs hardness of 1, and a cyan color. It was named after Tlaloc, the Aztec god of rain, in allusion to the high amount of ...

, cesbronite,

xocomecatlite Xocomecatlite is a rare tellurate mineral with formula: Cu3(TeO4)(OH)4. It is an orthorhombic mineral which occurs as aggregates or spherules of green needlelike crystals. It was first described in 1975 for an occurrence in the Oriental mine near ...

quetzalcoatlite Quetzalcoatlite is a rare tellurium oxysalt mineral with the formula Zn6Cu3(TeO6)2(OH)6 · AgxPbyClx+2y. It also contains large amounts of silver- and lead(II)chloride with the formula Agx Pby Clx+2y (x+y≤2). It has a Mohs hardness of 3 and it ...

teineite Teineite is a tellurite mineral with the formula Cu( Te O3) . 2 H2O. It has a Mohs hardness of 2.5 and it comes in many different shades of blue, ranging from cerulean blue to bluish-gray. The mineral millsite has the same chemical composition, ...

and

, start to break down.

References

Copper(II) minerals Sulfate minerals Lead minerals Tellurate mineral Zinc minerals Calcium minerals Tellurite and selenite minerals {{Sulfate-mineral-stub

Occurrence

See also

References